UNIMARK OIL LLC -- GARD ANTI RUST SAE 15W-40, (PRESERVATION BREA
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Material Safety Data Sheet
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NIIN: 01-359-8567
MSDS Num: CLFBQ
MSDS NAME: GARD ANTI RUST SAE 15W-40, (PRESERVATION BREAK-IN OIL)
Responsible Party
Name: UNIMARK OIL CO LLC
Address: 2727 ROE LANE
City: KANSAS CITY KS 66103-1543
Info Phone: 913-236-5000 FAX/913-432-8309
Emergency Phone Number: 913-236-5000
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Item Description Information
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Item Manager: S9G
Item Name: LUBRICATING OIL,ENGINE
Specification Number: MIL-L-21260
Type/Grade/Class: 15W-40 GRADE
Unit of Issue: GL
UI Container Qty: 1
Type of Container: BULK
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ORAL TOXICITY NOT DETERMINED.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: MILD EYE IRRITATION WITH DISCOMFORT, TEARING, OR
BLURRING OF VISION. SKIN: SKIN IRRITATION. PROLONGED OR REPEATED CONTACT;
DERMATITIS (DRYNESS, CHAPPING, REDDENING OF SKIN). INHALATION: OVEREXPOS URE
OF HOT MATERIAL CAUSE NONSPECIFIC DISCOMFORT, NAUSEA, HEADACHE, OR WEAKNESS.
CAUTION TO PREVENT AEROSOLIZATION OR MISTING W/O PROPER RESPIRATORY
PROTECTION. INGESTION: DO NOT INGEST. EXPECTED CONC ENTRATION OIL (70-100%)
INGESTION NON-TOXIC UNLESS LUNG ASPIRATION OCCURS. MAY LEAD TO CHEMICAL
PNEUMONITIS, PULMONARY EDEMA, HEMORRHAGE, AND MAY BE FATAL. GASTROINTESTINAL
DISCOMFORT, ASPIRATION, VOM ITING, ABDOMINAL CRAMPS, DIARRHEA.
Explanation Of Carcinogenicity: PER MSDS: CARCINOGENICTY: NOT DETERMINED.
Signs And Symptions Of Overexposure: EYE: MILD EYE IRRITATION WITH DISCOMFORT,
TEARING, OR BLURRING OF VISION. SKIN: SKIN IRRITATION. PROLONGED OR REPEATED
CONTACT; DERMATITIS (DRYNESS, CHAPPING, REDDENING OF SKIN). INHALATION:
OVEREXPOS URE OF HOT MATERIAL CAUSE NONSPECIFIC DISCOMFORT, NAUSEA, HEADACHE,
OR WEAKNESS. CAUTION TO PREVENT AEROSOLIZATION OR MISTING W/O PROPER
RESPIRATORY PROTECTION. INGESTION: DO NOT INGEST. EXPECTED CONC ENTRATION OIL
(70-100%) INGESTION NON-TOXIC UNLESS LUNG ASPIRATION OCCURS. MAY LEAD TO
CHEMICAL PNEUMONITIS, PULMONARY EDEMA, HEMORRHAGE, AND MAY BE FATAL.
GASTROINTESTINAL DISCOMFORT, ASPIRATION, VOM ITING, ABDOMINAL CRAMPS,
DIARRHEA.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER, CONTINUE
FLUSHING UNTIL IRRITATION SUBSIDES. IF IRRITATION PERSISTS, CALL PHYSICIAN.
IF MATERIAL IS HOT, TREAT FOR THERMAL BURNS, TAKE VICTIM TO HO SPITAL
IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA THOROUGHLY WITH
SOAP AND WATER. IF REDNESS/IRRITATION OCCUR GET MEDICAL HELP. IF MATERIAL IS
HOT, SUBMERGE INJURED AREA IN COLD WATER. IF SEVERELY BURNED, TAKE TO
HOSPITAL IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: IF
OVERCOME BY INHALATION OF HOT VAPORS, REMOVE TO FRESH AIR. USE OXYGEN IF
BREATHING IS DIFFICU LT OR ARTIFICIAL (SEE OTHER INFORMATION)
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Handling and Disposal
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Spill Release Procedures: IMMEDIATELY TURN OFF/ISOLATE ANY IGNITION SOURCE.
EVACUATE AREA & VENTILATE. PERSONNEL WEARING PROPER PROTECTIVE EQUIPMENT
SHOULD CONTAIN SPILL IMMEDIATELY WITH INERT MATERIAL (SAND, EARTH, CHEMICAL S
PILL PADS OF COTTON) BY FORMING DIKE. DIKES SHOULD BE PLACED TO CONTAIN SPILL
IN MANNER THAT WILL PREVENT MATERIAL FROM ENTERING SEWERS AND WATERWAYS.
(SEE SUPPLEMENTARY DATA).
Neutralizing Agent: CAUTION - IF SPILLED MATERIAL CLEANED UP USING REGULATED
SOLVENT, THE RESULTING WASTE MIXTURE MAY BE REGULATED.
Waste Disposal Methods: ALL DISPOSALS MUST COMPLY WITH FEDERAL, STATE, AND
LOCAL REGULATIONS. THE MATERIAL, IF SPILLED OR DISCARDED, MAY BE A REGULATED
WASTE. REFER TO STATE AND LOCAL REGULATIONS. DEPARTMENT OF TRANSPORTATIO N
REGULATIONS MAY APPLY FOR TRANSPORTING THIS MATERIAL WHEN SPILLED.
Handling And Storage Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO
NOT TRANSFER TO UNMARKED CONTAINERS. FIRE EXTINGUISHERS SHOULD BE KEPT
READILY AVAILABLE. SEE NFPA 30 AND OSHA 1910.106 - FLAMMABLE AND COMBUSTIBLE
LIQUIDS.
Other Precautions: EMPTY CONTAINERS RETAIN PRODUCT RESIDUE WHICH MAY EXHIBIT
HAZARDS OF MATERIAL, THEREFORE DO NOT PRESSURIZE, CUT, GLAZE, WELD, OR USE
FOR ANY OTHER PURPOSES. RETURN DRUMS TO RECLAMATION CENTERS FOR PRO PER
CLEANING AND REUSE. STORE CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAME, OR
OXIDIZING MATERIALS.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =220.C, 428.F
Autoignition Temp Text: N/D
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: USE DRY CHEMICAL, FOAM, WATER FOG OR CARBON DIOXIDE.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE-CAN BE USED TO COOL
CONTAINERS EXPOSED TO HEAT/FLAME. CAUTION SHOULD BE EXERCISED WHEN USING
WATER OR FOAM AS FROTHING MAY OCCUR ESPECIALLY IF SPRAYED INTO HOT, BURNING
LIQUI D.
Unusual Fire/Explosion Hazard: DENSE SMOKE MAY BE GENERATED WHILE BURNING.
TOXIC FUMES, GAS, VAPORS MAY EVOLVE ON BURNING. HEAVY FLAMMABLE VAPORS MAY
SETTLE ALONG GROUND LEVEL AND LOW SPOTS TO CREATE INVISIBLE FIRE HAZARD. THE
VAPO RS MAY EXTEND TO SOURCES OF IGNITION AND FLASH BACK. CARE SHOULD ALWAYS
BE EXERCISED IN DUST/MIST AREAS.
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Control Measures
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Respiratory Protection: NONE REQUIRED IF AIRBORNE CONCENTRATIONS ARE MAINTAINED
BELOW THRESHOLD LIMITS. OTHERWISE RESPIRATORY PROTECTION PROGRAM METTING OSHA
1910.134/ANSI Z88.2 REQUIREMENTS MUST BE FOLLOW. WHERE MISTING MAY OCCUR
WEAR MSHA/NIOSH APPROVED (OR EQUIVALENT) HALF-MASK FORM DUST/MIST AIR
PURIFYING RESPIRATOR.
Ventilation: MECHANICAL METHODS (FUMEHOODS OR AREA FANS)TO REDUCE LOCALIZED
VAPOR/MIST AREA.
Protective Gloves: IMPERVIOUS GLOVE-NEOPRENE, NITRILE RUBBER
Eye Protection: SAFETY GLASSES WITH SIDESHIELD, VENTED/SPLASH PROOF GOGGLES.
Other Protective Equipment: APRON AND OVERBOOTS OF CHEMICALLY IMPERVIOUS
MATERIALS SUCH AS NEOPRENE OR NITRILE RUBBER IS RECOMMENDED TO AVOID SKIN
SENSITIZATION. IF HANDLING HOT MATERIAL USE INSULATED PROTECTIVE EQUIPMENT.
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE; PROPERLY
DISPOSE OF CONTAMINATED LEATHER ARTICLES AND OTHER MATERIALS WHICH CANNOT BE
DECONTAMINATED. CONSUMPTION OF FOOD AND DRINK SHOULD BE AVOIDED.
Supplemental Safety and Health: ACCIDENTAL RELEASE MEASURES CONTINUED: LARGE
SPILL, ONCE CONTAINED, MAY BE PICKED UP USING EXPLOSION PROOF, NON-SPARKING
VACUUM PUMPS, SHOVELS, OR BUCKETS, AND DISPOSED OF IN SUITABLE CONTAINERS FOR
DISPOSAL. IF A LARGE SPILL OCCURS NOTIFY APPROPRIATE AUTHORITIES.
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Physical/Chemical Properties
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HCC: V6
Boiling Point: >260.C, 500.F
B.P. Text: EXPECTED B/P
Melt/Freeze Pt: =-27.2C, -17.F
M.P/F.P Text: ASTM D 97.
Vapor Pres: NEGLIGIBLE @ STP
Vapor Density: >1@STP
Spec Gravity: 0.89@15.6C(60F)
VOC Pounds/Gallon: 7.42
Viscosity: 14.20 CST AT 100C(212F)
Evaporation Rate & Reference: NEGLIGIBLE AT STP.
Solubility in Water: NEGLIGIBLE
Appearance and Odor: MILD PETROLEUM HYDROCARBON ODOR, DARK BROWN, CLEAR FLUID
Percent Volatiles by Volume: NEGLIG
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID HIGH TEMPERATURES AND PRODUCT
CONTAMINATION.
Materials To Avoid: AVOID CONTACT WITH ACIDS AND OXIDIZING MATERIALS.
Hazardous Decomposition Products: OXIDES OF C, ZN, CA, P, S. HYDROGEN SULFIDE
AND ALKYL MERCAPATANS AND OTHER SULFIDES MAY BE RELEASED. SMOKE, CO, CO2,
OTHER ALDEHYDES OF INCOMPLETE COMBUSTION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: ON RARE OCCASIONS PROLONGED/REPEATED EXPOSURE TO OIL
MIST POSES RISK OF PULMONARY DISEASE SUCH AS CHRONIC LUNG INFLAMMATION.
CONDITION USUALLY ASYMPTOTIC AS RESULT OF REPEATED SMALL ASPIRATIONS. SHORT
NESS OF BREATH & COUGH MOST COMMON SYMPTOMS. PROLONGED REPEATED CONTACT
MAY MAKE SKIN MORE SENSITIVE. CHRONIC TOXICITY: NOT DETERMINED. PRODUCT
CONTAINS ZINC ALKYL DITHIOPHOSPHATES (ZDP). SEVERAL ZDP' S REPORTED TO HAVE
WEAK MUTAGENIC ACTIVITY IN CULTURED MAMMALIAN CELLS BUT ONLY AT HIGH
CONCENTRATIONS THAT WERE TOXIC TO TEST CELLS. THIS PRODUCT CONCENTRATION NOT
BELIEVED TO POSE RISK.
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Ecological Information
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Ecological: MATERIAL MAY BE TOXIC TO AQUATIC ORGANISMS & SHOULD BE KEPT OUT
OF SEWAGE & DRAINAGE & ALL BODIES OF WATER. NO DATA AVAILABLE ON
ENVIRONMENTAL FATE.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SECTION 302/304 EHS: NONE. SECTION 311/312: ACUTE
(IMMEDIATE HEALTH EFFECTS): YES. SECTION 313 TOXIC CHEMICALS: ZINC: <0.20%
Federal Regulatory Information: UNDER SECTION 311 OF CLEAN WATER ACT (40 CFR
110) & OIL POLLUTION CONTROL ACT OF 1990, MATERIAL IS CONSIDERED AN OIL.
ANY SPILLS/DISCHARGES PRODUCING VISIBLE SHEEN OR FILM MUST BE REPORTED.
CONTACT NA TIONAL RESPONSE CENTER AT 800-424-8802.
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Other Information
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Other Information: INHALATION CONTINUED: RESPIRATION IF BREATHING HAS STOPPED.
DO NOT LEAVE VICTIM UNATTENDED. SEEK IMMEDIATE MEDICAL ATTENTION IF
NECESSARY. DO NOT INDUCE VOMITING. DO NOT INDUCE VOMITING DUE TO ASPIRAT ION
HAZARD. IMMEDIATELY GIVE 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. IF VOMITING OCCURS LOWER HEAD BELOW KNEES TO AVOID
ASPIRATION. SEEK IMMEDIATE MEDICAL ATTENTION.
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Transportation Information
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Trans ID NO: 157451
MSDS NAME: GARD ANTI RUST SAE 15W-40, (PRESERVATION BREAK-IN OIL)
MSDS Prepared Date: 06/30/2000
Review Date: 06/13/2001
Multiple KIT Number: 0
Unit Of Issue: GL
Container QTY: 1
Type Of Container: BULK
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: GARD ANTI RUST SAE 15W-40, (PRESERVATION BREAK-IN OIL)
Company: UNIMARK OIL CO LLC
Street: 2727 ROE LANE
City: KANSAS CITY KS
Zipcode: 66103-1543
Health Emergency Phone: 913-236-5000
Label Required IND: Y
Date Of Label Review: 06/13/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. EYE: MILD EYE IRRITATION WITH
DISCOMFORT, TEARING, OR BLURRING OF VISION. SKIN: SKIN IRRITATION. PROLONGED
OR REPEATED CONTACT; DERMATITIS (DRYNESS, CHAPPING, REDDENING OF SKIN).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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