33M GENERAL OFFICES, MARINE TR -- MARINE ADHESIVE SEALANT FAST CURE 5200 WHITE,
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Material Safety Data Sheet
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MSDS Num: CLDZZ
MSDS NAME: MARINE ADHESIVE SEALANT FAST CURE 5200 WHITE, 05120, 05220
Responsible Party
Name: 33M GENERAL OFFICES, MARINE TRADE PROJECT
Address: 3M CENTER
City: SAINT PAUL MN 55144-1000
Info Phone: 800-364-3577;651-737-6501
Emergency Phone Number: 1-800-364-3577
Resp. Party Other MSDS No.: 06-3844-5
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: 3M MINNESOTA MINING AND MFG CO ADHESIVES SEALERS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 800-364-3577/651-737-6501(24 HOURS)
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: CONTAINS TOLUENE WHICH APPEARS ON THE NAVY OCCUPATIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS
CONCERNING SAFE HANDLING & EXPOSURE INFO (FP N).EYE CONTACT: MODERA TE
EYE IRRITATION: SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, PAIN, TEARING,
AND HAZY VISION. SKIN CONTACT: ALLERGIC SKIN REACTION: SIGNS/SYMPTOMS CAN
INCLUDE REDNESS, SWELLING, BLISTERING, AND ITC HING. MILD SKIN IRRITATION:
SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, AND ITCHING. INHALATION:
ALLERGIC RESPIRATORY REACTION: SIGNS/SYMPTOMS CAN INCLUDE DIFFICULTY
BREATHING, WHEEZING, TIGHTNESS O F CHEST, (SIGNS & SYMPTOMS)
Explanation Of Carcinogenicity: SILICA: IARC GROUP 1, VOLUME 60, PAGE 41, 1997.
NTP 9TH ANNUAL REPORT ON CARCINOGENS, KNOWN TO BE HUMAN CARCINOGENS LIST.
Signs And Symptions Of Overexposure: HEALTH HAZARDS (CONT'D): AND RESPIRATORY
FAILURE. IRRITATION (UPPER RESPIRATORY): SIGNS/ SYMPTOMS INCLUDE SORENESS OF
NOSE, THROAT, COUGHING & SNEEZING. VAPORS OF UNCURED PRODUCT MAY CAUSE
IRRITATION OF THE RESPIRATORY SYSTEM. INGESTION: MAY CAUSE IRRITATION OF
GASTROINTESTINAL TISSUES: SIGNS/SYMPTOMS CAN INCLUDE PAIN, VOMITING,
ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, AND BLOOD IN FECES.
First Aid: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER. GET
IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY WASH SKIN WITH SOAP
AND LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHIN G. IF SIGNS/SYMPTOMS
OCCUR, CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE AND DISPOSE
OF CONTAMINATED SHOES. INHALATION: REMOVE PERSON TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPI RATION. IF BREATHING IS DIFFICULT, GET
IMMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. DRINK TWO
GLASSES OF WATER. CALL A PHYSICIAN.
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Handling and Disposal
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Spill Release Procedures: CONTAIN SPILL. EVACUATE UNPROTECTED PERSONNEL FROM
HAZARD AREA. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8%
CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10
MINUTES. AL TERNATIVELY, POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN
30 MINUTES. COVER WITH ABSORBENT. PLACE IN AN APPROVED DRUM, BUT DO NOT SEAL
THE DRUM FOR 48 HOURS TO AVOID POSSIBLE (OTHER PREC)
Neutralizing Agent: ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8% CONC
AMMONIA, 2% DETERGENT).
Waste Disposal Methods: CURE PRODUCT ACCORDING TO PRODUCT INSTRUCTIONS.
INCINERATE IN AN INDUSTRIAL OR COMMERCIAL FACILITY IN THE PRESENCE OF A
COMBUSTIBLE MATERIAL. DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL
IN A SANITARY LANDFILL. DISPOSE OF WASTE PRODUCT IN A FACILITY PERMITTED TO
ACCEPT CHEMICAL WASTE. (OTHE R INFORMATION)
Handling And Storage Precautions: AVOID EYE & SKIN CONTACT. AVOID BREATHING
OF VAPOR. AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING. USE
IN WELL-VENTILATED AREA. IF EXHAUST VENTILATION NOT SUFFICIENT, USE
APPROPRIATE R ESPIRATORY PROTECTION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions: N/P. SPILL/RELEASE PROCEDURES (CONT'D): PRESSURE BUILDUP.
NEUTRALIZE SPILL RESIDUE WITH DECONTAMINANT SOLUTION. REFER TO OTHER SECTIONS
OF THIS MSDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZAR DS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =110.6C, 231.F
Flash Point Text: ASTM D93
Autoignition Temp Text: N/D
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET,
NIOSH APPROVED (FP N) SELF-CONTAINED POSITIVE PRESSURE OR PRESSURE DEMAND
BREATHING APPARATUS, BUNKER COAT AND PANTS, BANDS AROUND ARMS, WAIST AND LEG
S, FACE MASK AND PROTECTIVE COVERING FOR EXPOSED AREAS OF THE HEAD.
Unusual Fire/Explosion Hazard: NONE KNOWN. FIRE AND EXPLOSION AVOIDANCE: KEEP
CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER
SOURCES OF IGNITION. NFPA HAZARD CODES: HEALTH-1, FIRE-0, REACTIVITY-1, UNU
SUAL REACTION HAZARD: NONE.
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Control Measures
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Respiratory Protection: NIOSH APPROVED HALF-MASK DUST RESPIRATOR BASED ON
AIRBORNE CONCENTRATION OF CONTAMINANTS AND IN ACCORDANCE WITH OSHA
REGULATIONS. AVOID BREATHING VAPORS. AVOID BREATHING DUST CREATED BY CUTTING,
SANDI NG OR GRINDING.
Ventilation: SUFFICIENT VENTILATION TO MAINTAIN EMISSIONS BELOW RECOMMENDED
EXPOSURE LIMITS. IF EXHAUST VENTILATION IS NOT ADEQUATE, USE APPROPRIATE
RESPIRATORY PROTECTION.
Protective Gloves: GLOVES (POLYETHYLENE/ETHYLENE VINYL ALCOHOL, POLYVINYL
ALCOHOL, (OTHER PROT)
Eye Protection: ANSI APPROVED VENTED GOGGLES OR SAFETY GLASSES WITH SIDE
SHIELDS.
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). USE APRON AND/OR COVERALLS TO PREVENT SKIN CONTACT. GLOVES
(CONT'D): POLYTETRAFLUOROETHYLENE TEFLON,OR FLUOROELASTOMER (VITON).
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE AND DISPOSE OF
CONTAMINATED SHOES. DO NOT INGEST.
Supplemental Safety and Health: ID NUMBER/U.P.C.: 60-9800-2078-2,
00-51135-06520-4, 60-9800-2082-4, 00-51135-05220-4, 60-9800-2216-8,
0051135-06525-9, 60-9800-2626-8, 00-51135-05120-7, 60-9800-2652-4,
00-51135-06520-4, 60-9800-2653- 2, 00-51135-06531-0, 60-9800-2982-5,
00-51135-06519-8, 60-9800-3560-5, 00-51135-06520-4, (OTHER INFO).
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Physical/Chemical Properties
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M.P/F.P Text: N/D
Spec Gravity: 1.33 WATER=1
Viscosity: CA. 100000.0 CPS
Solubility in Water: NIL
Appearance and Odor: THIXOTROPIC PASTE, WHITE, VERY SLIGHT ODOR.
Percent Volatiles by Volume: < 2% BY WT.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE.
Materials To Avoid: AMINES, ALCOHOLS, WATER. REACTION WITH WATER, ALCOHOLS AND
AMINES IS NOT HAZARDOUS IF CONTAINER CAN VENT TO THE ATMOSPHERE TO PREVENT
PRESSURE BUILDUP.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE, OXIDES OF
NITROGEN, HYDROGEN CYANIDE, ISOCYANATES, TOXIC VAPORS, GASES OR PARTICULATES.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: WARNING: CONTAINS A CHEMICAL WHICH CAN CAUSE BIRTH
DEFECTS (108-88-3; TOLUENE). TOLUENE IS INDICATED AS POTENTIAL CONTRIBUTOR TO
THE OVERALL EXPOSURE BY THE CUTANEOUS ROUTE INCLUDING MUCOUS MEMBRANE A ND
EYE, EITHER BY AIRBORNE OR, MORE PARTICULARLY, BY DIRECT CONTACT WITH THE
SUBSTANCE. VEHICLES CAN ALTER SKIN ABSORPTION. EXPOSURE LIMITS: ZINC OXIDE:
ACGIH TWA 5 MG/M3 (AS FUME), OSHA TWA 5 MG/M3 ( AS FUME). SOURCE OF EXPOSURE
LIMIT DATA: ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS:
TITANIUM DIOXIDE, ZINC OXIDE, P,P"-METHYLENEBIS(PHENYL ISOCYANATE),HEPTANE,
ACETONE, CYCLOHE XANE, AND TOLUENE.
OSHA: (ECOLOGICAL)
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Ecological Information
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Ecological: ENVIRONMENTAL DATA: NOT DETERMINED. TOXICOLOGICAL (CONT'D):
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION: TITANIUM DIOXIDE, ZINC OXIDE,
P,P'-METHYLENEBIS (PHENYL ISOCYANATE), HEPTANE, ACETONECYCLOHEX ANE, AND
TOLUENE. NONE: NONE ESTABLISHED: URETHANE PREPOLYMER, SYNTHETIC AMORPPHOUS
SILICA, FUMED, CRYSTALLINE FREE, SILICA, ACRYLATE POLYMER - NEW JEERSEY TRADE
SECRET REGISTRY NO. 04499600-5575P, AN D ALUMINA TRIHYDRATE.
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MSDS Transport Information
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Transport Information: N/P.
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Regulatory Information
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Sara Title III Information: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND 40 CFR PAART
372: ZINC OXIDE, P,P'-METHYLENEBIS (PHENYL ISOCYANATE), CYCLOHEXANE, AND
TOLUENE.
Federal Regulatory Information: VOLATILE ORGANIC COMPOUNDS: 0.1 LB/GAL
CALCULATED PER SCAQMD RULE 443.1. VOLATILE ORGANIC COMPOUNDS: 13 GMS/LITER
CALCULATED PER SCAQMD RULE 443.1. VOC LESS H2O & EXEMPT SOLVENTS: 13
GMS/LITER CALCULA TED PER SCAQMD RULE 443.1. EPCRA HAZARD CLASS: FIRE HAZARD:
NO. PRESSURE: NO. REACTIVITY: NO. ACUTE: YES. CHRONIC: YES.
State Regulatory Information: N/P.
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Other Information
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Other Information: SUPERCEDES MSDS OF 9-11-97. SUPPLEMENTAL SAFETY (CONT'D):
60-9800-3295-1, 00-51135-06520-4. WASTE DISPOSAL (CONT'D): SINCE REGULATIONS
VARY, CONSULT APPLICABLE REGULATIONS OR AUTHORITIES BEFORE DISPO SAL. U.S.
EPA HAZARDOUS WASTE NUMBER = NONE (NOT U.S. EPA HAZARDOUS).
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HAZCOM Label
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MSDS NAME: MARINE ADHESIVE SEALANT FAST CURE 5200 WHITE, 05120, 05220
Company: 3M MINNESOTA MINING AND MFG CO ADHESIVES SEALERS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 1-800-364-3577
Label Required IND: Y
Date Of Label Review: 06/13/2001
Status Code: A
Origination Code: G
Hazard And Precautions: CONTAINS TOLUENE WHICH APPEARS ON THE NAVY OCCUPATIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS
CONCERNING SAFE HANDLING & EXPOSURE INFO (FP N).EYE CONTACT: MODERA TE
EYE IRRITATION: SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, PAIN, TEARING,
AND HAZY VISION. SKIN CONTACT: ALLERGIC SKIN REACTION: SIGNS/SYMPTOMS CAN
INCLUDE REDNESS, SWELLING, BLISTERING, AND ITC HING. MILD SKIN IRRITATION:
SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, AND ITCHING. INHALATION:
ALLERGIC RESPIRATORY REACTION: SIGNS/SYMPTOMS CAN INCLUDE DIFFICULTY
BREATHING, WHEEZING, TIGHTNESS O F CHEST, (SIGNS & SYMPTOMS)
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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