US OIL & REFINING CO -- AUTOMOTIVE GASOLINE, MIDGRADE UNLEADED GASOLI
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Material Safety Data Sheet
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MSDS Num: CLFGZ
MSDS NAME: AUTOMOTIVE GASOLINE, MIDGRADE UNLEADED GASOLINE
Responsible Party
Name: US OIL & REFINING CO
Address: 3001 MARSHALL AVE
City: TACOMA WA 98421
Info Phone: 206-383-1651
Emergency Phone Number: 253-383-1651
Resp. Party Other MSDS No.: 11311020
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Ingredients
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Cas: 8006-61-9
RTECS #: LX3300000
Name: GASOLINE IS A COMPLEX MIXTURE OF HYDROCARBONS PRODUCED BY PROCESSING
CRUDE OIL. IT CONTAINS PRIMARILY ALIPHATIC, OLEFINIC AND AROMATIC
HYDROCARBONS IN THE RANGE OF C4 - C10.
Percent by Wt: 100.
OSHA PEL: 300 PPM
OSHA STEL: 500 PPM
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE
% low Wt: 0.
% high Wt: 10.
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE
% low Wt: 0.
% high Wt: 10.
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE
% low Wt: 0.
% high Wt: 5.
OSHA PEL: 1 PPM
OSHA STEL: 5 PPM (15 MIN)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 95-63-6
RTECS #: DC3325000
Name: 1, 2, 4 - TRIMETHYLBENZENE
% low Wt: 0.
% high Wt: 5.
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Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYLBENZENE
% low Wt: 0.
% high Wt: 3.
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 110-54-3
RTECS #: MN9275000
Name: N-HEXANE
% low Wt: 0.
% high Wt: 3.
OSHA PEL: 50 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 110-82-7
RTECS #: GU6300000
Name: CYCLOHEXANE
% low Wt: 0.
% high Wt: 1.
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 91-20-3
RTECS #: OJ0525000
Name: NAPHTHALENE. (MANUFACTURER'S INVALID CAS NUMBER 71-20-3)
% low Wt: 0.
% high Wt: 1.
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: HEALTH STUDIES HAVE SHOWN THAT MANY PETROLEUM HYDROCARBONS
POSE POTENTIAL HEALTH RISKA WHICH MAY VARY FROM PERSON TO PERSON. AS A
PRECAUTION EXPOSURE TO LIQUIDS, VAPORS, MISTS OR FUMES SHOULD BE MINIM IZED.
HIGH VAPOR CONCENTRATIONS (GREATER THAN 1000 PPM) ARE IRRITATING TO EYES AND
THE RESPIRATORY TRACT, AND MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA,
DROWSINESS, UNCONSCIOUSNESS, AND OTHER CENTRA L NERVOUS SYSTEM EFFECTS,
INCLUDING DEATH. WARNING: CONCENTRATED, PROLONGED AND DELIBERATE INHALATION
OF THIS PRODUCT MAY CAUSE BRAIN OR NERVOUS SYSTEM DAMAGE. PROLONGED AND
REPEATED EXPOSURE OF PREG NANT (SIGNS & SYMPTOMS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: BENZENE: IARC GROUP 1, IARC MONOGRAPHS
SUPPLEMENT 7, PAGE 120, 1987; KNOWN CARCINOGEN, NTP 9TH ANNUAL REPORT ON
CARCINS, 1998; OSHA REGULATED, 29 CFR 1910.1028.
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE & CHRONIC (CONT):
ANIMALS TO HIGH LEVELS OF TOLUENE (>1500 PPM) HAS BEEN REPORTED TO CAUSE
FETA DEVELOPMENTAL EFFECTS. PROLONGED AND REPEATED SKINCONTACT WITH THIS
PRODUCT TENDS TO REMOVE SKIN OILS, POSSIBLY LEADING TO IRRITATION AND
DERMATITIS. PRODUCT CONTACTING THE EYES MAY CAUSE EYE IRRITATION. THIS
PRODUCT MAY CONTAIN UP TO 5 WEIGHT PERCENT BENZENE. BENZENE CAN CAUSE AN EMIA
AND OTHER BLOOD DISEASES, INCLUDING LEUKEMIA (CANCER OF THE BLOOD-FORMING
SYSTEM), AFTER PROLONGED AND REPEATED EXPOSURES AT HIGH CONCENTRATIONS
(50-500 PPM). IT HAS ALSO CAUSEDFETAL DEFECTS IN T ESTS ON LABORATORY.
(TOXICOLOGICAL INFO)
Medical Cond Aggravated By Exposure: BENZENE - INDIVIDUALS WITH LIVER DISEASE
MAY BE MORE SUSCEPTIBLE TO TOXIC EFFECTS. HEXANE - INDIVIDUALS WITH NEURALGIC
DISEASE SHOULD AVOID EXPOSURE. (OTHER INFORMATION)
First Aid: INHALATION: IMMEDIATELY REMOVE FROM CONTAMINATED AREA TO FRESH AIR.
FOR RESPIRATORY DISTRESS, GIVE OXYGEN OR ADMINISTER CPR (CARDIOPULMONARY
RESUSCITATION), IF NECESSARY. OBTAIN PROMPT MEDICAL ATTENTI ON. EYE CONTACT:
FLUSH WITH CLEAN LOW-PRESSURE WATER FOR AT LEAST 15 MINUTES. IF IRRITATION
PERSISTS, OBTAIN MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY REMOVE
CONTAMINATED CLOTHING. WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. IF
IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. WASH CLOTHING THOROUGHLY BEFORE
REUSE, BUT DISCARD CONTAMINATED LEATHER GOODS. INGESTION: DO NOT INDUCE
VOMITING, S INCE ASPIRATION INTO (OTHER INFORMATION)
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Handling and Disposal
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Spill Release Procedures: CONTAIN SPILL. REMOVE ALL IGNITION SOURCES &
SAFELY STOP FLOW OF SPILL. IN URBAN AREAS, CLEANUP ASAP; IN NATURAL
ENVIRONMENTS, SEEK ADVICE FROM ECOLOGISTS. EVACUATE ALL NON-ESSENTIAL
PERSONNEL. USE PR OPER PROTECTIVE EQUIPMENT. BLANKET WITH FOAM OR USE WATER
FOG TO DISPERSE VAPORS. PADS . ABSORBENT MATERIAL CAN BE USED. GASOLINE WILL
FLOAT ON WATER AND RESULTING RUNOFF MAY CREATE (TRANSPORT INFO)
Waste Disposal Methods: MAXIMIZE PRODUCT RECOVERY FOR REUSE PRIOR TO DISPOSAL.
DISPOSE OF PRODUCT, CONTAMINATED MATERIAL, AND STORAGE TANK WATER BOTTOMS AS
AN EPA "IGNITABLE HAZARDOUS WASTE" (D001), UNLESS PROVEN OTHERWISE. USE
APPROVED TREATMENT, TRANSPORTERS, AND DISPOSAL SITES IN COMPLIANCE WITH ALL
APPLICABLE LAWS. TAN K BOTTOMS AND TANK WATER BOTTOMS (TRANSPORT INFO)
Handling And Storage Precautions: STORE AND TRANSPORT IN ACCORDANCE WITH ALL
APPLICABLE LAWS. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME! KEEP CONTAINERS
CLOSED! GROUND ALL DRUMS AND TRANSFER VESSELS WHEN HANDLING. THE PRESENCE OF
LE AD COMPOUNDS IN GASOLINE REQUIRES USE OF SPECIAL PROCEDURES AND PROTECTIVE
(STATE REGULATORY)
Other Precautions: IMPORTANT: READ THIS MSDS BEFORE HANDLING OR DISPOSING OF
THIS PRODUCT. PASS THIS INFO ON TO EMPLOYEES, CUSTOMERS & PRODUCT USERS.
FOR USE ONLY AS MOTOR FUEL. DO NOT USE GASOLINE AS A CLEANING AGENT. SOME OF
THE INFO PRESENT & CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN
DIRECT TEST DATA ON THE MIXTURE ITSELF.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =-43.C, -45.4F
Flash Point Text: APPROX (D-56)
Lower Limits: 1.3% APPROX.
Upper Limits: 8.2% APPROX.
Extinguishing Media: DRY CHEMICAL, FOAM, CARBON DIOXIDE, HALON. WATER FOG OR
WATER SPRAY ARE OF VALUE FOR COOLING, BUT MAY NOT ACHIEVE EXTINGUISHMENT.
Fire Fighting Procedures: FOR FIRES INVOLVING THIS MATERIAL, DO NOT ENTER ANY
ENCLOSED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED - FP N). COOL TANKS AND
CONTAI NERS EXPOSED TO FIRE WITH WATER.
Unusual Fire/Explosion Hazard: EXTREMELY FLAMMABLE! THIS MATERIAL RELEASES
VAPORS AT OR BELOW AMBIENT TEMPURATURES. WHEN MIXED WITH AIR IN CERTAIN
PROPORTIONS AND EXPOSED TO AN IGNITION SOURCE, THESE VAPORS CAN BURN IN THE
OPEN OR EXPLODE IN CONFINED SPACES. BEING HEAVIER THAN AIR, FLAMMABLE VAPORS
MAY TRAVEL LONG DISTANCES (STATE REGULATORY)
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Control Measures
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Respiratory Protection: AN (NIOSH) APPROVED ORGANIC VAPOR RESPIRATOR, SUPPLIED
AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE USED WHEN VAPOR
CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE LIMITS.
Ventilation: USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF THIS
MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves: CLEAN AND IMPERVIOUS PROTECTIVE GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). EYE PROTECTION SHOULD BE WORN WHENEVER THERE IS A LIKLIHOOD
OF SPLASHING OR SPRAYING LIQUID. CONTACT LENSES SHOULD NOT BE WORN.
Work Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES. IN CASE OF SKIN
CONTACT, WASH WITH MILD SOAP & WATER OR A WATERLESS HAND CLEANER. IMMEDIATELY
REMOVE SOILED CLOTHING & WASH THOROUGHLY BEFORE REUSE. DISCARD SHOES.
Supplemental Safety and Health: AVOID PROLONGED OR REPEATED SKIN CONTACT. IF
CONDITIONS OR FREQUENCY OF USE PRESENT DANGER OF EXPOSURE, CLEAN AND
IMPERVIOUS CLOTHING SUCH AS GLOVES, APRON, BOOTS, AND FACIAL PROTECTION
SHOULD BE WORN . CONTAINS INGREDIENTS LISTED AS NAVY OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS (FP N).
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Physical/Chemical Properties
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Vapor Pres: 7-15 APPROX @ 100F
Spec Gravity: 0.72-0.83 APPROX @ 39.2
Evaporation Rate & Reference: SLOWER THAN BUTYL ACETATE
Solubility in Water: NEGLIGIBLE
Appearance and Odor: COLORLESS, PETROLEUM NAPHTHA ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS, AND OPEN FLAME.
Materials To Avoid: REACTS WITH STRONG ACIDS AND STRONG OXIDIZING MATERIALS.
Hazardous Decomposition Products: BURNING OR EXCESSIVE HEATING MAY PRODUCE
CARBON MONOXIDE AND OTHER HARMFUL GASES AND VAPORS INCLUDING OXIDES AND/OR
OTHER COMPOUNDS OF LEAD.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: N/P. SIGNS & SYMPTOMS OF OVEREXPOSURE
(CONT): CONTAINS LIGHT HYDROCARBON COMPONENTS. LIFETIME STUDIES BY THE
AMERICAN PETROLEUM INSTITUTE HAVE SHOWN THAT KIDNEY DAMAGE AND KIDNEY CANCER
CAN OCCUR IN MALE RATS AFTER PROLONGED EXPOSURE AT ELEVATED CONCENTRATIONS
OF TOTAL GASOLINE. KIDNEYS OF MICE AND FEMALE RATS WERE UNAFFECTED. THE US
EPA RISK ASSESSMENT FORUM HAS CONCLUDED THAT MALE RAT KIDNEY TUMOR RESULTS
ARE NOT RELEVANT FOR HUMANS. TOTAL GASOLINE EXPOSURE ALSO PRODUCED LIVER
TUMORS IN FEMALE MICE ONLY. THE IMPLICATION OF THESE DATA FOR HUMANS HAS NOT
BEEN DETERMINED. THE PRESENCE OF N -HEXANE IN THIS (ECOLOGICAL INFO)
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Ecological Information
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Ecological: N/P. TOXICOLOGICAL INFO (CONT): PRODUCT REPRESENTS A DISTINCT
HAZARD OF PRODUCINGPERIPHERAL POLYNEUROPATHY, A PROGRESSIVE DISORDER OF THE
NERVOUS SYSTEM, WHICH WITH SUFFICIENT HIGH EXPOSURE HAS TH E POTENTIAL OF
BECOMING IRREVERSIBLE. THIS DISORDER HAS BEEN OBSERVED IN INDIVIDUALS EXPOSED
REPEATEDLY TO HIGH VAPOR CONCENTRATIONS (1000 - 1500 PPM) OF N-HEXANE OVER A
PERIOD OF SEVERAL MONTHS. THE OSHA PERMISSIBLE EPOSURE LIMIT (TWA-PEL) IS 50
PPM FOR N-HEXANE. INHALATION OF COMPONENTS OF EXHAUST FROM BURNING, SUCH AS
CARBON MONOXIDE, MAY CAUSE DEATH AT HIGH CONCENTRATIONS. EXPOSURE TO EXHAUST
OF THIS FUEL SHOULD BE MINIMIZED.
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MSDS Transport Information
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Transport Information: DOT SHIPPING NAME: GASOLINE, 3, UN 1203, II.
SPILL / LEAK PROCEDURES (CONT): CREATE AN EXPLOSION OR FIRE HAZARD. NOTIFY
THE NATIONAL RESPONSE CENTER (800 / 424-8802) AND COMPLY WITH ALL LAWS. G
ASOLINE OR CONTAMINATED MATERIALS MAY BE HAZARDOUS TO HUMAN AND OTHER LIFE.
WASTE DISPOSAL METHOD (CONT): MAY BE HAZARDOUS TO HUMAN, ANIMAL AND
AQUATIC LIFE. IF SPILL IS INTRODUCED INTO WASTEWA TER SYSTEM, THE CHEMICAL
AND BIOLOGICAL OXYGEN DEMAND WILL LIKELY INCREASE. POTENTIAL TREATMENT AND
DISPOSAL METHODS INCLUDE LAND FARMING, INCINERATION AND LAND DISPOSAL, IF
PERMITTED.
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Regulatory Information
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Sara Title III Information: TOXIC CHEMICAL RELEASE REPORTING, (SARA SECTION
313): (COMPONENT, CAS NUMBER, PERCENT - TYPICAL): TOLUENE, 108-88-3, < 10.
XYLENE, 1330-20-7, < 10. BENZENE, 71-43-2, < 4.6. ETHYLBENZENE,
100-41-4, < 2. 1,2,4-TRIMETHYLBENZENE, 95-63-6, < 5. ETHYLBENZENE,
100-41-4, < 3. N-HEXANE, 110-54-3, < 1. CYCLOHEXANE, 110-82-7, <1.
NAPHTHALENE, 91-20-3, < 1. THRESHOLD PLANNING QUANTITY (TPQ), (S
ARA 301 - 304): NO TPQ FOR PRODUCT OR ANY CONSTITUENT GREATER THAN 1% OR 0.1%
(CARCINOGEN).
Federal Regulatory Information: REPORTABLE QUANTITY (RQ), EPA 40 CFR 302
(CERCLA SECTION 102). THE RQ FOR: BENZENE - 10 LBS. CUMENE - 5000 LBS.
CYCLOHEXANE - 1000 LBS. ETHYLBENZENE - 1000 LBS. NAPHTHALENE - 100 LBS.
N-HEXANE - 1 LB. TOLUENE - 1000 LBS. XYLENE - 1000 LBS. EPA HAZARD
CLASSIFICATION: ACUTE HEALTH HAZARD: X. CHRONIC HEALTH HAZARD: X. FIRE
HAZARD: X. PRESSURE HAZARD: N/P. REACTIVE HAZARD: N/P. NOT APPLICABLE:
N/P. PHYSICAL / CHEMICAL PROPERTIES (CONT): VAPOR SP. GR. (AIR = 1 @
60 - 90F): A P 3.5. DRY POINT: AP 430F. VOLATILE CHARACTERISTICS:
APPRECIABLE.
State Regulatory Information: N/P. HANDLING AND STORAGE PRECAUTIONS (CONT):
EQUIPMENT FOR TANK, VESSEL, OR OTHER ENCLOSED SPACE ENTRY. REFER TO AMERICAN
PETROLEUM INSTITUTE PUBLICATIONS RP 2015 AND 2015A FOR SPECIAL PRECAUTION S.
ALL ELECTRICAL EQUIPMENT IN GASOLINE STORAGE AND / OR HANDLING AREAS SHOULD
BE INSTALLED IN ACCORDANCE WITH APPLICABLE REQUIREMENTS OF THE NATIONAL
ELECTRICAL CODE, NFPA. KEEP OUT OF REACH OF CHILD REN. UNUSUAL FIRE
AND EXPLOSION HAZARDS (CONT): ALONG THE GROUND BEFORE REACHING A POINT OF I
GNITION AND FLASHING BACK.
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Other Information
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Other Information: TRADE NAME: AUTOMOTIVE GASOLINE. OTHER NAMES: MULTIGRADE
UNLEADED GASOLINE. CHEMICAL FAMILY: HYDROCARBON. GENERIC NAME: PETROLEUM
NAPHTHAS (BLENDED). NFPA HAZARD RATING: HEALTH - 1, FIRE - 3, RE ACTIVITY
- 0, SPECIAL - N/P. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE (CONT):
PETROLEUM SOLVENTS / PETROLEUM HYDROCARBONS - SKIN CONTACT MAY AGGRAVATE AN
EXISTING DEMATITIS. FIRST AID PROC EDURES (CONT): THE LUNGS WILL CAUSE
CHEMICAL PNEUMONIA. MUST OBTAIN MEDICAL ATTENTION PROMPTLY. NOTE TO
PHYSICIAN: TOXIC SIGNS AND SYMPTOMS MAY FOLLOW CONTACT WITH THE SKIN OVER
LARGE AREAS OF THE BOD Y, INHALATION OF VAPORS, OR INGESTION.
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HAZCOM Label
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MSDS NAME: AUTOMOTIVE GASOLINE, MIDGRADE UNLEADED GASOLINE
Assigned IND: Y
Company: US OIL & REFINING CO
Street: 3001 MARSHALL AVE
City: TACOMA WA
Zipcode: 98421
Health Emergency Phone: 253-383-1651
Label Required IND: Y
Date Of Label Review: 06/19/2001
Status Code: A
Origination Code: G
Hazard And Precautions: HEALTH STUDIES HAVE SHOWN THAT MANY PETROLEUM
HYDROCARBONS POSE POTENTIAL HEALTH RISKA WHICH MAY VARY FROM PERSON TO
PERSON. AS A PRECAUTION EXPOSURE TO LIQUIDS, VAPORS, MISTS OR FUMES SHOULD BE
MINIM IZED. HIGH VAPOR CONCENTRATIONS (GREATER THAN 1000 PPM) ARE IRRITATING
TO EYES AND THE RESPIRATORY TRACT, AND MAY CAUSE HEADACHES, DIZZINESS,
ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, AND OTHER CENTRA L NERVOUS SYSTEM
EFFECTS, INCLUDING DEATH. WARNING: CONCENTRATED, PROLONGED AND DELIBERATE
INHALATION OF THIS PRODUCT MAY CAUSE BRAIN OR NERVOUS SYSTEM DAMAGE.
PROLONGED AND REPEATED EXPOSURE OF PREG NANT (SIGNS & SYMPTOMS OF
OVEREXPOSURE)
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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