FLEXBAR MACHINE CORP -- F.P. MONOMER, SELF CURE (SEE SUPPL)
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Material Safety Data Sheet
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NIIN: 01-237-8414
MSDS Num: CLDYG
MSDS NAME: F.P. MONOMER, SELF CURE (SEE SUPPL)
Kit Part: Y
Responsible Party
Name: FLEXBAR MACHINE CORP
Address: 250 GIBBS RD
City: ISLANDIA NY 11749-2697
Info Phone: 631-582-8440
Emergency Phone Number: 810 497-9000
Resp. Party Other MSDS No.: PRODUCT CODE: P 902 000D
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Item Description Information
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Item Manager: S9G
Item Name: FACSIMILE KIT,DEPOT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: KT
UI Container Qty: 1
Type of Container: UNKNOWN
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NOT PROVIDED
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: LIQUID OR HIGH VAPOR CONCENTRATION CAN IRRITATE EYES,
RESPIRATORY SYSTEM AND CAUSE SKIN RASHES. PROLONGED EXPOSURE CAUSES
HEADACHES, NAUSEA, CONFUSION, DROWSINESS, UNCONSCIOUSNESS, BRAIN AND CNS
DAMAG E. ABSORPTION INTO BODY MAY CAUSE FORMATION OF METHEMOGLOBIN WHICH MAY
CAUSE CYANOSIS, HEADACHES, DIZZINESS, NAUSEA, ABDOMINAL PAIN. MAY IRRITATE
EYES AND SKIN WITH DIRECT CONTACT. MAY CAUSE CONTACT D ERMATITIS, POISONING.
Explanation Of Carcinogenicity: HYDROQUINONE IS LISTED AS A SUSPECT CARCINOGEN
BY NTP. ALL HYDROQUINONE DATA GIVEN IN THIS MSDS IS FOR THE DRY POWDER, NOT
AS A COMPONENT OF A LIQUID MIXTURE. NONE OF THE OTHER COMPONENTS OF THIS MATE
RIAL ARE LISTED BY IARC, NTP, OSHA, OR ACIGH AS CARCINOGENS.
Signs And Symptions Of Overexposure: LIQUID OR HIGH VAPOR CONCENTRATION CAN
IRRITATE EYES, RESPIRATORY SYSTEM AND CAUSE SKIN RASHES. PROLONGED EXPOSURE
CAUSES HEADACHES, NAUSEA, CONFUSION, DROWSINESS, UNCONSCIOUSNESS. ABSORPTION
INTO BOD Y MAY CAUSE FORMATION OF METHEMOGLOBIN WHICH MAY CAUSE CYANOSIS,
HEADACHES, DIZZINESS, NAUSEA, ABDOMINAL PAIN. MAY IRRITATE EYES AND SKIN WITH
DIRECT CONTACT. MAY CAUSE CONTACT DERMATITIS.
Medical Cond Aggravated By Exposure: NOT PROVIDED
First Aid: INHALATION: REMOVE TO FRESH AIR. GET MEDICAL HELP IF DISCOMFORT
PERSISTS. EYES: FLUSH WITH WATER FOR 15 MINUTES, INCLUDING UNDER EYELIDS.
SKIN: WASH WITH SOAP AND WATER. INGESTION: FINSE MOUTH OUT WIT H WATER. DO
NOT INDUCE VOMITING. CALL DOCTOR IF AMOUNT WAS LARGE. CLOTHING: WASH
THOROUGHLY BEFORE REUSE. TREATMENT: MAINTAIN AIRWAY. PROVIDE OXYGEN AND/OR
VENTILATION ASSISTANCE, IF NEEDED. TREAT BUR NS OR ALLERGIC REACTIONS
CONVENTIONALLY AFTER DECONTAMINATION.
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Handling and Disposal
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Spill Release Procedures: EVACUATE AREA. ELIMINATE SOURCES OF IGNITION. USE
SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. DIKE, ABSORB WITH
INERT MATERIAL. TRANSFER TO PROPER CONTAINERS FOR DISPOSAL. USE NON-SPAR KING
TOOLS. CONTAMINATED MONOMER UNSTABLE. ADD INHIBITOR TO PREVENT
POLYMERIZATION. KEEP SPILLS, RUNOFFS OUT OF SEWERS AND OPEN BODIES OF WATER.
SPILLS ON POROUS SURFACES CAN CONTAMINATE GROUNDWATER.
Neutralizing Agent: NOT PROVIDED
Waste Disposal Methods: WHEN DISCARDED IT IS LISTED AS A HAZARDOUS WASTE BY THE
EPA UNDER RCRA U-152 WITH REPORTABLE QUANTITY (RQ) OF 1000 POUNDS (40 CFR
PART 302). INCINERATE LIQUID AND DIKING MATERIAL AFTER ADDITION OF EXC ESS
INH9BITOR, IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: OBSERVE PRECAUTIONS FOUND ON THE LABEL. STORE
IN COOL DRY PLACE AWAY FROM HEAT, SPARKS, FLAME AND DIRECT SUNLIGHT. CLOSE
CONTAINER AFTER EACH USE. GROUND ALL METAL CONTAINERS WHEN TRANSFERRING. USE
EX PLOSION-PROOF EQUIPMENT. CHECK INHIBITOR LEVELS EVERY THREE MONTHS.
Other Precautions: WASH FACE AND HANDS THOROUGHLY WITH SOAP AND WATER AFTER USE
AND BEFORE EATING, DRINKING, SMOKING OR APPLYING COSMETICS.
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Fire and Explosion Hazard Information
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Flash Point: =10.6C, 51.F
Autoignition Temp: =435.C, 815.F
Lower Limits: 2.12
Upper Limits: 12.5
Extinguishing Media: CHEMICAL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: WEAR SELF CONTAINED BREATHING APPARATUS, AND FULL
PROTECTIVE GEAR. USE WATER SPRAY TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard: VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND
FLASH BACK. HEAT CAN CAUSE POLYMERIZATION WITH RAPID RELEASE OF ENERGY WHICH
MAY RUPTURE CONTAINER EXPLOSIVELY. (SPONTANEOUS POLYMERIZATION MAY OCCUR ON
PRO LONGED STORAGE.)
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Control Measures
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Respiratory Protection: USE SELF-CONTAINED BREATHING APPARATUS WHEN NEEDED.
Ventilation: USE GOOD LOCAL EXPLOSION-PROOF VENTILATION WITH A MINIMUM CAPTURE
VELOCITY OF 100 FT/MIN (30 M/MIN) AT POINT OF MONOMER RELEASE.
Protective Gloves: IMPERVIOUS, NITRILE.
Eye Protection: SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES.
Other Protective Equipment: PROVIDE EYEWASH, SAFETY SHOWER AND IMPERVIOUS
CLOTHING. PROTECTIVE CREAMS SHOULD NOT BE USED FOR PROTECTION, BUT MAY BE
USED FOR EASE OF CLEAN UP.
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: PRODUCT CODE: P 902 0000. CONTD FROM PRODUCT
ID: HOOSIER P/N: 16000. OTHER MSDS NUMBERS: CLDYH, CLDYJ, CLDYK.
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Physical/Chemical Properties
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HCC: F2
NRC/State LIC No: NOT RELEVANT
Boiling Point: =101.1C, 214.F
M.P/F.P Text: NOT PROVIDED
Decomp Text: NOT PROVIDED
Vapor Pres: 29 MM HG@20C/ 68F
Vapor Density: 3.5@15.5C
Spec Gravity: 0.94
PH: NOT PROVIDED
Viscosity: NOT PROVIDED
Evaporation Rate & Reference: (BUTC=1): 3.0
Solubility in Water: 1.6 GM/100 @ 20C/68F
Appearance and Odor: CLEAR, PALE LIQUID, WITH AN ACRID FRUITY ODOR.
Percent Volatiles by Volume: 99+
Corrosion Rate: NOT PROVIDED
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Reactivity Data
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Stability Indicator: NO
Stability Condition To Avoid: UNSTABLE. HEAT AND IGNITION SOURCES, AGING AND
CONTAMINATION.
Materials To Avoid: REDUCING AND OXIDIZING AGENTS AND UV LIGHT. MATERIAL HAS
STRONG SOLVENT PROPERTIES AND CAN SOFTEN PAINT AND RUBBER.
Hazardous Decomposition Products: OXIDES OF CARBON WHEN BURNED.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: TEMPERATURES ABOVE 21C, 70F,
OXIDIZING/REDUCING AGENTS, PEROXIDES, ACIDS, ALKALIS AND AMINES.
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Toxicological Information
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Toxicological Information: METHYL METHACRYLATE MONOMER: LD50 ACUTE ORAL RAT:
7990 MG/KG. LD50 ACUTE DERMAL RABBIT: 35,500 MG/KG. LC50 ACUTE INHALATION
RAT: > 12,500 TO 16,500 PPM FOR 0.5 HOUR. SUBSTITUTED TOLUIDINE: LD50
INTRAP ERITONEAL MOUSE: 212 MG/KG. BENZOPHENONE: LD50 ORAL RAT: 7400 MG/KG.
HYDROQUINONE: LD50 ACUTE ORAL RAT: 400 MG/KG.
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Ecological Information
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Ecological: AQUATIC TOXICITY: FOR METHYL METHACRYLATE MONOMER, ESTIMATE OF 96
HOURS MEDIAN THRESHOLD LIMIT: 100-1000 PPM. FLATHEAD MINNOWS AND GOLDFISH:
420 PPM.BLUGILLS TLM24: 388 PPM. ECOLOGICAL TOXICITY: NONE KNOWN. FOR
HYDROQUINONE: 96 HOURS LC50 FLATHEAD MINNOWS 0.1-0.8 MG/L. 48 HR LC50
GOLDFISH: 0.287 MG/L.
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MSDS Transport Information
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Transport Information: DOT/UN SHIPPING NAME: METHYL METHACRYLATE MONOMER,
INHIBITED, SOLUTION, CLASS 3, UN 1247, PACKING GROUP II.
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Regulatory Information
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Sara Title III Information: METHYL METHACRYLATE MONOMER AND HYDROQUINONE ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372.
Federal Regulatory Information: OSHA DEFINES METHYL METHACRYLATE MONOMER AND
HYDROQUINONE AS HAZARDOUS UNDER 29 CFR 1910.1200.
State Regulatory Information: NOT PROVIDED
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Other Information
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Other Information: ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE.
N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED.
N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL.
SCBA = SELF CONTAINED BREATHING APPARATUS.
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Transportation Information
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Trans ID NO: 157412
MSDS NAME: F.P. MONOMER, SELF CURE (SEE SUPPL)
MSDS Prepared Date: 09/30/1998
Review Date: 06/11/2001
Multiple KIT Number: 0
Kit Part IND: Y
Unit Of Issue: KT
Container QTY: 1
Type Of Container: UNKNOWN
Additional Data: PROPER SHIPPING NAME, UN ID NUMBER, HAZARD CLASS, AND PACKING
GROUP PER MSDS.
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Detail DOT Information
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DOT PSN Code: JOB
DOT Proper Shipping Name: METHYL METHCRYLATE MONOMER, INHIBITED
Hazard Class: 3
UN ID Num: UN1247
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: T8
Packaging Exception: 150
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
Water/Ship/Other Req: 40
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Detail IMO Information
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IMO PSN Code: JZT
IMO Proper Shipping Name: METHYL METHACRYLATE, MONOMER, INHIBITED
IMDG Page Number: 3259
UN Number: 1247
UN Hazard Class: 3.2
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 3-07
MED First Aid Guide NUM: 330
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Detail IATA Information
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IATA PSN Code: RBQ
IATA UN ID Num: 1247
IATA Proper Shipping Name: METHYL METHACRYLATE MONOMER, INHIBITED
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
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Detail AFI Information
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AFI PSN Code: RBQ
AFI Proper Shipping Name: METHYL METHACRYLATE MONOMER, INHIBITED
AFI Hazard Class: 3
AFI UN ID NUM: UN1247
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: F.P. MONOMER, SELF CURE (SEE SUPPL)
Company: FLEXBAR MACHINE CORP
Street: 250 GIBBS RD
City: ISLANDIA NY
Zipcode: 11749-2697
Health Emergency Phone: 810 497-9000
Label Required IND: Y
Date Of Label Review: 06/11/2001
Status Code: A
MFG Label NO: NOT PROVIDED
Year Procured: 1999
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: NO
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: NOSE, LIVER, KIDNEY, EYE. CAUSES
IRRITATION. AVOID BREATHING VAPORS AND CONTACT WITH EYES AND SKIN. IF
INGESTED, RINSE MOUTH OUT WITH WATER. DO NOT INDUCE VOMITING. IF INHALED,
REMOVE TO FRESH AIR. IF IN EYES, FLUSH WITH WATER. SEE MSDS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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