MONSANTO CO -- ROUNDUP PRO HERBICIDE
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Material Safety Data Sheet
=======================================================
NIIN: 01-108-9578
MSDS Num: CLFDM
MSDS NAME: ROUNDUP PRO HERBICIDE
Responsible Party
Name: MONSANTO CO
Address: 800 N LINDBERGH BLVD
City: SAINT LOUIS MO 63167
Info Phone: 800-332-3111
Emergency Phone Number: 703-527-3887(COLLECT-NOT IN US)
Resp. Party Other MSDS No.: S00012732
=======================================================
Item Description Information
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Item Manager: S9G
Item Name: HERBICIDE,GLYPHOSATE
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: BX
Quantitative Expression: 00000000002EA
UI Container Qty: 1
Type of Container: CONTAINERS
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT PROVIDED
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONTACT: THIS PRODUCT MAY CAUSE PAIN, REDNESS AND
TEARING. SKIN CONTACT: THIS PRODUCT IS NO MORE THAN MILDLY IRRITATING .
INHALATION: THIS PRODUCT IS NO MORE THAN SLIGHTLY TOXIC IF INHALED BASED O N
TOXICITY STUDIES. INGESTION: THIS PRODUCT IS NO MORE THAN SLIGHTLY TOXIC. NO
SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED IF ONLY SMALL AMOUNTS ARE
SWALLOWED. SIMILAR FORMULATIONS HAS BEEN REPORT ED TO PRODUCE
GASTROINTESTINAL DISCOMFORT WITH IRRITATION OF THE MOUTH, NAUSEA, VOMITING
AND DIARRHEA. ORAL INGESTION OF LARGE QUANTITIES OF ONE SIMILAR PRODUCT HAS
BEEN REPORTED TO RESULT IN HYPOTENS ION AND LUNG EDEMA.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: EYE CONTACT: THIS PRODUCT MAY CAUSE PAIN,
REDNESS AND TEARING. SKIN CONTACT: THIS PRODUCT IS NO MORE THAN MILDLY
IRRITATING. INGESTION: SIMILAR FORMULATIONS HAS BEEN REPORTED TO PRODUCE
GASTROINTESTIN AL DISCOMFORT WITH IRRITATION OF THE MOUTH, NAUSEA, VOMITING
AND DIARRHEA.
Medical Cond Aggravated By Exposure: NONE KNOWN
First Aid: IF IN EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. IF EASY TO DO SO, REMOVE ANY CONTACT LENSES. GET MEDICAL ATTENTION.
REMOVE MATERIAL FROM SKIN AND CLOTHING. IF ON SKIN: IMME DIATE FIRST AID IS
NOT LIKELY TO BE REQUIRED. THIS MATERIAL CAN BE REMOVED WITH WATER. WASH
HEAVILY CONTAMINATED CLOTHING BEFORE REUSE. IF INHALED: IMMEDIATE FIRST AID
IS NOT LIKELY TO BE REQUIRED. IF SYMPTOMS OCCUR, REMOVE TO FRESH AIR. IF
SWALLOWED: IMMEDIATE FIRST AID IS NOT LIKELY TO BE REQUIRED. A PHYSICIAN OR
POISON CONTROL CENTER CAN BE CONTACTED FOR ADVICE. WASH HEAVILY CONTAMINATED
CLOTHI NG BEFORE REUSE.
=======================================================
Handling and Disposal
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Spill Release Procedures: FOR SPILL LESS THAN 1 GALLON, SOAK UP WITH
TOWELS/OTHER ABSORBENTS AND DISCARD IN TRASH. CLEAN AREA WITH SOAP AND WATER.
CONTAIN LARGE SPILLS. ABSORB WITH BENTONITE/OTHER CLAYS. PLACE IN A METAL
DRUM. THOROUGHLY SCRUB FLOOR WITH STRONG DETERGENT AND RINSE WITH WATER.
LARGE SPILLS THAT SOAK INTO GROUND SHOULD BE DUG UP, PLACED IN METAL DRUMS
AND DISPOSED OF PROPERLY.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: WASTES RESULTING FROM THE USE OF THIS PRODUCT THAT
CANNOT BE USED OR CHEMICALLY REPROCESSED SHOULD BE DISPOSED OF IN A LANDFILL
APPROVED FOR PESTICIDE DISPOSAL OR IN ACCORDANCE WITH APPLICABLE FEDERAL ,
STATE OR LOCAL PROCEDURES. EMPTIED CONTAINERS RETAIN VAPOR AND PRODUCT
RESIDUE. OBSERVE ALL LABELE D SAFEGUARDS UNTIL CONTAINER IS CLEANED.
Handling And Storage Precautions: DO NOT CONTAMINATE FOOD, FEED OR WATER BY
STORAGE OR DISPOSAL. DO NOT APPLY DIRECTLY TO WATER. DO NOT CONTAMINATE WATER
BY CLEANING OF EQUIPMENT OR DISPOSAL OF WASHWATERS.
Other Precautions: AVOID CONTACT WITH EYES OR CLOTHING. WASH HANDS BEFORE
EATING, DRINKING, CHEWING GUM, USING TOBACCO OR USING THE TOILET. REMOVE
CLOTHING IMMEDIATELY IF PESTICIDE GETS INSIDE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Lower Limits: UNKNOWN
Upper Limits: UNKNOWN
Extinguishing Media: IN CASE OF FIRE, USE WATER (FLOOD WITH WATER), CARBON
DIOXIDE, ALCOHOL FOAM, DRY CHEMICAL
Fire Fighting Procedures: FIREFIGHTERS AND OTHERS EXPOSED TO PRODUCTS OF
COMBUSTION SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD
BE THOROUGHLY DECONTAMINATED AFTER USE.
Unusual Fire/Explosion Hazard: NONE
=======================================================
Control Measures
=======================================================
Respiratory Protection: IN THE EVENT OF ABNORMAL EXPOSURE CONDITIONS, WEAR
NIOSH APPROVED EQUIPMENT. IN SITUATIONS WHERE AN AIR PURIFYING RESPIRATOR IS
APPROPRIATE TO BE USED, USE OF A FULL FACE RESPIRATOR EQUIPPED WITH PURI
FYING ELEMENTS FOR PROTECTION AGAINST ORGANIC VAPOR AND DUST/MIST APPROVED
FOR PESTICIDES IS RECOMMENDED. COMPLY WITH OSHA 29 CFR 1910.134.
Ventilation: NO SPIECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves: WEAR APPROPRIATE GLOVE.
Eye Protection: SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment: EYE WASH STATION, EMERGENCY SHOWER, APPROPRIATE
LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices: KEEP AND WASH PPE SEPARATELY FROM OTHER LAUNDRY.
Supplemental Safety and Health: EPA REGISTRATION NUMBER: 524-475. ABBREVIATION:
N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT
PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED.
CNS = CE NTRAL NERVOUS SYSTEM. GI = GASTROINTESTINAL. SCBA = SELF CONTAINED
BREATHING APPARATUS.
=======================================================
Physical/Chemical Properties
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HCC: T5
NRC/State LIC No: NOT RELEVANT
B.P. Text: NOT PROVIDED
M.P/F.P Text: NOT PROVIDED
Decomp Text: NOT PROVIDED
Vapor Pres: NOT PROVIDED
Spec Gravity: 1.17
PH: 4.99 (1% SOL'N)
Viscosity: NOT PROVIDED
Evaporation Rate & Reference: NOT PROVIDED
Solubility in Water: NOT PROVIDED
Appearance and Odor: CLEAR, VISCOUS, AMBER COLORED SOLUTION - PRACTICALLY
ODORLESS TO AMINE ODOR
Corrosion Rate: NOT PROVIDED
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: FOODSTUFFS, REDUCING AGENTS AND ACIDS.
Materials To Avoid: BASIC MATERIALS, GALVANIZED OR UNLINED STEEL (EXCEPT
STAINLESS STEEL) CONTAINERS OR SPRAY TANKS
Hazardous Decomposition Products: NONE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: CAN REACT WITH CAUSTIC (BASIC) MATERIALS TO
LIBERATE HEAT.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: SINGLE EXPOSURE (ACUTE) STUDIES INDICATE: ORAL-
FIFRA CATEGORY IV. DERMAL: FIFRA CATEGORY IV. INHALATION: FIFRA CATEGORY IV;
NOT DOT POISONOUS. EYE IRRITATION: FIFRA CATEGORY III. SKIN IRRITATION: FIF
RA CATEGORY IV. NO SKIN ALLERGY WAS OBSERVED IN GUINEA PIGS FOLLOWING
REPEATED SKIN EXPOSURE. IN REPEAT DOSING STUDIES (6-MONTHS), DOGS FED MON
0139 EXHIBITED SLIGHT BODY WEIGHT CHANGES. FOLLOWING REP EATED SKIN EXPOSURE
TO MON 0139, SKIN IRRITATION WAS THE PRIMARY EFFECT IN RABBITS.
=======================================================
Ecological Information
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Ecological: INVERTEBRATES: 48 HOURS EC50 DAPHNIA MAGNA: 11 MG/L; SLIGHTLY
TOXIC. WARMWATER FISH: 96-HR LC50 BLUEGILL SUNFISH: 7.5 MG/L; MODERATELY
TOXIC. GOLDWATER FISH: 96-HR LC50 RAINBOW TROUT: 5.5 MG/L: MODERA TELY TOXIC.
AVIAN SPECIES: 8-DAY LC50 BOBWHITE QUAIL: > 5,620 PPM; PRACTICALLY
NONTOXIC. 8-DAY LC50 MALLARD DUCK: > 5,620 PPM; PRACTICALLY NONTOXIC.
ARTHROPODS: 48-HR ORAL LD50 HONEYBEE: > 100 MICROGR AMS/BEE; PRACTICALLY
NONTOXIC. 48-HR CONTACT LD50 HONEYBEE: > 100 MICROGRAMS/BEE; PRACTICALLY
NONTOXIC.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: THE DATA PROVIDED IS FOR INFORMATION ONLY. PLEASE APPLY
THE APPROPRIATE REGULATIONS TO PROPERLY CLASSIFY YOUR SHIPMENT FOR
TRANSPORTATION. THIS PRODUCT IS NOT HAZARDOUS UNDER THE APPLICABLE DOT, ICAO/
IATA, OR IMDG REGULATIONS.
=======================================================
Regulatory Information
=======================================================
Federal Regulatory Information: EPA REGISTRATION NUMBER: 524-475. TSCA
INVENTORY: ALL COMPONENTS ARE LISTED IN THE TSCA INVENTORY. HAZARDOUS
CHEMICALS UNDER OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200):
SURFACTANT.
State Regulatory Information: NOT PROVIDED
=======================================================
Other Information
=======================================================
Other Information: NOTE: FOR ADDITIONAL HUMAN EMERGENCY FIRST AID OR TREATMENT
GUIDANCE, CALL COLLECT, DAY OR NIGHT (814) 694-4000.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 157487
MSDS NAME: ROUNDUP PRO HERBICIDE
MSDS Prepared Date: 04/22/2000
Review Date: 06/16/2001
Net Unit Weight: 48.7 LBS
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 1
Type Of Container: CONTAINERS
Additional Data: NOT REGULATED FOR TRANSPORTATION, PER MSDS.
=======================================================
Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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