===================== Product Identification =====================
MSDS NAME:1818 UNEPOXY TIN-FREE ANTI-FOULING PLUS BLACK
NIIN:00N069710
MSDS Number: CBKSM
=== Responsible Party ===
Company:PETTIT PAINT DIVISION KOP-COAT INC
Address:36 PINE ST
City:ROCKAWAY
State:NJ
ZIP:07866
Country:US
Info Phone Num:613-996-6666
Emergency Phone Num:613-996-6666;800-424-9300(CHEMTREC)
Preparer's Name:CA HOPE
CAGE:JO314
=== Contractor Identification ===
Company:KOP-COAT INC
Address:36 PINE ST
Box:City:ROCKAWAY
State:NJ
ZIP:07866
Country:US
Phone:201-625-3100; 800-221-4466
CAGE:11111
Company:PETTIT PAINT DIVISION KOP-COAT INC
Address:36 PINE ST
Box:City:ROCKAWAY
State:NJ
ZIP:07866
Country:US
Phone:613-996-6666
CAGE:JO314
============= Composition/Information on Ingredients =============
Name:COPPER (I) OXIDE; (COPPROUS OXIDE (AS CU DUSTS & MISTS))
CAS:1317-39-1
RTECS #:GL8050000
Fraction by Wt: 50-60%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 5%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SOLVENT NAPHTHA; (CAROMATIC SOLVENT NAPHTHA)
CAS:64742-94-5
RTECS #:WF3100000
Fraction by Wt: 15%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 0-3%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Name:PHTHALIC ACID, DIBUTYL ESTER; (BUTYL PHATHALATE)
CAS:84-74-2
RTECS #:TI0875000
Fraction by Wt: 1%
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:VOLATILE ORGANIC CONTENT: 394 G/L
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Name:FIRST AID PROC: CHARCOAL IN WATER TO VICTIM AS TOLERATED.
SEEK MED AID. DO NOT ATTEMPT TO GIVE ANYTHING BY MOUTH (ING 8)
RTECS #:9999999ZZ
Name:ING 7: TO UNCON PERS. NOTE TO MD: THERE IS NO SPECIFIC
ANTIDOTE FOR EFTS FROM OVEREXP TO THIS MATL. TREATMENT (ING 9)
RTECS #:9999999ZZ
Name:ING 8: SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND
THE CLINICAL CONDITION.
RTECS #:9999999ZZ
Name:SPILL PROC: THIS PROD RELEASED INTO ENVIRON MUST BE
REPORTED TO NATIONAL RESPONSE CENTER (1-800-424-8802). (ING 11)
RTECS #:9999999ZZ
Name:ING 10: WHEN THIS PRODUCT IS SPILLED OR LEAKED, THE
REPORTABLE QUANTITY IS 100 LBS OR MORE.
RTECS #:9999999ZZ
Name:OTHER PREC: DESIGNED TO COMPLY W/OSHA 1910.106. KEEP IN
CLSD, LABELED CONTR W/IN COOL (WELL-SHADED), DRY, VENT (ING 13)
RTECS #:9999999ZZ
Name:ING 12: AREA. PROT FROM PHYSICAL DMG. KEEP CONTRS CLSD WHEN
MATL IS NOT IN USE. MAINT GOOD HOUSEKEEPING. GROUND (ING 14)
RTECS #:9999999ZZ
Name:ING 13: & BOND DRUMS. DO NOT USE PRESS TO EMPTY DRUMS. DO
NOT WEAR CONTAM CLTHG. DISCARD CONTAM FOOTWEAR. KEEP (ING 15)
RTECS #:9999999ZZ
Name:ING 14: AWAY FROM HEAT & OPEN FLAME. DO NOT USE WITHOUT
FULLY UNDERSTANDING "REACTIVITY" SECTION.
RTECS #:9999999ZZ
Name:VENT: BELOW FLAMMABLE VAPOR CONCENTRATIONS. LOCAL EXHAUST
IS NECESSARY FOR USE IN ENCLOSED/CONFINED SPACES. (ING 17)
RTECS #:9999999ZZ
Name:ING 16: SEE OSHA REQUIREMENTS/NIOSH PUBLICATION # 113
"...CONFINED SPACES".
RTECS #:9999999ZZ
Name:OTHER PROT EQUIP: CONDITIONS, I.E., CONTACT POTENTIAL, WEAR
RESISTANT PROTECTIVE GARMENTS SUCH AS HEAD/NECK (ING 19)
RTECS #:9999999ZZ
Name:ING 18: COVER, APRONS, JACKETS, PANTS, COVERALLS, BOOTS,
ETC.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: DIRECT CONT W/LIQ/VAP MAY
CAUSE IRRIT. SKIN: PRLNG &/RPTD CONT MAY CAUSE DEFAT (REDNESS,
CRACKING, BLISTERING, IRRIT & DERM). INHAL: HIGH CONCS OF VAPS MAY
CAUSE RESP TRACT IRRIT & CNS DEP RESS (HDCH, WEAK, DIZZ, INCOORD &
POSS COLLAPSE). PRLNG &/RPTD INHAL OF HIGH CONCS OF METAL FUMES MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CAUSE METAL FUME FEVER (HDCH, DIZZ,
METALLIC TASTE IN MOUTH & GEN FLU-LIKE SYMPS). INGEST: MAY CAUSE GI
DISTURB SUCH AS NAUS, VOMIT, DIARR & EFTS SIMILAR TO THOSE
DESCRIBED UNDER INHAL. ASPI R OF PROD INTO LUNGS MAY CAUSE CHEM
PENUMIT WHICH CAN BE FATAL. CHRONIC: TOLUENE APPEARS ON NAVY LIST
OF OCCUP (SUP DAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PREEXISTING DISEASE
IN/HISTORY OF AILMENTS INVOLVING SKIN, EYE, RESP TRACT, LIVER,
KIDNEY, CNS ARE AT GREATER THAN NORMAL RISK OF DEVELOPING ADVERSE
EFTS WHEN EXPOSED TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MIN.
SEEK MED AID. SKIN: WASH THORO W/SOAP & WATER. IF REDNESS, ITCH,
BURNING/OTHER SYMPS DEVEL/PERSIST, SEEK MED AID. WASH CONTAM CLTHG
BEFORE REU SE. INHAL: REMOVE FROM EXPOS. IF BRTHG HAS STOPPED/IS
DFCLT, ADMIN ARTF RESP/OXYGEN AS INDICATED. SEEK MED AID. INGEST:
DO NOT INDUCE VOMIT. GIVE 1 GLASS OF MILK/1-2 OZ (30-60 G) OF
ACTIVATED (ING 7)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:75.0F,23.9C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEM/FOAM. WATER MAY BE
INEFFECTIVE. USE CARBON DIOXIDE, DRY CHEM, WATER SPRAY, ALCOHOL(SUP
DAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . USE WATER TO COOL FIRE-EXPOSED
CONTAINER/STRUCTURE/PROTECT PERSONNEL.
Unusual Fire/Explosion Hazard:VAPS FORM FLAM/EXPLO MIX IN AIR. VAPS
HEAVY, MAY TRAVEL (GROUND, PIT, SEWER) TO IGNIT SOURCE-FLASH.
OPEN/CLSD CONTRS MAY CONTAIN FLAM/EXPLO VAPS. (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:STOP SPILL/LEAK IF NO RISK INVOLVED. AVOID
BRTHG VAPS. ELIM ALL SOURCES OF IGNIT. VENT AREA. AVOID CONT W/HOT
LIQ & FUMES. TAKE UP CAREFULLY TO AVOID HEAT & SPARKS. USE INERT
ABSORB TO COMPLETE CLEAN- UP. THIS MATL REACTS W/OXIDIZING
MATLS.(ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:EMPTY CONTRS MAY RETAIN PROD RESIDUE
INCL FLAM/EXPLO VAPS. DO NOT CUT, DRILL, GRIND/WELD ON/NEAR FULL,
PARTIALLY FULL/EMPTY PROD CONTRS.
Other Precautions:AVOID PRLNG/RPTD CONT W/SKIN/EYES. AVOID PRLNG/RPTD
BRTHG OF VAPS, MISTS/FUMES. HANDLE & USE I/A/W OSHA
29CFR1910.106/LOC CODES. SPRAY PAINT I/A/W 29 CFR 1910.107. OBSERVE
GOOD PERS HYGIENE PRACT & RE C PROC. STORE IN AREAS/BLDGS (ING 12)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENT DOES NOT MAINT INHAL EXPOS < PEL(TLV),
USE NIOSH/MSHA APPRVD UNITS AS PER CURRENT 29 CFR 1910.134,
INSTRUCTIONS/WARNINGS & NIOSH-RESP DECISION LOGIC-PUB # 87.108. IF
W/IN PROT FACTOR, NIOSH/MS HA APPRVD AIR PURIFYING OV/FILTER UNITS.
Ventilation:PROVIDE SUFFICIENT GEN/LOC EXHAUST VENT IN VOL & PATTERN TO
CTL INHAL EXPOS BELOW CURRENT EXPOS LIM IN AREAS (ING 16)
Protective Gloves:HEAVY NEOPRENE OR EQUAL.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR INDUS-TYPE CLTHG & SFTY FOOTWEAR. DEPENDING ON WORKING (ING
18)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: OR UNIVERSAL TYPE FOAMS AS PER MFR'S REC. EXPLO HAZ: CLSD
CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT (FIRE). UNDER FIRE
CNDTNS, MAY EMIT IRRIT/TOX GAS &/FUMES. EFTS OF OVEREXP: CHEM
REPRO HAZ. SEEK CONSULT FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>230F,>110C
Vapor Density:>1
Spec Gravity:2.11
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK VISCOUS LIQUID, WITH A TYPICAL SOLVENT ODOR
Percent Volatiles by Volume:56.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING AGENTS, HEAT, SPARKS AND OPEN FLAMES.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, UPON
THERMAL DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS PRODUCT IS A US EPA DEFINED IGNITABLE
HAZARDOUS WASTE. DISPOSE OF AS AN IGNITABLE HAZARDOUS WASTE IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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