===================== Product Identification =====================
MSDS NAME:CUPRIC SULFATE ANHYDROUS, 61230
NIIN:00N069757
MSDS Number: CBKTR
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:516-467-3535
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:COPPER (II) SULFATE (1:1); (CUPRIC SULFATE ANHYDROUS) (SARA
313) (CERCLA)
CAS:7758-98-7
RTECS #:GL8800000
OSHA PEL:1 MG (CU)/M3
ACGIH TLV:1 MG(CU)/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:SUPDAT:BLADDER:CHANGES IN TUBULES. ENDOCRINE:TUMORS.
BLOOD:HEMORR, OTHER HEMOLYSIS W/OR W/OUT ANEMIA. PATERNAL (ING 3)
RTECS #:9999999ZZ
Name:ING 2:EFTS:SPERMATOGENESIS, TESTES, EPIDIDYMIS, SPERM DUCT.
EFTS ON FERTILITY:POST-IMPLANTATION MORTALITY, OTHER (ING 4)
RTECS #:9999999ZZ
Name:ING 3:MEASURES OF FERTILITY. EFTS ON EMBRYO/FETUS:FETOTOX.
SPECIFIC DEVELOPMENTAL ABNORMS:CNS, BODY WALL, (ING 5)
RTECS #:9999999ZZ
Name:ING 4:CARDIOVASCULAR SYS. TUMORIGENIC:EQUIVOCAL TUMORIGENIC
AGENT BY RTECS CRITERIA. ONLY SELECTED REGISTRY OF (ING 6)
RTECS #:9999999ZZ
Name:ING 5:TOX EFTS OF CHEM SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT):300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. CAUSES SKIN IRRITATION, SEVERE EYE
IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT. EXPOSURE CAN CAUSE: DAMAGE TO THE EYES,
GASTROINTESTINAL DISTURBANCES. CHRONIC:LABORATORY EXPERS HAVE SHOWN
MUTAGENIC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:EFTS. CHRONIC COPPER POIS IS TYPIFIED
BY HEPATIC CIRRHOSIS, BRAIN DMG & DEMYELINATION, KIDNEY DEFECTS, &
COPPER DEPOSITION IN CORNEA AS EXEMPLIFIED BY HUMANS W/WILSON'S
DISEASE. IT HAS ALSO BEEN REPORTED THAT COPPER POIS HAS LEADTO
HEMOLYTIC ANEMIA & ACCELERATES ARTERIOSCLEROSIS. TARGET ORGAN(S) &
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:IMMED WASH W/SOAP & COPIOUS AMTS OF WATER. REMOVE & WASH
CONTAM CLTHG PROMPTLY. EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR
@ LST 15 MIN. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH WITH
WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SP ILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, ON
CLOTHING. DO NOT BREATHE DUST. TOXIC. SEVERE EYE IRRITANT. POSSIBLE
MUTAGEN. KEEP TIGHTLY CLOSED. PROTECT FROM AIR.
Other Precautions:HYGROSCOPIC. HANDLE AND STORE UNDER NITROGEN.
ANHYDROUS COPPER (II) SULFATE REACTS VIOLENTLY WITH:HYDROXYLAMINE,
MAGNESIUM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IN NONVENTILATED
AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:LONG RUB/NEOPRENE GAUNTLET GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . RUBBER APRON.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MP:392F,200C (DEC). WASTE DISP METH:SODIUM HYPOCHLORITE. NEUT SOLN
BEFORE FLUSHING DOWN DRAIN. OBSERVE ALL FED, STATE & LOC ENVIRON
REGS. EFTS OF OVEREXP:DATA:LIVER, KIDNEYS, BLOOD.
BEHAVIORAL:SOMNOLE NCE, CONVLS/EFT ON SIZURE THRESHOLD, FOOD
INTAKE. GI:GASTRITIS, HYPERMOTILITY, DIARR, NAUS/VOMIT. KIDNEY,
URETER,(ING 2)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Vapor Pres:7.3 @ 25C
Spec Gravity:3.603
Appearance and Odor:LIGHT-GREY POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MOISTURE, CORRODES STEEL, FINELY POWDERED METALS, SENSITIVE TO AIR.
REACTS VIOLENTLY W/HYDROXYLAMINE, MAGNESIUM.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:MATL SHOULD BE DISSOLVED IN 1)WATER; 2)ACID
SOLN/3)OXIDIZED TO WATER-SOL STATE. PRECIPITATE MATL AS SULFIDE,
ADJUSTING PH OF SOLN TO 7 TO COMPLETE PRECIPITATION. FILTER INSOLS
& DISP OF THEM IN HAZ WA STE SITE. DESTROY ANY EXCESS SULFIDE WITH
(SUPDAT)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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