===================== Product Identification =====================
MSDS NAME:METHYLAMINE, 65568
NIIN:00N069754
MSDS Number: CBKTN
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:METHYLAMINE (CERCLA)
CAS:74-89-5
RTECS #:PF6300000
OSHA PEL:10 PPM
ACGIH TLV:5 PPM/15 STEL
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:OTHER PRECS:ZINC (TOGETHER W/ZINC ALLOYS & GALVANIZED
SURFS), ALUMINUM & NICKEL. CONT W/SILVER MAY FORM POTNTLLY (ING 3)
RTECS #:9999999ZZ
Name:ING 2:EXPLO CMPDS. REACTS W/NITROMETHANE & POSS OTHER NITRO
ALKANES TO PRDCE SHOCK-SENSITIVE MIXTURES. REACTS (ING 4)
RTECS #:9999999ZZ
Name:ING 3:VIOLENTLY WHEN MIXED W/OXIDIZING AGENTS SUCH AS
PERCHLORATES, NITRATES, PERMANGANATES, CHROMATES, NITRIC (ING 5)
RTECS #:9999999ZZ
Name:ING 4:ACID, HALOGENS & PEROXIDES. NATURAL RUB, BUNA S/N, &
CELLULOSE ACETATE ARE NOT COMPAT FOR USE W/METHYLAMINE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE
OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND
EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULM
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:EDEMA. SYMPS OF EXPOS MAY INCLUDE
BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HDCH, NAUS & VOMIT. TARGET ORGAN DATA:SENSE ORGANS &
SPECIAL SENSES:LACRIM. LUNGS, T HORAX/RESP:DYSPNAE. SKIN &
APPENDAGES (AFTER SYSTEMIC EXPOS):DERM, IRRIT. ONLY SELECTED
REGISTRY OF TOX EFTS OF (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED
(SHOW LBL WHERE POSS). EYES:FLUSH W/COPIOUS AMTS OF WATER FOR @ LST
15 MIN. SKIN:FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN WHILE
REMO VING CONTAM CLTHG & SHOES. DISCARD CONTAM CLTHG & SHOES.
INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS
DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS
(SUPDAT)
===================== Fire Fighting Measures =====================
Lower Limits:4.9%
Upper Limits:20.8%
Extinguishing Media:DO NOT EXTING BURNING GAS IF FLOW CANNOT BE SHUT
OFF IMMED. USE WATER SPRAY/FOG NOZZ TO KEEP CYL COOL. MOVE CYL
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DANGER:FLAMMABLE, CORROSIVE AND TOXIC LIQUID
AND GAS UNDER PRESSURE.
Unusual Fire/Explosion Hazard:MAY FORM EXPLOSIVE MIXTURES WITH AIR.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA AND KEEP PERS UPWIND. WEAR FULL
PROT EQUIP SUCH AS, BUTYL RUB CHEM-PROOF AIR SUIT, W/BRTHG AIR
SUPPLIED. SHUT OFF ALL IGNIT SOURCES. SHUT OFF LEAK IF THERE IS NOT
RISK. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BRTHE GAS, GET IN EYES, ON
SKIN, ON CLTHG. AVOID PRLNGD/RPTD EXPOS. CORR. TOX. KEEP TIGHTLY
CLSD. CYL TEMP SHOULD NOT EXCEED 125F (52C).
Other Precautions:KEEP AWAY FROM IGNIT SOURCES. NO SMKING. DO NOT
PUNCTURE/INCIN CYL. PRLNGD DIRECT CONT W/MERCURY WILL PRDCE EXPLO
CMPDS. INSTRUMENTS CNTNING MERCURY SHOULD NOT BE USED. CORRODES
COPPER, COPPER ALLOYS (INCLUDING BRASS & BRONZE), (ING 2)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IN NONVENTILATED
AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXING MEDIA:AWAY FROM FIRE IF THERE IS NO RISK. EFTS OF OVEREXP:CHEM
SUBSTANCES (RTECS) DATA IS PRESENT HERE. SEE ACTUAL ENTRY IN RTECS
FOR COMPLETE INFO. FIRST AID PROC:CONSCIOUS. CALL MD. SYMPS MAY BE
DELAYED. KEEP UNDER MED OBSERVATION.EYE PROT:AND FULL LENGTH
FACESHIELD .
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:-135F,-93C
Vapor Pres:27PSI@20C
Vapor Density:1.08 @ 20C
Appearance and Odor:COLORLESS GAS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES & ANHYDRIDES, OXIDIZING AGENTS, CHLOROFORMATES,
PHOSPHORUS HALIDES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CAUTION:NO-RETURN CYLINDER. DO NOT REUSE. EMPTY
CYLINDER WILL CONTAIN HAZARDOUS RESIDUE. FOLLOW PROPER DISPOSAL
TECHNIQUES. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|