===================== Product Identification =====================
MSDS NAME:PLSE2-3Y, SINGLE ELEMENT PLASMA STANDARD (SUPDAT)
NIIN:00N069720
MSDS Number: CBKSQ
=== Responsible Party ===
Company:SPEX CHEMICAL DIVISION
Address:203 NORCROSS AVENUE
City:METUCHEN
State:NJ
ZIP:08840
Country:US
Info Phone Num:908-549-7144
Emergency Phone Num:800-424-9300(CHEMTREC)
Preparer's Name:SUSHA RAMANE
CAGE:EO247
=== Contractor Identification ===
Company:SPEX CHEMICAL DIVISION
Address:203 NORCROSS STREET
City:METUCHEN
State:NJ
ZIP:08840
Country:US
Phone:908-494-1663/549-7144
CAGE:EO247
Company:SPEX INDUSTRIES INC
Box:UNKNOW
CAGE:SPEXX
============= Composition/Information on Ingredients =============
Name:NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 2-5%
OSHA PEL:2 PPM
ACGIH TLV:2 PPM; 4 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SELENIUM; (SE) (SARA 313) (CERCLA)
CAS:7782-49-2
RTECS #:VS7700000
Fraction by Wt: 0.1-1.0%
OSHA PEL:0.2 MG/M3
ACGIH TLV:0.2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 90-97%
Name:SUPP DATA: THE VAPOR & MIST MAY ERODE THE EXPOSED TEETH
W/PRLNGD EXPOS. INGEST OF LIQUID WILL CAUSE IMMED PAIN & (ING 5)
RTECS #:9999999ZZ
Name:ING 4: BURNS OF THE MOUTH, ESOPHAGUS AND GI TRACT. INHAL
MAY BE FATAL CAUSING SPASM, INFLAMM & EDEMA OF LARYNX(ING 6)
RTECS #:9999999ZZ
Name:ING 5: & BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS INCL BURNING SENSATION, COUGHING, WHEEZING(ING 7)
RTECS #:9999999ZZ
Name:ING 6: LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT.
SYMPS & HLTH HAZS FOR DILUTE NITRIC ACID ARE EXPECTED(ING 8)
RTECS #:9999999ZZ
Name:ING 8:OR GREATER, THE HEALTH HAZARDS FOR CONCENTRATED
NITRIC ACID ARE GIVEN.
RTECS #:9999999ZZ
Name:FIRE FIGHT PROC:METAL POWDERS, HYDROGEN SULFIDE, ETC.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THIS SOLUTION MAY BE HARMFUL IF
INHALED, INGESTED/UPON CONT W/SKIN/EYES. EXPOS TO SELENIUM MAY
CAUSE ABDOM PAINS, DIARR, VOMIT, CHEST PAINS, COUGHING & DFCLTY IN
BRTHG. INHAL MAY CAUSE LUNG IRRITS. SK IN CONT MAY CAUSE
DERMATITIS. CONC NITRIC ACID MAY BE FATAL IF TOO MUCH IS
INHALED/ABSORBED THRU SKIN.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONC NITRIC ACID VAPOR/MIST IS AN
IRRIT OF EYES, MUCOUS MEMBRANES & SKIN. IN CONT W/EYES, IT PRDCES
SEV BURNS WHICH MAY RESULT IN PERM DMG & VISUAL IMPAIRMENT. ON
SKIN, THE LIQUID/CONC VAPOR PRDCES IMMED, SEVERE & LIQ/CONC VAP
PRDCES IMMED, SEV & LIQ/CONC VAP PRDCES IMMED, SEV & PENETRATING
BURNS;(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER FOR AT LEAST 15 MINS OCCASIONALLY LIFTING
UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMD CLTHG, THEN FLUSH
W/WATER FOR AT LEAST 15 MINS. WASH CLTHG THORO BEFORE REUSE. INHAL:
MOVE TO F RESH AIR. INGEST: DO NOT INDUCE VOMITING. IMMED OBTAIN
MED HELP. SEND TO HOSPITAL. ONLY IF PATIENT CONSCIOUS, GIVE LARGE
QTYS OF WATER/MILK. IF IRRIT CONTINUES, GET MED ATTN IMMED.
===================== Fire Fighting Measures =====================
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
CONC HNO*3 REACTS EXPLOS W/COMBUST ORG/READILY OXIDIZABLE MATLS
SUCH AS ALCOHOL, WOOD, TURPENTINE (ING 10)
Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST, BUT IS STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUST MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELEASE FLAMM HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER
DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS COMPLETE.
WEAR CHEM RESIST GLASSES , GLOVES & CLTHG. WEAR APPROVED
RESPIRATOR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONC NITRIC ACID WILL ATTACK SOME
FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP
TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA. LAB COAT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TRADENAME/PART #: SOLUTION, 10,000 PPM OF SELENIUM IN 5% NITRIC ACID.
MATL TO AVOID: ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN
SULFIDE, ETC. CONTACT W/STRONG BASES WILL CAUSE VIOLENT SPLATTER
ING. EFTS OF OVEREXP: CONC SOLNS CAUSE DEEP ULCERS & STAIN SKIN
BRIGHT YELLOW/YELLOWISH BROWN COLOR. (ING 4)
================== Physical/Chemical Properties ==================
Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/AN ACRID ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IF REACTS EXPLOS W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS: (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST AND LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES AND VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR REGULATIONS. DISPOSE OF IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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