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Material Safety Data Sheet
Printing date 03/10/2008 Version 1 Reviewed on 03/10/2008
* 1 Identification of substance
路 Product details
路 Trade name: ODOROX MO2
路 Article number: 027-03-0006
路 Creation date: 10/24/2007
路 Manufacturer/Supplier:
Linde Canada Limited
BOC Canada Limited
5860 Chedworth Way
Mississauga, Ontario L5R 0A2
www.bocgases.ca
TELEPHONE NUMBER: (905) 501-1700
24-HOUR EMERGENCY TELEPHONE NUMBER: (905) 501-0802
EMERGENCY RESPONSE PLAN NO: 2-0101
Please ensure that this MSDS is received by the appropriate person
路 Information department: Customer Service Centre: 1-866-385-5349
* 2 Composition/Data on components
路 Chemical characterization
路 Dangerous components:
7782-44-7 Oxygen 23-100%
Danger: 2.4/1
75-18-3 dimethyl sulphide 0-5%
Danger: 2.6/2; 3.1.O/3, 3.2/2, 3.3/2A
路 Chemical components
124-38-9 Carbon Dioxide 0-5%
* 3 Hazards identification
路 Hazard description:
Oxidizing
路 WHMIS-symbols:
A - Compressed gas
C - Oxidizing materials
(Contd. on page 2)
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Material Safety Data Sheet
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Trade name: ODOROX MO2
(Contd. of page 1)
路 HMIS-ratings (scale 0 - 4)
HEALTH 0 Health = 0
Fire = 0
FIRE 0
Reactivity = 3
REACTIVITY 3
路 NFPA ratings (scale 0 - 4)
0 Health = 0
0 3 Fire = 0
Reactivity = 3
OX
路 Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Contact with combustible material may cause fire.
路 Classification system:
The classification is in line with internationally approved calculation standards. It is expanded, however, by
information from technical literature and by information furnished by supplier companies.
路 GHS label elements
Danger
2.4/1 - May cause or intensify fire; oxidizer.
Warning
2.5/C - Contains gas under pressure; may explode if heated.
路 Prevention:
Keep/Store away from clothing/combustible materials.
Keep reduction valves free from grease and oil.
路 Response:
Call a POISON CENTER or doctor/physician if you feel unwell.
In case of fire: Stop leak if safe to do so.
路 Storage:
Store in a well-ventilated place.
Protect from sunlight. Store in a well-ventilated place.
* 4 First aid measures
路 After inhalation: Supply fresh air; consult doctor in case of complaints.
路 After skin contact: Generally the product does not irritate the skin.
路 After eye contact: Rinse opened eye for at least 15 minutes under running water. Then consult a doctor.
路 After swallowing: Not applicable
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* 5 Fire fighting measures
路 Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
路 Protective equipment: Wear self-contained respiratory protective device.
* 6 Accidental release measures
路 Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventillation.
Eliminate ignition sources
Stop leak - ONLY if possible to do so without risk.
路 Measures for environmental protection: Prevent seepage into sewage system, workpits and/or cellars.
路 Measures for cleaning/collecting: Ensure adequate ventillation.
* 7 Handling and storage
路 Handling:
路 Information for safe handling:
Handle with care. Avoid jolting, friction, and impact.
Use only in well ventilated areas.
Store cylinders upright with valve protection cap in place and firmly secured to prevent falling or being knocked
over.
If difficulty with operating cylinder valve is experienced discontinue use and contact supplier.
路 Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50掳C. Do not pierce or
burn, even after use.
路 Storage:
路 Requirements to be met by storerooms and receptacles:
Do not expose cylinder to temperatures higher than 50掳C (122 掳F)
路 Information about storage in one common storage facility:
Store separately from cylinders containing flammables by a minimum distance of 20' or by a barrier of non-
combustible material at least 5' high having a fire resistant rating of at least 30minutes.
Sources of ignition should be removed from storage area.
路 Further information about storage conditions:
Keep cylinder valve tightly closed.
Store cylinder in a well ventilated area.
Store in accordance with local fire code and/or building code or any pertaining regulations.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems:
Adequate local ventillation.
Safety showers and eyewash stations should be nearby.
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Material Safety Data Sheet
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Trade name: ODOROX MO2
(Contd. of page 3)
路 Components with limit values that require monitoring at the workplace:
124-38-9 Carbon Dioxide (0-5%)
EL Short-term value: 15000 ppm
Long-term value: 5000 ppm
75-18-3 dimethyl sulphide (0-5%)
EL 10 ppm
路 Additional information: The lists that were valid during the creation were used as basis.
路 Personal protective equipment:
路 General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Protective clothing should be kept free of oil and grease.
PPE should be inspected and maintained regularly to retain it's effectiveness.
路 Breathing equipment:
Use atmosphere-supplying respirators (e.g. supplied-air: demand, pressure-demand, or continuous-flow or self-
contained breathing apparatus: demand or pressure-demand or combination supplied-air with auxiliary self-
contained air supply atmosphere-supplying respirator) in case of insufficient ventilation.
路 Protection of hands:
Protective gloves.
路 Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
路 Eye protection: Safety glasses
* 9 Physical and chemical properties
路 General Information
Gaseous.
Form:
Colorless
Color:
Extremely disagreeable.
Odor:
路 Change in condition
Boiling point/Boiling range: -253掳C
路 Flash point: Not applicable.
路 Flammability (solid, gaseous): Contact with combustible material may cause fire.
路 Ignition temperature: 560.0掳C
路 Danger of explosion: Explosive when mixed with combustible material.
路 Explosion limits:
4.0 Vol %
Lower:
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Material Safety Data Sheet
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Trade name: ODOROX MO2
(Contd. of page 4)
75.6 Vol %
Upper:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
路 Dangerous reactions
May react violently with reducing agents.
Violently oxidises organic substances.
May react violently with combustible substances.
路 Dangerous products of decomposition: No dangerous decomposition products known.
* 11 Toxicological information
路 Acute toxicity:
路 LD/LC50 values that are relevant for classification:
75-18-3 dimethyl sulphide
Oral LD50 3300 mg/kg (rat)
Dermal LD50 >5000 mg/kg (rabbit)
Inhalative LC50/4hr 40250 mg/l (rat)
路 Primary irritant effect:
路 on the skin: No irritating effect.
路 on the eye: No irritating effect.
路 Sensitization: No sensitizing effects known.
13 Disposal considerations
路 Product:
路 Recommendation:
Cylinder and unused product should be returned to vendor. Disposable cylinder must be disposed of in
accordance with local regulations.
路 Uncleaned packagings:
路 Recommendation:
Cylinder and unused product should be returned to vendor. Disposable
cylinder must be disposed of in accordance with local regulations.
路 Recommended cleansing agent: None applicable.
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Trade name: ODOROX MO2
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* 14 Transport information
路 TDG and DOT regulations:
路 Hazard class: 2
路 Identification number: UN3156
路 Proper shipping name (technical name): COMPRESSED GAS, OXIDIZING, N.O.S.
路 Label 2.2 + 5.1
路 Maritime transport IMDG:
路 IMDG Class: 2
路 UN Number: 3156
路 Label 2.2 + 5.1
路 Marine pollutant: No
路 Propper shipping name: COMPRESSED GAS, OXIDIZING, N.O.S.
路 Air transport ICAO-TI and IATA-DGR:
路 ICAO/IATA Class: 2.1
路 UN/ID Number: 3156
路 Label 2.2 + 5.1
路 Propper shipping name: COMPRESSED GAS, OXIDIZING, N.O.S.
路 UN "Model Regulation": UN3156; COMPRESSED GAS, OXIDIZING, N.O.S.; 2.2 ( 5.1)
* 15 Regulations
路 Sara
路 Section 355 (extremely hazardous substances):
None of the ingredient is listed.
路 Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
路 TSCA (Toxic Substances Control Act):
All ingredients are listed.
(Contd. on page 7)
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Material Safety Data Sheet
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Trade name: ODOROX MO2
(Contd. of page 6)
路 Proposition 65
路 Chemicals known to cause cancer:
None of the ingredients is listed.
路 Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
路 Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
路 Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
路 Cancerogenity categories
路 EPA (Environmental Protection Agency)
None of the ingredients is listed.
路 NTP (National Toxicology Program)
None of the ingredients is listed.
路 TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
路 NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
路 OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
路 Canadian substance listings:
路 Canadian Domestic Substances List (DSL)
All ingredients are listed.
路 Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
路 Canadian Ingredient Disclosure list (limit 1%)
124-38-9 Carbon Dioxide
路 Product related hazard informations:
The product was classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations (CPR) and the MSDS contains all the information required by the CPR.
路 Hazard symbols:
Oxidizing
路 Risk phrases:
Contact with combustible material may cause fire.
路 Safety phrases:
Keep container tightly closed in a cool place.
Keep away from combustible material.
This material and its container must be disposed of as hazardous waste.
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Trade name: ODOROX MO2
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* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
路 Department issuing MSDS: Customer Service Centre: 1-866-385-5349
路 Contact: Canada Technical Services: 1-866-385-5349
路 Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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