Lion Oil Company
Product UNLEADED GASOLINE Revision No. 3
MSDS No. LO0002 Date of Preparation: 8/22/01
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Gasoline, Unleaded
Chemical Formula:
CAS Number: 8006-61-9
Synonyms: 84 Octane Sub Grade, 87 Octane Regular, 89 Octane Mid Grade, 91 Octane Premium, 92 Octane
Premium, 93 Octane Premium
Description: Clear or light yellow colored liquid with characteristic hydrocarbon odor.
Manufacturer or Distributor: Lion Oil Co. , 1000 McHenry St. ,El Dorado, AR 71730; (870) 862-8111
24-hr Emergency Phone Number: 鈥淔OR CHEMICAL EMERGENCY鈥? Spill, Leak, Fire, Exposure or Accident
CALL CHEMTREC 鈥? Day or Night 800-424-9300
Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number % vol
Gasoline, including: 8006-61-9 100
Benzene 71-43-2 0-4.9
Toluene 108-88-3 5-15
Xylenes (mixed isomers) 1330-20-7 5-14
Cyclohexane 110-82-7 0-1
Ethylbenzene 100-41-4 0-3
Hexane 110-54-3 0-5
Trimethylbenzene 95-63-6 0-3
Naphthalene 91-20-3 0-1
Cumene 98-82-8 0-1
Section 3 - Hazards Identification
露露露露露 Emergency Overview 露露露露露 HMIS
1
H
DANGER! 3
F
Volatile and Flammable Liquid R 0
Keep Away From Ignition sources. Gasoline Vapors are heavier than Air and may PPE鈥?
鈥燬ec. 8
Travel some distance to an ignition source and flash back.
CONTAINS BENZENE; Long-Term, repeated exposure to gasoline may cause
Cancer, Blood and Nervous System Damage
HARMFUL OR FATAL IF SWALLOWED 鈥? Can enter lungs and cause damage
May cause eye and skin irritation.
Use as a motor fuel only. Never use as a solvent.
露露露露露 露露露露露
Potential Health Effects
Primary Entry Routes: Inhalation, Skin Absorption, Ingestion, Skin and/or Eye contact.
Target Organs: Eyes, Skin, Respiratory System, Central Nervous System, Liver, and Kidneys
8/22/01 MSDS No. LO0002 UNLEADED GASOLINE
Carcinogenicity: The International Agency for Research on Cancer (IARC) has determined that gasoline is possibly
carcinogenic to Humans (Group 2B). Contains Benzene which has been designated a carcinogen by IARC (group
1), NPT, and OSHA.
Medical Conditions Aggravated By Long-Term Exposure:
Benzene 鈥? Individuals with liver disease may be more susceptible to toxic effects.
Hexane 鈥? Individuals with neurological disease should avoid exposure.
Petroleum Hydrocarbons 鈥? Skin contact may aggravate an existing dermatitis.
Acute Effects
Inhalation: Inhalation causes intense burning of mouth, throat, and respiratory tract. Can cause headaches,
dizziness, drowsiness, convulsions, coma, cyanosis and generalized depression. Large amounts in lungs could
cause pulmonary edema, which can be fatal.
Eye: Eye contact causes tearing, redness and severe irritation.
Skin: Skin contact from prolonged or frequent exposure to liquids or vapors can cause irritation and dermatitis.
Ingestion: Do Not Induce Vomiting. May be harmful or fatal if swallowed. Ingestion can caused blurred vision,
vertigo, vomiting and cyanosis. Seek medical attention.
Chronic Effects: Benzene has been classified as a leukemogen and may produce anemia, leukemia from repeated or
prolonged exposure to high concentrations.
Section 4 - First Aid Measures
Inhalation: Move to fresh air. If overcome by vapor, remove from exposure and call a physician immediately. If
breathing is irregular or has stopped, start resuscitation, administer oxygen, if available. Seek medical attention.
Eye Contact: Flush with water for 15 minutes. Contact doctor for additional advice.
Skin Contact: Remove any contaminated clothing and wash skin with soap and water, launder or dry-clean clothing
before reuse.
Ingestion: Section Do not induce vomiting. If spontaneous vomiting is about to occur, place victim鈥檚 head below
knees. Seek medical attention.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Section 5 - Fire-Fighting Measures
Flash Point: -45 F
Flash Point Method: TCC
Autoignition Temperature: > 536 F
LEL: 1.4 %
UEL: 7.6 %
Flammability Classification: Flammable Liquid Class 1B
Extinguishing Media: Dry chemical, Halon, CO2, foam, water. Water may not be effective and water fog can be
used to cool containers. Water may splash and spread flaming liquid.
Unusual Fire or Explosion Hazards: Keep away from heat, sources of ignition and strong oxidizers. Can react
violently with oxidizing agents.
Hazardous Combustion Products: Fumes, smoke carbon monoxide, sulfur oxides, aldehydes and other
decomposition products, in the case of incomplete combustion
Special Fire-Fighting Procedures: Vapors can readily form explosive mixtures with air. Heavier than air vapors can
flow along surfaces to ignition sources and flash back. Used self contained breathing in enclosed areas.
Section 6 - Accidental Release Measures
鈥淔OR CHEMICAL EMERGENCY鈥? Spill, Leak, Fire, Exposure or Accident
CALL CHEMTREC 鈥? Day or Night 800-424-9300
Spill /Leak Procedures: Danger, Flammable, eliminate all ignition sources. Equipment use in spill cleanup must be
grounded to prevent sparking.
Small Spills: Take up with an absorbent material and place in containers, seal tightly for proper disposal.
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8/22/01 MSDS No. LO0002 UNLEADED GASOLINE
Large Spills: Isolate the hazard area and restrict entry to unnecessary personnel. Shut off source of leak only if it
can be done so safely or dike and contain the spill. Wear appropriate respirator and protective clothing. Water fog
may be useful in suppressing vapor cloud contain run-off. Remove with vacuum trucks. Soak up residue with sand
or other suitable material, place in containers for proper disposal. Flush with water and disposal of flushing
solutions as above. Local, state and federal disposal regulations must be followed.
Regulatory Requirements: Recovered non-usable material is regulated by the US EPA as a hazardous waste due
to its ignitibility characteristics (D001) and its benzene content (D018).
Section 7 - Handling and Storage
Handling Precautions: Do not get in eyes, on skin or on clothing. Do not breathe vapors, mists or fumes. Wear
protective equipment described in section 8 is exposure conditions warrant. Use only with adequate ventilation.
Storage Requirements: Keep away from open flame, high temperatures, sparks, pilot lights, static electricity, open
flames and other sources of ignition. Store in well ventilated area. Store in tightly closed containers. Bond and
ground containers during transfer of gasoline.
Section 8 - Exposure Controls / Personal Protection
OSHA PEL ACGIH TLV NIOSH REL NIOSH
Ingredient TWA STEL TWA STEL TWA STEL IDLH
Gasoline 300 ppm 500 ppm
Benzene 1 ppm 5 ppm 0.5 ppm 2.5 ppm 0.1 ppm 1.0 ppm 500 ppm
Toluene 200 ppm 300 ppm 50 ppm 100 ppm 150 ppm 500 ppm
Xylenes (mixed 100 ppm 100 ppm 150 ppm 100 ppm 150 ppm 900 ppm
isomers)
Cyclohexane 300 ppm 300 ppm 300 ppm 1300 ppm
Ethylbenzene 100 ppm 100 ppm 125 ppm 100 ppm 125 ppm 800 ppm
Hexane 500 ppm 50 ppm 50 ppm 1100 ppm
Trimethylbenzene N. D. 25 ppm 25 ppm N. D.
Naphthalene 10 ppm 10 ppm 15 ppm 10 ppm 15 ppm 250 ppm
Cumene 50 ppm 50 ppm 50 ppm 900 ppm
Engineering Controls
Ventilation: Provide explosion proof ventilation to meet TLV requirements in enclosed work areas.
Protective Clothing/Equipment
Gloves: Use chemical resistant gloves to prevent skin contact.
Goggles: Wear chemical goggles if eye contact is likely.
Respiratory: Use organic vapor cartridge respirators for exposures over TLV up to 1000 ppm. Use fresh air or self
contained breathing equipment for unknown or high concentrations.
Contaminated Equipment: Launder or dry-clean contaminated clothing before reuse.
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8/22/01 MSDS No. LO0002 UNLEADED GASOLINE
Section 9 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Negligible
Appearance and Odor: Clear and light yellow Other Solubilities: No Data
with characteristic light hydrocarbon odor. Boiling Point: 80 鈥? 430 F
Odor Threshold: No Data Freezing/Melting Point: NA
Vapor Pressure: 8.5 鈥? 15.0 psi @ 100 F Viscosity: No Data
Refractive Index: No Data
Vapor Density (Air=1): 3 - 4
Surface Tension: No Data
Formula Weight: No Data
% Volatile: 100%
Density:
Evaporation Rate: >1 (Butyl Acetate = 1)
Specific Gravity (H2O=1, at 4 掳C): 0.70 鈥?
0.77
pH: NA
Section 10 - Stability and Reactivity
Stability: This Material is Stable.
Polymerization: Hazardous Polymerization will not occur.
Chemical Incompatibilities: Keep away from Oxidizing agents.
Conditions to Avoid: Keep away from open flame, high temperatures, and other sources of ignition.
Hazardous Decomposition Products: Fumes, smoke carbon monoxide, sulfur oxides, aldehydes and other
decomposition products, in the case of incomplete combustion
Section 11- Toxicological Information
Eye Effects: man 500 ppm / 1hour Inhalation Effects: Man TCLo:900 ppm / 1 hour: eye effects,
Moderate irritation effects Central nervous system effects, Pulmonary system effects
Human 140 ppm / 8 hour mild irritation Acute Oral Effects:
effects LD50 (rat)=0.5 to 5 g/kgs
Skin Effects: Repeated or chronic dermal As little as 10-15 g may be lethal in children.
Chronic Effects:
contact may result in drying of the skin,
Carcinogenicity: IARC possible human carcinogen, rating 2B
lesions, and other dermatologic conditions.
Benzene, IARC known carcinogen to humans, rating 1
Section 12 - Ecological Information
Aquatic Toxicity: 90 ppm/24hr/juvenile American shad/TLm/fresh water; 91 mg/l/24hr/juvenile American
shad/TLm/salt water
Section 13 - Disposal Considerations
Disposal: Local, state and federal disposal regulations must be followed.
Disposal Regulatory Requirements: Recovered non-usable material is regulated by the US EPA as a hazardous
waste due to its ignitibility characteristics (D001) and its benzene content (D018).
Container Cleaning and Disposal: 鈥淓mpty鈥? Container Warning: . 鈥淓mpty鈥? containers retain product residue (liquid
and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
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8/22/01 MSDS No. LO0002 UNLEADED GASOLINE
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101):
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description information.
DOT Shipping Name: Gasoline
DOT Hazard Class: 3
DOT ID No.: UN1203
DOT Packing Group: II
Hazard Label: Flammable Liquid
Section 15 - Regulatory Information
.
EPA Regulations:
RCRA Hazardous Waste Number: D001
RCRA Hazardous Waste Classification (40 CFR 261): D018
CERCLA Reportable Quantity (RQ) (40 CFR 302.4):
Compound CAS Number RQ
Benzene 71-43-2 10
Toluene 108-88-3 1000
Xylenes (mixed isomers) 1330-20-7 100
Cyclohexane 110-82-7 1000
Ethylbenzene 100-41-4 1000
Hexane 110-54-3 5000
Trimethylbenzene 95-63-6 -----
Naphthalene 91-20-3 100
Cumene 98-82-8 5000
SARA 311/312 Codes (40 CFR 370 / 29 CFR 1910.1200): Fire YES
Pressure NO
Reactivity NO
Immediate (acute) YES
Delayed (chronic) YES
SARA Toxic Chemical (40 CFR 372) Section 313:
Compound CAS Number Concentration %
Benzene 71-43-2 0-4.9
Toluene 108-88-3 5-15
Xylenes (mixed isomers) 1330-20-7 5-14
Cyclohexane 110-82-7 0-1
Ethylbenzene 100-41-4 0-3
Hexane 110-54-3 0-5
Trimethylbenzene 95-63-6 0-3
Naphthalene 91-20-3 0-1
Cumene 98-82-8 0-1
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed
TSCA (40 CFR 710): This product, or its components are listed on the Toxic Substance Control Act (TSCA)
Chemical Substance Inventory.
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8/22/01 MSDS No. LO0002 UNLEADED GASOLINE
State Regulations: The following chemicals are specifically listed by individual states, for details on each states
regulatory requirements you should contact the appropriate agency in that state.
Compound CAS Number States
Benzene 71-43-2 CA, CA65, MA, NY, NJ, TX, FL, Il, PA
Toluene 108-88-3 CA, CA65, MA, NJ, TX, FL, IL, PA
Xylenes (mixed isomers) 1330-20-7 CA, MA, NY, NJ, TX, FL, IL, PA
Cyclohexane 110-82-7 CA, MA, NJ, TX, FL, IL, PA
Ethylbenzene 100-41-4 CA, MA, NJ, TX, FL, IL, PA
Hexane 110-54-3 CA, MA, TX, FL, IL, PA
Trimethylbenzene 95-63-6 MA, TX, FL, PA
Naphthalene 91-20-3 CA, MA, NJ, TX, FL, IL, PA
Cumene 98-82-8 CA, MA, NJ, TX, FL, IL, PA
CA 鈥? CALIFORNIA STATE SUPERFUND HAZARDOUS SUBSTANCE
CA65 鈥? CALIFORINA PROPOSITION 65 CARCINOGENS OR REPRODUCTIVE TOXINS
MA 鈥? MASSACHUSETTS SUBSTANCE LIST
NY 鈥? NEW YORK HAZARDOUS SUBSTANCE BULK STORAGE LIST
NJ 鈥? NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE
TX 鈥? TEXAS AIR CONTAMINANTS WITH HEALTH EFFECTS SCREENING LEVEL
FL 鈥? FLORIDA TOXIC SUBSTANCE LIST
IL 鈥? TOXIC SUBSTANCE DISCLOSURE TO EMPLOYEES LIST
PA 鈥? PENNSYLVANIA HAZARDOUS SUBSTANCE LIST
SECTION 16 - Other Information
Prepared By: Bobby Lee, 8/22/01
Revision Notes: All sections revised and converted to ANSI Z400.1 16 section format.
Disclaimer: LION OIL COMPANY PROVIDES THIS INFORMATION FOR THE USER'S CONSIDERATION.
LION OIL COMPANY BELIEVES THIS INFORMATION IS ACCURATE, BUT NOT ALL INCLUSIVE IN ALL
CIRCUMSTANCES. USER SHOULD ENSURE THAT USER HAS CURRENT DATA RELEVANT FOR ITS
PURPOSES. NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING MERCHANTABILITY, FITNESS
OR OTHERWISE IS GIVEN.
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