Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Identification of the Substance:
Trade Name: TOMATO OIL 010
Chemical Name: Mixture of flavor ingredients.
Use of the Substance:Flavor ingredient
Company Identification:
_______________________________________________________________________
Millennium Specialty Chemicals Inc. Lyondell European Headquarter
a Lyondell Company Millennium Chemicals
P.O. Box 389 C/O N.V. SCM EUROPE S.A.
Jacksonville, FL 32201, USA Avenue Ariane, 5/ 2F
Telephone: 904-768-5800 B-1200 Brussels-Belgium
Fax:904-768-2200 Telephone: +32.2.774.25.10 Fax:+32.2.774.25.77
_______________________________________________________________________
Emergency Telephone: CHEMTREC: (USA, Canada): 1-800-424-9300 ;(All Others): 703-527-3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Typical
CAS Number EINECS Number Ingredient Weight %
57-55-6 200-309-2 PROPYLENE GLYCOL > 50
75-18-3 200-846-2 DIMETHYL SULFIDE 1-10
EU Classifications (refer to Section 16 for descriptions):
Symbol(s) Risk Phrase Code(s) Safety Phrase Code(s)
Xi R(10)-36/38 S24/25
3. HAZARDS IDENTIFICATION
This substance is classified as dangerous according to EU Directive 1999/45/EC.
Potential Health Effects
Acute Health Effects:
Contact with the undiluted material may cause eye and skin irritation.
Chronic Health Effects:
Not Determined.
4. FIRST AID MEASURES
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 1 of 6
Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
Inhalation:
Seek fresh air immediately. If breathing is difficult, seek medical advice.
Eye Contact:
Flush with water for at least 15 minutes. If irritation develops, get
medical attention.
Skin Contact:
Remove contaminated clothing. Wash affected areas with plenty of soap and
water. If irritation develops, seek medical advice.
Ingestion:
Drink lots of water to dilute substance. Get medical attention immediately
or contact a poison control center for advice.
5. FIRE FIGHTING MEASURES
Suitable Fire Extinguishing Media:
Carbon dioxide, dry chemical, foam.
Unsuitable Fire Extinguishing Media:
If water must be used, use as a spray only.
Special Exposure Hazards:
Flammable liquid. Avoid heat, sparks and open flames.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, oxides of sulfur, acrid fumes.
Special Protective Equipment for Fire Fighters:
Standard turnout gear for flammable liquids.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Standard turnout gear for flammable liquids.
Environmental Precautions:
Do not allow the substance or solutions of the substance to be discharged
into lakes, streams, ponds or public waters.
Cleanup Procedures:
Small spills should be absorbed by dirt, sand, or other absorbent. Large
spills may be pumped into containers for recovery/disposal.
7. HANDLING AND STORAGE
Handling:
Wear safety glasses or goggles, rubber gloves and apron when handling
material. If transferring to or from the container, use proper
grounding procedures.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 2 of 6
Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
Storage:
Do not store in close proximity to excessive heat, open flames, strong
acids or strong bases. To minimize product degradation, avoid prolonged
exposure of the substance to air. Keep container tightly closed when
not in use.
Ventilation:
Mechanical exhaust may be needed in confined and poorly ventilated areas.
Safety Stations:
An eyewash station and a safety shower should be readily available and
clearly marked.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits:
None found.
Exposure Controls:
Respiratory Protection:
A respirator is not normally required. If vapor concentration is suspected
to be high, use a NIOSH approved organic vapor respirator
Eye Protection:
Wear safety glasses or goggles.
Hand Protection:
Wear standard industrial type rubber gloves.
Skin Protection:
A rubber apron is recommended when handling the material for extended
periods of time.
Personal Hygiene:
Wash hands and other exposed areas of skin with soap and water after
handling the material.
Environmental Controls:
No environmental exposure controls required under Community environmental
protection laws.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information:
Property Result
Appearance: Nearly colorless liquid.
Odor: Strong tomato.
Important Health, Safety and Environmental Information:
Property Result
pH: Not determined.
Boiling Point: 369F (187C) (Distillation)
Flash Point: 72F (22C) (Tag Closed Cup)
Melting Point: Not determined.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 3 of 6
Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
Flammability: Not determined.
Explosive Properties: Not an explosive.
Oxidizing Properties: Not determined.
Vapor Pressure: Not determined.
Solubility in Water (Weight%): 100
Solubility in Alcohol(Weight%): 100
Fat Solubility: Not determined.
Partition Coefficient (n-Octanol/Water): Not determined.
Viscosity: Not determined.
Vapor Density (air=1): Not determined.
Evaporation Rate (Butyl Acetate=1): Not determined.
Autoignition Temperature: Not determined.
Specific Gravity: 1.024 @ 25 C
10. STABILITY AND REACTIVITY
Stability:
Substance is stable and unreactive under conditions of normal use.
Conditions to Avoid:
Prolonged or excessive heat and/or exposure to air may cause non-hazardous
decomposition and/or oxidation of the substance.
Materials to Avoid:
Avoid contact with strong acids, strong bases, and materials that react
with glycols and sulfides.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, oxides of sulfur, acrid fumes.
11. TOXICOLOGICAL INFORMATION
Primary Target Organs: Eyes, skin.
Primary Entry Route(s): Eyes, Skin.
Medical Conditions Aggravated by Overexposure No known conditions.
Acute Toxicity:
Parameter Result
Acute Oral Toxicity: Not determined.
Acute Inhalation Toxicity: Not determined.
Acute Dermal Toxicity: Not determined
Eye Irritancy: Contact with the undiluted material may cause irritation.
Dermal Irritancy: Contact with the undiluted material may cause irritation.
Skin Sensitization: Not determined.
Mutagenicity: Not determined
Teratogenicity: Not determined.
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not determined.
Mobility: Not determined.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 4 of 6
Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
Persistence and Degradability: Not determined.
Bioaccumulation Potential: Not determined.
Ozone Depleting Substances: None.
Volatile Organic Compounds: Not determined.
13. DISPOSAL CONSIDERATIONS
Disposal Methods: This material, if discarded, is considered a hazardous waste by EPA
regulations 40 CFR 261.
Safe Handling of Wastes: Refer to Section 8 for information pertaining to personal protective
equipment and exposure controls when handling this material for
disposal.
Community Provisions: Dispose of this material at a local, state or federally approved landfill,
incinerator or recovery facility.
14. TRANSPORT INFORMATION
DOT Non-Bulk Shipping Name: Flammable Liquid, n.o.s.(Contains Dimethyl Sulfide), 3,
UN1993, PGII
DOT Bulk Shipping Name: Flammable Liquid, n.o.s.(Contains Dimethyl Sulfide), 3,
UN1993, PGII
DOT Label(s): FLAMMABLE LIQUID
ADR/RID Classification: 1993 Flammable Liquid, n.o.s.; 3,3 (b),ADR
IATA Classification: Flammable Liquid, n.o.s.(Contains Dimethyl Sulfide), 3,
UN1993, PGII
IMDG Classification: 3.2
Marine Pollutant: No.
NAERG Number: 128
15. REGULATORY INFORMATION
Chemical Inventories Status:
USA (TSCA): Compliant
European Community (EINECS): Compliant
Canada (DSL): Compliant
Australia (AICS): Compliant
Japan (IEC): Not Compliant
Korea (KECI/ECL): Not Compliant
Philippines (PICCS): Compliant
China (SEPA/CICS): Compliant
USA: Federal:
SARA Title III Section 302/304: None.
SARA Title III Section 311/312: Yes.
SARA Title III Section 313: None.
Hazardous Air Pollutants: None.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 5 of 6
Product Code 40N93AS
Revision Date 11/27/2002
Material Safety Data Sheet Supersedes 04/29/2002
USA: States:
Dimethylsulfide; CAS No. 75-18-3; 4%: Massachusetts Hazardous Substance
List / New Jersey RTK / Pennsylvania Hazardous Substance List
Propyleneglycol; CAS No. 57-55-6; 95.4%: Pennsylvania Hazardous
Substance List
International:
16. OTHER INFORMATION
EU Classifications:
Symbol Code(s): Symbol Phrase(s):
Xi IRRITANT
Risk Phrase Codes: Risk Phrases:
R(10)-36/38 Flammable. Irritating to skin and eyes.
Safety Phrase Codes: Safety Phrases:
S24/25 Avoid contact with eyes and skin.
U.S. NPCA/HMIS Hazardous Materials Information System
Health Flammability Reactivity Personal Protection*
1 3 1 C
0 - Minimal Hazard: No significant risk to health.
1 - Slight Hazard: Irritation or minor reversible injury possible.
2 - Moderate Hazard: Temporary or minor injury may occur.
3 - Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given.
4 - Severe Hazard: Life-threatening, major or permanent damage mayresult from single or repeated exposures.
* This rating will generally suffice for normal operating conditions.Please note however, that the type of personal
protection utilized may change based on specific use conditions (refer to Section 8).
Reason(s) for (Re)issue:
Format change per 2001/58/EC.
Technical Contact(s):
Environmental and Regulatory Affairs Dept.
References:
RIFM - Research Institute for Fragrance Materials RTECS- Registry of Toxic Effects of Chemical Substances
Acronyms: NTP(National Toxicology Program); IARC (International Agency for
Research on Cancer); OSHA (Occupational Health and Safety
Administration); DOT (U.S. Dept. of Transportation); NIOSH (National
Institute of Occupational Safety and Health)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 6 of 6
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