MATERIAL SAFETY DATA SHEET
SECTION I: IDENTIFICATION OF PRODUCT
Diversity Technologies Corp.
COMPANY: DATE: Dec. 14, 2004
rd
PHONE: 780-468-4064
8750 鈥? 53 Ave.
FAX: 780-469-1899
Edmonton, AB T6E 5G2
SUPER-LIG (Lignite)
PRODUCT NAME:
PRODUCT USE: Oil well drilling fluid additive.
CHEMICAL FAMILY: Natural mineral; leonardite CAS #: 1415-93-6
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
WHMIS CLASSIFICATION: D2A
WORKPLACE HAZARD: Potential carcinogen; contains free silica
TRANSPORTATION OF DANGEROUS GOODS (TDG)
PROPER SHIPPING NAME: Not regulated under TDG
TDG CLASSIFICATION: Not applicable
UN NUMBER (PIN): Not applicable
PACKING GROUP: Not applicable
SECTION II: HAZARDOUS INGREDIENTS
INGREDIENT PERCENT CAS NUMBER LD50Oral-Rat LC50Inhal-Rat ACGIH-TLV
0.1 mg/m3
Crystalline silica, quartz 1-2 14808-60-7 Not available Not available
SECTION III: HEALTH HAZARDS
[ ] EYE CONTACT [ ] SKIN [XX] INHALATION [ ] INGESTION
ROUTE OF ENTRY:
EYE CONTACT: May cause mechanical irritation.
SKIN CONTACT: Prolonged or repeated contact may irritate skin in some individuals.
INGESTION: No toxic effects expected.
INHALATION: May of dust may cause irritation of the upper respiratory tract. Long-
term inhalation of crystalline silica may not cause noticeable injury or
illness even though permanent lung damage may be occurring. Long-
term inhalation may cause silicosis, a progressive, disabling and,
sometimes, fatal lung disease. Chronic inhalation exposure to
crystalline silica quartz has been observed to cause lymph node effects,
kidney effects and auto-immune disease.
Super-Lig (Lignite) Page 2 of 4
CARCINOGENICTY: Crystalline silica when inhaled in the form of quartz or crystobalite from
occupational sources is carcinogenic to humans: The International
Agency for Research on Cancer (IARC) has concluded that this
chemical is carcinogenic to humans (Group 1). The American
Conference of Governmental Industrial Hygienists (ACGIH) has
designated this chemical as a suspected human carcinogen (A2). The
US National Toxicology Program (NTP) has listed this chemical as a
known human carcinogen.
TERATOGENICITY: No information available.
REPRODUCTIVE
No information available.
TOXICITY:
MUTAGENICTY: Crystalline silica has been shown to cause mutagenic effects in human
cells in-vitro.
SYNERGISTIC
No information available.
PRODUCTS:
SECTION IV: FIRST AID MEASURES
SKIN CONTACT: If irritation occurs or at the end of shift, wash with soap and water until
clean. Obtain medical attention if irritation persists.
EYE CONTACT: Flush eyes with gently flowing warm water until particles are removed.
If irritation persists obtain medical attention.
INGESTION: If large amounts are swallowed, obtain immediate medical attention.
INHALATION: Move victim to fresh air. Apply oxygen or artificial respiration if
required. If breathing difficulties or distress continues, obtain medical
attention.
SECTION V: PHYSICAL DATA
APPEARANCE AND ODOUR: Dark brown to black powder or granules; little odour
SPECIFIC GRAVITY: 1.5
Not applicable
BOILING POINT (掳C):
Not applicable
MELTING POINT (掳C):
SOLUBILITY IN WATER: Slight pH: 3.5-5.0 (2 g/100 mL H2O)
PERCENT VOLATILE BY VOLUME: Not available
EVAPORATION RATE: Not applicable
VAPOUR PRESSURE (mmHg): Not applicable
VAPOUR DENSITY (air = 1) Not applicable
BULK DENSITY: Not available
Super-Lig (Lignite) Page 3 of 4
SECTION VI: FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: >400掳F (Cleveland Cup)
FLAMMABLE LIMITS: Not applicable
EXTINGUISHING MEDIA: Water fog, foam, rock dust.
SPECIAL FIRE FIGHTING Self-contained breathing apparatus required for fire
PRODCEDURES: fighting personnel. Move containers from fire area,
if possible.
UNUSUAL FIRE AND May explode if dust is suspended in air and ignition
EXPLOSION HAZARDS: source is present. Granules burn similar to coal or
wood.
SECTION VII: REACTIVITY DATA
STABILITY: STABLE [XX] UNSTABLE [ ]
INCOMPATIBILITY NIOSH approved dust mask recommended. Use
(CONDITIONS TO AVOID): approved respirator for silica bearing dust if
concentration of airborne dust exceeds TLV.
CONDITIONS OF REACTIVITY: Not available.
HAZARDOUS DECOMPOSITION Oxides of carbon, oxides of sulphur and
PRODUCTS: hydrocarbons may be produced on combustion.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR [XX] MAY OCCUR [ ]
SECTION VIII: PREVENTATIVE MEASURES
SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: NIOSH approved dust mask recommended. Use
approved respirator for silica bearing dust if
concentration of airborne dust exceeds TLV.
VENTILATION: General mechanical sufficient for normal conditions
for use. Use local exhaust ventilation, process
enclosure or other engineering controls to maintain
dust levels below TLV.
PROTECTIVE GLOVES: Not required; personal preference.
EYE PROTECTION: Safety glasses with side shield or goggles are
recommended.
OTHER PROTECTIVE EQUIPMENT As appropriate to prevent contact with body. Ensure
(Specify): eyewash station and emergency shower are available.
Super-Lig (Lignite) Page 4 of 4
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Do not breathe dust. Use normal precautions against bag breakage or spills of bulk material.
Avoid creation of respirable dust. Use good housekeeping in storage and use areas to prevent
accumulation of dust in work areas. Use adequate ventilation and dust collection. Maintain and
use proper, clean respiratory equipment. Launder clothing that has become dusty. Empty
containers (bags, bulk containers, storage tanks, etc.) retain silica residue and must be handled in
accordance with the provision of this MSDS. Store in a cool, dry area.
STEPS TO BE TAKEN IN CASE THE MATERIAL IS SPILLED OR RELEASED
Use appropriate safety equipment. Eliminate ignition sources. Avoid creating dust clouds.
Vacuum if possible to avoid generating airborne dust. Collect uncontaminated material for
repackaging. Collect contaminated material in approved containers for disposal.
WASTE DISPOSAL METHOD
Dispose of in accordance with federal, provincial and local regulations. It is the responsibility of
the end-user to determine if material meets the criteria of hazardous waste at the time of disposal.
Empty packaging must be recycled or disposed of according to local regulations.
SECTION IX: PREPARATION
THE INFORMATION CONTAINED HEREIN IS GIVEN IN GOOD FAITH,
BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.
DATE ISSUED: December 14, 2004 BY: Product safety committee
SUPERSEDES: January 5, 2004 PHONE: 780-440-4923
Diversity Technologies Corp. is the parent company of
Canamara-United Supply, Hollimex Products and The Drilling Depot
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