SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET PP 318
Threshold Limited Value None established for this mixture. (ACGIH 1983-84).
ALDON 1533 W.Henrietta Rd.
Thiram: [CAS No. 137-26-8] TWA: 5 mg/m3 ; STEL: 10 mg/m3.
PP 318
Avon, New York 14414 MSDS No.
CORPORATION January 10, 1992
Effective Date
(716) 226-6177 As dust may cause irritation of nose, throat and skin. May be harmful if inhaled (as dust) or
Effects of Overexposure swallowed. Do not breathe dust, spray, mist. Avoid contact with eyes, skin or clothing.
Cases of allergic contact eczema have been reported. Thiram is the primary cause of ill
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE effects of this product. To the best of our knowledge, the chemical, physical and
toxicological properties have not been thoroughly investigated. Exercise appropriate
CHEMTREC
Product PLANT GROWTH HORMONE WITH FUNGICIDE
procedures to minimize potential hazards.
800-424-9300 2
Health
Chemical Emergency and
庐
Gibberellic Acid with Thiram Day 716-226-6177
Synonyms 0
Fire
First Aid Procedures
Night 716-334-4222 INGESTION: If swallowed, if conscious, give one or two glasses of water to
Formula C 19H 22O6 /C6H12N 2S4 /H2O 0
Reactivity drink, induce vomiting. Repeat until vomit fluid is clear. Call physician
NFPA
Unit(s) Size immediately. Never give anything by mouth to an unconscious person.
HAZARD RATING
50, 100, 500 mL.
SKIN: Flush with water, then wash with mild soap and water. EYES: Flush
LEAST SLIGHT MODERATE HIGH EXTREME
C.A.S. No. 0 1 2 3 4 thoroughly with water for at least 15 minutes, lifting lower and upper eyelids
77-06-5 (Gibberellic Acid)
occasionally. Get medical attention. INHALATION: If inhaled as dust or
SECTION II HAZARDOUS INGREDIENTS OF MIXTURES mist, remove to fresh air, treat symptomatically and get medical attention.
SECTION VI REACTIVITY DATA
Principal Hazardous Component(s) % TLV Units
Unstable Conditions to Avoid
Stability
Gibberellic Acid: (CAS No. 77-06-5) 0.1% None established. Excessive temperature or heat.
Stable X
3
Incompatibility
Thiram: (CAS No. 137-26-8) 3.8% TWA: 5 mg/m
Strong oxidizers.
(Materials to Avoid)
Water: (CAS No. 7732-18-5) 96.1%
Hazardous When heated to decomposition, emits toxic fumes of oxides of nitrogen (NOx)
CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION TO SKIN AND EYES.
Decomposition Products and oxides of sulfur (SOx).
SECTION III PHYSICAL DATA
Hazardous Polymerization Conditions to Avoid
Melting Point (掳F) Specific Gravity (H2 O = 1)
Freezes approx. 0掳C (32掳F) Approx. 1.0
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Approx. 100掳C (212掳F) 96%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 14 (water) Ether =1) Water solvent greater than 1.
(
Steps to be taken in case
Vapor Density (Air=1) 0.7 (water)
Small spills: Flush to sewers with copious amounts of water. Large
material is released or spilled
spills: Absorb in paper, vermiculite, sand, earth. Place in a suitable
Solubility in Water Thiram portion of mixture is insoluble in water.
container. Incinerate. Wash spill area with soap and water.
Appearance & Odor White to tan colored slurry when mixed; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
SECTION IV FIRE AND EXPLOSION HAZARD DATA Waste Disposal Method These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flash Point Flammable Limits in Air Upper
(Method Used) % by Volume
Non-flammable (NA). NA -------- -------- Dispose of in an approved incinerator equipped with an afterburner and scrubber.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use any media suitable for extinguishing supporting fire.
Media
None needed in normal laboratory handling. If misty conditions prevail, work in ventilation
Respiration Protection
(Specify Type) hood or wear a NIOSH-approved respirator.
SPECIAL FIREFIGHTING
Yes. No.
Local Exhaust Special
PROCEDURES
Ventilation Mechanical (General) Other
Recommended. No.
In fire conditions, wear a NIOSH-approved self-contained breathing
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
apparatus and full protective clothing.
Other Protective
Smock, apron, eye wash station, proper gloves, proper ventilation.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool place. Shake container before use.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
When heated to decomposition, emits toxic fumes of oxides of
nitrogen (NO ) and oxides of sulfur (SO ). Avoid contact with eyes, skin and clothing.
x x
Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Date
Rev. No. 1/10/92
No. 2 Alexander A. Piccirilli AP
Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered
by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 safety and health of employees.
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