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MSDS Material Safety Data Sheet
CAS

111-76-2
126-86-3

File Name: MSDS_7210_US_15Mar05.asp
                                                                                                                    Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

1 Identification of substance

Product details

Trade name: 7210
Application of the substance / the preparation: Defoamers, Anti-foaming agent

Manufacturer/Supplier:
Kester Tel.(847) 297-1600
515 E. Touhy Ave. Fax.(847) 390-9338
Des Plaines, IL 60018

Information department:
MSDS Coordinator Tel. (847) 699-5755
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number: (800)424-9300
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada): (703)527-3887


2 Composition/Data on components

Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
111-76-2 2-butoxyethanol 50-100%
126-86-3 2,4,7,9-tetramethyldec-5-yne-4,7-diol 10-25%


3 Hazards identification

WHMIS Hazard Symbols



:=
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
NFPA ratings (scale 0 - 4)
Health = 2
2 Fire = 2
2 0 Reactivity = 0
(Contd. on page 2)
USA




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Page 2/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 1)
HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 2
FIRE 2
Reactivity = 0
REACTIVITY 0




4 First aid measures

General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: Seek immediate medical advice.


5 Fire fighting measures

Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Protective equipment: Wear self-contained respiratory protective device.


6 Accidental release measures

Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with clay, dry sand, or other inert material. Do not use combustible materials such as sawdust. Place in a
chemical waste container.


7 Handling and storage

Handling:
Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.
(Contd. on page 3)
USA




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Page 3/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 2)

Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.


8 Exposure controls and personal protection

Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
111-76-2 2-butoxyethanol
PEL 240 mg/m鲁, 50 ppm
Skin
REL 24 mg/m鲁, 5 ppm
Skin
TLV 97 mg/m鲁, 20 ppm
NIC-A3
Additional information:
PEL = Permissible Exposure Limit (OSHA)
REL= Recommended Exposure Limit (NIOSH)
TLV= Threshold Limit Value (ACGIH)
OSHA= Occupational Safety and Health Administration
ACGIH= American Conference of Governmental Industrial Hygienists
NIOSH= National Institute for Occupational Safety and Health

Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-
contained breathing apparatus should be worn.
Protection of hands:



S Protective gloves


Material of gloves:
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:



R Tightly sealed goggles

(Contd. on page 4)
USA




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Page 4/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 3)
Safety glasses
Body protection: Apron


9 Physical and chemical properties

General Information

Form: Liquid
Color: Light yellow
Odor: Mild

Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 171掳C (340掳F)

Flash point: 74掳C (165掳F)

Ignition temperature: 238掳C (460掳F)

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:
Lower: 1.1 Vol %
Upper: 10.6 Vol %

Vapor pressure at 20掳C (68掳F): 0.88 mm Hg

Density at 20掳C (68掳F): 0.899 g/cm鲁

Solubility in / Miscibility with
Water: Partly miscible.


10 Stability and reactivity

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Aldehydes
USA
(Contd. on page 5)




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Page 5/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 4)


11 Toxicological information

Acute toxicity:
LD/LC50 values that are relevant for classification:
111-76-2 2-butoxyethanol
Oral LD50 1480 mg/kg (rat)
Dermal LD50 400 mg/kg (rab)
126-86-3 2,4,7,9-tetramethyldec-5-yne-4,7-diol
Oral LD50 4600 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
through inhalation:
Fumes during use may irritate mucous membranes and respiratory system. High concentrations can cause
headache, dizziness, narcosis, and nausea.
through ingestion:
May cause gastrointestinal irritation.
May be harmful if swallowed.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant


12 Ecological information

General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.


13 Disposal considerations

Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


14 Transport information

DOT regulations:
Identification number: NA1993
Packing group: III
Proper shipping name (technical name): COMBUSTIBLE LIQUID, N.O.S (2-butoxyethanol)
(Contd. on page 6)
USA




DR
Page 6/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 5)
Remarks: Product is regulated for transport only when shipped in quantities
ofgreater than 119 gallons.

Land transport ADR/RID (cross-border):
ADR/RID class: -
Not regulated.

Maritime transport IMDG:
IMDG Class: -
Not regulated.
Marine pollutant: No

Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: -
Not regulated.


15 Regulations

USA The following information relates to product regulation specific to the USA.

SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.

California Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity:
None of the ingredients is listed.

Carcinogenicity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
(Contd. on page 7)
USA



DR
Page 7/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/15/2005 Reviewed on 03/15/2005

Trade name: 7210

(Contd. of page 6)
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

CANADA: The following information relates to product regulation specific to Canada.

Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification:
B3
D2B

Components on Ingredient List for WHMIS:
2-butoxyethanol

EUROPEAN UNION
The following information relates to product regulation specific to the directives of the European Union.

Risk phrases:
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.

Safety phrases:
Keep out of the reach of children.
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label.
Dispose of this material and its container to hazardous or special waste collection point.


16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and assumes no
responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this
Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any
process. All chemical products should be used only by, or under the direction of, technically qualified personnel
who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication
regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for
hazard information.

Department issuing MSDS: Product Safety
Contact: Stacey Pole, MSDS Coordinator Tel. (847) 699-5755
USA




DR

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