CHEMTREC Transporation
Emergency Phone: 800-424-
9300
Material Safety Pittsburgh Poison Control
Center
Health Emergency No.: 412-
Data Sheet 681-6669
NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving
chemicals
Section 1 - Chemical Product / Company Information
CARBOCOAT W/R PRIMER Revision Date: 05/04/2006
Product Name:
Identification
PLMSDS 8222S1NL Supercedes : 05/04/2006
Number:
Product
FOR INDUSTRIAL USE ONLY
Use/Class:
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
350 Hanley Industrial Ct.
St. Louis, MO 63144
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less ThanACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
TALC 014807-96-6 15.0 N/E N/E N/E N/E
2BUTOXY ETHANOL 111-76-2 10.0 25 PPM N/E 120 MGM3 NE
PROPYLENE GLYCOL 5131-66-8 10.0 N/E N/E N/E N/E
N-BUTYL ETHER
SEC-BUTYL ALCOHOL 78-92-2 5.0 100 PPM N/E N/E N/E
VINYLPYRROLIDINONE 88-12-0 5.0 N/E N/E N/E N/E
Section 3 - Hazards Identification
Emergency Overview: Use ventilation necessary to keep exposures below recommended exposure limits, if
any.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. May be harmful if absorbed through the
skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled, may affect the brain or nervous system, causing
dizziness, headache, or nausea. May cause nose and throat irritation. Use in inadequately ventilated areas
may result in irritation headache and nausea.
Effects Of Overexposure - Ingestion: May be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Under normal use conditions, this product is not expected to
cause adverse health effects. Reports have associated repeated and prolonged occupational overexposure to
solvents with permanent brain and nervous system damage.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Medical Conditions Prone to Aggravation by Exposure: If you have a condition that could be aggravated
by exposure to dust or organic vapors, see a physician prior to use.
Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.
First Aid - Skin Contact: Launder clothing before reuse. In case of contact, wash skin immediately with soap
and water.
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if
symptoms persist or exposure was severe.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point, F: 122F Lower Explosive Limit, %: 1.0
Upper Explosive Limit, %: 15.8
(Setaflash)
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: This is a water based product, however it does contain small amounts
of volatile organic compounds (See Section II). Vapors are heavier than air and will accumulate. Vapors will
form explosive concentrations with air. Vapors travel long distances and will flashback.
Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH approved
self-contained breathing unit and complete body protection. Cool surrounding containers with water in case of
fire exposure.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling equipment
must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear appropriate
personal protection clothing and equipment. Follow exposure controls/personal protection guidelines in Section
8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant material and seal tightly
for proper disposal. Dispose of in accordance with local, state and federal regulations. Refer to Section 15 for
SARA Title III and CERCLA information.
Section 7 - Handling And Storage
Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty containers.
Use only in accordance with Carboline application instructions, container label and Product Data Sheet. Avoid
breathing vapors or spray mist.
Storage: Protect from Freezing! Keep container closed when not in use.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).
Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2.
User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not
able to monitor, use MSHA/NISOH approved supplied air respirator. Follow all current OSHA requirements for
respirator use.
Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to
skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.
Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.
Other protective equipment: Eye wash and safety showers should be readily available.
Hygienic Practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and
smoking in immediate work area should be prohibited.
Section 9 - Physical And Chemical Properties
212 F (100 C) - 442 F (228 C) Heavier than Air
Boiling Range: Vapor Density:
Ester Odor N/D
Odor: Odor Threshold:
Viscous Liquid Slower Than Ether
Appearance: Evaporation Rate:
Soluble
Solubility in H2O:
N/D 1.15
Freeze Point: Specific Gravity:
N/D 8.0 - 9.0
Vapor Pressure: PH:
Liquid
Physical State:
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Heat, sparks and open flames.
Incompatibility: None
Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these operations.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: N/D Product LC50: N/D
Chemical Name CAS Number LD50 LC50
TALC 014807-96-6 NOT AVAILABLE NOT AVAILABLE
2BUTOXY ETHANOL 111-76-2 1746 MG/KG, RAT, ORAL 700PPM/7HRS MOUSE, INHALATION
PROPYLENE GLYCOL N-BUTYL ETHER 5131-66-8 NOT AVAILABLE NOT AVAILABLE
SEC-BUTYL ALCOHOL 78-92-2 2500 MG/KG, RAT, ORAL > 8000 PPM/4 HRS, RAT, INHALATION
VINYLPYRROLIDINONE 88-12-0 NOT AVAILABLE NOT AVAILABLE
Section 12 - Ecological Information
Ecological Information: No data
Section 13 - Disposal Information
Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.
Section 14 - Transportation Information
Paint Packing Group: III
DOT Proper Shipping
Name:
N/A Hazard Subclass:N/A
DOT Technical Name:
3 128
DOT Hazard Class: Resp. Guide
Page:
UN 1263
DOT UN/NA Number:
Additional Notes: None.
Section 15 - Regulatory Information
CERCLA - SARA HAZARD CATEGORY
This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
2BUTOXY ETHANOL 111-76-2
SEC-BUTYL ALCOHOL 78-92-2
TOXIC SUBSTANCES CONTROL ACT
All components of this product are listed on the TSCA inventory.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
No TSCA 12(B) Substances exist in this product
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
WATER 7732-18-5
ALKYD RESIN TRADE SECRET
TITANIUM DIOXIDE 013463-67-7
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
WATER 7732-18-5
ALKYD RESIN TRADE SECRET
TITANIUM DIOXIDE 013463-67-7
CALIFORNIA PROPOSITION 65
Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:
Chemical Name CAS Number
CARBON BLACK 001333-86-4
Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:
No California Proposition 65 Reproductive Toxins exist
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: B3 D2B
Section 16 - Other Information
HMIS Ratings
Health: 2 Flammability: 2 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 326
REASON FOR REVISION: Changed to 16 Section Format
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations
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