BIO-CIDE INTERNATIONAL, INC. PRODUCT: OXINE
MATERIAL SAFETY DATA SHEET
=============================================================================================
==
EMERGENCY TELEPHONE: (405) 329-5556 (24 Hours)
2845 Broce Drive
Norman, OK 73072
=============================================================================================
==
SECTION I: PRODUCT IDENTIFICATION VOLATILES (BY VOLUME): 97% (Water)
PRODUCT NAME: OXINE OCTANOL/WATER PARTITION COEFFICIENT: NE
CHEMICAL FAMILY: Mixture of Oxychlorine EVAPORATION RATE: Comparable to Water
Compounds SOLUBILITY IN WATER: Complete
SYNONYMS: N/A CAS #: None (Mixture) pH, CONCENTRATE: 8.0 to 8.6
NFPA RATING: (with 0 for no hazard to 4 for life OTHER DISTINGUISHING CHARACTERISTICS: N/A
threatening) ==================================================
Fire: 0 Health: 1 Reactivity: 1 SECTION IV: FIRE AND EXPLOSIVE HAZARD
Special: None INFORMATION
WARNING STATEMENT: Product may cause eye and skin FLASH POINT: None to solution boiling point.
irritation METHOD: N/A
EFFECTIVE DATE: June 1994 AUTOIGNITION TEMPERATURE: N/E
SUPERSEDES: March 1994
================================================== DECOMPOSITION TEMPERATURE: N/E (for dry sodium
SECTION II: HAZARDOUS INGREDIENTS chlorite: 180 - 200掳C)
INGREDIENT (CAS #)
FIRE EXTINGUISHING MEDIA: Water unless
OSHA ACGIH
contraindicated by other material involved in fire.
PERCENT PEL TLV STEL OTHER
Sodium Chlorite 3.35 NE NE NE Irritant FIRE-FIGHTING EQUIPMENT: Standard protective gear
(7758-19-2) Minimum with self-contained breathing apparatus.
SPECIAL FIRE-FIGHTING EXPLOSIVE HAZARDS: Do
Chlorine Dioxide Trace 0.1 0.1 0.3 SARA 313
not allow solutions to evaporate to dryness. If chlorine dioxide gas
(10049-04-4) PPM PPM PPM
is produced, vent to atmosphere. Open or vent any large containers
________ of 2% product.
TOTAL 3.35
NE = NOT ESTABLISHED NL = NOT LISTED
UNUSUAL FIRE OR EXPLOSIVE HAZARDS: The sodium
(C) = IDENTIFIED AS A CARCINOGEN BY OSHA, IARC,
chlorite is a strong oxidizer, which supports combustion. Chlorine
NTP, OR ROTECS
dioxide, which may evolve from solutions, is explosive in the
This document is prepared pursuant to the OSHA Hazard Communication gaseous phase at concentrations greater than 10% by volume. Do
Standard (29 CFR 1910.1200). In addition, other substances not classified as
not allow chlorine dioxide gas to accumulate within a confined
鈥淗azardous鈥? per this OSHA Standard may be listed. The identity of other
space.
ingredients will be made available as provided in this standard.
==================================================
==================================================
SECTION V: REACTIVITY DATA
SECTION III: PHYSICAL/CHEMICAL DATA
STABILITY: Product is stable.
APPEARANCE AND ODOR: Clear liquid with very faint
chlorinous odor.
CONDITIONS TO AVOID: Avoid storing product under
BOILING POINT: 213掳F (100.5掳C) conditions in which it could evaporate to crystalline salt.
MELTING POINT: N/A
INCOMPATIBLE MATERIALS: Avoid accidental contact with
SPECIFIC GRAVITY: 1.03 g/ml (20掳C) acids, chlorine compounds, hypochlorites (bleach), sulfur and sulfite
_____________________________________________________________________________________________________________________
PRODUCT: Oxine M.S.D.S.
2845 Broce Drive 鈥? P.O. Box 722170 鈥? Norman, Oklahoma U.S.A., 鈥? (405) 329-5556 鈥? FAX: (405) 329-2681
compounds, phosphorus, organic solvents, and
combustible/flammable materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Exposure to
acids or chlorine compounds can produce uncontrolled generation of
chlorine dioxide gas.
SYMPTOMS OF OVER-EXPOSURE: Skin and eye irritation.
HAZARDOUS POLYMERIZATION: Does not occur.
Exposure to chlorine dioxide from activation can produce coughing,
==================================================
sore throat, headache, and dizziness.
SECTION VI: HEALTH HAZARD DATA
FIRST AID
INGESTION: Rat Oral LD (50): 4,360 mg/kg.
Ingestion may produce gastric discomfort, nausea, vomiting, and
SKIN CONTACT: Wash affected area thoroughly with soap and
diarrhea. Intake of large quantities may produce
water. Remove contaminated clothing and rinse thoroughly with
methemoglobinemia.
water before laundering or discard. If irritation occurs, seek medical
attention.
EYE CONTACT: Based on rabbit studies, 2% product has been
given an EPA Category III rating as a mild irritant. Exposure can
EYE CONTACT: Flush eyes thoroughly with water, making
produce slight irritation of conjunctiva, cornea, and eyelid.
certain eyelids are held open. If irritation or burning persist, seek
medical attention.
SKIN CONTACT: Based on rabbit studies, 2% product is listed
as 鈥減ractically not an irritant鈥?. Prolonged exposure may produce
INHALATION: Unactivated 2% product normally has no
localized irritation, contact dermatitis, mild erythema, and edema.
respiratory effects. If exposure to chlorine dioxide produced from
activation occurs, remove victim to fresh air. Contact a physician if
SKIN ABSORPTION: Highly unlikely to be absorbed through
respiratory distress continues.
skin in toxic amounts. Rabbit Acute Dermal LD(50) > 2,020 mg/kg.
INGESTION: DO NOT INDUCE VOMITING. Contact a
INHALATION: Acute Inhalation: LC (50) > 5.61 mg/1.
physician or Poison Control Center immediately.
Prolonged inhalation of fog or mist containing 2% product may be
irritating to nose and throat.
PLEASE NOTE: Above procedures are recommended as
emergency first aid precautions only. They are not intended to
SYSTEMIC AND OTHER EFFECTS: None known.
replace or supplant the treatment advice of an physician or other
authorized health care specialist.
CHRONIC EXPOSURE EFFECTS: May cause localized
==================================================
irritation to areas exposed to product.
SECTION VIII: CONTROL MEASURE/PERSONAL
PROTECTION EQUIPMENT
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Skin disorders, such as dermal allergies and dermatitis. Exposure to
VENTILATION: Open air or good room ventilation is normally
chlorine dioxide produced by activation can aggravate pulmonary
adequate for safe use of this product. Avoid breathing any vapors or
disorders, such as emphysema.
fumes resulting from acid activation.
CARCINOGENICITY: Active ingredients are not listed by
RESPIRATORY PROTECTION: In accordance with OSHA
ROTECS, OSHA, IARC, or NTP. No evidence to date implicating
regulations (29 CFR 1910.134 and 29 CFR 1910.1000), fogging or
product as carcinogen or tumor promoter.
spraying applications may require worker respiratory protection,
such as: (1) NIOSH/MSHA approved air-purifying respirators, or
MUTAGENICITY: Though product active ingredient is a
(2) NIOSH/MSHA approved canister/cartridge facial respirators
chemical oxidant, no evidence to date for mutagenicity from whole
rated for chlorine/acid vapors or specified for chlorine dioxide.
animal or in vitro studies.
EYE PROTECTION: Good manufacturing practice recommends
REPRODUCTIVE EFFECTS: No known effects to date.
use of chemical safety goggles for all applications involving
chemical handling.
OTHER HEALTH HAZARDS/HEALTH EFFECTS: None
known.
PROTECTIVE CLOTHING: Good manufacturing practice
==================================================
recommends that, at a minimum, rubber, neoprene, or other
SECTION VIII: FIRST AID
chemically impervious gloves be worn for all applications involving
chemical handling.
TARGET ORGANS: Skin, eyes. For chlorine dioxide produced
from activation: respiratory tract and exposed mucous membranes.
_____________________________________________________________________________________________________________________
PRODUCT: Oxine M.S.D.S.
2845 Broce Drive 鈥? P.O. Box 722170 鈥? Norman, Oklahoma U.S.A., 鈥? (405) 329-5556 鈥? FAX: (405) 329-2681
OTHER PROTECTIVE MEASURES: Product should be stored SECTION XI: REGULATORY STATUS
and applied in close proximity to a safety show, chemical eyewash
station, or other fresh water source. Federal EPA Regulations
TSCA: All product ingredients are on inventory.
SARA TITLE 312/313: Neither the product nor its constituent
ingredients are listed under SARA reporting requirements. Chlorine
dioxide produced from activation is listed under SARA 313.
SECTION IX: SPILL, LEAK, AND DISPOSAL RCRA: Not considered a hazardous waste either categorically or
PROCEDURES by chemical listing.
ENVIRONMENTAL NOTIFICATION: All spills and leaks CLEAN WATER ACT: Neither product nor constituent
involving more than 10 gallons should be reported to the nearest ingredients is listed as priority pollutant.
regional EPA office or designated state emergency response office
within 24 hours. Spills from ocean vessels or which may CLEAN AIR ACT: Neither product nor constituent ingredients
contaminate U.S. coastal waterways should be reported to the is listed a priority pollutant.
nearest Coast Guard office within 24 hours.
Federal OSHA Regulations
SPILL OR LEAK PROCEDURES: Small spills, involving less
than 10 gallons, may be flushed to a designated and permitted sewer Neither product nor constituent ingredients is classified as an acute
system with copious amounts of water. Larger spills should be or chronic health hazard by OSHA. Chlorine dioxide produced by a
contained and neutralized with sodium bisulfite or sodium tivation is regulated with an air exposure limit of 0.1 ppm TLV and
thiosulfate (1.2 lbs neutralizer per each estimated lb. Of spilled 0.3 ppm STEL.
material) or disposed of as chemical waste in the manner indicated
below. The vicinity of the spill should be thoroughly flushed with Federal Department of Transportation
water after clean-up. At no time should the spilled material be
allowed to dry to a crystalline salt. Do not discharge this product to Not regulated.
storm drains or to any surface or ground water source unless
specifically allowed under a valid NPDES permit. State Laws
DISPOSAL PROCEDURE: Small quantities, less than 10 CALIFORNIA: Not regulated under the provisions of Proposition
gallons, may be flushed to an authorized and permitted sewer with 65 (Safe Drinking Water and Toxic Enforcement Act of 1986).
copious amounts water. Larger volumes should be taken to an
authorized chemical disposal site (Class I or landfill) in accordance NEW JERSEY: Sodium Chlorite is listed under New Jersey鈥檚
with all federal, state, and local regulations. Consult with selected Chemical Inventory Notification Requirement (NJAC 7:1Z).
facility regarding the need for prior neutralization of waste. Estimated release notification, however, is not required.
==================================================
SECTION X: SPECIAL PRECAUTIONS PLEASE NOTE: Regulatory requirements are subject to change
and may vary from one location to another. It is the users
PRODUCT STORAGE: Store in a cool, dry, well-ventilated responsibility to ensure compliance with all applicable federal, state,
location away from acids, chlorine and chlorine compounds, and local regulations pertaining to the purchase, transport, storage,
hypochlorites (bleach), organic solvents, sulfur and sulfite use, and disposal of this product.
compounds, phosphorus, combustible/flammable materials, and ==================================================
direct sunlight. Keep containers tightly closed when not in use and The information contained in this Material Safety Data Sheet has
open carefully to prevent spillage. Storage on wooden floors and been assembled by the manufacturer, based on its own studies and
pallets is not recommended. on research accomplished by others. The manufacturer gives this
information without warranty, expressed or implied. The
PRODUCT HANDLING:. Use product only as directed by the information contained herein is accurate as of the date posted, to the
label or by your authorized Bio-Cide representative. Avoid contact best knowledge of the manufacturer.
with skin and eyes; avoid breathing any vapors or fumes resulting
from product activation. Wash thoroughly after handling.
Thoroughly rinse all protective gear and handling equipment, such
as transfer pumps and lines, with water prior to reuse or storage.
Keep away from children, animals, and unauthorized personnel.
OTHER PRECAUTIONS: Product my bleach clothing and fabric
materials, such as draperies and carpets.
==================================================
_____________________________________________________________________________________________________________________
PRODUCT: Oxine M.S.D.S.
2845 Broce Drive 鈥? P.O. Box 722170 鈥? Norman, Oklahoma U.S.A., 鈥? (405) 329-5556 鈥? FAX: (405) 329-2681
_____________________________________________________________________________________________________________________
PRODUCT: Oxine M.S.D.S.
2845 Broce Drive 鈥? P.O. Box 722170 鈥? Norman, Oklahoma U.S.A., 鈥? (405) 329-5556 鈥? FAX: (405) 329-2681
|