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MSDS Material Safety Data Sheet
CAS

10-27-6
10-38-2
10034-96-5

File Name: montereyagresources_com---TechMaxGran-m.asp

TECMANGAM

Material Safety Data Sheet



SECTION I: CHEMICAL PRODUCT鈥揅OMPANY IDENTIFICATION

ERACHEM MEXICO, S.A. DE C.V.
Domicilio Conocido
Carretera Tampico - Valles km 28,
C.P. 92018 Tam贸s, Municipio de P谩nuco, Ver.
(Via Tampico, Tam.) M茅xico
Phone # (52-833) 2-10-27-62 to 64, (52-833) 2-10-38-24 and 2-10-36-29
FAX # (52-833) 2-10-38-25

(800) 424-9300-CHEMTREC (24 Hour Emergency Response)

PRODUCT: TECMANGAM庐
SUBSTANCE: Soluble Manganese Sulfate fertilizer micronutrient and trace
element for animal feed premixes.
TRADE NAMES: TECMANGAM庐
SYNONYMS: Manganese Sulfate, MnSO4, Manganese Monosulfate,
Monohydrate Manganese Sulfate.
CHEMICAL FAMILY: Mixture
MSDS REVISION DATE: 24 NOVEMBER 2005


SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS

COMPONENT: Manganese Sulfate Monohydrate
CAS NUMBER: 10034-96-5
RTECS NUMBER: OP1050000 (Manganese Sulfate), ZC0110000 (Water)
WEIGHT %: >98
PROBABLE CONTAMINANTS: None




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TECMANGAM

Material Safety Data Sheet


SECTION 3: HAZARDS IDENTIFICATION

NFPA RATINGS: (SCALE 0-4): HEALTH=1, FIRE=0, REACTIVITY=0
EMERGENCY OVERVIEW: Odorless; cream-colored powder. Avoid breathing
dust. Avoid contact with eyes and skin. Avoid prolonged or repeated
contact with skin. Avoid ingestion. Use with adequate ventilation. Wash
thoroughly after handling.
POTENTIAL HEALTH EFFECTS:
INHALATION:
Short Term Effects: May be harmful if inhaled. May cause irritation of
the nasal passages. Additional effects may include shortness of
breath and asthma.
Long Term Effects: May cause digestive disorders, loss of voice,
headaches, difficulty in walking, joint pain, twitching, hearing loss
and visual disturbances.
SKIN CONTACT:
Short Term Effects: Prolonged or repeated contact may cause
irritation.
Long Term Effects: No information available on significant adverse
effects.
EYE CONTACT:
Short Term Effects: Dust may cause irritation.
Long Term Effects: May cause redness and swelling of the eyes.
INGESTION:
Short Term Effects: May cause digestive disorders.
Long Term Effects: May cause irregular heartbeat and kidney
damage.
CARCINOGEN STATUS:
OSHA: No NTP: No LARC: No




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TECMANGAM

Material Safety Data Sheet


SECTION 4: FIRST AID MEASURES

INHALATION: Remove from exposure area to fresh air immediately. If
breathing has stopped, perform artificial resuscitation. Keep person
warm and at rest. Treat symptomatically and supportively. Get
medical attention immediately.
SKIN CONTACT: Remove contaminated clothing and shoes immediately. Wash
affected area with soap or mild detergent and large amounts of water until
no evidence of chemical remains (at least 15-20 minutes). Wash clothing
before reuse. Get medical attention immediately.
EYE CONTACT: Flush eyes immediately with large amounts of water or normal
saline solution, occasionally lifting upper and lower lids until no evidence of
chemical remains (at least 15-20 minutes). Get medical attention
immediately.
INGESTION: If vomiting occurs, keep head lower than hips to prevent aspiration.
Treat symptomatically and supportively. Get medical attention immediately.

NOTE TO PHYSICIAN: Antidote: The antidote recommended is as for
manganese poisoning from Dreisbach, Handbook of Poisoning, 12th Edition.
However, the decision as to whether the severity of poisoning requires
administration of any antidote and actual dose required should be made by
a qualified medical personnel.

SECTION 5: FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat
or flame.
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or regular
foam. For larger fires use water spray, fog or regular foam (1196 North
American Emergency Response Guidebook, RSPA P 5800.7)
FIREFIGHTING: Move product from fire area if you can without risk. Extinguish
fire using agent suitable for type of surrounding fire and/or chemicals. Do
not use water directly on material. Avoid breathing vapors; keep upwind.
Dike area to prevent runoff and contamination of water sources, if possible.
Avoid breathing vapors or dust.
FLASH POINT: No data available

LOWER FLAMMABLE LIMIT: No data available
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TECMANGAM

Material Safety Data Sheet

UPPER FLAMMABLE LIMIT: No data available
AUTOIGNITION: No data available
HAZARDOUS COMBUSTION PRODUCTS: Thermal decomposition may
release toxic oxides of sulfur.


SECTION 6: ACCIDENTAL RELEASE MEASURES
OCCUPATIONAL SPILL: Do no touch spilled material. Pick-up dry spills by
scooping, shoveling or vacuuming and place into containers for later
disposal. Wear protective equipment. Keep unnecessary people away.
Isolate hazard area and deny entry to avoid material dispersal. Wash
thoroughly after handling. Use with adequate ventilation.

SECTION 7: HANDLING AND STORAGE
Observe all federal, state and local regulations when storing this product. Since
emptied packages retain product residue, follow label warnings even after package
is emptied.

SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION

EXPOSURE LIMITS:
Manganese and/or Manganese Compounds:
5 mg (Mn)/m3 OSHA ceiling
5 mg (Mn)/m3 ACGIH ceiling (dust)
1 mg (Mn)/m3 ACGIH TWA (fume)
3 mg (Mn)/m3 ACGIH STEL (fume)
VENTILATION: Provide local exhaust ventilation system to meet published
exposure limits.
EYE PROTECTION: Wear safety glasses with splash shields or safety
goggles/shield to prevent contact with this product.
EMERGENCY WASH FACILITIES: Where there is any possibility that an
employee鈥檚 eyes and /or skin may be exposed to this product, the
employer should provide an eye wash fountain and quick drench
shower within the immediate work area for emergency use.
CLOTHING: Employee must wear appropriate protective clothing and
equipment to prevent repeated or prolonged skin contact with this
product.

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TECMANGAM

Material Safety Data Sheet

GLOVES: Employee must wear appropriate protective gloves to prevent
contact with this product.
RESPIRATOR: The respirator selected must be based on contamination
levels found in the work place and specific to the job assignment. Do
not exceed the working limits of the respirator. Respirators must also
be jointly approved by the National Institute for Occupational Safety
and Health and the Mine Safety and Health Administration (NIOSH-
MSHA).
FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE
OR HEALTH CONDITIONS: Any self-contained breathing apparatus
that has a full facepiece and is operated in a pressure-demand or
other positive-pressure mode. Any supplied-air respirator that has a
full facepiece and is operated in a pressure-demand or other positive-
pressure mode in combination with an auxiliary self-contained
breathing apparatus operated in pressure-demand or other positive-
pressure mode.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

DESCRIPTION: Odorless cream colored powder.
MELTING POINT: Not available.
BOILING POINT: Not applicable.
SPECIFIC GRAVITY: (H2O=1): 0.87 at 20/20 C.
VAPOR PRESSURE: Not applicable.
VAPOR DENSITY: Not applicable.
WATER SOLUBILITY: Appreciable (approx. 99%)


SECTION 10: STABILITY AND REACTIVITY

REACTIVITY: Stable under normal temperature and pressures.
CONDITIONS TO AVOID: None known to Erachem Mexico
INCOMPATIBILITIES:
Manganese Sulfate: No data available.
HAZARDOUS DECOMPOSITION: Thermal decomposition may release toxic
oxides of manganese and sulfur.

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TECMANGAM

Material Safety Data Sheet

POLYMERIZATION: Hazardous polymerization has not been reported to occur
under normal temperatures and pressures.




SECTION 11: TOXICOLOGICAL INFORMATION

TOXICITY DATA (Manganese Sulfate):
LD50 (anhydrous): 332 mg/kg, intraperitoneal, mouse; mutagenic,
reproductive effects, tumorigenic data 鈥? see Registry of Toxic Effects of
Chemical Substances (RTECS) file.
(monohydrate): mutagenic, reproductive effects data (RTECS).
LD50 (tetrahydrate): 534 mg/kg, intraperitoneal, mouse; mutagenic data
(RTECS).
CARCINOGEN STATUS: None
ACUTE TOXICITY LEVEL: Insufficient data.
TARGET EFFECTS: No data available.

HEALTH EFFECTS (Manganese Sulfate):
INHALATION: 10,000 ppm (Mn) immediately dangerous to life or health.
Acute Exposure: Exposure to the dust of manganese compounds may
cause irritation of the mucous membranes with symptoms of
coughing and shortness of breath. This material may be absorbed
into the blood stream and deposited into the liver, spleen, brain
and other organs where it accumulates.
Chronic Exposure: Repeated exposure to the dust of manganese
compounds anywhere from 3 months to 2 years, may produce
chronic manganese poisoning . The early stage of this disease is
insidious with symptoms of apathy, anorexia, asthenia, headache,
hypersomnia, spasms, weakness of the legs, arthralgias and
irritability. As the disease progresses into the intermediate phase,
psychosis develops with symptoms of visual hallucinations, double
vision, impaired hearing, uncontrollable impulses, mental
confusion, and euphoria. In the last stage of the disease,
neurological disturbances develop that simulate Parkinson鈥檚

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TECMANGAM

Material Safety Data Sheet

disease. These disturbances include excessive salivation, muscle
weakness, muscle rigidity, tremor of upper extremities and head,
and impaired gait. The severity of chronic manganese poisoning
depends upon the length of exposure and the stage of the disease
when exposure is terminated. The prognosis is more favorable in
the young and in those with only a few years exposure. Chronic
manganese poisoning is not a fatal disease but it can be
extremely disabling.
SKIN CONTACT:
Acute Exposure: May cause irritation.
Chronic Exposure: No data available.
EYE CONTACT:
Acute Exposure: May cause redness and irritation.
Chronic Exposure: Repeated or prolonged contact may cause irritation
and conjunctivitis.
INGESTION:
Acute Exposure: Manganese compounds may cause gastrointestinal
disturbances with abdominal pain and nausea. Large inhaled particles
may be cleared from the respiratory tract and swallowed. The rate of
absorption can be influenced by the dietary level of manganese and
iron, the type of manganese compound, iron deficiency and age.
However, the risk of intoxication by this route is not considered great.
Chronic Exposure: No data available.


SECTION 12: ECOLOGICAL INFORMATION

ENVIRONMENTAL IMPACT RATING (0-4): No data available.
ACUTE AQUATIC TOXICITY: No data available.
DEGRADABILITY: No data available.
LOG BIOCONCENTRATION FACTOR (BCF): No data available.
LOG OCTANOL/WATER PARTITION COEFFICIENT: No data available.

SECTION 13: DISPOSAL INFORMATION

Observe all federal, state and local regulations when disposing of this substance.



7

TECMANGAM

Material Safety Data Sheet

SECTION 14: TRANSPORT INFORMATION

DOT Shipping Name-ID Number: Non-regulated.




SECTION 15: REGULATORY INFORMATION

TSCA STATUS Yes
40 CFR 302.4 CERCLA SECTION 103: No
40 CFR 355.30 SARA SECTION 302: No
40 CFR 355.40 SARA SECTION 304: No
40 CFR 372.65 SARA SECTION 313: No
29 CFR 1910.119 OSHA Process Safety No
California Proposition 65 No
40 CFR 370.21 SARA HAZARD CATEGORIES
SARA SECTIONS 311.312:
ACUTE HAZARD: No
CHRONIC HAZARD: No
FIRE HAZARD: No
REACTIVITY HAZARD: No
SUDDEN RELEASE HAZARD: No

SECTION 16: OTHER INFORMATION

Individuals handling this product should be informed of the recommended safety
precautions and should have access to this information.

This information relates to the specific product designated and may not be valid for such
product used in combination with any other materials or in any other processes. Such
information is to the best of our knowledge and belief, accurate and reliable as of the date
compiled. However, no representation, warranty or guarantee is made as to its accuracy,
reliability, or completeness. It is the user麓s responsibility to satisfy themselves as to the
suitability and completeness of such information for their own particular use. We do not
accept liability for any loss or damage that may occur from the use of this information nor
do we offer warranty against patent infringement.

Erachem Mexico reserves the right to refuse shipment of this product to any consumer
who fails to demonstrate the ability to consistently handle and use it safely and in
8

TECMANGAM

Material Safety Data Sheet

compliance with all applicable laws, rules and regulations. Such demonstration may
require on site inspection of any or all storage, processing, packaging and other handling
systems that come in contact with it.

Customers are responsible for compliance with local, state and federal regulations that
may be pertinent in the storage, application and disposal of this product.




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