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MSDS Material Safety Data Sheet
CAS

1317-61-9

File Name: canon_com_au---a30.asp
                                                                                        Page 1 of 9

F41-4102
MATERIAL SAFETY DATA SHEET

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE
COMPANY / UNDERTAKING
Product Name: CANON CARTRIDGE A30 (BLACK)

Description: An assembly for Canon FC. PC-3/5/6/7, composed of a
photosensitive Drum, black toner powder, a corona unit, a developer
unit and a cleaner blade. The toner powder cannot be removed, until
the cartridge is forced to be broken.

Not classified as hazardous according to the
STATEMENT OF HAZARDOUS NATURE:
criteria on Worksafe Australia.
Manufacturer: Canon Inc.
30-2, Shimomaruko 3-Chome, Ohta-ku Tokyo, Japan
Phone: 03-3758-2111
Distributor: Canon Australia Pty Ltd
1 Thomas Holt Drive
North Ryde NSW 2113
Phone: (02) 9805-2000
Date of preparation: 28 December 1989
Revised: 05 December 2005
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Ingredient(s)
Chemical Name CAS# Weight % EU Symbol EU R-Phrase

Styrene acrylate copolymer 50 鈥? 60

Iron oxide (1317-61-9) 30 鈥? 40



Chemical Name USA OSHA PEL ACGIH TLV

15mg/m3 (Total dust) 10mg/m3 (Total dust)
5mg/m3 (Respirable fraction)



Chemical Name EU ILV DFG MAK

6mg/m3
(Feinstaubkonzentration)




Date of Issue: December 28, 1989 Revised:05 December 2005
Page 2 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS 鈥? Continued

Carcinogen
Chemical Name CAS # Reference
None


Other Ingredient(s)
Chemical / Generic Name Weight %


None


SECTION 3 HAZARDS IDENTIFICATION

Emergency Toner cartridge contains fine powder with slight plastic odour.
Overview:



Potential Health Effects and Symptoms:
Inhalation: Toner is finely divided solid. Do not breathe the dust.


Ingestion: No data available



Eye: No specific hazard is known to Canon. However, any material that contacts
the eye may be irritating.


Skin: Low hazard for industrial handling.


Chronic Effects: No data available



Medical Conditions Generally known to be Aggravated by Exposure:
No data available




Date of Issue: December 28, 1989 Revised:05 December 2005
Page 3 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 4 FIRST AID MEASURES

First Aid Measures:
Inhalation: No data available


Ingestion: No data available


Eye: Flush with plenty of water.


Skin: No data available


Note to Physicians: No data available


SECTION 5 FIRE FIGHTING MEASURES

Fire Fighting Measures:
Extinguishing CO2, Water, dry chemicals.
Media:

Unsuitable
Extinguishing Media: No data available

Special Fire None.
Fighting Procedures:

Unusual Fire and This material like most organic material in powder form, is capable of
Explosion Hazards: creating a dust explosion.

Fire and Explosive Properties:
Flash Point (掳C): No data available

Flammable No data available.
(Explosive) Limits:

Autoignition No data available
Temperature (掳C):

Flammability: Non-flammable solid (According to test method of USA 16CFR 1500.44
And 84/449/EEC (Annex V) A.10.)




Date of Issue: December 28, 1989 Revised:05 December 2005
Page 4 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 5 FIRE FIGHTING MEASURES - Continued

Fire and Explosive Properties 鈥? Continued:

Autoflammability: No data available

Explosive Properties: No data available

Oxidising Properties: No data available

Hazardous No data available
Combustion Products:

Other Properties: No data available




SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal Precautions: No data available


Environmental No data available
Precautions:

Method for No toner spillage occurs in normal operation or handling. If it should
Cleaning Up: occur, avoid inhalation of the dust. Sweep material onto paper or
collect it.



SECTION 7 HANDLING AND STORAGE

Handling: Keep away from contact with oxidising materials.


Storage: Keep out of the reach of children.




Date of Issue: December 28, 1989 Revised:05 December 2005
Page 5 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines: SEE SECTION 2



Engineering Controls: Good ventilation should be sufficient.

Personal Protection Equipment(s):
o Required x Not Required
Respiratory
Protection:
o Required x Not Required
Eye / Face
Protection:
o Required x Not Required
Skin Protection:


SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Fine powder
Odour: Slight plastic odour
pH in concentrate: Cannot be determined
Boiling Point / Range (掳C): Not available for solid mixtures.
Melting Point / Range (掳C): 100 - 150掳C
pH in dilution as used: Cannot be determined.
Flash Point (掳C): No data available
Flammable (Explosive) Limits: No data available
Autoignition Temperature (掳C): No data available
Flammability: Non-flammable solid (According to test method of USA
16CFR 1500.44 and 84/449/EEC (Annex V) A.10.)
Autoflammabailty: No data available
Explosive Properties: No data available
Oxidizing Properties: No data available
Vapour Pressure: Negligible
Vapour Density: Not applicable
Density / Specific Gravity: 1.4 鈥? 1.6
Water Solubility: Negligible
Solubility in organic solvents: Partially soluble in toluene and xylene.
Partition Coefficient No data available
(n-Octanol / Water):
Percent Volatile: Negligible
Evaporation Rate: No data available



Date of Issue: December 28, 1989 Revised:05 December 2005
Page 6 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 10 STABILITY AND REACTIVITY

x Stable o Unstable
Stability:

Conditions to Avoid: No data available

Materials to Avoid: No data available

Hazardous Decomposition Combustion will produce carbon dioxide and possibly toxic
Products: chemicals such as carbon monoxide.
o May Occur x Will Not Occur
Hazardous Polymerisation

Incompatibility of Toner: Strong oxidisers

SECTION 11 TOXICOLOGICAL INFORMATION

Acute Toxicity:

Inhalation: No data available



Ingestion: No data available



Eye: No data available



Skin: No data available



Sensitisation: No data available



Mutagenicity: Negative (test strains: S. typhimurium)



Reproductive No data available

Toxicity:



Date of Issue: December 28, 1989 Revised:05 December 2005
Page 7 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 11 TOXICOLOGICAL INFORMATION - Continued

Carcinogenicity: No carcinogen or potential carcinogen, according to IARC
Monographs, NTP, OSHA(USA) regulation and EC Directive.



Others: No data available



SECTION 12 ECOLOGICAL INFORMATION

Mobility: No data available

Persistence / No data available
Degradability:

Bioaccumulation: No data available

Ecotoxicity: No data available

Other Adverse No data available
Effects:



SECTION 13 DISPOSAL CONSIDERATION


Method of Disposal: The waste toner could be considered as plastic waste. For incineration,
package it adequately. Do not disperse the toner into fire. Disposal should
be subject to federal, state or local laws.



SECTION 14 TRANSPORT INFORMATION


UN# No data available
UN Shipping Name: No data available
UN Classification: No data available
UN Packing Group: No data available
Special Precautions: No data available




Date of Issue: December 28, 1989 Revised:05 December 2005
Page 8 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 15 REGULATORY INFORMATION

EU Information:
Information on the Label:
Symbol & No data available
Indication:
R-Phrase: No data available

S-Phrase: No data available

Dangerous Component(s):
No data available

Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: No data available

(EC)3093/94: No data available

(EEC)2455/92: No data available

Others: No data available

USA Information:
Information on the Label:
Signal Word: No data available


Hazard warning: No data available

Safety Advice: No data available

Hazardous No data available
Component(s):

SARA Title III 搂313:
Chemical Name Weight %

None

California Proposition 65:
Chemical Name Weight

None



Date of Issue: December 28, 1989 Revised:05 December 2005
Page 9 of 9

F41-4106
MATERIAL SAFETY DATA SHEET

SECTION 16 OTHER INFORMATION

Other Information:

No data available




Literature Reference:

- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environment Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report
on Carcinogens
- World Health Organisation International Agency for Research on Cancer , IARC Monographs
on the Evaluation on the Carcinogenic Risk of Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 88/379/EEC and their amendments
- EU Regulation (EC)3093/94, (EEC)2455/92 and their amendments

Abbreviations:

鈥楨U鈥? stands for European Union.
鈥極SHA PEL鈥? stands for PEL (Permissible Exposure Limit) under Occupational Safety and Health
Administration.
鈥楢CGIH TLV鈥? stands for TLV (Threshold Limit Value) under American Conference of
Government Industrial Hygienists.
鈥楨U ILV鈥? stands for Indicative Limit Values for Occupational Exposure under EU Directive
91/322/EEC.
鈥楧FG MAK鈥? stands for MAK (Maximale Arbeitsplatzkonzentrationen) under Deutsche
Forschungsgemeinschaft.
鈥楾WA鈥? stands for Time Weighted Average
鈥業ARC鈥? stands for International Agency for Research on Cancer.
鈥楴TP鈥? stands for National Toxicology Program (USA).


This information relates only to the specific material designated and may not be valid for such
material used in combination with any other material or in any other process. And it is based on the
level of our knowledge as of the date of preparation.




Date of Issue: December 28, 1989 Revised:05 December 2005

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