Page 1 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Canon Color BJ Cartridge BC-33e
Product Name:
4611A / F45-2071
Product Code:
Distributor: Canon Australia Pty Ltd
Company Name: Canon Inc.
1 Thomas Holt Drive
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
Address: North Ryde NSW 2113
Use of the Product: Ink for Ink Jet Printer Phone: (02) 9805-2000
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
CAS # / Weight USA
EU Symbol/
Chemical Name / ACGIH TLV EU ILV DFG MAK
EC # % OSHA PEL
R-Phrase
Generic name
None / None
Glycerin 56-81-5 / 5 - 10 (as mist) (as mist) Not established Not established
TWA = 10 mg/m3
200-289-5 Total dust
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3
TWA = 20 ppm, 10 ppm, 26 mg/m3
Xn / R22
Ethylene glycol 107-21-1 / 2-6 Not established (aerosol)
52 mg/m3
(Contained in cyan and 203-473-3 Ceiling =
100 mg/m3
magenta ink) STEL = 40 ppm,
104 mg/m3
10 ppm, 44 mg/m3
Xn / R22
Diethylene glycol 111-46-6 / 2-6 Not established Not established Not established
203-872-2
Copper, Xi / R36
90295-11-7 / 2-6 Not established Not established Not established Copper and its
[29H,31H-phthalocyaninato(2-)
291-001-7 compounds
-N29,N30,N31,N32] -,
Inhalable fraction
aminosulfonyl sulfo derivs.,
1.0 mg/m3
sodium salts
(Contained only in cyan ink)
F / R11
Isopropyl alcohol 67-63-0 / 1-3 TWA = 400 ppm, TWA = 400 ppm, Not established 200 ppm,
980 mg/m3 983 mg/m3 500 mg/m3
Xi / R36
(Contained in cyan , 200-661-7
magenta and yellow ink) R67 STEL = 500 ppm,
1230 mg/m3
Xi / R36
Quinoline derivative Confidential 1-3 Not established Not established Not established Not established
(Contained only in
magenta ink)
Xi / R36
Triazine derivative Confidential 1-3 Not established Not established Not established Not established
R52/53
(Contained only in
magenta ink)
Xi / R36
Ammonium benzoate 1863-63-4 / 1-3 Not established Not established Not established Not established
(Contained only in black 217-468-9
ink)
None / None
Ammonia derivative Confidential 5 - 10 Not established Not established Not established Not established
(Contained in cyan ,
magenta and yellow ink)
None / None
Triol Confidential 5 - 10 Not established Not established Not established Not established
(Contained only in black
ink)
Water None / None
7732-18-5 / 60 - 80 Not established Not established Not established Not established
231-79-12
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 2 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
< Carcinogen >
Chemical Name CAS # Reference
None
SECTION 3 HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE: Not classified as hazardous according to the
EU Classification:
criteria on Worksafe Australia.
Not classified as dangerous.
Emergency Overview:
A set of four colors ink cartridges. (Black, Cyan, Magenta and Yellow)
All the ink is liquid mixture with slight odor.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Glycerin mist may cause physical irritation and difficulty breathing.
Over exposure to ethylene glycol, diethylene glycol and/or isopropyl alcohol may cause headache, nausea,
dizziness, vomiting, drowsiness, cough and sore throat.
Ingestion:
Ingestion of glycerin, ethylene glycol, diethylene glycol and/or isopropyl alcohol may cause headache, nausea,
dizziness, vomiting, drowsiness, abdominal pain, dullness, diarrhea and sore throat.
Eye:
Black and Magenta : May cause minimal irritation based on the animal test data of similar composition ink.
Cyan and Yellow : May cause minimal irritation based on the animal test data of this ink.
(See SECTION 11)
Skin:
Black : May be no irritation and no sensitization based on the animal test data of similar composition ink.
Cyan and Yellow : May cause mild irritation and no sensitization based on the animal test data of this ink.
Magenta : May cause mild irritation and no sensitization based on the animal test data of similar composition ink.
(See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
SECTION 4 FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 3 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
SECTION 5 FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2, water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO2 and NOx
Other Properties:
None
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.
SECTION 7 HANDLING AND STORAGE
Handling:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
When contact, wash out immediately.
Storage:
Keep in a cool and dry place. Keep away from heat and flame.
Protect from sunlight.
Keep out of the reach of children.
Specific Uses:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (Also refer to SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Required
Respiratory Protection:
Not Required
Eye/Face Protection: Required
Not Required
Skin Protection: Required
Not Required
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 4 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Black, cyan, magenta and yellow liquid
Appearance:
Slight odor
Odor:
7.7 - 10.4
pH:
Not available
Boiling Point/Range(掳C):
Not available
Melting Point/Range(掳C):
Not available
Decomposition Temperature(掳C):
Black : Estimate None
Flash Point(掳C):
Color : Estimate 55 - 57 (Tag.closed cup. Do not sustain combustion.)
Not available
Flammable (Explosive) Limits:
Not available
Autoignition Temperature(掳C):
Black : Neither flammable nor combustible.
Flammability:
Color : Classified as "Combustible liquid" under OSHA-HCS.
Not classified as "flammable" or "combustible" under FHSA.
Not classified as "flammable" under 1999/45/EC.
None
Explosive Properties:
None
Oxidizing Properties:
Vapor Pressure : Not available
Vapor Density : Not available
Density / Specific Gravity: 1.04 - 1.10
Water Solubility : Miscible
Fat Solubility : Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%): 60 - 80
Evaporation Rate: Not available
1.7 - 2.6
Viscosity (mPa s):
SECTION 10 STABILITY AND REACTIVITY
Stable
Stability:
Unstable
None
Conditions to Avoid:
Acids, bases, oxidizing materials and reducing agents
Materials to Avoid:
CO, CO2, NOx and Ammonia
Hazardous Decomposition Products:
May Occur
Hazardous Polymerization:
Will Not Occur
None
Conditions to Avoid:
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 5 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Cyan : Estimated LD50 > 2500 mg/kg, 0/6 mortalities at 2000 mg/kg (rat)
Magenta : [Data of similar composition ink] Estimated LD50 > 2500 mg/kg (rat)
OECD Guidelines No.423 (1996)
96/54/EC Method B1 tris
Black and Yellow : Not available
Eye:
Cyan : Minimal irritant, Maximum Group Mean Score = 6.0, Class 3 (rabbit)
Yellow : Minimal irritant, Maximum Group Mean Score = 4.7, Class 3 (rabbit)
Black and Magenta : [Data of similar composition ink] Minimal irritant (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Skin:
Cyan : Mild irritant, Primary Irritation Index = 1.8 (rabbit)
Yellow : Mild irritant, Primary Irritation Index = 0.2 (rabbit)
Black : [Data of similar composition ink] Non irritant (rabbit)
Magenta : [Data of similar composition ink] Mild irritant (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Sensitization:
Cyan and Yellow : Non sensitizer, Sensitization rate = 0 % (0/10) (guinea pig)
Black and Magenta : [Data of similar composition ink] Non sensitizer (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Mutagenicity:
Ames test :
All colors : Negative (test strains: S.typhimurium & E.Coli)
Chromosome aberration test :
Magenta : Negative (test strains: Human peripheral blood lymphocytes)
Black, Cyan and Yellow : Not available
Reproductive Toxicity:
Not available
Carcinogenicity:
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP,
OSHA regulations or Annex I to Directive 67/548/EEC.
Others:
Not available
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 6 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
SECTION 12 ECOLOGICAL INFORMATION
Not available
Mobility:
Persistence /
Not available
Degradability:
Bioaccumulation: Not available
Not available
Ecotoxicity:
Other Adverse Effects: Not available
SECTION 13 DISPOSAL CONSIDERATION
Method of Disposal:
Disposal may be subject to federal, state and local laws.
SECTION 14 TRANSPORT INFORMATION
None
UN #:
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Yes
Marine Pollutant: Chemical name (wt%):
No
Special Precautions: None
SECTION 15 REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)2037/2000: Not regulated
Not regulated
(EEC)2455/92:
None
Others:
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 7 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
< USA Information >
Information on the Label under FHSA:
Signal Word: Not required
Hazard warning:
Not required
Safety Advice:
Not required
Hazardous Component(s):
None
SARA Title III 搂313:
Weight %
Chemical Name
"Ethylene glycol" (107-21-1) (Contained in cyan and magenta ink) 2-6
"Copper Compounds" (Contained only in cyan ink) 2-6
(as Cu) (< 0.35)
California Proposition 65:
Weight %
Chemical Name
None
< Canada Information >
WHMIS Controlled Product: Not applicable (Manufactured article)
< Australia Information >
Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC.
SECTION 16 OTHER INFORMATION
R11 : Highly flammable.
R22 : Harmful if swallowed.
R36 : Irritating to eyes.
R67 : Vapours may cause drowsiness and dizziness.
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Section 9
Date of Issue: July 21, 2000 Revised: October 16, 2002
Page 8 of 8
MSDS #: IC1166-0202
MATERIAL SAFETY DATA SHEET Product Code: 4611A / F45-2071
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EEC)2455/92
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission Act 1985.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the
date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance
with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any
nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
Date of Issue: July 21, 2000 Revised: October 16, 2002
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