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MSDS Material Safety Data Sheet
CAS

56-81-5
111-48-8
90295-11-7
67-63-0
9014-85-1

File Name: canon_com_au---bc05.asp
                                                                                                                                                Page 1 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Canon Color BJ Cartridge BC-05
Product Code: 0885A / F45-0891
Distributor: Canon Australia Pty Ltd
Company Name: Canon Inc.
1 Thomas Holt Drive
Address: 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan North Ryde NSW 2113
Use of the Product: Ink for Ink Jet Printer Phone: (02) 9805-2000
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
CAS # / Weight EU Symbol/ USA
Chemical Name / ACGIH TLV EU ILV DFG MAK
EC # % R-Phrase OSHA PEL
Generic name
Glycerin 56-81-5 / 5 - 10 None / None (as mist) (as mist) Not established Not established
TWA = 10 mg/m3
200-289-5 Total dust
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3

Thiodiglycol 111-48-8 / 5 - 10 Xi / R36 Not established Not established Not established Not established
203-874-3




Copper,
90295-11-7 / 2-6 Xi / R36 Not established Not established Not established Copper and its
[29H,31H-phthalocyaninato(2-)-N
291-001-7 compounds
29,N30,N31,N32]-,
aminosulfonyl sulfo derivs.,
Inhalable fraction
sodium salts
1.0 mg/m3
(Contained only in cyan ink)




Isopropyl alcohol 67-63-0 / 1-3 F / R11 TWA = 400 ppm, TWA = 200 ppm, Not established 200 ppm,
980 mg/m3 492 mg/m3 500 mg/m3
(Contained only in 200-661-7 Xi / R36
magenta ink) R67 STEL = 400 ppm,
984 mg/m3


Poly(oxy-1,2-ethanediyl),.alpha.,.
9014-85-1 / 1-3 Xi / R41 Not established Not established Not established Not established
alpha.'-
Not applicable
[1,4-dimethyl-1,4-bis(2-methylpro
pyl)-
2-butyne-1,4-diyl]bis
[.omega.-hydroxy-



C. I. Direct Violet 107 Not registered /
1-3 Xi / R41 Not established Not established Not established Not established
- The substance name in
413-180-4
accordance with 67/547/EEC is
stated in SECTION 16
(Contained only in magenta ink)




Not registered /
C.I. Direct Yellow 173 1-3 Xi / R41 Not established Not established Not established Not established
414-410-6
(Contained only in
yellow ink)



TWA = 5 mg/m3
Triethanolamine 102-71-6 / <3 None / None Not established Not established Not established
(Contained in magenta 203-049-8
and yellow ink)



Ammonia derivative Confidential 5 - 10 None / None Not established Not established Not established Not established




Water 7732-18-5 / 60 - 80 None / None Not established Not established Not established Not established
231-79-12




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 2 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891


< Carcinogen >
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA regulations or
Annex I to Directive 67/548/EEC.


SECTION 3 HAZARDS IDENTIFICATION
EU Classification: STATEMENT OF HAZARDOUS NATURE: Not classified as hazardous according to the
criteria on Worksafe Australia.
Not classified as dangerous.
Emergency Overview:
A set of three colors ink cartridges. (Cyan, Magenta and Yellow)
All the ink is liquid mixture with slight odor.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Over exposure to vapor or mist may cause respiratory tract irritation, cough, dizziness, drowsiness, headache
and nausea.
Ingestion:
May cause abdominal pain, diarrhea, dizziness, drowsiness, dullness, headache, nausea and vomiting.
Eye:
All colors : May cause minimal irritation. (See SECTION 11)
Skin:
Cyan and Yellow : May cause mild irritation and no sensitization.
Magenta : Neither irritation nor sensitization is expected.
(See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified

SECTION 4 FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with lukewarm, gently flowing water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 3 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

SECTION 5 FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2 , water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO2 , NOx and SOx
Other Properties:
None

SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.

SECTION 7 HANDLING AND STORAGE
Handling:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
In case of contact, wash out the contaminated area immediately.
Storage:
Keep in a cool and dry place. Protect from sunlight.
Keep away from heat and flame.
Keep out of the reach of children.
Specific Uses:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (See also SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Respiratory Protection: Required
Not Required
Eye/Face Protection: Required
Not Required
Skin Protection: Required
Not Required




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 4 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Cyan, magenta and yellow liquid
Odor: Slight odor
pH: 7.0 - 10.7
Boiling Point/Range(掳C): Not available
Melting Point/Range(掳C): Not available
Decomposition Temperature(掳C): Not available
Flash Point(掳C): Magenta : 56.1 (Tag.Closed Cup. Combustion is not sustainable.)
Cyan and Yellow : Estimate None
Flammable (Explosive) Limits: Not available

Autoignition Temperature(掳C): Magenta : 470 (ASTM-E659)
Cyan and Yellow : Not available
Flammability: Magenta : Classified as "Combustible liquid" under OSHA-HCS.
Not classified as "flammable" or "combustible" under FHSA.
Not classified as "flammable" under 1999/45/EC.
Cyan and Yellow : Neither flammable nor combustible.
Explosive Properties: None
Oxidizing Properties: None
Vapor Pressure : Not available
Vapor Density : Not available
Density / Specific Gravity: 1.04 - 1.10
Water Solubility : Miscible
Fat Solubility : Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%): 60 - 80
Evaporation Rate: Not available
Viscosity (mPa s): 1.6 - 2.6

SECTION 10 STABILITY AND REACTIVITY
Stability: Stable
Unstable
Conditions to Avoid: None
Materials to Avoid: Acids, bases, oxidizing materials and reducing agents
Hazardous Decomposition Products: CO, CO2 , NOx, Ammonia and SOx
Hazardous Polymerization: May Occur
Will Not Occur
Conditions to Avoid: None




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 5 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Yellow : Estimated LD 50 > 5000 mg/kg, 0/3 mortalities at 2000 mg/kg (rat)
OECD Guidelines No.423 (1996)
96/54/EC Method B1 tris

Cyan and Magenta : Not available
Eye:
Cyan : Minimal irritant, Maximum Group Mean Score = 8.0 - 10.0, Class 3 (rabbit)
Magenta : Minimal irritant, Maximum Group Mean Score = 2.7, Class 3 (rabbit)
Yellow : Minimal irritant, Maximum Group Mean Score = 4.7, Class 3 (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Skin:
Cyan : Mild irritant, Primary Irritation Index = 0.3 (rabbit)
Magenta : Non irritant, Primary Irritation Index = 0.0 (rabbit)
Yellow : Mild irritant, Primary Irritation Index = 0.5 (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Sensitization:
All colors : Non sensitizer, Sensitization rate = 0 % (0/10) (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Mutagenicity:
Ames test
Cyan : Negative (test strains: S.typhimurium)
Magenta and Yellow : Negative (test strains: S.typhimurium & E.Coli)
Reproductive Toxicity:
Not available
Carcinogenicity:
Not available
Others:
Not available




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 6 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

SECTION 12 ECOLOGICAL INFORMATION
Mobility: Not available
Persistence
Not available
/ Degradability:
Bioaccumulation: Not available
Ecotoxicity: Not available

Other Adverse Effects: Not available

SECTION 13 DISPOSAL CONSIDERATION
Method of Disposal:
Disposal should be subject to federal, state and local laws.

SECTION 14 TRANSPORT INFORMATION
UN #: None
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Marine Pollutant: Chemical name (wt%):
Yes
No
Special Precautions: None

SECTION 15 REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)2037/2000: Not regulated
(EC)304/2003: Not regulated
Others: None




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 7 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891

< USA Information >
Information on the Label under FHSA:
Signal Word: Not required
Hazard warning:
Not required
Safety Advice:
Not required
Hazardous Component(s):
None
SARA Title III 搂313:
Chemical Name Weight %
"Copper Compounds" (Contained only in cyan ink) 2-6
(as Cu) (< 0.35)
California Proposition 65:
Chemical Name Weight %
None
< Canada Information >
WHMIS Controlled Product: Not applicable (Manufactured article)
< Australia Information >
Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC.

SECTION 16 OTHER INFORMATION

"C. I. Direct Violet 107 " :
"A mixture of: sodium 5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-
triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-disulfonatonaphthalen-2-ylazo]-isophthalate; ammonium
5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]
-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-disulfonatonaphthalen-2-ylazo]-isophthalate;
5-[8-[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-1,3,5-triazi
n-2-ylamino]-1-hydroxy-3,6-disulfonaphthalen-2-ylazo]-isophthalic acid"


R11 : Highly flammable. R36 : Irritating to eyes. R41 : Risk of serious damage to eyes.
R67 : Vapours may cause drowsiness and dizziness.


Entirely revised.




Date of Issue: Revised:
January 19, 1996 September 9, 2003
Page 8 of 8
MSDS #: IC1301-0101
MATERIAL SAFETY DATA SHEET Product Code: 0885A / F45-0891


Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EC)304/2003
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]




Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatz-Konzentration) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
STEL: Short Term Exposure Limit.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission.



The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the date
hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims responsibility for any
reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own determination as to its
suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance with applicable Federal,
state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any nature whatsoever resulting from
the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.




Date of Issue: Revised:
January 19, 1996 September 9, 2003

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