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F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE
COMPANY / UNDERTAKING
Product Name: COLOUR BJ CARTRIDGE BC-21e
Not classified as hazardous according to the
STATEMENT OF HAZARDOUS NATURE:
criteria on Worksafe Australia.
Manufacturer: Canon Inc.
30-2, Shimomaruko 3-Chome, Ohta-ku Tokyo, Japan
Phone: 03-3758-2111
Distributor: Canon Australia Pty Ltd
1 Thomas Holt Drive
North Ryde NSW 2113
Phone: (02) 9805-2000
Date of preparation: 9 September 1997
Revised:05 December 2005
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Ingredient(s)
Chemical Name CAS# Weight % EU Symbol EU R-Phrase
Glycerin 56-81-5 5-10 None None
Ethylene glycol 107-21-1 <10 Xn R22
(contained only in black ink)
Isopropyl alcohol 67-63-0 <5 No Concern No Concern
with health with health
Chemical Name USA OSHA PEL ACGIH TLV
Glycerin ( as mist ) ( as mist )
Total dust Total dust
TWA=15 mg/m3 TWA=10 mg/m3
Respirable fraction
TWA=5mg/m3
Ethylene glycol None (aerosol)
Ceiling = 39.4 ppm
(contained only in black ink)
= 100mg/ m3
Isopropyl alcohol TWA=400 ppm, 980mg/m3 TWA=400 ppm, 983mg/m3
STEL=500 ppm, 1230mg/m3
Chemical Name EU ILV DFG MAK
Glycerin None None
Ethylene glycol None MAK= 10ppm, 26mg/m3
(contained only in black ink)
Isopropyl alcohol None MAK=400 ppm, 980mg/m3
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 2 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS 鈥? Continued
Carcinogen
Chemical Name CAS # Reference
None
Other Ingredient(s)
Chemical / Generic Name Weight %
Water 70 鈥? 90 (Black ink)
60 鈥? 90 (Colour ink)
Water-soluble organic compound 5 鈥? 10
Water-soluble organic solvent 5 鈥? 10
(contained only in colour ink)
SECTION 3 HAZARDS IDENTIFICATION
Emergency A set of four colours ink cartridge (Black, cyan, magenta, yellow)
Overview: All the ink is liquid mixture with slight odour.
Potential Health Effects and Symptoms:
Inhalation: No effects are expected under intended use.
May be harmful if inhaled in large amount.
Ingestion: May be harmful if swallowed.
Eye: Black ink: May be no irritant based on the animal test data of similar ink.
Colour ink: May cause slight irritation based on the animal test data.
Skin: Black ink: May cause slight irritation based on the animal test data of similar
ink.
Colour ink: May be no irritant based on the animal test data.
Chronic Effects: Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
Date of Issue: 10 September 1997 Revised:05 December 2005
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F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 4 FIRST AID MEASURES
First Aid Measures:
Inhalation: If person breathes in large amounts, remove to fresh air.
Get medical attention.
Ingestion: Give one or two glasses of water.
Call a physician.
Eye: Immediately flush with water for 15 minutes.
If irritation persists, get medical attention.
Skin: Wash with water and detergent.
If irritation persists, get medical attention.
Note to Physicians: None.
SECTION 5 FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing CO2, Water or dry chemicals.
Media:
Unsuitable None.
Extinguishing Media:
Special Fire None.
Fighting Procedures:
Unusual Fire and None.
Explosion Hazards:
Fire and Explosive Properties:
Black: 47.8 掳C / Colour: 56.0 掳C, (Tag c.c: Combustion not continued)
Flash Point (掳C):
Flammable No data available.
(Explosive) Limits:
Autoignition Black: 539掳C, Colour: 470掳C (ASTM-E659)
Temperature (掳C):
Flammability: Classified as 鈥渃ombustible liquid鈥? under OSHA-HCS (USA) and
鈥渘on-flammable鈥? under 88/379/EEC(EU).
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 4 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 5 FIRE FIGHTING MEASURES - Continued
Fire and Explosive Properties 鈥? Continued:
Autoflammability: None.
Explosive Properties: None.
Oxidising Properties: None.
Hazardous CO, CO2 and NOx.
Combustion Products:
Other Properties: None.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with skin and eyes.
Environmental It is recommended to keep away from drains, surface- and
Precautions: ground-water.
Method for Wipe off with wet cloth or paper.
Cleaning Up:
SECTION 7 HANDLING AND STORAGE
Handling: Avoid contact with skin, eyes and clothing, when contact, wash
out immediately.
Storage: Keep out of the reach of children.
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 5 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines: Not established.
See SECTION 2
Engineering Controls: Use usual ventilation to keep airborne concentrations
below the exposure limit. ( See SECTION 2)
Personal Protection Equipment(s):
o Required x Not Required
Respiratory
Protection:
o Required x Not Required
Eye / Face
Protection:
o Required x Not Required
Skin Protection:
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black, cyan, magenta and yellow liquid
Odour: Slight odour
pH: 8 - 10
Boiling Point / Range (掳C): No data available
Melting Point / Range (掳C): No data available
Decomposition Temperature (掳C): No data available
Flash Point (掳C): Black: 47.8掳C / Colour: 56.0掳C, (Tag. c.c : Combustion not
continued)
Flammable (Explosive) Limits: No data available
Autoignition Temperature (掳C): Black: 539掳C, Colour: 470掳C (ASTM-E659)
Flammability: Classified as 鈥渃ombustible liquid鈥? under OSHA-HCS(USA)
and 鈥渘on-flammable鈥? under 88/379/EEC(EU).
Autoflammabailty: None
Explosive Properties: None
Oxidizing Properties: None
Vapour Pressure: No data available
Vapour Density: No data available
Density / Specific Gravity: Black: 1.04, Colour: 1.07 - 1.08
Water Solubility: miscible
Fat Solubility: No data available
Partition Coefficient No data available
(n-Octanol / Water):
Percent Volatile: No data available
Evaporation Rate: No data available
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 6 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 10 STABILITY AND REACTIVITY
x Stable o Unstable
Stability:
Conditions to Avoid: None
Materials to Avoid: None
Hazardous Decomposition CO, CO2, NOx and Ammonia
Products:
o May Occur x Will Not Occur
Hazardous Polymerisation
Conditions to Avoid: None
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation: No data available
Ingestion: No data available
Eye: (Yellow ink) Rabbit: Minimally irritating (M1): the calculated maximum
Draize score: 4 (EPA (FIFRA) Pesticide Assessment Guideline par. 81-4 鈥淧rimary Eye
Irritation Study鈥?)
(Black) Data of similar composition ink:
Rabbit: Non-irritating: a maximum group mean score = 0.0
(FSHA: US 16CFR 1500.42, According to a modified Key and Calandra system)
Skin: (Yellow ink) Rabbit: Non-irritating: a primary irritation index : 0.0
(EPA (FIFRA) Pesticide Assessment Guideline par.81-5
鈥淧rimary Dermal Irritation Study鈥?)
(Black ink) Data of similar composition ink:
Rabbit: Mild irritant: a primary irritation index = 1.1
(FSHA: US 16CFR 1500.41, According to the Draize classification scheme)
Sensitisation: No data available
Mutagenicity: Negative (test strains: S. typhimurium)
Reproductive No data available
Toxicity:
Date of Issue: 10 September 1997 Revised:05 December 2005
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F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 11 TOXICOLOGICAL INFORMATION - Continued
Carcinogenicity: No human carcinogen or potential carcinogen, according to IARC
Monographs, NTP, OSHA(USA) regulation and EU Directive
(Annex I to Directive 67/548/EEC).
Others: None
SECTION 12 ECOLOGICAL INFORMATION
Mobility: No data available
Persistence / No data available
Degradability:
Bioaccumulation: No data available
Ecotoxicity: No data available
Other Adverse No data available
Effects:
SECTION 13 DISPOSAL CONSIDERATION
Method of Disposal: Disposal may be subject to federal, state, and local laws.
SECTION 14 TRANSPORT INFORMATION
UN# None
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Special Precautions: None
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 8 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 15 REGULATORY INFORMATION
EU Information:
Information on the Label:
Symbol & Not required
Indication:
R-Phrase: Not required
S-Phrase: Not Required
Dangerous Component(s):
None
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)3093/94: Not regulated
(EEC)2455/92: Not regulated
Others: None
USA Information:
Information on the Label:
Signal Word: Not required
Hazard warning: Not required
Safety Advice: Not required
Hazardous None
Component(s):
SARA Title III 搂313:
Chemical Name Weight %
Ethylene glycol <10
(contained only in black ink)
Copper compound <5
(contained only in cyan ink)
California Proposition 65:
Chemical Name Weight
None
Date of Issue: 10 September 1997 Revised:05 December 2005
Page 9 of 9
F45-1301
MATERIAL SAFETY DATA SHEET IC0168-0108
SECTION 16 OTHER INFORMATION
Other Information:
None
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environment Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report
on Carcinogens
- World Health Organisation International Agency for Research on Cancer , IARC Monographs
on the Evaluation on the Carcinogenic Risk of Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 88/379/EEC and their amendments
- EU Regulation (EC)3093/94, (EEC)2455/92 and their amendments
Abbreviations:
鈥楨U鈥? stands for European Union.
鈥極SHA PEL鈥? stands for PEL (Permissible Exposure Limit) under Occupational Safety and Health
Administration.
鈥楢CGIH TLV鈥? stands for TLV (Threshold Limit Value) under American Conference of
Government Industrial Hygienists.
鈥楨U ILV鈥? stands for Indicative Limit Values for Occupational Exposure under EU Directive
91/322/EEC.
鈥楧FG MAK鈥? stands for MAK (Maximale Arbeitsplatzkonzentrationen) under Deutsche
Forschungsgemeinschaft.
鈥楾WA鈥? stands for Time Weighted Average
鈥業ARC鈥? stands for International Agency for Research on Cancer.
鈥楴TP鈥? stands for National Toxicology Program (USA).
The Information, data and recommendations set forth herein (the 鈥淚nformation鈥?) are presented in good faith and are
believed to be correct as of the date hereof. The company / manufacturer makes no representations as to the
completeness or accuracy of the Information and disclaims responsibility for any reliance thereon. The Information is
provided upon the condition that the persons receiving same will make their own determination as to its suitability for
their purposes prior to use. Any use of the information must be determined by the user to be in accordance with
applicable Federal, State and Local laws and regulations. In no event will the company / manufacturer be responsible
for damages for any nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT
TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Date of Issue: 10 September 1997 Revised:05 December 2005
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