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MSDS Material Safety Data Sheet
CAS

56-81-5
107-21-1
111-46-6
67-63-0

File Name: canon_com_au---bc33.asp
                                                                                             Page 1 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
SECTION 1
COMPANY/UNDERTAKING
CANON BJ CARTRIDGE BC-33 FOR BUBBLE JET PRINTER
Product Name:
Not classified as hazardous according to the
STATEMENT OF HAZARDOUS NATURE:
criteria on Worksafe Australia.
Manufacturer: Canon Inc.
30-2, Shimomaruko 3-Chome, Ohta-ku Tokyo 146-8501, Japan
Phone: +81 3 3758-2111
Distributor: Canon Australia Pty Ltd
1 Thomas Holt Drive
North Ryde NSW 2113 Date of preparation : 18 February 2000
Phone: (02) 9805-2000 Revised:05 December 2005

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous Ingredient(s)
EU Symbol EU R-Phrase
Chemical Name CAS # Weight %
None
Glycerin 56-81-5 <8 None

R22
Ethylene glycol 107-21-1 <9 Xn
(Contained in cyan and magenta ink)

Diethylene glycol R22
111-46-6 <6 Xn
(Contained in black, cyan and magenta ink)
R36, 67
67-63-0 <3 Xi
Isopropyl alcohol (Contained in color ink)
Chemical Name USA OSHA PEL ACGIH TLV
(as mist)
Glycerin (as mist)
Total dust TWA = 15 mg/m3 TWA = 10 mg/m3
Respirable fraction TWA = 5 mg/m3
Ethylene glycol
(Contained in cyan and magenta ink) (aerosol) Ceiling = 100mg/m3
Not established
Diethylene glycol Not established
Not established
(Contained in black, cyan and magenta ink)
TWA = 400 ppm, 983 mg/m3
TWA = 400 ppm, 980 mg/m3
Isopropyl alcohol (Contained in color ink) STEL = 500 ppm, 1230 mg/m3

Chemical Name EU ILV DFG MAK
Glycerin Not established Not established

TWA = 10ppm, 26mg/m3
Ethylene glycol Not established
(Contained in cyan and magenta ink)

Diethylene glycol TWA = 10 ppm, 44 mg/m3
Not established
(Contained in black, cyan and magenta ink)
TWA = 200 ppm, 500 mg/m3
Not established
Isopropyl alcohol (Contained in color ink)

Date of Issue: February 18, 2000 Revised:05 December 20057
Page 2 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS - Continued

Carcinogen
Chemical Name CAS # Reference
None


Other Ingredient(s)
Chemical/Generic Name Weight %
Water 60 - 80

Ammonia derivative (Contained in color ink) <8
Glycol (Contained only in yellow ink) <8
Polyol (Contained only in black ink) <8
Black pigment (Contained only in black ink) <6


SECTION 3 HAZARDS IDENTIFICATION

Emergency A set of four colors ink cartridge. (Black, cyan, magenta and yellow)
Overview: All the ink is liquid mixture with slight odor.
Vapor or mist may cause respiratory tract and eye irritation.
Harmful if swallowed.



Potential Health Effects and Symptoms:
No adverse effects are expected under normal use.
Inhalation:
Over exposure to isopropyl alcohol, ethylene glycol and/or diethylene glycol may cause headache,
nausea, dizziness, vomiting, drowsiness, cough and sore throat. Glycerin mist may cause physical
irritation and difficulty breathing.

Ingestion: Ingestion of isopropyl alcohol, ethylene glycol, diethylene glycol and/or glycerin
may cause nausea, drowsiness, dizziness, vomiting, abdominal pain, headache and
dullness.

Eye: May cause minimal irritant based on the animal test data. (See SECTION 11)



May cause mild irritant and no sensitization based on the animal test data. (See
Skin:
SECTION 11 )


Chronic Effects: Not identified



Medical Conditions Generally known to be Aggravated by Exposure:
Not identified



Date of Issue: February 18, 2000 Revised:05 December 2005
Page 3 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 4 FIRST AID MEASURES


First Aid Measures:
Inhalation: If symptoms are experienced, move victim to fresh air and obtain medical advice.




Ingestion: If victim is conscious and alert, give one or two cupfuls of water.
If irritation or discomfort occur, obtain medical advice immediately.



Eye: Immediately flush with water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.



Skin: Wash with water and soap or mild detergent.
If irritation persist, obtain medical advice.



Note to None
Physicians:



SECTION 5 FIRE FIGHTING MEASURES


Fire Fighting Measures:
Extinguishing Media: CO2, water, foam or dry chemicals.

Unsuitable None
Extinguishing Media:
None
Special Fire
Fighting Procedures:
None
Unusual Fire and
Explosion Hazards:

Fire and Explosive Properties:
Black : None, Cyan : 56.0, Magenta : 55.0, Yellow : 56.5 (Tag. closed cup. Do not sustain combustion.)
Flash Point(掳C):
Flammable(Explosive) No data available
Limits:
Autoignition No data available
Temperature(掳C):
Black : Not classified as "flammable" or "combustible liquid" under FHSA (USA), OSHA-HCS(USA) and 88/379/EEC(EU).
Flammability: Color : Classified as "non-flammable" under 88/379/EEC(EU) and FHSA (USA) and "combustible liquid" under OSHA-HCS(USA).




Date of Issue: February 18, 2000 Revised:05 December 2005
Page 4 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 5 FIRE FIGHTING MEASURES - Continued


Fire and Explosive Properties - Continued:
Autoflammability: None
Explosive Properties: None
Oxidizing Properties: None
Hazardous CO, CO2 and NOx.
Combustion Products:

Other Properties: None



SECTION 6 ACCIDENTAL RELEASE MEASURES


Personal Precautions: Avoid contact with skin, eyes and clothing.




Environmental Do not release into sewer, surface water or ground water.
Precautions:



Method for Cleaning Wipe off with wet cloth or paper.
Up:




SECTION 7 HANDLING AND STORAGE


Handling: Avoid contact with skin, eyes and clothing. When contact, wash out immediately.




Storage: Keep out of the reach of children.
Keep in a cool and dry place.




Date of Issue: February 18, 2000 Revised:05 December 2005
Page 5 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines: Not established for this material.
(See SECTION 2)




Engineering Controls: Use usual ventilation to keep airborne concentrations below the exposure
limit.(See SECTION 2)

Personal Protection Equipment(s):
Required Not Required
Respiratory
Protection:

Eye/Face Required Not Required
Protection:

Skin Protection: Required Not Required



SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Black, cyan, magenta and yellow liquid

Odor: Slight odor
pH: Black : 6.5-8.0, Color : 10-11
Boiling Point/Range(掳C): No data available
Melting Point/Range(掳C): No data available
Decomposition Temperature(掳C): No data available
Black : None, Cyan : 56.0, Magenta : 55.0, Yellow : 56.5 (Tag. closed cup. Do not sustain combustion.)
Flash Point(掳C):
Flammable (Explosive) Limits: No data available
Autoignition Temperature(掳C): No data available
Flammability: Black : Not classified as "flammable" or "combustible liquid" under FHSA (USA), OSHA-HCS(USA) and 88/379/EEC(EU).
Color : Classified as "non-flammable" under 88/379/EEC(EU) and FHSA (USA) and "combustible liquid" under
OSHA-HCS(USA).


None
Autoflammability:
None
Explosive Properties:
None
Oxidizing Properties:
No data available
Vapor Pressure:
Vapor Density: No data available
Density / Specific Gravity: 1.05 - 1.07
Water Solubility: Miscible
Fat Solubility: No data available
Partition Coefficient
No data available
(n-Octanol/Water):
65-85 %
Percent Volatile:
No data available
Evaporation Rate:
Date of Issue: February 18, 2000 Revised:05 December 2005
Page 6 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 10 STABILITY AND REACTIVITY

Stability: Stable Unstable
Conditions to Avoid: None

Materials to Avoid: None

Hazardous Decomposition CO, CO2, NOx and Ammonia.
Products:

Hazardous Polymerization: May Occur Will Not Occur
Conditions to Avoid: None


SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation: No data available




No data available
Ingestion:




Black : Minimal irritant; Maximum Group Mean Score = 5.3, Class 3 (rabbit)
Eye:
Cyan : Minimal irritant; Maximum Group Mean Score = 8.7, Class 3 (rabbit)
Magenta : Minimal irritant; Maximum Group Mean Score = 8.0, Class 3 (rabbit)
Yellow: Minimal irritant; Maximum Group Mean Score = 6.7, Class 3 (rabbit)
OECD Guidelines No.405
Commission Directive 92/69/EEC Method B5

Black : Mild irritant; Primary Irritation Index (PII) = 0.5 (rabbit)
Skin:
Cyan : Mild irritant; Primary Irritation Index (PII) = 0.8 (rabbit)
Magenta : Mild irritant; Primary Irritation Index (PII) = 1.2 (rabbit)
Yellow : Mild irritant; Primary Irritation Index (PII) = 1.3 (rabbit)
OECD Guidelines No.404
Commission Directive 92/69/EEC Method B4

Sensitization: Non sensitizer; (guinea pig) Sensitization rate= 0% (0/10)
OECD Guidelines No.406
Commission Directive 92/69/EEC Method B6

Mutagenicity: Ames test : Negative
(test strains: S.typhimrium)


Reproductive No data available
Toxicity:


Date of Issue: February 18, 2000 Revised:05 December 2005
Page 7 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 11 TOXICOLOGICAL INFORMATION - Continued

No human carcinogen or potential carcinogen, according to ACGIH, DFG, IARC
Carcinogenicity:
Monographs, NTP, OSHA(USA) regulation and EU Directive (Annex I to Directive
67/548/EEC).


Others: None




SECTION 12 ECOLOGICAL INFORMATION

Mobility: No data available


Persistence / No data available
Degradability:

Bioaccumulation: No data available


Ecotoxicity: No data available


Other Adverse No data available
Effects:

SECTION 13 DISPOSAL CONSIDERATION

Method of Disposal: Disposal may be subject to federal, state and local laws.




SECTION 14 TRANSPORT INFORMATION


UN #: None
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Special Precautions: None


Date of Issue: February 18, 2000 Revised:05 December 2005
Page 8 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101

SECTION 15 REGULATORY INFORMATION

EU Information:
Information on the Label:
Symbol & Not required
Indication:
Not required
R-Phrase:


S-Phrase: Not required



Dangerous None
Component(s):


Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated

(EC)3093/94: Not regulated

(EEC)2455/92: Not regulated

None
Others:

USA Information:
Information on the Label :
Signal Word: None
Hazard warning: None


None
Safety Advice:



None
Hazardous
Component(s):

SARA Title III 搂313:
Chemical Name Weight %
Ethylene glycol (107-21-1) <9

Copper compounds (Contained only in cyan ink) <5
As copper metal < 0.35
California Proposition 65:
Chemical Name Weight %
None


Date of Issue: February 18, 2000 Revised:05 December 2005
Page 9 of 9
F45-1491
MATERIAL SAFETY DATA SHEET IC0289-0101
SECTION 16 OTHER INFORMATION

Other Information:
None




Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure
Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on
Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the
Evaluation on the Carcinogenic Risk of Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 88/379/EEC
- EU Regulation (EC)3093/94, (EEC)2455/92


Abbreviations:
"EU" stands for European Union.
"OSHA PEL" stands for PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration.
"ACGIH TLV" stands for TLV(Threshold Limit Value) under American Conference of Governmental Industrial
Hygienists.
"EU ILV" stands for Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC.
"DFG MAK" stands for MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
"TWA" stands for Time Weighted Average.
"IARC" stands for International Agency for Research on Cancer.
"NTP" stands for National Toxicology Program (USA).
"OSHA HCS" stands for Occupational Safety and Health Act, Hazard Communication Standard.
"FHSA" stands for Federal Hazardous Substances Act.



The information, data and recommendations set forth herein (the "Information") are presented in good faith and are
believed to be correct as of the date hereof. The company/manufacturer makes no representations as to the
completeness or accuracy of the Information and disclaims responsibility for any reliance thereon. The Information
is provided upon the condition that the persons receiving same will make their own determination as to its suitability
for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance with
applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible
for damages of any nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT
TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.




Date of Issue: February 18, 2000

Revised Date: 05 December 2005

Date of Issue: February 18, 2000 Revised:05 December 2005

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