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MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
BJW7250 Cyan
Product Name: Canon Ink Tank BCI-1401C
Distributor: Canon Australia Pty Ltd
Product Code: 7569A001AA
Company Name: 1 Thomas Holt Drive,
Canon Inc.
North Ryde NSW 2113
Address: 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
Ph: 02 9805 2000
Use of the Product: Ink for Ink Jet Printer
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
CAS # / Weight EU Symbol/ USA
Chemical Name / ACGIH TLV EU ILV DFG MAK
EC # % R-Phrase OSHA PEL
Generic name
Glycerin 56-81-5 / 5 - 10 None/ None (as mist) (as mist) Not established Not established
TWA = 10 mg/m3
200-289-5 Total dust
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3
Ethylene glycol 107-21-1 / 2-6 Xn/ R22 Not established (aerosol) TWA = 20 ppm, 10 ppm,
52 mg/m3 26 mg/m3
203-473-3 Ceiling =
100 mg/m3 STEL = 40 ppm,
104 mg/m3
Diethylene glycol 111-46-6 / 2-6 Xn/ R22 Not established Not established Not established 10 ppm,
44 mg/m3
203-872-2
Copper, 90295-11-7 / 2-6 Xi/ R36 Not established Not established Not established Copper and its
[29H,31H-phthalocyaninato(2-)-
291-001-7 compounds
N29,N30,N31,N32]-,
Inhalable fraction
aminosulfonyl sulfo derivs.,
1.0 mg/m3
sodium salts
Isopropyl alcohol 67-63-0 / 1-3 F/ R11, TWA = 400 ppm, TWA = 400 ppm, Not established 200 ppm,
980 mg/m3 983 mg/m3 500 mg/m3
200-661-7 Xi/ R36,
R67 STEL = 500 ppm,
1230 mg/m3
Poly(oxy-1,2-ethanediyl), 9014-85-1 / 1-3 Xi/ R41 Not established Not established Not established Not established
.alpha.,.alpha.'-[1,4-dimethyl-1,4- Not applicable
bis(2-methylpropyl)-2-butyne-1,4
-diyl]bis[.omega.-hydroxy-
Ammonia derivative Confidential 5 - 10 None/ None Not established Not established Not established Not established
Water 7732-18-5 / 50 - 70 None/ None Not established Not established Not established Not established
231-79-12
Date of Issue: June 17, 2002 Revised:
Page 2 of 8
MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
< Carcinogen >
Chemical Name CAS # Reference
None
SECTION 3 HAZARDS IDENTIFICATION
EU Classification:
Not classified as dangerous.
Emergency Overview:
Ink tank containing cyan liquid ink with slight odor.
Combustible liquid and vapor.
Vapor or mist may cause respiratory tract, skin and eye irritation.
Potential Health Effects and Symptoms:
Inhalation:
No adverse effects are expected under intended use.
Glycerin mist may cause physical irritation and difficulty breathing.
Over exposure to ethylene glycol, diethylene glycol and/or isopropyl alcohol may cause headache, nausea,
dizziness, vomiting, drowsiness, sore throat and cough.
Ingestion:
Ingestion of glycerin, ethylene glycol, diethylene glycol and/or isopropyl alcohol may cause headache, nausea,
dizziness, vomiting, drowsiness, sore throat, abdominal pain, dullness and diarrhea.
Eye:
May cause minimal irritation based on the animal test data of this ink.
(See SECTION 11)
Skin:
May be no irritation and no sensitization based on the animal test data of this ink.
(See SECTION 11)
Chronic Effects:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
Not identified
SECTION 4 FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Immediately flush with water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Note to Physicians:
None
Date of Issue: June 17, 2002 Revised:
Page 3 of 8
MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
SECTION 5 FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2, water, foam or dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO, CO2 and NOx
Other Properties:
None
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid breathing vapor or mist.
Avoid contact with skin, eyes and clothing.
Environmental Precautions:
Do not release to sewer, surface water or ground water.
Method for Cleaning Up:
Wipe off with wet cloth or paper.
SECTION 7 HANDLING AND STORAGE
Handling:
Avoid breathing vapor or mist.
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing. When contact, wash out immediately.
Storage:
Keep away from heat and flame.
Keep in a cool and dry place.
Protect from sunlight.
Specific Uses:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Not established for this ink. (Also refer to SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Respiratory Protection: Required
Not Required
Eye/Face Protection: Required
Not Required
Skin Protection: Required
Not Required
Date of Issue: June 17, 2002 Revised:
Page 4 of 8
MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Cyan liquid
Odor: Slight odor
pH: 9.4 - 10.4
Boiling Point/Range(掳C): Not available
Melting Point/Range(掳C): Not available
Decomposition Temperature(掳C): Not available
Flash Point(掳C): 57.2 (Tag. closed cup. Do not sustain combustion.)
Flammable (Explosive) Limits: Not available
Autoignition Temperature(掳C): Not available
Flammability: Classified as "Combustible liquid" under OSHA-HCS.
Not Classified as "flammable" or "combustible" under FHSA.
Not Classified as "flammable" under 1999/45/EC.
Explosive Properties: None
Oxidizing Properties: None
Vapor Pressure : Not available
Vapor Density : Not available
Density / Specific Gravity: 1.09
Water Solubility : Miscible
Fat Solubility : Not available
Partition Coefficient (n-Octanol/Water): Not available
Percent Volatile (%): 50 - 70
Evaporation Rate: Not available
Viscosity (mPa s): 2.5 - 3.1
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable
Unstable
Conditions to Avoid: None
Materials to Avoid: Acids, bases, oxidizing materials and reducing agents
Hazardous Decomposition Products: CO, CO2, NOx and Ammonia
Hazardous Polymerization: May Occur
Will Not Occur
Conditions to Avoid: None
Date of Issue: June 17, 2002 Revised:
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MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Not available
Eye:
Minimal irritant, Maximum Group Mean Score = 4.0 Class 3 (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Skin:
Non irritant, Primary Irritation Index = 0.0 (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Sensitization:
Non sensitizer, Sensitization rate = 0% (0/10) (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Mutagenicity:
Ames test : Negative (test strains: S.typhimurium & E.Coli)
Reproductive Toxicity:
Not available
Carcinogenicity:
No component of this ink is listed as human carcinogen or potential carcinogen in IARC Monographs, NTP,
OSHA regulations or Annex I to Directive 67/548/EEC.
Others:
Not available
Date of Issue: June 17, 2002 Revised:
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MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
SECTION 12 ECOLOGICAL INFORMATION
Mobility: Not available
Persistence / Degradability: Not available
Bioaccumulation: Not available
Ecotoxicity: Not available
Other Adverse Effects: Not available
SECTION 13 DISPOSAL CONSIDERATION
Method of Disposal:
Disposal may be subject to federal, state and local laws.
SECTION 14 TRANSPORT INFORMATION
UN #: None
UN Shipping Name: None
UN Classification: None
UN Packing Group: None
Marine Pollutant: Chemical name (wt%):
Yes
No
Special Precautions: None
SECTION 15 REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Safety data sheet available for professional user on request.
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)2037/2000: Not regulated
(EEC)2455/92: Not regulated
Others: None
Date of Issue: June 17, 2002 Revised:
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MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
< USA Information >
Information on the Label under OSHA HCS:
Signal Word: Not required
Hazard warning:
COMBUSTIBLE LIQUID AND VAPOR.
VAPOR OR MIST MAY CAUSE RESPIRATORY TRACT, SKIN AND EYE IRRITATION.
Safety Advice:
Not required
Hazardous Component(s):
Glycerin (56-81-5) 5 - 10 % Ethylene glycol (107-21-1) 2-6%
Isopropyl alcohol (67-63-0) 1-3%
SARA Title III 搂313:
Chemical Name Weight %
Ethylene glycol (107-21-1) 2-6
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, aminosulfonyl sulfo derivs., 2-6
sodium salts (90295-11-7)
(as Cu) (< 0.35)
California Proposition 65:
Chemical Name Weight %
None
< Canada Information >
WHMIS Controlled Product: Not applicable (Manufactured article)
< Australia Information >
Statement of Hazardous Nature: Not classified as hazardous according to criteria of NOHSC.
SECTION 16 OTHER INFORMATION
R11 : Highly flammable.
R22 : Harmful if swallowed.
R36 : Irritating to eyes.
R41 : Risk of serious damage to eyes.
R67 : Vapours may cause drowsiness and dizziness.
Date of Issue: June 17, 2002 Revised:
Page 8 of 8
MSDS #: IC1056-0101
MATERIAL SAFETY DATA SHEET 7569A001AA
Product Code:
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EEC)2455/92
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission Act 1985.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the
date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance
with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any
nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
Date of Issue: June 17, 2002 Revised:
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