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MSDS Material Safety Data Sheet
CAS

25852-47-5
9004-96-0
81-07-2
80-15-9
57-55-6
112945-52-5
613-48-9
13463-67-7

File Name: ezmsds_com---12.asp
Product Name: Removable Threadlocker 242(R)                                       Page 1 of 5



LOCTITE CORPORATION 05/26/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 01 of 05

Removable Threadlocker 242(R)
24205

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Removable Threadlocker 242(R)
Item No.: 24205
Product Type: Anaerobic

2. COMPOSITION, INFORMATION ON INGREDIENTS

Ingredients CAS No. %

Polyglycol dimethacrylate 25852-47-5 60-65
Polyglycol oleate 9004-96-0 25-30
Saccharin 81-07-2 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
Propylene glycol 57-55-6 1-3
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 1-3
N,N-Dialkyltoluidines 613-48-9 0.1-1
TITANIUM DIOXIDE 13463-67-7 0.1-0.5

* This component is listed as a SARA Section 313 Toxic Chemical.

Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)

CUMENE HYDROPEROXIDE None None 1ppm(6mg/m3)
Skin(WEEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
TITANIUM DIOXIDE 10 mg/m3 15 mg/m3 None
Total dust

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)

3. HAZARDS IDENTIFICATION

Toxicity: Mild eye irritant. Propylene glycol is a mild
skin irritant.
Primary Routes of Entry: Eye, skin contact.
Signs and Symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals.

LOCTITE CORPORATION 05/26/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100




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Product Name: Removable Threadlocker 242(R) Page 2 of 5



MATERIAL SAFETY DATA SHEET Page 02 of 05

Product Name: Removable Threadlocker 242(R)
Item No.: 24205

3. HAZARDS IDENTIFICATION (continued)

Existing Conditions
Aggravated by Exposure: Propylene glycol: dermatitis.

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

Polyglycol dimethacrylate ALG IRR NO NO NO
Polyglycol oleate IRR NO NO NO
Saccharin NTO NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
Propylene glycol IRR NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
N,N-Dialkyltoluidines NTO NO NO NO
TITANIUM DIOXIDE IRR RES NO NO NO
-------------------------------------------------------------------------------

Abbreviations

N/A Not Applicable ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant MUT Mutagen
NTO No Target Organs NUI Nuisance dust
RES Respiratory

4. FIRST AID MEASURES

Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Does not apply.
Skin Contact: Wash thoroughly with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.

5. FIRE FIGHTING MEASURES

Flash Point: More than 200掳F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon.
Unusual Fire or
Explosion Hazards: None

Explosive Limits:

LOCTITE CORPORATION 05/26/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 03 of 05




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Product Name: Removable Threadlocker 242(R) Page 3 of 5




Product Name: Removable Threadlocker 242(R)
Item No.: 24205

5. FIRE FIGHTING MEASURES (continued)

(% by volume in air)Lower Propylene glycol: 2.6%
(% by volume in air)Upper Propylene glycol: 12.5%

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Soak up in an inert absorbant. Store in a partly
filled, closed container until disposal.

7. HANDLING AND STORAGE

Safe Storage: Store below 100掳F
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Neoprene, rubber, or butyl rubber gloves.
Ventilation: Does not apply
Respiratory Does not apply.

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Blue liquid
Odor: Mild
Boiling Point: More than 300掳F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.1 at 75掳F
Volatile Organic Compound
(EPA Method 24) 4.478%; 49.3 grams per liter
Vapor Pressure: Less than 5mm at 80掳F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, free radical initiators, inert
gases.
Conditions to Avoid: None known.
Hazardous Decomposition
Products (non-thermal): None

LOCTITE CORPORATION 05/26/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 04 of 05




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Product Name: Removable Threadlocker 242(R) Page 4 of 5




Product Name: Removable Threadlocker 242(R)
Item No.: 24205

11. TOXICOLOGICAL INFORMATION

Oral LD50 more than 10000 mg/kg.
Dermal LD50 more than 5000 mg/kg.

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material

14. TRANSPORTATION INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None

15. REGULATORY INFORMATION

CA Proposition 65: No California Proposition 65 chemicals are known
to be present.

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 1*
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.

NFPA is a registered trademark of the National Fire Protection Assn.

LOCTITE CORPORATION 05/26/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 05 of 05




file://C:\Documents%20and%20Settings\Paul%20Whitesell\My%20Documents\All%20... 10/26/2004
Product Name: Removable Threadlocker 242(R) Page 5 of 5




Product Name: Removable Threadlocker 242(R)
Item No.: 24205

16. OTHER INFORMATION (continued)

HMIS is a registered trademark of the National Paint and Coatings Assn.

Prepared By: Stephen Repetto
Title: Research Chemist - Health & Regulatory Affairs
Company: Loctite Corporation
1001 Trout Brook Crossing, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 27, 1999 Revision: 0033



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