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MSDS Material Safety Data Sheet
CAS

57-55-6

File Name: whitakeroil_com---PGIND.asp
                                     MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT

PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
7/1/2000
MSDS CD DATE :
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY

PRODUCT CODE AND NAME

PGIND PROPYLENE GLYCOL - INDUSTRIAL


Chemical Name and/or Family or Description:

Glycol




COMPANY INFORMATION

Huntsman ICI Chemicals, LLC
500 Huntsman Way
Salt Lake City, UT 84108

TELEPHONE NUMBERS
Transportation Emergency
Company: (409) 727-0831
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (713) 235-6432
Technical Information: (512) 459-6543



2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
NONE X
OSHA IARC NTP OTHER

Composition:

Chemical Name CAS Number Exposure Limits Range in %
1,2-propanediol 57-55-6 100.00

THIS PRODUCT IS CONSIDERED NON-HAZARDOUS ACCORDING TO OSHA (1910.1200).




1
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Colorless mobile liquid

Odor:
Mild odor

WARNING STATEMENT
CAUTION! ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE



Hazardous Material National Fire Protection
0
Health Flammability
1
Information System Association NFPA
1
Fire
0 0 Reactivity
(United States) (United States) Health
0
Reactivity

Personal protection Specific danger




POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X Skin X Inhalation X Ingestion
Effects of Overexposure

Acute:
May cause minimal irritation, experienced as temporary discomfort.
Eyes:
Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may
Skin:
cause defatting of skin or irritation, seen as local redness with possible mild discomfort.

Other than the potential skin irritation effects noted above, acute (short term) adverse effects
are not expected from brief skin contact; see other effects, below, and Section 11 for
information regarding potential long term effects.
Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations
Inhalation:
generated from spraying, heating the material or as from exposure in poorly ventilated areas
or confined spaces, may cause irritation of the nose and throat, headache, nausea, and
drowsiness.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea
Ingestion:
may occur. Aspiration may occur during swallowing or vomiting resulting in lung damage.
Unknown
Sensitization Properties:

Chronic:
No adverse effects have been documented in humans as a result of chronic exposure. Section 11 may contain applicable
animal data.

Medical Conditions Aggravated by Exposure:
There is no evidence that this product aggravates an existing medical condition.


Other Remarks:
None




2
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

4. FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists.

Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists.

Ingestion:
If person is conscious and can swallow, give two glasses of water (16 oz.) but do not induce vomiting. If vomiting occurs, give fluids
again. Have medical personnel determine if evacuation of stomach or induction of vomiting is necessary. Do not give anything by
mouth to an unconscious or convulsing person.
Inhalation:
If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or
respiratory irritation persists.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung injury. If evacuation of stomach is necessary, use
method least likely to cause aspiration, such as gastric lavage after endotracheal intubation. Contact a Poison Center for
additional treatment information.


5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
371.1 (700 F)
Flash Point (degrees C):
100 (212 F) CC
Flammable Limits % (Lower-Upper):
Lower: 2.6
Upper: 12.5
Recommended Fire Extinguishing Agents And Special Procedures:

Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers. Water
or foam may cause frothing.
Unusual or Explosive Hazards:

None

Special Protective Equipment for Firefighters:

No special equipment or procedures required.



6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:

Contain spill if possible, contain with absorbent materials such as clay or soil, and shovel up. Avoid skin and eye contact.




3
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

7. HANDLING AND STORAGE
Precautions to be Taken in

Handling:
Minimum feasible handling temperatures should be maintained.

Storage:
Periods of exposure to high temperatures should be minimized. Water contamination should be avoided.



8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)

Eye/Face Protection:
Safety glasses, chemical type goggles, or face shield recommended to prevent eye contact.

Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or dry-cleaned.


Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust ventilation is not available or inadequate, use
MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for the Total Product:
None established for product.



9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Colorless mobile liquid

Odor:
Mild odor

Boiling Point (degrees C):
187.2 (369 F)

Melting/Freezing Point (degrees C):
< -60 (< -76 F)
Specific Gravity (water=1):
1.0381

pH:
6
Vapor Pressure:
< 1 mm Hg at 25 C ( 77 F)


4
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
Viscosity:
< 20 cSt at 40 C ( 104 F )

VOC Content:
28% by ASTM D 2369

Vapor Density (Air=1):
2.6
Solubility in Water (%):
> 10
Other:
None



10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
None of these X
Air Water Heat Strong Oxidizers Others

Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.

Hazardous Polymerizations:
DO NOT OCCUR



11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Believed to be practically non-toxic
Dermal:
LD50 > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
Skin:
(Draize) Believed to be < .50 /8.0 (rabbit) no appreciable effect
Eyes:
(Draize)Believed to be < 15.00 /110 (rabbit) no appreciable effect
Sensitization:
Not determined.
Other:

None




5
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its
purchased form. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the
product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may
render the resulting materials hazardous.
Remarks:
None


13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Not regulated

Hazard Class:
Not regulated

Identification Number:
Not regulated

Packing Group:
Not regulated

Label Required:
Not regulated



IMDG
Proper Shipping Name:
Not regulated
ICAO
Proper Shipping Name:
Not regulated

TDG
Proper Shipping Name:
Not regulated
Hazard Class:
Not regulated

Identification Number:
Not regulated

Label Required:
Not regulated




6
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances

Chemical Name CAS Number Range in % TPQ RQ
None.

Section 311 Hazardous Categorization:
N/A X
Acute Chronic Fire Pressure Reactive
Section 313 Toxic Chemical

Chemical Name CAS Number Concentration
None.

CERCLA 102(a)/DOT Hazardous Substances:

Chemical Name CAS Number Range in % RQ
None.

States Right-to-Know Regulations:
Chemical Name State Right-to-know
None.

State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan), LA (Louisiana), MA
(Massachusetts), NJ (New Jersey), PA (Pennsylvania), RI (Rhode Island)

California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.

Chemical Name CAS Number
None.
INTERNATIONAL REGULATIONS:


TSCA Inventory Status:
This product, or its components, are listed on, or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
WHMIS Classification:
Not regulated.

Canadian Inventory Status:
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).

EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances (EINECS) or
the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).

Japan Inventory Status:
This product, or its components, are listed on or are exempt from the Japanese Ministry of International Trade and Industry (MITI)
inventory.




7
PRODUCT CODE AND NAME PGIND PROPYLENE GLYCOL - INDUSTRIAL
:
ISSUE DATE : 07/01/1999
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN

15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
LC50-96hr Aquatic toxicity rating is believed to be > 100.00 mg/liter practically nontoxic

Mobility:
Not determined.

Persistence and Biodegradability:
This product is reported to have a moderate (>= 30%) rate of biodegradation in a test for ready biodegradation.

Potential to Bioaccumulate:
This product is reported to have a low potential to bioconcentrate.

Remarks:
None


16. OTHER INFORMATION 07/01/1999
This product is currently on the FDA's GRAS (generally regarded as safe) list.
Supercedes: 5/20/1997 The following section has been revised: 1

Print Date: 06/09/2000


THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED
FOR THE PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN鈥橲 PRODUCT SAFETY PROGRAM. IT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE PRODUCT BY A PROPERLY TRAINED PERSON.
YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESIGNATED, AND DOES NOT
RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE OF THE PRODUCT IN ANY
PROCESS. THE DATA IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO
EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS FOR A PARTICULAR PURPOSE IS MADE
WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE INFORMATION CONTAINED IN THIS DATA SHEET.

TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT,
THE USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT
UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.

CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR
ALL HUNTSMAN PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (713) 235-6432 OR DIRECTING YOUR INQUIRIES TO:

HUNTSMAN
COORDINATOR, PRODUCT SAFETY
P.O. Box 27707
HOUSTON, TX 77227-7707

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR
MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE
REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN.
ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO
HUNTSMAN, COORDINATOR, PRODUCT SAFETY AT THE ABOVE ADDRESS.

COPYRIGHT 漏 1999 BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.

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