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MSDS Material Safety Data Sheet
CAS

1569-01-3
10215-30-2
57-55-6
25265-71-8
29911-27-1

File Name: whitakeroil_com---PNP_msds.asp
                                                                                     MSDS No.:            BE1607
Material Safety Data Sheet Variant: Asia-EN
Version No: 1.1
Validation Date: 28.12.2001
ARCOSOLV庐 PNP

SECTION 1: IDENTIFICATION
Product Name: ARCOSOLV庐 PNP
Product Number: 000000000000499218

Chemical Name: 2-Propanol, 1-Propoxy-

CAS Number: 1569-01-3

Chemical Family: Aliphatic Propylene Glycol Ethers
Synonyms: Propylene Glycol n-Propyl Ether, PNP, Dipropylene Glycol Monopropyl Ether

Lyondell Greater China, Ltd.
Manufacturer: Telephone Numbers:
Emergency: (886) 933-635-556
4101 41/F., The Lee Gardens
33 Hysan Avenue, Causeway Bay Taiwan
Hong Kong

Non-Emergency: +852 2882-2668


SECTION 2 : Composition/Information on Ingredients
Concentration by Wt./Mol%
Avg. Min. Max.
Component Name: CAS #. EU Inventory Number:
1-Propoxy-2-Propanol 1569-01-3 EINECS 216-372-4 90.0
2-Propoxy-1-Propanol 10215-30-2 Not Assigned 6.9
Propylene Glycol 57-55-6 EINECS 200-338-0 4.9
Dipropylene Glycol 25265-71-8 EINECS 246-770-3 4.9
Dipropylene Glycol Monopropyl 29911-27-1 EINECS 249-949-4 4.9
Ether

SECTION 3: HAZARD IDENTIFICATION
Hazards: Flammable liquid. Irritant. No complementary information is available.

Physical State: Liquid.

Color: Clear, colorless.

Odor: Mild odor.

Potential Health Effects

Routes of Exposure: Eye Skin.

Signs and Symptoms
of Acute Exposure: See component summary.

鈥? May cause severe eye irritation. Excessive exposures may affect central nervous system
1-Propoxy-2-
(CNS), cause skin irritation and produce anesthetic or narcotic effects.
Propanol



Page 1 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001

鈥? Slight eye irritant.
Propylene Glycol

鈥? Dipropylene Glycol Slight eye irritant. Slight skin irritant.

鈥? Dipropylene Glycol Slight eye irritant. Slight ingestion hazard.
Monopropyl Ether
Skin: May cause moderate skin irritation. Extensive/prolonged or repeated exposure to this
material can result in significant absorption.

Inhalation: Prolonged overexposure may cause coughing, shortness of breath, dizziness and
intoxication.

Eye: May cause severe eye irritation. Mild to severe conjunctivitis may develop, seen as
excess redness and swelling of the conjunctiva. Permanent corneal damage is not
expected.

Ingestion: This material may be a slight health hazard if ingested in large quantities.

Chronic Health See component summary.
Effects:
鈥? 1-Propoxy-2- Repeated or prolonged skin contact may cause progressive dermatitis and may aggravate
pre-existing dermatitis. Repeated or prolonged exposure to vapors may aggravate asthma
Propanol
and other respiratory conditions.

鈥? No chronic health hazards are expected to occur from anticipated conditions of normal use
Propylene Glycol
of this material.

鈥? Dipropylene Glycol No adverse chronic health effects are expected from anticipated conditions of normal use
of this material.

鈥? Dipropylene Glycol No adverse chronic health effects are expected from anticipated conditions of normal use
Monopropyl Ether of this material.

Conditions
Aggravated by This material or its emissions may affect the central nervous system (CNS) and/or
Exposure: aggravate pre-existing CNS disorders. Prolonged observation may be indicated.


SECTION 4: FIRST AID MEASURES
General: After adequate first aid, no further treatment is required unless symptoms reappear.

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain medical attention if breathing difficulty persists.

Eye: Immediately flush the eyes with large amounts of clean low-pressure water for at least 15
minutes, occasionally lifting the upper and lower lids. If pain or irritation persists, promptly
obtain medical attention.

Skin: Promptly remove soiled clothing/wash thoroughly before reuse. Wash skin thoroughly with
mild soap and water. Flush with lukewarm water for 15 minutes. If sticky, use waterless
cleaner first. Seek medical attention if ill effect or irritation develops.

Ingestion: If large quantity swallowed, give lukewarm water (pint/ 1/2 litre) if victim completely
conscious/alert. Do not induce vomiting. Risk of damage to lungs exceeds poisoning risk.
Obtain emergency medical attention.


Page 2 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001

Physician's
Detoxification If swallowed, DO NOT INDUCE VOMITING. Gastric lavage and cathartic indicated. Treat
Procedures: symptomatically. Treatment of overexposure should be directed at the control of symptoms
and the clinical condition of the patient.


SECTION 5: FIRE FIGHTING MEASURES
Flammability Flammable liquid.
Classification:
Flash Point / Method: ~ 48 掳C(118.4 掳F)(TCC)

Auto-Ignition
Temperature: No Data Available.


Flammable Limits: LOWER: 1.3 vol%

UPPER: 16.9 vol%

Hazardous
Combustion Thermal decomposition may produce carbon monoxide and other toxic vapors.
Products:
Special Conditions to Fine sprays/mists may be combustible at temperatures below normal flash point. When
Avoid: heated above the flash point, releases flammable vapors. When mixed with air and
exposed to ignition source, vapors can burn in open or explode if confined. Vapors may be
heavier than air. May travel long distances along the ground before igniting and flashing
back to vapor source.

Extinguishing Media: Suitable: SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Use water spray, water fog or alcohol-resistant foam.

Unsuitable: Do not use solid water stream/may spread fire.

Fire Fighting Protective Equipment/Clothing: Wear positive pressure self-contained breathing
Instructions: apparatus (SCBA). Structural firefighters protective clothing will only provide limited
protection.

INSTRUCTIONS: Fight fire from maximum distance or use unmanned hose holders or
monitor nozzles. Move containers form fire area if you can do it without risk. Cool
containers with flooding quantities of water until well after fire is out. Withdraw
immediately in case of rising sound from venting safety devices or discoloration of tank.
Always stay away from tanks engulfed in fire. For massive fire, use unmanned hose
holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.


SECTION 6: ACCIDENTAL RELEASE MEASURES
Release Response: Extinguish all ignition sources. All equipment used when handling this product must be
grounded. Do not touch or walk through spilled material. Stop leak if you can do it without
risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor
suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or
other non-combustible material and transfer to containers. Use clean non-sparking tools to
collect absorbed material. Dike large spills and place materials in salvage containers.
Water spray may reduce vapor; but may not prevent ignition in closed spaces.


SECTION 7: HANDLING AND STORAGE

Page 3 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001

Handling: For industrial use only. Keep container tightly closed when not in use. Handle empty
containers with care. All electrical equipment should be grounded and conform to
applicable electric codes and regulatory requirements. Flammable/combustible residue
remains after emptying. Properly ground containers before beginning transfer. Use only
non-sparking tools. Isolate, vent, drain, wash and purge systems or equipment before
maintenance or repair. Extinguish all ignition sources. Check atmosphere for
explosiveness and oxygen deficiencies. Observe precautions pertaining to confined space
entry.

Storage: Storage under nitrogen atmosphere is recommended to minimize possible formation of
highly reactive peroxides. Store only in tightly closed, properly vented containers away
from heat, sparks, open flame and strong oxidizing agents. Store in properly lined
steel/stainless steel to avoid slight discoloration from mild steel/copper. Some
plastics/rubbers are attacked by Glycol Ethers/Ether Esters. This product will absorb water
if exposed to air.


SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering General room or local exhaust ventilation is usually required to meet exposure limit(s).
Controls:
Personal Protection:
Inhalation: If exposure exceeds the exposure limit(s), use respiratory equipment recommended or
approved by appropriate local, state or international agency.

Skin: Wear chemical resistant gloves such as: Butyl rubber. or Viton(TM). When skin contact
is possible, protective clothing including gloves, apron, sleeves, boots, head and face
protection should be worn. The equipment must be cleaned thoroughly after each use.

Eye: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying liquid, airborne particles, or
vapor.

Other Hygienic Selection of appropriate personal protective equipment should be based on an evaluation
Practices: of the performance characteristics of the protective equipment relative to the task(s) to be
performed, conditions present, duration of use, and the hazards and/or potential hazards
that may be encountered during use. Emergency eye wash fountains and safety showers
should be available in the immediate vicinity of any potential exposure.

Recommended Work
Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or
using toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse.

Occupational Exposure Limits:

Component Name: Source / Date Value / Units Type Notation Carcinogenic
Listing*
1-Propoxy-2-Propanol US (ACGIH) / 2001 No occupational N/L
exposure limit(s)
have been
established for this
substance.

2-Propoxy-1-Propanol US (ACGIH) / 2001 No occupational
exposure limit(s)
have been
established for this
substance.

Propylene Glycol US (ACGIH) / 2001 N/L

Page 4 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001



Dipropylene Glycol US (ACGIH) / 2001 N/L

Dipropylene Glycol US (ACGIH) / 2001 No occupational
Monopropyl Ether exposure limit(s)
have been
established for this
substance.

*1 = OSHA 2 = IARC 3 = NTP 4 = Others N/L = Not Listed See Section 11 for more information


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Density: ~ 890 kg/m3, @ (25 掳C/77 掳F)

Specific Gravity: Vapor:
~ 0.89, @ (20 掳C/68 掳F), (Water = 1.0 ~ 4, @ (15 - 20 掳C/60 - 68 掳F), (Air
at 4掳C (39.2掳F)) = 1.0)

Boiling Point: pH:
~ 150 掳C/302 掳F, @ 760 mm Hg Not applicable.

Vapor Pressure: Viscosity:
~ 1.7 mm Hg, @ (20 掳C /68 掳F) No Data Available.

Solubility: Solubility (Water):
Complete (In All Proportions).


Octanol/Water Melting/
Partition Coefficient Freezing
Log Pow = ~ 0.62
in Kow: Point: < -70 掳C/-94 掳F

Dry Point: Evaporatio
No Data Available.
n Rate: ~ 0.22
(butyl acetate = 1)

Other Physical &
Chemical Properties: Additional properties may be listed in Sections 3 and 5.


SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: This material is stable when properly handled and stored.

Conditions to Avoid: Heat, sparks, open flame, and other ignition sources.

Incompatibility with: Strong bases.

Decomposition Products: Combustion may produce oxides of carbon and other toxic gases.

Hazardous Polymerization: Not expected to occur.

Reactions with Air and Not expected to occur.
Water:

SECTION 11: TOXICOLOGICAL INFORMATION
Product
Summary: Repeated or prolonged skin contact may cause progressive dermatitis and may aggravate pre-
existing dermatitis.

Page 5 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001




Component Summary:
1-Propoxy-2-Propanol
LD50 (Oral)
Rat 2504 MG/KG

LD50 (Skin)
Rabbit 3550 MG/KG

Target Organ Effects Eye. Respiratory system. CNS depressant. Skin.

Propylene Glycol
LD50 (Oral)
Rat 20,000 MG/KG

Mouse 22,000 MG/KG


LD50 (Skin)
Rabbit 20,800 MG/KG

SKIN EFFECTS: High concentrations of Propylene Glycol in water when held in contact with human skin
under closed conditions have been reported to cause skin irritation (Cosmetics and Toiletries 99:83-
91,1984). The authors attribute the observations to a sweat retention reaction by skin. No reactions were
observed in open patch tests with human subjects. One literature report indicates rare eczematous skin
reactions and even more rarely an allergic skin reaction from exposure to Propylene Glycol (Anderson and
Starr, Hautzart 33 (1) 1982).

Target Organ Effects Eye. Skin.

Dipropylene Glycol

Rat 14,800 MG/KG


Rabbit > 17,800 MG/KG

Repeated Dose Toxicity No known chronic or adverse effects have been associated with repeated
exposure to this material.

Dipropylene Glycol Monopropyl Ether

Rat ~ 1442 MG/KG


Rabbit ~ 5037 MG/KG

Repeated Dose Toxicity No known chronic or adverse effects have been associated with repeated
exposure to this material.


SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: This material is expected to be non-hazardous to aquatic species.
Page 6 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001



Toxicity to Fish:/Amphibians

Test type Species Value / Units
LC50 / 96 HOURS fathead minnow 3,421 mg/l


Toxicity to Aquatic: Inverterbrates:

Test type Species Value / Units
EC50 / 48 HOURS daphnia 3,600 mg/l

Environmental It is soluble in water. It may enter soil and may contaminate water. It is not expected to
Fate: adsorb onto soils or sediments. This material is likely to evaporate from dry soil but not from
water. BOD (Closed Bottle Test)= 84 % ThOD (20 day)

Bioaccumulation: This material is not expected to bioaccumulate. BCF = 1.7

Biodegradation: This material is expected to be readily biodegradable.


SECTION 13: DISPOSAL CONSIDERATIONS
Contaminated product, soil, water, container residues and spill cleanup materials may be
hazardous wastes. Comply with applicable local, state or international regulations
concerning solid or hazardous waste disposal and/or container disposal.

SECTION 14: TRANSPORT INFORMATION
Proper Shipping Flammable liquids, n.o.s. (Propylene glycol n-propyl ether)
Name:

UN/NA ID: UN 1993

NAER Guidebook: Marine Pollutant: No
128

Labels: Flammable liquid.

DOT Hazard Class: 3, PG III IMDG Hazard
Class: 3, PG III

ADR/VLG Hazard ICAO/IATA
Class: Hazard Class:
3 3, PG III

ADNR/VBG Hazard RID/VSG Hazard
Class: Class:
3 3


SECTION 15: REGULATORY INFORMATION
Regulatory Status: All components of this product are listed or are exempt from listing on the TSCA 8(b)
inventory. If identified components of this product are listed under the TSCA 12(b)
Export Notification rule, they will be listed below.



SECTION 16: OTHER INFORMATION
DISCLAIMER OF
Page 7 of 8
MSDS No.: BE1607
Material Safety Data Sheet Variant: Asia-EN
ARCOSOLV庐 PNP Version No: 1.1
Validation Date: 28.12.2001

RESPONSIBILITY: This document is generated for the purpose of distributing health, safety, and
environmental data. It is not a specification sheet nor should any displayed data be
construed as a specification. The information on this MSDS was obtained from
sources which we believe are reliable. However, the information is provided without
any warranty, expressed or implied, regarding its correctness. Some information
presented and conclusions drawn herein are from sources other than direct test data
on the substance itself. The conditions or methods of handling, storage, use and
disposal of the product are beyond our control and may be beyond our knowledge.
For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage, or expense arising out of or in any way connected with
handling, storage, use, or disposal of this product. If the product is used as a
component in another product, this MSDS information may not be applicable.

Latest Revision(s): Revised Section(s): 14 December 4 2001

END OF DOCUMENT




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