SDA 3C 200 pf
Material Safety Data Sheet
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade name SDA 3C 200 pf
Synonyms SDA 3C / Denatured Alcohol
Manufacturer/Supplier SASOL CHEMICALS NORTH AMERICA LLC (An affiliate of Sasol North America Inc.)
Address 900 Threadneedle, Houston, TX 77079
Telephone CHEMTREC North America Transportation Emergency (24-hr) (800) 424-9300
CHEMTREC World Wide (703) 527-3887
Other Emergencies (24-hr) (337) 494-5142
MSDS and Product Information (8:00am-4:30pm CST) (281) 588-3491
Health and Safety Information (8:00am-4:00pm CST) (281) 588-3492
SECTION 2 COMPOSITION AND INFORMATION ON INGREDIENTS
Components CAS -No. Weight %
Ethanol 64-17-5 95
2-Propanol 67-63-0 5
See Section 8 for Exposure Guidelines and Section 15 for Regulatory Classifications.
SECTION 3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Appearance Clear Liquid
Odor Alcohol.
Precautions WARNING! FLAMMABLE LIQUID AND VAPOR. CAUSES EYE, SKIN, AND
RESPIRATORY TRACT IRRITATION. Keep away from heat and flame. Do not get in
eyes, on skin, or on clothing. Wash thoroughly after handling. Keep container closed.
Use only with adequate ventilation.
Environmental Do not flush into surface water or sanitary sewer system. Low potential to affect aquatic
precautions organisms and secondary waste treatment organisms. Readily biodegradable. Not likely
to bioconcentrate.
POTENTIAL HEALTH EFFECTS
Eyes Irritating to eyes. May cause corneal inflammation.
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Skin Prolonged skin contact may cause skin irritation and/or dermatitis. Normal care and
personal hygiene should prevent skin effects.
Inhalation Irritation of the nose and throat, dizziness, and headache.
Ingestion Depression of central nervous system. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea. Prolonged ingestion may cause liver damage, "fetal-
alcohol syndrome" in pregnant females and neuronal degeneration. Aspiration
(breathing) into lungs, caused while vomiting, may result in severe pulmonary injury.
(See Section 11 for Toxicological Information)
SECTION 4 FIRST AID MEASURES
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. When symptoms persist or in all cases of doubt seek medical advice.
Wash contaminated clothing before re-use.
Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration.
If breathing is difficult, give oxygen. Call a physician immediately.
Ingestion If swallowed, call a physician or poison control center immediately. Do not induce
vomiting without medical advice. Never give anything by mouth to an unconscious
person.
SECTION 5 FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
Flash point 5 掳C 41 掳F
Autoignition ca. 400 掳C 752 掳F
temperature
Flammable limits in Lower explosion limit: 4 %(V)
air % by volume Upper explosion limit: 20 %(V)
Fire and explosion Flash back possible over considerable distance. NFPA Class IB flammable liquid.
Extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Fire fighting Wear self-contained breathing apparatus and protective suit. Keep containers and
instructions surroundings cool with water spray.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
Steps to be taken in Evacuate personnel to safe areas. Remove all sources of ignition. Contain and collect
case of spill or leak spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national regulations
(see Section 13). Do not flush into surface water or sanitary sewer system.
Spill precautions Material can create slippery conditions.
SECTION 7 HANDLING AND STORAGE
Safe handling advice Ensure all equipment is electrically grounded before beginning transfer operations.
Storage/Transport Ambient.
pressure
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING MEASURES
Mechanical ventilation may be necessary if working with this product in enclosed areas
and/or at elevated temperatures.
PERSONAL PROTECTIVE EQUIPMENT
Eyes When contact with liquid is possible, use a face shield and/or chemical splash goggles.
Otherwise use safety glasses with side shields or goggles.
Skin Wear suitable protective clothing, gloves and eye/face protection.
Inhalation Respiratory protection is normally not required except in emergencies or when conditions
cause excessive airborne levels of mists or vapors. NIOSH-approved organic vapor air-
purifying respirator, self-contained breathing apparatus, or air-supplied respirators where
there may be potential for overexposure.
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EXPOSURE GUIDELINES
Components Exposure limit(s)
Ethanol OSHA PEL 1,000 ppm(1,900 mg/m3)
ACGIH TLV (8-hour) 1,000 ppm(1,880 mg/m3)
2-Propanol OSHA PEL 400 ppm(983 mg/m3)
ACGIH TLV (8-hour) 400 ppm(983 mg/m3)
ACGIH STEL 500 ppm(1,230 mg/m3)
PEL= Permissible Exposure Limits TWA= Time Weighted Average (8 hr.)
TLV= Threshold Limit Value STEL= Short Term Exposure Limit (15 min.)
EL= Excursion Limit WEEL= Workplace Environmental Exposure Level
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Liquid
Colour Clear
Odour Alcohol.
Form Liquid
Boiling point/range 74 - 80 掳C 165.2 - 176 掳F
Vapour pressure ca. 50 mm Hg @ 20 掳C
Vapor density ca. 1.5
Solubility (water) Miscible.
Melting point/range ca. -114 掳C -173 掳F
Density 0.79 g/cm3 @ 15.5 掳C (200 pf)
Evaporation rate ca. 2 (n-butyl acetate = 1)
SECTION 10 STABILITY AND REACTIVITY
Conditions to avoid Keep away from heat and sources of ignition.
Hazardous Combustion products include carbon dioxide, carbon monoxide and possibly other
decomposition unidentified organic compounds.
products
Incompatability with Can react with strong oxidizers, inorganic acids, and halogens.
other materials
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Hazardous None.
polymerization
SECTION 11 TOXICOLOGICAL INFORMATION
Eyes No data available
Skin Slightly irritating.
Test Substance: Ethanol Slightly irritating.
Test Substance: Isopropanol
Inhalation Acute 8 hours LC50 (rat): 16,000 mg/l Test Substance: Ethanol
Acute 8 hours LC50 (rat): 12,800 mg/l Test Substance: Isopropanol
Ingestion Acute oral LD50(rat): 6,200 - 17,800 mg/kg
Test Substance: Ethanol
Acute oral LD50(rat): 5,800 mg/kg
Test Substance: Isopropanol
CARCINOGENICITY
This product contains no carcinogenic substances.
SECTION 12 ECOLOGICAL INFORMATION
Aquatic toxicity Low potential to affect aquatic organisms and secondary waste treatment organisms.
LC50 (Trout) 96 hours 13,000 mg/l
Test Substance: Ethanol
LC50 (P. Promelas (fathead minnow)) 96 hours 15,300 mg/l
Test Substance: Ethanol
LC50 (Goldfish) 8 hours 250 ppm
Biodegradation Readily biodegradable. Not likely to bioconcentrate.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste code D001 - Ignitability (RQ 100 LB) This product has the RCRA characteristic of ignitability.
Re-evaluation of the product may be required by the user at the time of disposal, since
the product uses, transformations, mixtures, contamination, and spillage may change the
classification.
Disposal methods Dispose of only in accordance with local, state, and federal regulations. Do not
contaminate any lakes, streams, ponds, groundwater or soil.
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Empty containers Empty containers retain product residue (liquid and/or vapor) and can be dangerous. DO
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR
DEATH. Empty drums should be completely drained, triple-rinsed, properly bunged and
promptly returned to a drum reconditioner, or properly disposed.
SECTION 14 TRANSPORT INFORMATION
DOT description Ethanol solutions, 3, UN 1170, II
IATA description Ethanol solutions, 3, UN 1170, II
IMDG description Ethanol solutions, 3, UN 1170, II
SECTION 15 REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
OSHA classification
Flammable liquid, eye irritant and skin irritant
TSCA Inventory Listing
Components CAS -No.
Ethanol 64-17-5
2-Propanol 67-63-0
SARA 302 Status
Components CAS -No. Weight %
Contains no chemicals subject to SARA 302 reporting.
SARA 311/312 Classification
"Immediate (acute) health hazard", "Fire hazard"
SARA 313 Chemical
Components CAS -No. Weight %
2-Propanol 67-63-0 5
CERCLA Hazardous Substance
Components CERCLA RQ Weight %
Contains no chemicals subject to CERCLA.
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INTERNATIONAL REGULATIONS
Workplace Hazardous Materials Information System (WHMIS) Classification
Class B, Division 2: Flammable liquid.
Class D, Division 2, Subdivision B: Toxic material.
Australian Inventory of Chemical Substances (AICS) Listing
Listed on the AICS.
Japanese Minister of International Trade and Industry (MITI) Inventory Listing
Listed on MITI.
Canadian Domestic Substance List (DSL) Inventory Listing
Listed on the DSL.
European Inventory of Existing Commercial Chemical Substances (EINECS) Listing
Not listed on EINECS.
Phillipines Inventory List (PICCS)
Listed on PICCS.
Korean Inventory List
Listed on the ECL.
China Inventory List
Listed on the China inventory.
STATE REGULATIONS
California Safe Drinking Water Act (Prop 65) Listing
Components CAS -No.
Contains no chemical subject to California Prop 65.
SECTION 16 OTHER INFORMATION
HAZARD RATINGS
Health Flammability Reactivity
HMIS 1 3 0
NFPA 1 3 0
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THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL
PURPOSES ONLY, UPON THE EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN
ASSESSMENT OF APPROPRIATE USE AND APPROPRIATE SHIPPING, TRANSFER AND STORAGE MATERIALS
AND PROCE DURES FOR SASOL NORTH AMERICA'S PRODUCTS. ALTHOUGH BASED ON INFORMATION
SOURCES WHICH SASOL NORTH AMERICA CONSIDERS ACCURATE AND RELIABLE, SASOL NORTH
AMERICA MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING ANY WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, REGARDING THE VALIDITY OF THIS
INFORMATION, THE INFORMATION SOURCES UPON WHICH THE SAME ARE BASED, OR THE RESULTS TO
BE OBTAINED, AND EXPRESSLY DISCLAIMS LIABILITIES FOR DAMAGES OR INJURIES RESULTING FROM
THE USE THEREOF.
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