Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Product Name: 'PERKLONE ' D / EXT / MD
Use of Substance / Preparation: Dry cleaning fluid and Degreasing agent.
For details on specific grades please refer to technical literature.
Address/Phone No.: INEOS Chlor Americas Inc
2036 Foulk Road, Suite 204
Wilmington, Delaware, 19810
Tel No (866) 296-0146.
Emergency Phone No.: call CHEMTREC 1-800-424-9300
For medical emergencies call 1-800-317-9643
2. COMPOSITION/INFORMATION ON INGREDIENTS
PRODUCT DESCRIPTION
Perchloroethylene (tetrachloroethylene) stabilised.
HAZARDOUS INGREDIENT(S) CAS No. % ACGIH TLV
(w/w)
Perchloroethylene (Tetrachloroethylene) 000127-18-4 >99 25ppm TWA
3. HAZARDS IDENTIFICATION
Emergency Overview
Harmful by inhalation. High exposures by inhalation will cause anaesthetic effects. This may result in a loss of conciousness and
could prove fatal if exposure has been severe.
Repeated and/or prolonged skin contact may cause reddening, burning and blisters. Repeated exposure to levels well above the
occupational exposure limit may produce adverse effects on the liver and kidneys.
Perchloroethylene has been shown to cause cancer in rodents, but this is by a mechanism of little or no relevance to man, even at
high exposure levels.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Eye : Liquid splashes and high concentrations of vapor may cause irritation.
Skin: Irritating to skin. Will remove the natural greases resulting in dryness, cracking
and dermatitis. Repeated and/or prolonged skin contact may cause reddening,
burning and blisters. Can be absorbed through skin but not in sufficient amounts
to cause adverse effects.
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Ingestion: High atmospheric concentrations will lead to anaesthetic effects and adverse
effects on the central nervous system. Symptoms may include lightheadedness,
nausea, vomiting and headache. Exposure to concentrations of 1500ppm for 20
minutes causes lightheadedness. Very high concentrations may result in a loss of
consciousness. Very high exposures may cause an abnormal heart rhythm and
prove suddenly fatal.
Inhalation: High atmospheric concentrations will lead to anaesthetic effects and adverse
effects on the central nervous system. Symptoms may include lightheadedness,
nausea, vomiting and headache. Exposure to concentrations of 1500ppm for 20
minutes causes lightheadedness. Very high concentrations may result in a loss of
consciousness. Very high exposures may cause an abnormal heart rhythm and
prove suddenly fatal.
Chronic effects: Repeated exposure to levels well above the occupational exposure limit may
produce adverse effects on the liver and kidneys.
Perchloroethylene has been associated with cancer in rodents. Extensive
evaluations of possible mechanisms have led to the conclusion that they are of
little, if any, relevance to man even at high exposure levels. Studies in workers
have failed to demonstrate a relationship between exposure to perchloroethylene
and cancer.
Carcinogenicity / Regulatory Status: See Regulatory Information (Section 11).
4. FIRST-AID MEASURES
Inhalation: Remove patient from exposure, keep warm and at rest. DO NOT walk the patient about. Administer oxygen if
necessary. Apply artificial respiration if breathing has ceased or shows signs of failing. During resuscitation,
care must be taken to avoid contamination by the substance from the patient.
Obtain immediate medical attention.
Skin Contact: Remove contaminated clothing. Wash skin with soap and water.
If symptoms develop, obtain medical attention.
Eye Contact: Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes.
Obtain medical attention.
Ingestion: Provided the patient is conscious, wash out mouth with water and give 200-300 ml (half a pint) of water to
drink.
Obtain immediate medical attention.
Note to Physicians
Symptomatic treatment and supportive therapy as indicated. Adrenaline and similar sympathomimetic drugs should be avoided
following exposure as cardiac arrhythmia may result with possible subsequent cardiac arrest. Gastric lavage may be effective and
should preferably be undertaken within 1 hour. Aspiration of this material into the lungs should be avoided. Following ingestion
adsorbents such as activated charcoal may be of value.
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5. FIRE-FIGHTING MEASURES
Non-flammable. Welding or cutting should not be carried out on any vessel likely to contain solvent as toxic and corrosive
decomposition products (hydrogen chloride) can be formed.
Containers may burst if overheated.
Extinguishing Media: Keep fire exposed containers cool by spraying with water.
Fire Fighting Protective Equipment: A self contained breathing apparatus and full protective clothing must be worn in
fire conditions.
6. ACCIDENTAL RELEASE MEASURES
Provided it is safe to do so, isolate the source of the leak.
Ensure suitable personal protection (including respiratory protection) during removal of spillages.
Small spillages: Adsorb spillages onto sand, earth or any suitable adsorbent material. Transfer to a container for disposal or
recovery.
Large spillages: Contain spillages with sand, earth or any suitable adsorbent material. Do not allow to enter drains, sewers or
waterways. Spillages or uncontrolled discharges into waterways must be alerted to the Environment Agency or other appropriate
regulatory body.
7. HANDLING AND STORAGE
7.1 HANDLING
Do not breathe vapor. Use only in well ventilated areas. Avoid contact with skin and eyes.
The vapour is heavier than air and may reach dangerously high concentrations in pits, tanks, and other confined spaces. In such
cases provide adequate ventilation or wear suitable respiratory protective equipment with positive air supply. Avoid contact with
naked flames and hot surfaces as toxic and corrosive decomposition products (hydrogen chloride ) can be formed. Do not weld
in the presence of vapours as toxic decomposition products may be formed. When using do not smoke.
7.2 STORAGE
Containers should be of mild steel, or amber or dark green solvent resistant plastic or glass.
Keep away from direct sunlight. Keep container dry. Keep in a cool, well ventilated place. Keep away from heat, sources of
ignition and direct sunlight. All bulk storage vessels should be made of steel and require a suitable vent or pressure relief valve
and secondary containment to prevent uncontrolled losses from accidental release. Do not use aluminium or its alloys in the
construction of storage vessels, pipework and ancillary equipment, including internal components e.g. pump impellers. Storage
tanks should be bunded to accomodate 110% of the tank volume.
Use of galvanised components should be avoided because of the risk of producing highly toxic dichloroacetylene.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable protective clothing and gloves.
Nitrile rubber is better than PVC. Gloves should be changed regularly to avoid permeation problems. Gloves should be changed if
excessive exposure has occurred. Wear eye/face protection. Atmospheric levels should be controlled in compliance with the
occupational exposure limit. Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure
limit is likely. Positive air supplied RPE is recommended.
Exposure Guidelines
Product(s) TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁 Notes
Perchloroethylene 25 - 100 - BEI ACGIH
(Tetrachloroethylene) TLV
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9. PHYSICAL AND CHEMICAL PROPERTIES
These properties are the most relevant and no other properties are available.
For specific physical properties of individual grades, please refer to technical literature and/or product specifications.
Form: volatile liquid
Color: clear
Odor: characteristic ethereal
Boiling Point (Deg C): 121
Melting Point (Deg C): -22.4
Vapor Pressure (mm Hg): 14.7 at 20 Deg C
Solubility (Water): marginally soluble
0.015% w/w at 25 Deg C
Solubility (Other): miscible with most organic solvents
Specific Gravity: 1.623 at 20 Deg C
Vapor Density (Air= 1): 5.83 at 74 Deg C
10. STABILITY AND REACTIVITY
Stable under normal conditions.
Hazardous Reactions: May react violently with metals such as sodium, potassium and barium,
particularly if they are finely divided. May react with freshly galvanized
surfaces to produce highly toxic dichloroacetylene.
Hazardous Decomposition Product(s): Contact with red hot surfaces, sparks or naked flames may generate toxic fumes
of phosgene and hydrogen chloride.
11. TOXICOLOGICAL INFORMATION
This health hazard assessment is based on a consideration of the composition of this product.
Inhalation
High atmospheric concentrations will lead to anaesthetic effects and adverse effects on the central nervous system. Symptoms
may include lightheadedness, nausea, vomiting and headache. Exposure to concentrations of 1500ppm for 20 minutes causes
lightheadedness. Very high concentrations may result in a loss of consciousness. Very high exposures may cause an abnormal
heart rhythm and prove suddenly fatal.
Skin Contact
Irritating to skin. Will remove the natural greases resulting in dryness, cracking and dermatitis. Repeated and/or prolonged skin
contact may cause reddening, burning and blisters. Can be absorbed through skin but not in sufficient amounts to cause adverse
effects.
Eye Contact
Liquid splashes and high concentrations of vapor may cause irritation. Permanent damage is unlikely.
Ingestion
The swallowing of small splashes is unlikely to cause any adverse effects. Large amounts may cause internal irritation, nausea,
vomiting and may lead to drowsiness and unconsciousness.
Long Term Exposure
Repeated exposure to levels well above the occupational exposure limit may produce adverse effects on the liver and kidneys.
Perchloroethylene has been associated with cancer in rodents. Extensive evaluations of possible mechanisms have led to the
conclusion that they are of little, if any, relevance to man even at high exposure levels. Studies in workers have failed to
demonstrate a relationship between exposure to perchloroethylene and cancer.
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Product Name: 'PERKLONE ' D / EXT / MD
12. ECOLOGICAL INFORMATION
This environmental hazard assessment is based on the properties of perchloroethylene.
Environmental Fate and Distribution
High tonnage material produced in wholly contained systems.
High tonnage material used in partially contained systems.
Liquid with high volatility.
The product is essentially insoluble in water.
The product has no potential for bioaccumulation.
Persistence and Degradation
The substance is degraded fairly rapidly in the lower atmosphere (troposphere). Atmospheric lifetime is approximately 5
months. Does not deplete ozone. The substance evaporates rapidly from open water systems but persists in groundwater.
Toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This effect is mitigated by its rapid
evaporation from open water systems.
Effect on Effluent Treatment
The product is anticipated to be substantially removed in biological treatment processes.
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with local, state or national legislation. Transfer solvent residues to a labelled, sealed container
for disposal or recovery. Waste disposal must be by an accredited contractor. Large volumes may be suitable for redistillation by
solvent recovery contractors. Solvent residues must not be allowed to enter drains, sewers or watercourses or to contaminate the
ground.
Welding or cutting should not be carried out on any vessel likely to contain solvent as toxic and corrosive decomposition products
(hydrogen chloride) can be formed.
14. TRANSPORT INFORMATION
AIR
ICAO/IATA
-primary: 6.1
UN Packing group Air: III
SEA
IMDG
-primary: 6.1
Marine Pollutant: Classified as a Marine Pollutant (P)
U.N. Packing group Sea: III
Proper Shipping Name: TETRACHLOROETHYLENE
ROAD/RAIL
ADR/RID Class: 6.1
ADR Sin: 1897
TDG / DOT
Hazard Class: 6.1
Identification Number: UN 1897
Packing Group: III
Hazardous Substance(RQ): 100lbs / 45.4kg
Placard: KEEP AWAY FROM FOOD, 1897, Class 6
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Product Name: 'PERKLONE ' D / EXT / MD
15. REGULATORY INFORMATION
TSCA Inventory Status
All components of this product are listed on the TSCA Inventory.
CERCLA
This material is listed in Table 302.4 of 40 CFR Part 302 as a hazardous substance with a reportable quantity of 100 lbs.
Releases to air, land or water which exceed the RQ must be reported to the NAtional Response Centre, 800-424-8802.
SARA
Sections 313 and 40 CFR 372: This product is subject to reporting requirements.
Hazard Categories:
Sections 311/312 (40 CFR 370.2): An immediate health hazard, A delayed health hazard.
CALIFORNIA PROPOSITION 65: This product contains a chemical (s) known to the State of California to cause cancer.
Canada
This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations) and this
MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
Controlled Products Regulations (WHMIS) Classification:
Class D1B: Toxic material causing immediate and serious toxic effects.
Class D2A: Very toxic material causing other toxic effects.
CEPA / Canadian Domestic Substances List (DSL):
The substances in this product are on the Canadian Domestic Substances List (CEPA DSL).
EU
EINECS : 204-825-9
Inventories
United States, Australia, Canada, China, EU, Japan, Korea, Philippines
16. OTHER INFORMATION
NFPA Ratings : Health 2, Flammability 0, Reactivity 0
.
'Perklone' is a trade mark of Ineos Chlor Limited.
Information in this publication is believed to be accurate and is given in good faith, but it is for the Customer to satisfy itself of
the suitability for its own particular purpose. Accordingly, Ineos Chlor Limited gives no warranty as to the fitness of the Product
for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that
such exclusion is prevented by law. Freedom under Patent, Copyright and Designs cannot be assumed.
Any trade marks herein identified are trade marks of companies within the INEOS Chlor Group.
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GLOSSARY
ACGIH - American Conference of Govermental Industrial Hygienists
CAS - Chemical Abstracts Service Registry Number
CFR - Code of Federal Regulations
COM - The company aims to control exposure in its workplace to this limit
DOT - Department of Transportation
EINECS - European Inventory of Existing Commercial Chemical Substances
OSHA - Occupational Safety & Health Administration
SARA - Superfund Amendments and Reauthorization Act of the U.S. EPA
TDG - Transportation of Dangerous Goods Act/Regulations
TLV - Threshold Limit Value
TSCA - Toxic Substances Control Act
TWA - Time-Weighted Average
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