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MSDS Material Safety Data Sheet
CAS

7782-44-7
001-00-8

File Name: prism_princeton_edu---oxygen.asp
Material Safety Data Sheet #12831                     wysiwyg://content.511/http://www.mgindustries.com/msds/SubLookup.asp?SubName=12831&SUBMIT1=Go%21



Print MSDS Sheet
MGI12831 Page 001 of 010
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SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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MG INDUSTRIES EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY CHEMTREC:
MALVERN, PENNSYLVANIA 19355 1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: OXYGEN, COMPRESSED GAS
TRADE NAMES/SYNONYMS:
OXYGEN; DIOXYGEN; MOLECULAR OXYGEN; OXYGEN MOLECULE; PURE OXYGEN; STCC
4904350; UN 1072; O2; MGI12831; RTECS RS2060000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 07 1990
REVISION DATE: Sep 18 2001
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SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS
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COMPONENT: OXYGEN, COMPRESSED GAS
CAS NUMBER: 7782-44-7
EC NUMBER (EINECS): 231-956-9
EC INDEX NUMBER: 008-001-00-8
PERCENTAGE: 100.0
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SECTION 3 HAZARDS IDENTIFICATION
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NFPA RATINGS (SCALE 0-4): HEALTH=0 FIRE=0 REACTIVITY=0
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, gas.
MAJOR HEALTH HAZARDS: No significant target effects reported.
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat. May
ignite combustibles.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: irritation, changes in body temperature, nausea,
difficulty breathing, irregular heartbeat, dizziness, disorientation,
hallucinations, mood swings, pain in extremities, tremors, lung congestion,
convulsions
LONG TERM EXPOSURE: irritation, chest pain, lung damage
SKIN CONTACT:
SHORT TERM EXPOSURE: no information on significant adverse effects
LONG TERM EXPOSURE: no information on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation
MGI12831 Page 002 of 010
LONG TERM EXPOSURE: no information on significant adverse effects
INGESTION:
SHORT TERM EXPOSURE: no information on significant adverse effects
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: No
NTP: No
IARC: No
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SECTION 4 FIRST AID MEASURES
------------------------------------------------------------------------------
INHALATION: If adverse effects occur, remove to uncontaminated area. Give
artificial respiration if not breathing. Get immediate medical attention.
SKIN CONTACT: If frostbite or freezing occur, immediately flush with plenty of



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lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is
not available, gently wrap affected parts in blankets. Get immediate medical
attention.
EYE CONTACT: Wash eyes immediately with large amounts of water, occasionally
lifting upper and lower lids, until no evidence of chemical remains. Get
medical attention immediately.
INGESTION: If a large amount is swallowed, get medical attention.
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SECTION 5 FIRE FIGHTING MEASURES
------------------------------------------------------------------------------
FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. May ignite or
explode on contact with combustible materials. Containers may rupture or
explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers
with water from unmanned hose holder or monitor nozzles until well after
fire is out. If this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let the fire
burn. Use extinguishing agents appropriate for surrounding fire. Cool
containers with water. Apply water from a protected location or from a safe
distance.
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SECTION 6 ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------------------------
OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Avoid contact with combustible
MGI12831 Page 003 of 010
materials. Keep unnecessary people away, isolate hazard area and deny entry.
Ventilate closed spaces before entering.
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SECTION 7 HANDLING AND STORAGE
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STORAGE: Store and handle in accordance with all current regulations and
standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep
separated from incompatible substances.
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SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION
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EXPOSURE LIMITS:
OXYGEN, COMPRESSED GAS:
No occupational exposure limits established.
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with
applicable exposure limits.
EYE PROTECTION: Eye protection not required, but recommended.
CLOTHING: Protective clothing is not required.
GLOVES: Protective gloves are not required.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, gas.



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MOLECULAR WEIGHT: 31.9988
MOLECULAR FORMULA: O2
BOILING POINT: -297 F (-183 C)
FREEZING POINT: -360 F (-218 C)
VAPOR PRESSURE: 760 mmHg @ -183 C
VAPOR DENSITY (air=1): 1.1
SPECIFIC GRAVITY: Not applicable
DENSITY: 1.309 g/L @ 25 C
WATER SOLUBILITY: 3.2% @ 25 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
MGI12831 Page 004 of 010
VISCOSITY: 0.02075 cP @ 25 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: alcohol
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SECTION 10 STABILITY AND REACTIVITY
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REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid contact with combustible materials. Protect from
physical damage and heat. Containers may rupture or explode if exposed to
heat.
INCOMPATIBILITIES: combustible materials, halo carbons, metals, bases,
reducing agents, amines, metal salts, oxidizing materials
OXYGEN:
ACETALDEHYDE: Rapid oxidation progressing to explosion.
ACETYLENE: Mixtures of the gases may explode on heating or compression; the
liquids form a powerful explosive.
POLY(ACRYLONITRILE-BUTADIENE): Forms impact-sensitive mixture with the
liquid.
SEC-ALCOHOLS: Forms explosive peroxides.
ALKALI METALS: Ignition.
ALKALINE-EARTH METALS: Ignition.
ALKALINE-EARTH PHOSPHIDES: Incandescence on heating.
ALLYLIC COMPOUNDS: May form explosive peroxides.
ALUMINUM BOROHYDRIDE: Explosive reaction.
AMMONIA: Possible explosion.
BERYLLIUM BOROHYDRIDE: Explosive reaction.
BORON ARSENOTRIBROMIDE: Ignites on contact with the gas.
BORON TRICHLORIDE: Vigorous reaction on sparking.
BUTEN-3-YNE: Forms explosive peroxides.
CARBON: May ignite in the gas; forms explosive mixtures with the liquid.
CARBON DISULFIDE: Possible ignition.
CARBON MONOXIDE (LIQUID): Forms explosive mixture with the liquid.
CHLOROTRIFLUOROETHYLENE: Forms explosive peroxides.
COMBUSTIBLE MATERIALS: The flammability of combustible compounds greatly
increases with an increase in oxygen concentration; some materials may
become spontaneously combustible or explosive. Contact of combustible
compounds with liquid oxygen is likely to result in a dangerous explosion.
CYANOGEN (LIQUID): Forms explosive mixture with the liquid.
CYCLOHEXANE-1,2-DIONE BIS(PHENYLHYDRAZONE): Forms explosive compound.
CYCLOOCTATETRAENE: May form explosive peroxides.
DIBORANE: Explosive mixture on heating.
DIBORON TETRAFLUORIDE: Explosive mixture.
DIMETHYLKETENE: Forms explosive peroxide.
DIMETHYL SULFIDE: Explosive reaction above 210 C.
DIOXANE: May form explosive peroxides.
ETHERS: May form explosive peroxides.



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FLAMMABLE MATERIALS: The flammability of materials greatly increases as the
oxygen concentration increases; some compounds may become spontaneously
combustible or explosive. Contact with liquid oxygen is likely to result
MGI12831 Page 005 of 010
in
dangerous explosions.
FLUORINE + HYDROGEN: Explosive mixture.
HALOGENATED HYDROCARBONS: Many halogenated hydrocarbons ignite or explode
with
the gas under pressure; contact with the liquid may result in a dangerous
explosion.
HYDRAZINE: Forms explosive mixtures.
HYDROCARBONS: Mixtures with the gas may ignite or explode particularly under
pressure or when heated; contact with the liquid is likely to result in a
dangerous explosion.
HYDROGEN: Explosive mixture, particularly in the presence of a catalyst.
HYDROGEN SULFIDE: Explosive mixture.
LITHIATED DIALKYLNITROSAMINES: May form explosive compounds.
LITHIUM HYDRIDE (POWDER): Very powerful explosive with the liquid.
METALS: Many metals ignite or explode in the gas, particularly if heated or
in
powder form. Contact of metal powders with the liquid is likely to result
in a dangerous explosion.
METAL HALIDES: Ignition.
METAL HYDRIDES: Ignition or explosion.
METHANE (LIQUID): Forms explosive mixture with the liquid.
METHOXYCYCLOOCTATETRAENE: Forms explosive compound.
NICKEL CARBONYL: Ignites or explodes at low pressure.
NITROGEN (LIQUID): Explosive if subjected to radiation.
NON-METAL HYDRIDES: May ignite or explode.
OXYGEN DIFLUORIDE: Explosive mixture.
PHENYLDICHLOROAMINE: Explosive reaction.
PHOSPHINE: Forms explosive mixture.
PHOSPHOROUS: Vigorous reaction.
PHOSPHORUS TRIBROMIDE: Explosive reaction.
PHOSPHOROUS TRIFLUORIDE: Explosive reaction.
PHOSPHOROUS TRIOXIDE: Ignition.
POLY(CYANOETHYLSILOXANE): Forms impact sensitive mixture with the liquid.
POLY(DIMETHYLSILOXANE): Forms impact sensitive mixture with the liquid.
POLYSTYRENE: Forms impact-sensitive mixture with the liquid.
POLYMERS: Contact with the liquid may result in rapid, hazardous oxidation
with possible explosions.
POTASSIUM CARBONYL: Violent reaction.
POTASSIUM PEROXIDE: Violent reaction.
PROPYLENE OXIDE: Explosive mixture.
SILANE + CHLORINE: Explosive mixture.
SILANES: Ignition or explosion.
STYRENE: Forms explosive peroxide.
TEFLON (POLYTETRAFLUOROETHYLENE): Ignites at high temperature and reduced
pressure.
TETRABORON DECAHYDRIDE: Explosive mixture.
TETRAFLUOROETHYLENE: Forms explosive peroxides.
TETRAFLUOROHYDRAZINE: Explosion in the presence of organic matter.
TETRAHYDROFURAN: Forms explosive peroxides.
TETRAPHOSPHORUS HEXAOXIDE: Ignition.
TRIRHENIUM CHLORIDE: May form explosive chlorine oxides on heating.
VINYL COMPOUNDS: May form explosive peroxides.
HAZARDOUS DECOMPOSITION:
MGI12831 Page 006 of 010
Thermal decomposition products: miscellaneous decomposition products
POLYMERIZATION: Will not polymerize.



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SECTION 11 TOXICOLOGICAL INFORMATION
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OXYGEN, COMPRESSED GAS:
TOXICITY DATA:
100 pph/14 hour(s) inhalation-human TCLo; 100 pph/24 hour(s)-3 day(s)
continuous inhalation-rat TCLo; 95 pph/24 hour(s)-2 day(s) continuous
inhalation-rat TCLo
MUTAGENIC DATA:
cytogenetic analysis - human lymphocyte 40 pph 4 day(s); cytogenetic
analysis - hamster ovary 20 pph 3 day(s)-continuous; cytogenetic analysis -
hamster lung 80 pph; sister chromatid exchange - hamster ovary 20 pph;
mutation in mammalian somatic cells - hamster lung 95 pph 24 hour(s);
cytogenetic analysis - chicken embryo 80 pph
REPRODUCTIVE EFFECTS DATA:
12 pph inhalation-woman TCLo/10 minute(s) 26-39 week(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/12 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/9 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-mouse TCLo/24 hour(s) 8 day(s) pregnant female
continuous
ADDITIONAL DATA: Toxic action is greatly enhanced by exercise or by presence
of moderate amounts of carbon dioxide.
OXYGEN, COMPRESSED GAS:
TOXICITY DATA:
100 pph/14 hour(s) inhalation-human TCLo; 100 pph/24 hour(s)-3 day(s)
continuous inhalation-rat TCLo; 95 pph/24 hour(s)-2 day(s) continuous
inhalation-rat TCLo
MUTAGENIC DATA:
cytogenetic analysis - human lymphocyte 40 pph 4 day(s); cytogenetic
analysis - hamster ovary 20 pph 3 day(s)-continuous; cytogenetic analysis -
hamster lung 80 pph; sister chromatid exchange - hamster ovary 20 pph;
mutation in mammalian somatic cells - hamster lung 95 pph 24 hour(s);
cytogenetic analysis - chicken embryo 80 pph
REPRODUCTIVE EFFECTS DATA:
12 pph inhalation-woman TCLo/10 minute(s) 26-39 week(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/12 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/9 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-mouse TCLo/24 hour(s) 8 day(s) pregnant female
continuous
ADDITIONAL DATA: Toxic action is greatly enhanced by exercise or by presence
of moderate amounts of carbon dioxide.
HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE:
OXYGEN: Pure oxygen, especially if not properly humidified, may cause
mucous membrane irritation and pulmonary edema after 24 hours. Air
normally contains 20-21% oxygen. As exposure to higher concentrations
and/or greater than atmospheric pressure continues symptoms of toxicity
MGI12831 Page 007 of 010
may develop and increase in severity. Respiratory system effects may
include a progressive decrease in vital capacity, tightness in the chest
and discomfort, coughing, congestion, tracheobronchitis, pneumonia, edema,
atelectasis and increased depth of respiration, rapid panting or
asthma-like attacks, apnea in inspiratory position, fibroblastic
proliferation, and hyperplasia of alveolar cells. Cardiovascular system
effects may include bradycardia, hyperthermia or hypothermia and
peripheral vasoconstriction. The nervous system may be affected with mood
changes, nausea, dizziness, slowing of mental processess, malaise,
hilarity, apprehension, paresthesias including tingling of fingers and
toes, fasciculation of the lips and face, muscular twitching, visual and
auditory hallucinations, general convulsions and epileptic seizures, loss



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of consciousness and collapse. At increased atmospheric pressures, vision
may be affected. Symptoms may include photophobia, amblyopia, mydriasis,
bilateral progressive constriction of visual field, impaired central
vision, constriction of retinal vasculature, and possible loss of vision.
However, no change in the visual fields or visual acuity was found after
breathing pure oxygen for four and one-half hours at normal atmospheric
pressures. Animal studies indicate exposure to oxygen under high pressure
has caused hemolytic anemia. In pregnant women exposed to 100% oxygen for
20 minutes, the response was a fetal cardiac rate which decreased and
became variable.
CHRONIC EXPOSURE:
OXYGEN: Inhalation of pure oxygen for periods up to 16 hours per day for
many days at atmospheric pressure has caused no observed injury to man.
Administration at atmospheric pressures at concentrations of 60% and 80%
may be followed by adverse effects, including severe cough, acute chest
pain associated with a decrease in vital capacity, intra-alveolar edema
and atelectasis. It is possible that prolonged low-level injury may
produce severe fibrotic changes in the lungs. However, after a human was
exposed to high concentrations of oxygen for 150 days, severe irreversible
retinal atrophy occurred. Dogs exposed to pure oxygen for 48 hours were
found to develop retinal and choroidal detachments. Reproductive effects
have been reported in animal studies.
SKIN CONTACT:
ACUTE EXPOSURE:
OXYGEN: No adverse effects have been reported from the gas. Due to rapid
evaporation, the cryogenic liquid may cause frostbite with redness,
tingling and pain or numbness. In more severe cases, the skin may become
hard and white and develop blisters.
CHRONIC EXPOSURE:
OXYGEN: No adverse effects have been reported.
EYE CONTACT:
ACUTE EXPOSURE:
OXYGEN: May cause irritation if not properly humidified. Due to rapid
evaporation, the cryogenic liquid may cause frostbite with redness, pain
and blurred vision.
CHRONIC EXPOSURE:
OXYGEN: No adverse effects have been reported.
MGI12831 Page 008 of 010
INGESTION:
ACUTE EXPOSURE:
OXYGEN: Ingestion of a gas is unlikly. If the cryogenic liquid is
swallowed, frostbite damage of the lips, mouth and mucous membranes may
occur.
CHRONIC EXPOSURE:
OXYGEN: No data available.
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SECTION 12 ECOLOGICAL INFORMATION
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Not available
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SECTION 13 DISPOSAL CONSIDERATIONS
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Dispose in accordance with all applicable regulations. Subject to disposal
regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
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SECTION 14 TRANSPORT INFORMATION
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U.S. DOT 49 CFR 172.101:
PROPER SHIPPING NAME: Oxygen, compressed
ID NUMBER: UN1072
HAZARD CLASS OR DIVISION: 2.2



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LABELING REQUIREMENTS: Nonflammable gas; Oxidizer
PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.314, 315
QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
CARGO AIRCRAFT ONLY: 150 kg
CANADIAN TRANSPORTATION OF DANGEROUS GOODS: No classification assigned.
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Oxygen, compressed
UN NUMBER: UN1072
ADR/RID CLASS: 2
ITEM NUMBER: 1(a)/1O
WARNING SIGN/LABEL: 2; 05/2; 05; 13
HAZARD ID NUMBER: 20/25
AIR TRANSPORT IATA/ICAO:
PROPER SHIPPING NAME: Oxygen, compressed
UN/ID NUMBER: UN1072
IATA/ICAO CLASS: 2.2
SUBSIDIARY RISK: 5.1
LABEL: Nonflammable gas; Oxidizer
MGI12831 Page 009 of 010
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Oxygen, compressed
UN/ID NUMBER: UN1072
IMDG CLASS: 2(2.2)
SUBSIDIARY RISK LABEL: Oxidizing agent
EmS No.: 2-04
MFAG Table No.: none
IMDG CODE PAGE: 2169
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SECTION 15 REGULATORY INFORMATION
------------------------------------------------------------------------------
U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated.
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30):
Not regulated.
SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40):
Not regulated.
SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: No
CHRONIC: No
FIRE: Yes
REACTIVE: No
SUDDEN RELEASE: Yes
SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated.
OSHA PROCESS SAFETY (29CFR1910.119): Not regulated.
STATE REGULATIONS:
California Proposition 65: Not regulated.
CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: Not determined.
EUROPEAN REGULATIONS:
EC CLASSIFICATION (ASSIGNED):
O Oxidizing
EC Classification may be inconsistent with independently-researched data.
DANGER/HAZARD SYMBOL:
O Oxidizing
EC RISK AND SAFETY PHRASES:
R8 Contact with combustible material may cause fire.
S2 Keep out of reach of children.



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S 17 Keep away from combustible material.
MGI12831 Page 010 of 010
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK):
STATE OF CLASSIFICATION: VwVwS
CLASSIFICATION UNDER HAZARD TO WATER: 0
NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): Listed on inventory.
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
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SECTION 16 OTHER INFORMATION
------------------------------------------------------------------------------
MSDS SUMMARY OF CHANGES
SECTION 3 HAZARDS IDENTIFICATION
Copyright 1984-2001 MDL Information Systems, Inc. All rights reserved.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.




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