Material Safety Data Sheet:
ANTEC BIOFOAM
SECTION 1 - PRODUCT IDENTIFICATION
ANTEC BIOFOAM
Product identifier/Trade name:
NONE
Product code/Internal Identification:
HEAVY DUTY CLEANER in 20 L container
Product use/Description:
SULPHAMIC ACID MIXTURE
Product chemical name:
N/Ap
Chemical family:
May 26, 2003
MSDS preparation/review date:
V茅toquinol Canada Inc.
Supplier identifier:
2000 Chemin Georges, Lavaltrie, Qu茅 (Canada), J5T 3S5
T茅l. (450) 586-2252
(613) 996-6666 (CANUTEC)
Emergency phone number:
1-800 463-5060 OR
(418) 656-8090 (CONTROL POISON CENTER)
Antec International Ltd
Manufacturer identifier:
Windham Road, Chilton Industrial Estate, Sudbury, Suffolk,
C010 6XD
Same as supplier
Emergency phone number:
E 鈥? Corrosive liquid.
WHMIS Classification:
SECTION 2 - CHEMICAL COMPOSITION / HAZARDOUS INGREDIENTS
Hazardous Ingredients CAS # % (weight) LD50 LC50 (specie)
(route, specie)
3160 mg/kg (oral, rat) N/Av
Sulphamic acid 5329-14-6 7-13
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview
CORROSIVE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. CAUSES SEVERE IRRITATION AND
BURNS TO SKIN, EYE, DIGESTIVE TRACT AND RESPIRATORY TRACT. MAY CAUSE LUNG DAMAGE.
POTENTIAL HEALTH EFFECTS (for more details, refer to Section 11)
Skin, eye, ingestion and inhalation.
Primary entry route(s):
Effects of short-term (acute) and long-term (chronic) exposure:
Inhalation:
Causes severe irritation of the respiratory tract.
Skin:
Causes moderate to severe skin irritation.
Eye:
N/Ap: not applicable N/Av: not available Page 1 of 6
Material Safety Data Sheet:
ANTEC BIOFOAM
Causes severe irritation (mild scarring to blistering, disintegration, ulceration, severe scarring and clouding).
Ingestion:
Should ingestion occur, severe pain, burning of the mouth, throat and esophagus. May result in vomiting and diarrhea.
SECTION 4 - FIRST AID MEASURES
Inhalation:
Remove source of contamination or have victim move to fresh air. If breathing is difficult, give oxygen. If not breathing,
give artificial respiration. Obtain medical attention immediately.
Skin contact:
Flush contaminated area with lukewarm, gently running water for at least 20 minutes or until the chemical is removed. Under
running water, remove contaminated clothing. If irritation persists, obtain medical advice. Completely decontaminate
clothing before reuse or discard.
Eye contact:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes, or until the chemical is
removed, while holding the eyelid(s) open. Obtain medical attention immediately
Ingestion:
NEVER give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink two glasses of water. If vomiting occurs, repeat
administration of water. Obtain medical attention immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Not considered a fire hazard.
Fire hazards/conditions of flammability:
Flash point (Method): N/Ap
N/Ap
Lower flammable limit (% by
volume):
N/Ap
Upper flammable limit (% by
volume):
N/Ap
Sensitivity to mechanical impact:
N/Ap
Sensitivity to static discharge:
Auto-ignition temperature: N/Ap
Suitable extinguishing media:
Carbon dioxide, dry chemical powder and appropriate foam for surrounding fire.
Special fire-fighting procedures/equipment:
During a fire, irritating/toxic smoke and fumes may be generated. Vapours can accumulate in confined spaces, resulting in a
toxicity and flammability hazard. A self-contained breathing apparatus is required for fire-fighting personnel to protect
themselves from toxic products produced during the combustion. Closed containers may explode with the pressure building
from the heat. Use water to cool fire exposed containers and prevent this situation.
Ammonia and oxides of sulphur and nitrogen evolve during combustion.
Hazardous combustion products:
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
CORROSIVE. Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only.
Remove incompatibles. Wear adequate personal protective equipment (See Section 8). Ventilate area.
Spill response/Cleanup:
Stop the flow if it can be done safely. Prevent material from entering waterways, sewers or confined spaces. SMALL
N/Ap: not applicable N/Av: not available Page 2 of 6
Material Safety Data Sheet:
ANTEC BIOFOAM
SPILLS: Soak up spill with absorbent material which does not react with spilled chemical. Put material in suitable, covered,
labelled containers. Flush area with neutralizing solution. LARGE SPILLS: Contain spill with earth, sand, or absorbent
material which does not react with spilled material. Place in suitable, covered, labelled containers. Contact fire and
emergency services and supplier for advice. Contaminated absorbent material may pose the same hazards as the spilled
product.
Environmental precautions:
For large spills, notify government occupational health and safety and environmental authorities. Confine spill, preventing it
from entering sewer lines or waterways. Dispose of as per local, state and federal regulations.
SECTION 7 - HANDLING AND STORAGE
Safe handling procedures:
CORROSIVE. Before handling, it is very important that engineering controls are operating and that protective equipment
requirements and personal hygiene measures are being followed. People working with this chemical should be properly
trained regarding its hazards and its safe use. Use in a in well-ventilated area. Avoid generating vapours or mists. Inspect
containers for leaks before handling. Never return contaminated material to its original container. Label containers
appropriately. Keep containers closed when not in use. Assume that empty containers contain residues which are hazardous.
Do not use with incompatible materials such as strong bases.
Storage requirements:
Store in a cool, dry and well-ventilated area. Store away from incompatible materials such as strong bases. Inspect all
incoming containers to make sure they are properly labelled and not damaged. Store in suitable, labelled containers. Keep
containers tightly closed. Empty containers may contain hazardous residues. Keep closed. Keep absorbents for leaks and
spills readily available. Storage area should be clearly identified, clear of obstruction and accessible only to trained
personnel. Inspect periodically for damage or leaks. Have appropriate fire extinguishers and spill clean-up equipment in or
near storage area. Do not allow product to freeze.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering controls:
Local exhaust ventilation system is recommended to maintain concentrations of contaminants below exposure limits.
Respiratory Protection:
Respiratory protection is required if the concentrations are higher than the exposure limits. Use a NIOSH approved respirator
if the exposure limits are unknown.
Protective Clothing/Equipment:
Wear chemically protective gloves (impervious), boots, aprons, and gauntlets to prevent prolonged or repeated skin contact.
Wear protective chemical safety goggles or in a splash environment in combination with a face shield. Make emergency
eyewash stations, safety/quick-drench showers, and washing facilities available in work area. Separate contaminated work
clothes from street clothes. Launder before reuse.
Comments:
Avoid contact with skin and eyes. Avoid breathing vapours or mists. Never eat, drink, or smoke in work areas. Practice
good personal hygiene after using this material.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical state, colour and odour: Clear, colourless liquid with caracteristic odour.
Odour threshold: N/Av
2.3 (1 % aqueous solution)
pH :
N/Av
Boiling point:
Melting/freezing point: N/Av
N/Av
Vapour pressure:
N/Ap: not applicable N/Av: not available Page 3 of 6
Material Safety Data Sheet:
ANTEC BIOFOAM
Soluble
Solubility in water:
Coefficient of oil/water distribution: N/Av
Specific gravity or density (water = 1, at 4 oC): N/Av
N/Av
Vapour density:
Evaporation rate: N/Av (butyl acetate = 1)
% volatile by volume: N/Av
SECTION 10 - REACTIVITY AND STABILITY DATA
Stability and reactivity:
Stable at room temperature, in normal handling and storage conditions.
Hazardous polymerisation will not occur.
Polymerisation:
Conditions to avoid:
Avoid STRONG BASES, STRONG OXIDIZING AGENTS鈥?
Materials to avoid:
Avoid STRONG BASES, STRONG OXIDIZING AGENTS 鈥?
Hazardous decomposition products:
Amonia and oxides of sulphur and nitrogen evolve during combustion.
SECTION 11 - TOXICOLOGICAL INFORMATION
Exposure limits:
Ingredient OSHA PEL ACGIH TLV Other exposure
limits
TWA STEL TWA STEL
Sulphamic acid N/Av N/Av N/Av N/Av N/Av
For more details, refer to Section 3.
Carcinogenicity:
No ingredient listed by IARC, ACGIH, NTP and OSHA as a carcinogen.
Teratogenicity, mutagenicity, other reproductive effects: N/Av
N/Av
Skin sensitization:
Respiratory tract sensitization: N/Av
Synergistic materials: N/Av
SECTION 12 - ECOLOGICAL INFORMATION
Environmental effects: N/Av
N/Av
Important environmental characteristics:
Aquatic toxicity: N/Av
SECTION 13 - WASTE DISPOSAL
Handling and storage conditions for disposal:
Store material for disposal as indicated in Handling and Storage (Section 7).
Methods of disposal:
Review federal, provincial and local government requirements prior to disposal. Disposal by controlled incineration or secure
N/Ap: not applicable N/Av: not available Page 4 of 6
Material Safety Data Sheet:
ANTEC BIOFOAM
landfill may be acceptable.
SECTION 14 - TRANSPORTATION INFORMATION
Transportation of Dangerous Goods (TDG) :
Shipping description: This product is regulated according to those Regulations.
Proper shipping name: SULPHAMIC ACID
Class: 8
Identification number: UN2967
Packing group: III
SECTION 15 - REGULATORY INFORMATION
In Canada
WHMIS information:
Product is regulated according to the Controlled Product Regulation (CPR) criteria in Canada.
Hazardous Materials Identification System (HMIS):
HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 0
PERSONAL PROTECTION: Section 8.
HAZARD: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Severe
National Fire Protection Association (NFPA):
HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 0
PERSONAL PROTECTION: Section 8.
HAZARD: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Severe
SECTION 16 - OTHER INFORMATION
ICC The Compliance Center Inc. for V茅toquinol
Prepared by:
(514) 636-8146 or (450) 586-2252
Telephone number:
References:
1. Manufacturer鈥?/suppliers鈥? MSDS.
2. Documents provided by the 芦R茅pertoire toxicologique de la CSST禄.
3. Canadian Centre for Occupational Health and Safety, CHEMINFO, 2003.
Abbreviations:
ACGIH American Conference of Governmental Industrial Hygienists
C Ceiling
CAS Chemical Abstract Service
CFR Code of Federal Regulations (Transportation in U.S.A.)
DOT Department of Transport (U.S.A.)
DSL Domestic Substance List
IARC International Agency for Research on Cancer
LC Lethal concentration
LD Lethal Dosage
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program (U.S.A.)
OSHA Occupational Safety and Health Administration (U.S.A.)
PEL Permissible Exposure Limit
STEL Short-term Exposure Limit
N/Ap: not applicable N/Av: not available Page 5 of 6
Material Safety Data Sheet:
ANTEC BIOFOAM
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
TWA Time Weighted Average
USEPA United States Environmental Protection Agency
WHMIS Workplace Hazardous Materials Information System
End of the MSDS
N/Ap: not applicable N/Av: not available Page 6 of 6
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