Material Safety Data Sheet
Page: 1 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6I
Product Name : FUSION SUPER WG HERBICIDE - PART 1
Classified as hazardous according to criteria of NOHSC
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
Product Name FUSION SUPER WG HERBICIDE - PART 1
Product Code 0505 PART 1
Product Use For the control of certain grasses in crops as per the Directions for Use table on
the label.
Company Name Crop Care Australasia Pty Ltd (ABN 53 061 362 347)
Address 77 Tingira Street Pinkenba
Queensland 4008 Australia
Emergency Tel. 1800 033 498
Telephone/Telex Tel: (07) 3867 9100 Fax: (07) 3867 9110
Number
Product Type Group A Herbicide
Other Information This MSDS describes, to the best of our knowledge, the properties of the
concentrated product. The physical properties and some of the assessments do not
apply to the properties of the product once it has been diluted for application.
Acute health effects of the diluted product are likely to be much less severe.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Solid
Characterization
Ingredients Name CAS Proportion
Inert fillers 30-60 %
Dispersants 10-30 %
Fluazifop-p, present as the butyl 79241-46-6 212 g/kg
ester
Other Information This MSDS describes the properties of PART 1 of the two pack product FUSION SUPER
WG HERBICIDE. Refer to the MSDS for PART 2 for more information.
3. HAZARDS IDENTIFICATION
Possible risk of harm to the unborn child.
Other Information Poisons Schedule S6
4. FIRST AID MEASURES
Inhalation Remove affected person to fresh air until recovered.
If symptoms develop or persist, seek medical advice.
Ingestion If swallowed do NOT induce vomiting; seek medical advice immediately and show this
container or label or contact the Poisons Information Centre on 13 11 26 (Aust).
Make every effort to prevent vomit from entering the lungs by careful placement of
the patient.
Rinse mouth and then drink plenty of water.
Seek medical advice immediately.
Skin Wash affected areas thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If irritation persists, seek medical advice.
Eye If in eyes, hold eyelids open and wash with copious amounts of water for at least
15 minutes.
Seek medical advice if irritation develops or persists.
First Aid Facilities If poisoning occurs, contact a doctor or Poisons Information Centre on 13 11 26
(Australia).
Advice to Doctor Treat symptomatically.
5. FIRE FIGHTING MEASURES
Extinguishing Media Water fog, foam, carbon dioxide or dry chemical.
Material Safety Data Sheet
Page: 2 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6I
Product Name : FUSION SUPER WG HERBICIDE - PART 1
Classified as hazardous according to criteria of NOHSC
Hazardous If involved in a fire, it will emit oxides of carbon, oxides of nitrogen, oxides
Combustion Products of sulfur and possibly fluorinated hydrocarbons.
Protective Equipment Breathable air apparatus should be worn when fighting a fire in which Fusilade WG
is involved.
Other Information Prevent fire water from entering drains or water bodies.
6. ACCIDENTAL RELEASE MEASURES
Spills & Disposal Recover the product by sweeping up or vacuuming without raising dust.
Collect spilled material and waste in sealable open-top type containers for
disposal.
Personal Protection For appropriate personal protective equipment (PPE), refer Section 8.
Environmental This product is a herbicide and spills can damage crops, pastures and desirable
vegetation.
Precautions
7. HANDLING AND STORAGE
Handling Avoid generating dusts while handling the product and mixing.
If dusts are generated, it is advisable to wear a dust mask, refer Section 8.
Storage Store in the closed, original container in a dry, cool well ventilated area out of
direct sunlight.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Limits The manufacturer has recommended the following exposure standard for fluazifop-P
butyl: TLV (TWA) 0.5 mg/m3, STEL - mg/m3.
Respiratory Protection If dusts are present, wear a class P1 dust mask.
Personal Protective When opening the container, preparing spray and using the prepared spray wear
cotton overalls buttoned to the neck and wrist and a washable hat, elbow-length
Equipment
PVC gloves and goggles.
Eng. Controls Handle in well ventilated areas, generally natural ventilation is adequate.
Avoid generating and inhaling dusts.
Hygiene Measures After use and before eating, drinking or smoking, wash hands, arms and face
thoroughly with soap and water.
After each day's use, wash contaminated clothing and safety equipment.
Requirements NSW regulations require that people who use pesticides in their job or business
Concerning Special must have training in the application of the materials. By 1st September, 2005
all users must have received such training.
Training
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Brown granules
Solubility in Water Disperses in water.
Vapour Pressure 0.0033 mPa @ 20掳C for fluazifop-P butyl
Partition co-efficient, Kow Log P is 4.5
n-octanol/water
Flammability Non combustible material.
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions.
Hydrolyses at pH >9.0.
Hazardous Hazardous polymerisation is not possible.
Polymerization
Hazardous Reaction Keep away from strong oxidising agents.
11. TOXICOLOGICAL INFORMATION
Toxicology No harmful effects are expected if the precautions on the label and this MSDS are
followed.
Information
Material Safety Data Sheet
Page: 3 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6I
Product Name : FUSION SUPER WG HERBICIDE - PART 1
Classified as hazardous according to criteria of NOHSC
Inhalation May cause irritation to the respiratory tract.
Ingestion Possible symptoms of exposure to the concentrate include: nausea, vomiting and
abdominal pains.
Skin May irritate the skin.
Eye May irritate the eyes.
Chronic Effects Evidence from animal studies indicate that repeated or prolonged exposure to
fluazifop-P butyl can result in liver and kidney disorders and developmental
effects in an unborn child.
Reproductive Toxicity Evidence from animal studies suggests the potential for developmental toxicity on
repeated or prolonged exposure.
Mutagenicity The weight of evidence indicates that fluazifop-P butyl does not present a
mutagenic risk.
Carcinogenicity The weight of the evidence is that fluazifop-P butyl is not carcinogenic.
Acute Toxicity - Oral The following data is for the active ingredient, fluazifop-P butyl.
LD50 (rat, female) 2451 mg/kg
LD50 (rat, male) 3680 mg/kg
LD50 (rabbit) 621 mg/kg
Acute Toxicity - LD50 (rat) >2000 mg/kg for fluazifop-P butyl
Dermal
Acute Toxicity - LC50 (rat) (4hr) >5.24 mg/l for fluazifop-P butyl
Inhalation
Eye Irritation Mild eye irritant.
Skin Irritation Mild skin irritant.
Skin Sensitisation Product is not a skin sensitiser.
Other Information The Australian Acceptable Daily Intake (ADI) for fluazifop-butyl for a human is
0.003 mg/kg/day, set for the public for daily, lifetime exposure. This is based on
the NOEL of 0.3 mg/kg/day, the level determined to show no effects during long
term exposure for the most sensitive indicators and the most sensitive species.
(Ref: Comm. Dept. of Health and Ageing, 'ADI List', TGA, June 2004).
12. ECOLOGICAL INFORMATION
Known Harmful Harmful to fish and other aquatic organisms.
Effects on the
Environment
Other Precautions Do not contaminate dams, waterways or sewers with this product or the containers
which have held this product.
Environ. Protection Spray drift can cause damage, read the label for more information.
Acute Toxicity - Fish LC50 (96 hr) for rainbow trout is 1.07 mg/l for fluazifop-P butyl
Acute Toxicity - LC50 (48 hr) for daphnia is >1 mg/l for fluazifop-P butyl.
Daphnia
Acute Toxicity - Other The following data is for the active ingredient, fluazifop-P butyl.
Birds: Not toxic to birds. LD50 for mallard duck is >3528 mg/kg
Organisms
Bees: Not toxic to bees. LD50 >200 碌g/bee.
13. DISPOSAL CONSIDERATIONS
Product Disposal On site disposal of the concentrated product is not acceptable.
Ideally, the product should be used for its intended purpose. If there is a need
to dispose of the product, approach local authorities who hold periodic
collections of unwanted chemicals (ChemCollect).
Material Safety Data Sheet
Page: 4 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6I
Product Name : FUSION SUPER WG HERBICIDE - PART 1
Classified as hazardous according to criteria of NOHSC
Container Disposal Thoroughly wash out the inner and add washings to the spray tank. Dispose of
washed inner and cardboard box in landfill.
If no landfill is available, bury the containers below 500mm in a disposal pit
specifically marked and set up for this purpose clear of waterways, desirable
vegetation and tree roots.
Empty containers and product should not be burnt.
14. TRANSPORT INFORMATION
U.N. Number None Allocated
DG Class None Allocated
Hazchem Code None Allocated
Packing Group None Allocated
Storage and Transport Considered non dangerous for transport by the Australian Code for the Transport of
Dangerous Goods by Road and Rail.
15. REGULATORY INFORMATION
Risk Phrase R63 Possible risk of harm to the unborn child.
Safety Phrase S13 Keep away from food,drink and animal feeding stuffs.
S2 Keep out of reach of children.
S36/37 Wear suitable protective clothing and gloves.
S46 If swallowed, seek medical advice immediately and show this container or
label.
Poisons Schedule S6
Hazard Category Harmful
Packaging & POISON
KEEP OUT OF REACH OF CHILDREN
Labelling
READ SAFETY DIRECTIONS BEFORE OPENING OR USING
AICS (Australia) All of the components in this product are listed on the Australian Inventory of
Chemical Substances.
16. OTHER INFORMATION
Contact Person/Point Normal Hours: Mr Volker Maier Phone: (03) 9282 1000
After Hours: Shift Supervisor Phone: 1800 033 498
Revisions Highlighted First Issue
...End Of MSDS...
Material Safety Data Sheet
Page: 1 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6J
Product Name : FUSION SUPER WG HERBICIDE - PART 2
Classified as hazardous according to criteria of NOHSC
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
Product Name FUSION SUPER WG HERBICIDE - PART 2
Product Code 0505 PART 2
Product Use For the control of certain grasses in crops as per the Directions for Use table on
the label.
Company Name Crop Care Australasia Pty Ltd (ABN 53 061 362 347)
Address 77 Tingira Street Pinkenba
Queensland 4008 Australia
Emergency Tel. 1800 033 498
Telephone/Telex Tel: (07) 3867 9100 Fax: (07) 3867 9110
Number
Product Type Group A Herbicide
Other Information This MSDS describes, to the best of our knowledge, the properties of the
concentrated product. The physical properties and some of the assessments do not
apply to the properties of the product once it has been diluted for application.
Acute health effects of the diluted product are likely to be much less severe.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Solid
Characterization
Ingredients Name CAS Proportion
Talc 14807-96-6 >60%
Butroxydim 13164-12-2 250 g/kg
Dispersants <10%
Other Information This MSDS describes the properties of PART 2 of the two pack product FUSION SUPER
WG HERBICIDE. Refer to the MSDS for PART 1 for more information.
3. HAZARDS IDENTIFICATION
Harmful if swallowed.
Irritating to skin.
May cause harm to the unborn child
Other Information Poisons Schedule S5
4. FIRST AID MEASURES
Inhalation Remove affected person to fresh air until recovered.
If symptoms develop or persist, seek medical advice.
Ingestion If swallowed do NOT induce vomiting; seek medical advice immediately and show this
container or label or contact the Poisons Information Centre on 13 11 26 (Aust).
Make every effort to prevent vomit from entering the lungs by careful placement of
the patient.
Rinse mouth and then drink plenty of water.
Obtain medical advice.
Skin Wash affected areas thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If irritation persists, seek medical advice.
Eye If in eyes, hold eyelids open and wash with copious amounts of water for at least
15 minutes.
Seek medical advice if irritation develops or persists.
First Aid Facilities If poisoning occurs, contact a doctor or Poisons Information Centre on 13 11 26
(Australia).
Advice to Doctor Treat symptomatically.
5. FIRE FIGHTING MEASURES
Material Safety Data Sheet
Page: 2 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6J
Product Name : FUSION SUPER WG HERBICIDE - PART 2
Classified as hazardous according to criteria of NOHSC
Extinguishing Media Water fog, foam, carbon dioxide or dry chemical.
Hazardous Combustible solid.
Combustion Products If involved in a fire, it will emit oxides of carbon, oxides of nitrogen and
possibly sulfur oxides.
Protective Equipment Breathable air apparatus should be worn when fighting a fire in which this product
is involved.
Other Information Prevent fire water from entering drains or water bodies.
6. ACCIDENTAL RELEASE MEASURES
Spills & Disposal Recover the product by sweeping up or vacuuming without raising dust.
Collect spilled material and waste in sealable open-top type containers for
disposal.
On-site disposal of concentrate is not acceptable.
Personal Protection For appropriate personal protective equipment (PPE), refer Section 8.
Environmental This product is a herbicide and spills can damage crops, pastures and desirable
vegetation.
Precautions
7. HANDLING AND STORAGE
Handling Avoid generating dusts while handling the product and mixing.
If dusts are generated, it is advisable to wear a dust mask, refer Section 8.
Do NOT contaminate dams, rivers or streams, or any other water bodies with
chemical or used containers.
Storage Store in the closed, original container in a dry, cool well ventilated area out of
direct sunlight.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Limits The manufacturer has recommended the following exposure standard for butroxydim:
TLV (TWA) 0.5 mg/m3, STEL - mg/m3.
NOHSC has set the following exposure standard for talc : TLV (TWA) 2.5 mg/m3,
STEL -.
Respiratory Protection If dusts are present, wear a class P1 dust mask.
Personal Protective When opening the container, preparing spray and using the prepared spray wear
cotton overalls buttoned to the neck and wrist and a washable hat, elbow-length
Equipment
PVC gloves and goggles.
Eng. Controls Handle in well ventilated areas, generally natural ventilation is adequate.
Avoid generating and inhaling dusts.
Hygiene Measures After use and before eating, drinking or smoking, wash hands, arms and face
thoroughly with soap and water.
After each day's use, wash contaminated clothing and safety equipment.
Requirements NSW regulations require that people who use pesticides in their job or business
Concerning Special must have training in the application of the materials. By 1st September, 2005
all users must have received such training.
Training
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Off white granules
Odour Unpleasant, sickly odour
Melting Point 81掳C for butroxydim
Solubility in Water Disperses in water.
Solubility of butroxydim is 6.9 mg/l @ 20掳C
Vapour Pressure 1 x 10-3 mPa @ 20掳C for butroxydim
Partition co-efficient, Kow Log P is 1.9 (pH7 @ 25掳C for butroxydim)
n-octanol/water
Flammability Combustible
Other Information pKa is 4.36
Material Safety Data Sheet
Page: 3 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6J
Product Name : FUSION SUPER WG HERBICIDE - PART 2
Classified as hazardous according to criteria of NOHSC
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions.
Hydrolyses slowly at pH <7.
Hazardous Hazardous polymerisation is not possible.
Polymerization
Hazardous Reaction Keep away from strong oxidising agents.
11. TOXICOLOGICAL INFORMATION
Toxicology No harmful effects are expected if the precautions on the label and this MSDS are
followed.
Information
Inhalation May cause irritation to the respiratory tract.
Ingestion Possible symptoms of exposure to the concentrate include: nausea, vomiting and
abdominal pains.
Skin Will irritate the skin.
Eye May irritate the eyes.
Chronic Effects Chronic exposure can cause damage to the liver.
Reproductive Toxicity At doses toxic to maternal animals, butroxydim has been shown to produce
developmental toxicity in a number of species.
Mutagenicity The weight of evidence indicates that butroxydim does not present a mutagenic
risk.
Carcinogenicity The weight of the evidence is that butroxydim is not carcinogenic.
Acute Toxicity - Oral The following data is for the active ingredient, butroxydim.
LD50 (rat, female) 3476 mg/kg
LD50 (rat, male) 1635 mg/kg
Acute Toxicity - LD50 (rat) >2000 mg/kg for butroxydim
Dermal
Acute Toxicity - LC50 (rat) (4hr) >2.99 mg/l for butroxydim
Inhalation
Eye Irritation Mild eye irritant.
Skin Irritation May cause irritation.
Skin Sensitisation Product is not a skin sensitiser.
Other Information The Australian Acceptable Daily Intake (ADI) for butroxydim for a human is 0.005
mg/kg/day, set for the public for daily, lifetime exposure. This is based on the
NOEL of 0.5 mg/kg/day, the level determined to show no effects during long term
exposure for the most sensitive indicators and the most sensitive species. (Ref:
Comm. Dept. of Health and Ageing, 'ADI List', TGA, June 2004).
12. ECOLOGICAL INFORMATION
Other Precautions Do not contaminate dams, waterways or sewers with this product or the containers
which have held this product.
Environ. Protection Spray drift can cause damage, read the label for more information.
Persistence / Average field half life of butroxydim is 9 days.
Degradability
Acute Toxicity - Fish The following is data for the active ingredient, butroxydim.
LC50 (96 hr) for rainbow trout is >6.9 mg/l.
LC50 (96 hr) for bluegill sunfish is 8.8 mg/l.
Acute Toxicity - LC50 (48 hr) for daphnia is >3.7 mg/l for butroxydim.
Daphnia
Acute Toxicity - Other The following data is for the active ingredient, butroxydim.
Birds: Not toxic to birds. LD50 for mallard duck is >2000 mg/kg
Organisms
LD50 for bobwhite quail is 1221 mg/kg
Bees: Not toxic to bees. LD50 >200 碌g/bee.
Material Safety Data Sheet
Page: 4 of 4
Issue Date : March 2005 ISSUED by CRPCARE
Infosafe No. 3NU6J
Product Name : FUSION SUPER WG HERBICIDE - PART 2
Classified as hazardous according to criteria of NOHSC
13. DISPOSAL CONSIDERATIONS
Product Disposal On site disposal of the concentrated product is not acceptable.
Ideally, the product should be used for its intended purpose. If there is a need
to dispose of the product, approach local authorities who hold periodic
collections of unwanted chemicals (ChemCollect).
Container Disposal Thoroughly wash out the inner and add washings to the spray tank. Dispose of
washed inner and cardboard box in landfill.
If no landfill is available, bury the containers below 500mm in a disposal pit
specifically marked and set up for this purpose clear of waterways, desirable
vegetation and tree roots.
Empty containers and product should not be burnt.
14. TRANSPORT INFORMATION
U.N. Number None Allocated
DG Class None Allocated
Hazchem Code None Allocated
Packing Group None Allocated
Storage and Transport Considered non dangerous for transport by the Australian Code for the Transport of
Dangerous Goods by Road and Rail.
15. REGULATORY INFORMATION
Risk Phrase R22 Harmful if swallowed.
R38 Irritating to skin.
R61(2) May cause harm to the unborn child
Safety Phrase S13 Keep away from food,drink and animal feeding stuffs.
S2 Keep out of reach of children.
S36/37 Wear suitable protective clothing and gloves.
S46 If swallowed, seek medical advice immediately and show this container or
label.
Poisons Schedule S5
Hazard Category Toxic,Irritant
Packaging & CAUTION
KEEP OUT OF REACH OF CHILDREN
Labelling
READ SAFETY DIRECTIONS BEFORE OPENING OR USING
AICS (Australia) All of the components in this product are listed on the Australian Inventory of
Chemical Substances.
16. OTHER INFORMATION
Contact Person/Point Normal Hours: Mr Volker Maier Phone: (03) 9282 1000
After Hours: Shift Supervisor Phone: 1800 033 498
Revisions Highlighted First Issue
...End Of MSDS...
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