Syngenta Crop Protection Canada, Inc.
MATERIAL SAFETY DATA SHEET
VENTURE庐 L
Date issued: 03-09-18 (Y/M/D)
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Company : Syngenta Crop Protection Canada, Inc
140 Research Lane
Guelph, ON
N1G 4Z3
Phone number : 1-87S-YNGENTA (1-877-964-3682)
Emergency phone : 1-800-327-8633 (1-800-FASTMED)
: VENTURE庐 L
Name used on label
Product use : Herbicide
Formulation Number : A12791N
Registration Number : 21209
Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Identity CAS-no. Typical % Other information
FLUAZIFOP-P-BUTYL TECHNICAL
79241-46-6 13 % w/w
Petroleum Solvent
64742-94-5 30 .. 60 % w/w
ISOBUTANOL
78-83-1 4 .. 10 % w/w
Section 3 - HAZARDS IDENTIFICATION
Physical hazards: None
Health hazards: Irritant (skin, eye, respiratory passages) Harmful by
ingestion.
Section 4 - FIRST AID MEASURES
IF IN EYES:
Immediately flush eyes with running water for a minimum of 20 minutes.
Hold eyelids open during flushing. If irritation persists, repeat
flushing. Obtain medical attention immediately.
IF ON SKIN:
Flush skin with running water for a minimum of 20 minutes. Start flushing
while removing contaminated clothing. If irritation persists, repeat
flushing. Obtain medical attention immediately.
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IF SWALLOWED:
Provided the patient is conscious, wash out mouth with water. Immediately
contact Syngenta鈥檚 Emergency Information Network at 1-800-F-A-S-T-M-E-D
(327-8633). Do not induce vomiting. Vomiting should only be induced under
the direction of a physician or a poison control center. If spontaneous
vomiting occurs, have victim lean forward with head down to avoid
breathing in of vomitus, rinse mouth and administer water. Obtain
immediate medical attention.
IF INHALED:
Remove victim to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is labored, give oxygen. Obtain
immediate medical attention.
MEDICAL ADVICE:
This product contains materials that may cause severe pneumonitis if
aspirated. If ingestion has occurred less than 2 hours earlier, carry out
careful gastric lavage; use endotracheal cuff if available, to prevent
aspiration. Observe patient for respiratory difficulty from aspiration
pneumonitis. Give artificial resuscitation and appropriate chemotherapy if
respiration is depressed. Symptomatic treatment and supportive therapy as
indicated.
Section 5 - FIRE FIGHTING MEASURES
Flash point: 40 掳C Method: TCC
Autoignition temperature: Not available.
Flammable limits (LEL): Not available.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS:
During a fire, irritating and possibly toxic gases may be generated by thermal
decomposition or combustion. FLAMMABLE LIQUID. Can release vapours that form
explosive mixtures at temperatures above the flashpoint.
EXTINGUISHING MEDIA:
For large fires, use foam or water-fog; avoid use of water jet. For small
fires, use foam, carbon dioxide or dry powder extinguishant. Water spray
should be used to cool containers.
PROTECTIVE EQUIPMENT:
Self-contained breathing apparatus with full face-piece and protective clothing.
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Section 6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:
Steps to be taken in case material is released or spilled:
Contain spill and keep out of sewers and drains. Wear suitable protective
clothing.
METHODS FOR CLEANING UP:
Generously cover the contaminated areas with common, household detergent
(e.g. TIDE, registered trademark of Proctor and Gamble Co.). Using a stiff
brush and small amounts of water, work the detergent into the remaining
spilled material forming a slurry. Brush the slurry into cracks and
crevices and allow to stand for 2-3 minutes. Be careful to completely
avoid skin or eye contact. Do not splatter on oneself or bystanders.
Remove as much as possible by absorbing with inert material. Remove any
contaminated soil. Place in closed, labeled containers and store in a safe
place to await disposal.
Seal drum and dispose of contaminated material in a facility permitted for
hazardous waste. Large spills should be handled according to a spill plan.
Otherwise, in case of emergency call, day or night, 1-800-327-8633
Deactivating Chemicals:
None known.
Section 7 - HANDLING AND STORAGE
SAFE HANDLING ADVICE:
Take precautionary measures against static discharges. Use spark-resistant
tools and avoid "splash-filling" of containers. Use normal good industrial
hygiene and housekeeping practices.
REQUIREMENTS FOR STORAGE ROOMS:
Keep in a cool, well-ventilated place. Keep away from heat and sources of
ignition. Keep container tightly closed.
ADDITIONAL INFORMATION:
Do not expose sealed containers to temperatures above 40 Deg. C.
Storage Temperature
Ideal storage temperature is 10-27 Deg. C.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure limits
Syngenta Standard FLUAZIFOP-P-BUTYL TECHNICAL
8 hr TWA 0.5 mg/m鲁
OES/HSE ISOBUTANOL
8 hr TWA 50 ppm
150 mg/m鲁
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15 min STEL 75 ppm
225 mg/m鲁
ENGINEERING CONTROLS:
Local exhaust ventilation preferred. General exhaust is acceptable.
EYE PROTECTION:
Eye contact with the material should be avoided through the use of
chemical safety glasses, goggles or a face-shield, selected in regard to
exposure potential.
BODY PROTECTION:
PVC has been shown to be impervious to brodifacoum.
RESPIRATORY PROTECTION:
Use MSHA-NIOSH approved respirator for pesticides.
SPECIAL PRECAUTIONS OR OTHER COMMENTS:
Use ventilation adequate to maintain safe levels. Avoid contact with eye,
skin and clothing. Wash with soap and water immediately after use or
contact. Remove contaminated clothing and wash before reuse. Do not store
near feed, food, or within the reach of children.
Other protective equipment:
Eyewash station and safety shower in work area
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: liquid
Colour: amber to dark brown
Odour: Hydrocarbon
Boiling point: Not available.
Freezing temperature: < -25 掳C
Vapor Pressure: Not available.
Evaporation Rate: Not available.
Bulk density: Not available.
Vapour density: Not available.
Specific gravity: 0.95 g/mL at 20 掳C
Solubility: emulsifiable
pH: 5.16 @ 23掳C (4% emulsion)
Threshold odour: Not available.
Viscosity: 6.9 cps
Volatile by volume: Not available.
Mechanical Impact:
Burning time: Not available.
Explosive properties: Not applicable
Discharge Rate: Not available.
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Section 10 - STABILITY AND REACTIVITY
HAZARDOUS REACTIONS (CONDITIONS TO AVOID)
Stability: Stable under normal conditions. Can be made to burn under fire
conditions.
Incompatibility: Strong oxidizing agents. Unstable under highly alkaline
conditions.
Hazardous polymerization: Will not occur.
Conditions to avoid: High temperatures, sparks, open flames. Keep away
from sources of ignition
- No Smoking.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition products are toxic and may include hydrocarbons, oxides
of carbon and nitrogen and fluorine compounds. Mists from heated solution
may cause respiratory irritation.
Section 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY (LETHAL DOSES)
LD50 Oral rat: 2451 mg/kg
Additional inform. : Fluazifop-p-butyl
This product may cause irritation, a burning sensation
of the mouth, throat and respiratory tract and
abdominal pain. Central nervous system (CNS)
depression, peripheral nervous system (PNS) effects,
liver damage & damage to the reproductive system.
LD50 Dermal rabbit: > 2076 mg/kg
Additional inform. : Repeated and/or prolonged contact may cause dermatitis.
May cause defatting, drying and cracking of the skin.
May be absorbed through intact skin. Central nervous
system (CNS) depression, peripheral nervous system
(PNS) effects, liver damage & damage to the
reproductive system.
LC50 Inhalation rat: > 5240 mg/m鲁 Period: 4 hours
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Additional inform. : Product is irritating to the nose, throat and
respiratory tract. Central nervous system (CNS)
depression, peripheral nervous system (PNS) effects,
liver damage & damage to the reproductive system.
LC50 Inhalation rat: 8000 ppm - 4 hours
Additional inform. : ISOBUTANOL SOLUTION
ACUTE TOXICITY (IRRITATION, SENSITIZATION ETC.)
Eye contact Results: IRRITANT
Additional inform. : This product causes irritation, redness and pain.
GENERAL INFORMATION ABOUT ACUTE OR OTHER TOXICITIES
Other effects of overexposure:
CNS depression is characterized by headache, dizziness, drowsiness, nausea
vomiting and incoordination. Severe overexposure may lead to comma and
possible death due to respiratory failure.
Peripheral neuropathy is a progressive disorder of the nervous system
characterized by sensory and motor abnormalities, muscle spasms, weakness
and pain in the arms and legs, numbness and tingling of the fingers and
toes and paralysis.
Intentional misuse of organic solvents (eg. "glue sniffing") over
prolonged periods of time may be habit forming and lead to behavioral
changes.
Teratogenic/fetotoxic/embryotoxic effects in rats consisted of increased
incidence of diaphramatic hernia and reduced body weights at high dose
levels relative to that seen in the control groups. Human exposure trials
have indicated that skin absorption is unlikely to result in accumulation
of significant levels and therefore the risk of these effects occurring is
thought to be negligible. Nevertheless, it is prudent to restrict
exposures to this product by the ongoing use of protective equipment and
appropriate control measures and techniques.
General information
The ingredient(s) of this product is (are) not classified as carcinogenic
by ACGIH or IARC, not regulated as carcinogens by OSHA and not listed as
carcinogens by NTP.
Large doses of fluazifop-p-butyl may cause reproductive effects based on
studies in laboratory animals. It is our belief that, under conditions of
normal occupational exposure, this product should not pose such a hazard
to the worker.
There is no evidence of mutagenic potential.
Large doses of fluazifop-p-butyl may cause teratogenic/embryotoxic effects
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based on studies in laboratory animals. It is our belief that, under
conditions of normal occupational exposure, this product should not pose
such a hazard to the worker.
Section 12 - ECOLOGICAL INFORMATION
ECOTOXICITY
Additional inform. : This material is toxic to fish and wildlife.
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Method:
Dispose of in facility permitted for hazardous waste.
Container disposal:
Empty container retains product residue. Triple rinse, or equivalent, empty
container, return rinse water to dilution mixture, and dispose of dilution
mixture as a hazardous waste if it cannot be disposed of by use according to
label instructions. Do not reuse container. Offer it for recycling or
reconditioning, or puncture and dispose of in properly permitted landfill.
Section 14 - TRANSPORT INFORMATION
TRANSPORT/ADDITIONAL INFORMATION
Road (TDG) transport:
Not Regulated By TDG
Section 15 - REGULATORY INFORMATION
HAZARDOUS INGREDIENTS
FLUAZIFOP-P-BUTYL TECHNICAL
ISOBUTANOL
Other regulations, restrictions and prohibitions
Pest Control Products (PCP) Act Registration No.:
21209
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Section 16 - OTHER INFORMATION
The information contained herein is offered only as a guide to the
handling of this specific material and has been prepared in good faith by
technically knowledgeable personnel. It is not intended to be
all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is
given or implied and Syngenta will not be liable for any damages,
losses, injuries or consequential damages which may result from the use of
or reliance on any information contained herein. This Material Safety Data
Sheet is valid for three years. This product is under the jurisdiction of
the Pest Control Products Act and is exempt from the requirements for a
WHMIS compliant MSDS. Hazardous properties of all ingredients have been
considered in the preparation of this MSDS. Read the entire MSDS for the
complete hazard evaluation of this product.
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