MATERIAL SAFETY DATA SHEET
In Case of Emergency, Call
Syngenta Crop Protection, Inc.
1-800-888-8372
Post Office Box 18300
Greensboro, NC 27419
1. PRODUCT IDENTIFICATION
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Product Name: Product No.: A7850D
EPA Signal Word: Caution
Active Ingredient(%): Fludioxonil (50.0%) CAS No.: 131341-86-1
Chemical Name: 4-(2,2-difluoro-1,3-benzodioxol-4-yl)-1H-pyrrole-3-carbonitrile
Chemical Class: Substituted Benzodioxalcarbonitrile Fungicide
EPA Registration Number(s): 100-969 Section(s) Revised: 2, 8
2. COMPOSITION/INFORMATION ON INGREDIENTS
ACGIH
OSHA NTP/IARC/OSHA
Other
TLV
PEL Carcinogen
Material
Crystalline Silica, Quartz 10 mg/m鲁/(%SiO2+2) 0.05 mg/m鲁 (respirable 0.05 mg/m鲁 IARC Group 2A
(respirable dust) silica) (respirable dust)**
Sodium Sulfate Not Established Not Established Not Established No
Talc 20 mppcf (containing <1% 2 mg/m鲁 (respirable; <1% 2 mg/m鲁 (respirable) IARC Group 3
quartz) TWA crystalline silica) TWA TWA
**
Fludioxonil (50.0%) Not Established Not Established 10 mg/m鲁 TWA*** No
** recommended by NIOSH
*** Syngenta Occupational Exposure Limit (OEL)
Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.
Syngenta Hazard Category: B, S
3. HAZARDS IDENTIFICATION
Symptoms of Acute Exposure
Causes mild eye and skin irritation.
Hazardous Decomposition Products
Can decompose at high temperatures forming toxic gases.
Physical Properties
Appearance: Off-white powder
Odor: Sweet, soap-like
Unusual Fire, Explosion and Reactivity Hazards
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
4. FIRST AID MEASURES
Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison
contol center or doctor, or going for treatment.
If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment
Ingestion:
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advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so
after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses,
Eye Contact:
if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center
or doctor for treatment advice.
Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-
20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
Inhalation:
respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or
doctor for further treatment advice.
Notes to Physician
There is no specific antidote if this product is ingested.
Treat symptomatically.
Medical Condition Likely to be Aggravated by Exposure
None known.
5. FIRE FIGHTING MEASURES
Fire and Explosion
Flash Point (Test Method): Not Applicable
Flammable Limits (% in Air): Lower: % Not Applicable Upper: % Not Applicable
Autoignition Temperature: Not Applicable
Flammability: Not Flammable
Unusual Fire, Explosion and Reactivity Hazards
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
In Case of Fire
Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing
apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of
combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause
environmental damage. If water is used to fight fire, dike and collect runoff.
6. ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage
and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8.
Sweep up material and place in a compatible disposal container. Scrub area with hard water detergent (e.g. commercial
products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible
disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for
disposition.
7. HANDLING AND STORAGE
Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages
or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is
a potential for exposure to the material. Wash thoroughly with soap and water after handling.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR
THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT.
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.
Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for
Ingestion:
exposure to the material. Wash thoroughly with soap and water after handling.
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Eye Contact: Where eye contact is likely, use chemical splash goggles.
Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and
chemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear.
Inhalation: A respirator is not normally required when handling this substance. Use effective engineering controls to
comply with occupational exposure limits.
In case of emergency spills, use a NIOSH approved respirator with any N, R, or P or HE filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Off-white powder
Odor: Sweet, soap-like
Melting Point: 392掳F
Boiling Point: Not Applicable
Specific Gravity/Density: 0.37 g/cm鲁
8 - 9 (1% solution in H2O @ 77掳F
pH:
(25掳C))
Solubility in H2O
Fludioxonil: 1.8 mg/l @ 77掳F (25掳C)
Vapor Pressure
Fludioxonil: 2.9 x 10(-9) mmHg @ 77掳F (25掳C)
10. STABILITY AND REACTIVITY
Stability: Stable under normal use and storage conditions.
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None known.
Materials to Avoid: None known.
Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity/Irritation Studies (Finished Product)
Ingestion: Practically Non-Toxic
Oral (LD50 Rat) : > 5,050 mg/kg body weight
Dermal: Slightly Toxic
Dermal (LD50 Rabbit) : > 2,020 mg/kg body weight
Inhalation: Practically Non-Toxic
Inhalation (LC50 Rat) : > 6.5 mg/l air - 4 hours
Eye Contact: Slightly Irritating (Rabbit)
Skin Contact: Slightly Irritating (Rabbit)
Skin Sensitization: Not a Sensitizer (Guinea Pig)
Reproductive/Developmental Effects
Fludioxonil: Delayed development at doses causing maternal toxicity.
Chronic/Subchronic Toxicity Studies
Liver and kidney toxicity at high dose levels.
Fludioxonil:
Carcinogenicity
Fludioxonil: Marginal increase (7%) of liver tumors (female, rats: 3,000 ppm); Within historical control range
(1 to 10%).
Other Toxicity Information
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None
Toxicity of Other Components
Crystalline Silica, Quartz
Chronic inhalation exposure to crystalline silica is known to cause silicosis and pulmonary fibrosis in humans.
Experimental animals exposed to crystalline silica developed respiratory tract cancers.
Sodium Sulfate
Exposure may cause irritation of the nose, throat and lungs. Repeated or prolonged contact to the skin results in
dermatitis. May cause mild irritation to the eyes.
Talc
Limited potential for respiratory disease.
Target Organs
Active Ingredients
Fludioxonil: Liver, kidney
Inert Ingredients
Crystalline Silica, Quartz: Respiratory tract
Sodium Sulfate: Respiratory tract, skin, eye
Talc: Respiratory tract
12. ECOLOGICAL INFORMATION
Summary of Effects
Fludioxonil:
Practically nontoxic to birds and bees, but highly toxic to aquatic invertebrates and fish.
Eco-Acute Toxicity
Fludioxonil: Bees LC50/EC50 > 25 ug/bee
Invertebrates (Water Flea) LC50/EC50 0.90 ppm
Fish (Trout) LC50/EC50 0.47 ppm
Fish (Bluegill) LC50/EC50 0.74 ppm
Birds (8-day dietary - Bobwhite Quail) LC50/EC50 > 5,200 ppm
Birds (8-day dietary - Mallard Duck) LC50/EC50 > 5,200 ppm
Eco-Chronic Toxicity
Fludioxonil: Fish (Fathead minnow) Early Life Stage MATC 0.028 mg/l
Invertebrate (Daphnia Magna) Life Cycle MATC 0.025 mg/l
Mallard Reproduction NOEC 700 ppm
Bobwhite Reproduction NOEC 125 ppm
Environmental Fate
Fludioxonil:
The information presented here is for the active ingredient, fludioxonil.
Does not bioaccumulate. Persistent in soil. Stable in water. Low mobility in soil. Sinks in water (after 24 h).
13. DISPOSAL CONSIDERATIONS
Disposal
Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state,
and federal health and environmental regulations.
Characteristic Waste: Not Applicable
Listed Waste: Not Applicable
14. TRANSPORT INFORMATION
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DOT Classification
Ground Transport - NAFTA
Not regulated.
B/L Freight Classification
Fungicides, NOIBN, O/T Poison
Comments
Water Transport - International
Proper Shipping Name: Environmentally Hazardous Substance, Solid, N.O.S. (Fludioxonil), Marine Pollutant
Hazard Class or Division: Class 9
Identification Number: UN 3077
Packing Group: PG III
Do not ship by air.
15. REGULATORY INFORMATION
EPCRA SARA Title III Classification
Acute Health Hazard
Section 311/312 Hazard Classes:
Section 313 Toxic Chemicals: Not Applicable
California Proposition 65
Not Applicable
CERCLA/SARA 302 Reportable Quantity (RQ)
None
RCRA Hazardous Waste Classification (40 CFR 261)
Not Applicable
TSCA Status
Exempt from TSCA, subject to FIFRA
16. OTHER INFORMATION
NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal
1 Slight
Health: 1
Health: 1
2 Moderate
Flammability: 1
Flammability: 1
3 Serious
Reactivity: 0
Instability: 0
4 Extreme
For non-emergency questions about this product call:
1-800-334-9481
Original Issued Date: 03/24/1999
Revision Date: Replaces: 03/30/2004
10/22/2004
The information and recommendations contained herein are based upon data believed to be correct.
However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein.
RSVP# : SCP-955-00288E
End of MSDS
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