NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 02998 Final 05/04/04 Page 1
SHIRLAN庐
PRODUCT IDENTIFICATION
UN Number .............................. D.G. Class ........
: 3082 :9
Hazchem .................................. Sub. Risk..........
: 2X : Marine Pollutant
th
Toxic Substances Schedule ... : 4 Schedule Harmful Substance (fluazinam)
Pack. Grp .................................. : III
NFPA ....... : (Health) - (Flammability) - (Reactivity)
3 - 1 - 1
Use
For the control of botrytis, downy mildew and phomopsis (dead arm) in grapes, botrytis, sclerotinia
and late blight in field tomatoes, early blight, late blight and sclerotinia in potatoes, powdery scab on
potatoes and clubroot in vegetable brassicas.
Ingredients CAS No Proportion
Fluazinam 79622-59-6 50%w/v
Ingredients determined to be non hazardous - To volume
Physical Description/Properties
Appearance.................. : Light brown liquid
Boiling Range.............. : Not determined
Melting Range ............. : Not applicable
Solubility in Water....... : Miscible in water
Vapour Pressure ......... : Not determined
Vapour Density............ : Not determined
Volatile Component .... : Not applicable
Specific Gravity........... : 1.30
Flash Point................... : Not applicable
Flammability Limits .... : Not applicable
Explosive Limits.......... : Not applicable
Autoignition Temp ...... : Not applicable
Form ............................. : Liquid (suspension concentrate)
Log Pow ......................... : 3.56
pH ................................. : 7.1
Continued on next page 鈥︹??.
Nufarm Limited Registered Office: Victoria, Australia. NZ Branch Office: Auckland, New Zealand
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 02998 Final 05/04/04 Page 2
SHIRLAN庐
HEALTH HAZARD INFORMATION
Acute Effects
Eye
An eye irritant.
Skin
Contact with skin will result in irritation. A skin sensitiser. Repeated or prolonged skin contact may
lead to allergic contact dermatitis.
Inhaled
Inhalation of vapours, mist or aerosols may produce respiratory irritation.
Swallowed
No adverse effects expected, however large amounts may cause nausea and vomiting.
Other Health Effects
Repeated or prolonged exposure may cause allergic disorders.
Chronic Effects
No data available.
First Aid
Eye
Flush eyes with plenty of water for 15 minutes holding eyelids open if necessary. Seek medical
assistance.
Skin
Immediately flush body and clothes with large amounts of water. Remove contaminated clothing and
footwear. Wash affected areas with soap and water. If a large area is affected seek medical
assistance.
Inhaled
Remove patient to fresh air. Lay down and keep warm and rested. If breathing is shallow or has
stopped ensure airway is clear and apply resuscitation. Seek medical assistance immediately.
Swallowed
Never give anything by mouth to an unconscious person. If swallowed do NOT induce vomiting. For
advice, contact the National Poisons Centre (0800 764 766). Seek medical assistance immediately.
Other First Aid
No other information available.
Advice to Doctor
Treat symptomatically.
Toxicity Data
Fluazinam technical:
Acute oral LD50(rat) >5000mg/kg
Acute dermal LD50(rat) >200mg/kg
Inhalation LC50(rat) >0.55mg/L/4hr
Skin irritation Severe irritant (rabbit), may cause sensitisation
Eye irritation Severe irritant (rabbit)
Patch testing on 10 volunteers showed that the product caused a type IV allergic reation.
Symptoms observed include localised swelling itchiness and red spots in affected skin regions.
Once exposure had stopped full recovery occurs within a short period of time.
ADI (Acceptable Daily Intake) for humans is 0.004mg/kg/day.
Continued on next page 鈥︹??.
Nufarm Limited Registered Office: Victoria, Australia. NZ Branch Office: Auckland, New Zealand
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 02998 Final 05/04/04 Page 3
SHIRLAN庐
PRECAUTIONS FOR USE
Exposure Standards
No exposure limits have been specifically assigned for this product.
Engineering Controls
Use only in a well ventilated area. Keep containers closed when not in use.
Facilities storing or utilising this material should be equipped with an eyewash facility and safety
shower.
Personal Protection
Avoid all personal contact.
Wear overalls, safety boots, safety goggles, gloves and a NIOSH approved organic
vapour/particulate respirator.
Wash protective clothing before storage or reuse.
Wash thoroughly after handling and before eating, drinking or smoking.
Flammability
Not combustible.
Environment
Aquatic toxicity:
Very toxic to aquatic organisms.
Risk of bioaccumulation in an aquatic species is high.
LC50(96h) Salmo gairdneri 0.11mg/L
LC50(96h) Carp 0.15mg/L
EC50(48h) Selenastrum 0.54mg/L
capricornatum (Algae)
EC50(48h) Daphnia magna 0.19mg/L
Terrestrial toxicity:
Harmful to terrestrial species
Fluazinam technical:
Oral LD50 Bobwhite quail 1782mg/kg
Oral LD50 Mallard duck 4190mg/kg
Oral LD50 Bee >0.1mg/bee (not toxic to bees)
Contact LD50 Bee >0.2mg/bee
Soil toxicity:
Fluazinam technical:
LC50(28d) Worm >1000mg/kg
Environmental Fate, Distribution and Persistence:
Half life in soil is 4 days
Not readily biodegradable in water (test: 5% CO2, 84 days)
Avoid contaminating waterways.
Continued on next page 鈥︹??.
Nufarm Limited Registered Office: Victoria, Australia. NZ Branch Office: Auckland, New Zealand
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 02998 Final 05/04/04 Page 4
SHIRLAN庐
SAFE HANDLING INFORMATION
Storage and Transport
ROAD TRANSPORT: Environmentally Hazardous Substance, Liquid, N.O.S. (fluazinam)
UN#3082 Hazchem 2X
Class 9 Packaging Group III
SEA TRANSPORT: Environmentally Hazardous Substance, Liquid, N.O.S. (fluazinam)
UN#3082
Class 9 Packaging Group III
STORAGE: Store in original container in a cool, dry, ventilated place away from direct heat or
direct sunlight. Store away from foodstuffs, children and animals. Keep container sealed when
not in use.
Packaging and Labelling
1L & 5L plastic jerrycans.
Caution 鈥? Keep out of reach of children
Spills and Disposal
Spills: Wear protective clothing. Clear area of unprotected personnel.
Contain spill and absorb with sand, soil or absorbent granules. Do not allow
product or washings to enter the waterways or sewer. If spill does enter
waterways contact the local authority. Collect in an appropriate sealable
labelled container for disposal in an approved landfill.
Product To avoid disposal all attempts should be made to utilise the product completely
Disposal: in accordance with it鈥檚 registered use. Dilute unusable product according to the
label and pour onto fallow land. Prevent the product from entering natural water
sources.
Container Triple rinse container and add residue to spray tank. Burn if circumstances
Disposal: (especially wind direction) permit, otherwise, bury in landfill.
Reactivity Data
Stable for a least 2 years when stored in the original unopened container at ambient
temperatures.
Fire/Explosion Hazard
Wear full protective clothing and self-contained breathing apparatus.
Extinguishing media: Water fog, fine water spray, foam dry agent (carbon dioxide, dry chemical
powder)
Not combustible, however following evaporation of aqueous component residual material will
burn if ignited. On burning will emit toxic fumes
Continued on next page 鈥︹??.
Nufarm Limited Registered Office: Victoria, Australia. NZ Branch Office: Auckland, New Zealand
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 02998 Final 05/04/04 Page 5
SHIRLAN庐
ADDITIONAL INFORMATION
CONTACT POINTS
NORMAL HOURS: Emergency Response Co-ordinator: (649) 268 2920
24Hr Tollfree Emergency No: Phone: 0800 651 911
IN AN EMERGENCY, DIAL 111 - FIRE OR POLICE
24Hr Emergency No: National Poisons Centre Phone: 0800 764 766
Final Page
Nufarm Limited Registered Office: Victoria, Australia. NZ Branch Office: Auckland, New Zealand
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