Material Safety Data Sheet U.S. Department of Labor
May be used to comply with Occupational Safety and Health Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be consulted Form Approved
for specific requirements. OMB No. 1218-0072
IDENTITY (As Used on Label and List)
Bonide KleenUp Plus Fence & Yard Edger RTU ID # 4432
Date: March 7, 2000
Section I
Products, Inc. (800) 424-9300
6301 Sutliff
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Bonide Road (315) 736-8231
Oriskany, NY 13424
Section II - Hazardous Ingredients/Identity
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Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits % (Optional )
Glyphosate CAS#38641-94-0 0.25
Oxyfluorfen CAS#42874033 0.25
Section III - Physical Information
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APPEARANCE AND ODOR: Clear Yellow Liquid SOLUBILITY IN WATER: Miscible
BOILING POINT: No data available SPECIFIC GRAVITY (water=1): No data available
BULK DENSITY: 8.83 lb./gal. VAPOR DENSITY (air=1): No data available
EVAPORATION RATE (Butyl Acetate =1): Not determined VAPOR PRESSURE: Not determined
PERCENT VOLATILE (By Volume): Not determined pH: 7-8
Section IV - Fire and Explosion Hazard Information
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FLASH POINT (Specify Method - C): >200 to 0 degrees TAG CC
FIRE EXTINGUISHING MEDIA: Water spray, dry chemical.
FLAMMABLE LIMITS (Percent by Volume): No data available carbon dioxide.
FIRE FIGHTING INSTRUCTIONS: This material will not burn. Smoke from fires involving this material may
present unusual hazards. Avoid breathing smoke and mists. Avoid contact with fallout and runoff. Minimize the
amount of water used for fire fighting. Do not enter any enclosed area without full protective equipment, including
self-contained breathing equipment. Contain and isolate runoff and debris for proper disposal. Read the entire
document.
NFPA HAZARD RATING: 0 Least 1 Slight 1 Health 2 Moderate 0 Flammability
3 High 0 Reactivity 4 Severe
Section V - Reactivity Information
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STABILITY: Stable
CONDITIONS TO AVOID: No data available
INCOMPATIBILITY (Avoid contact with): May react with strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc.
HAZARDOUS DECOMPOSITION PRODUCTS: Heating this material generate toxic fumes.
HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: None known
Section VI - Health Information
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TOXICOLOGICAL INFORMATION: EYES: Corneal involvement or irritation cleaning in 7 days or less. The Draize
Eye Irritation Score (range, 0-110) in rabbits is 2.0.
SKIN: Mild to slight irritation at 72 hours. (No irritation or slight erythema). The Draize Skin Primary Irritation
Score (range 0-8) for a 4 hour exposure (rabbits) is 0. The dermal LD50 in rabbits is greater than 5 g/kg.
INHALATION: The 4-hour inhalation LC50 in rats in > 6.3 mg/l.
INGESTION: The oral LD50 in rats is greater than 5 g/kg.
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Bonide KleenUp Plus Grass & Weed Killer RTU ID # 4432 2 of 3
TOXICOLOGICAL INFORMATION (cont鈥檇)
IMMEDIATE CONCERNS: AVOID CONTACT WITH EYES KEEP OUT OF REACH OF CHILDREN
EYE: This substance is slightly irritating to the eyes. Eye contact may include discomfort, tearing, swelling, redness,
and blurred vision.
SKIN: This substance is not expected to cause prolonged or significant skin irritation. If absorbed through the skin,
this substance is considered practically non-toxic to internal organs.
INGESTION: If swallowed, this product may cause gastrointestinal tract irritation.
INHALATION: If inhaled, this substance is considered practically non-toxic to internal organs.
FIRST AID MEASURES:
EYES: Flush eyes immediately with fresh water for at least 15 minutes while holding the eyelids open. Remove
contact lenses if worn. No additional first aid should be necessary. However, if irritation persists, see a doctor.
SKIN: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove
any contaminated clothing.
INGESTION: If swallowed, immediately telephone a poison control center, emergency treatment center or a
physician for advice. DO NOT make person vomit unless directed to do so by medical personnel. If medical advice
cannot be obtained, then immediately take person and product container with label to an emergency treatment center.
INHALATION: If respiratory discomfort or irritation occurs, move the person to fresh air. See a doctor is discomfort
or irritation continues.
ECOTOXICOLOGICAL INFORMATION: This material may be toxic to aquatic organisms and should be kept out
of sewage and drainage systems and all bodies of water.
Studies performed with a concentrated solution of the isopropylamine salt of glyphosate indicate the following:
MON 0139 Technical (62%)
48-hr LC50 Daphnia: 930 mg/L. Practically Nontoxic 96-hr LC50 Bluegill: >1,000 mg/L. Practically Nontoxic
96-hr LC50 Trout: >1,000 mg/L. Practically Nontoxic 96-hr LC50 Carp: >10,000 ppm. Practically Nontoxic
Section VII - Spill or Leak Procedures
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Steps to be taken in case material is released or spilled:
SMALL SPILL: Soak up spilled material with paper towels and discard in trash.
LARGE SPILL: Liquid spills on floor or other impervious surfaces should be contained or diked, and should be
absorbed with attapulgite, bentonite or other absorbent clays. Collect contaminated absorbent, place in plastic-lined
metal drum and dispose of in accordance with instructions provided under Section VII. Thoroughly scrub floor or
other impervious surface with a strong industrial type detergent solution and rinse with water. For liquid spills that
soak into the ground, contact the applicable Federal, State and or County Health Dept. for disposal recommendations.
If disposal is required then refer to Section VII for instructions. Leaking containers should be separated from non-
leaking and either the container or its contents transferred to a drum or other non-leaking container and disposed of in
accordance with instructions provided under Section VII. Any recovered spilled liquid should be similarly collected
and disposed of. Do not contaminate water, foodstuffs, or feed by storage or disposal.
WASTE DISPOSAL METHOD: FOR LARGE SPILLS:
Material collected that cannot be reprocessed should be disposed of in a landfill approved for pesticide disposal or in
accordance with applicable Federal, State, or local procedures.
PRODUCT DISPOSAL: It is recommended that the entire product be used up, carefully following all label directions
and precautions. If necessary to dispose of partially filled product container, then securely wrap it in several layers of
newspaper and discard in trash.
EMPTY CONTAINER: Do not reuse container. Rinse thoroughly before discarding in trash.
Section VIII - Special Protection Information
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PERSONAL PROTECTION:
EYES AND FACE: For application of product in accordance with label instructions, no special eye protection is
needed. Handling of the product is not likely to present an eye exposure concern during normal handling. In the
event of an accidental discharge of the material during manufacture or handling which could cause eye contact,
workers should wear goggles or a face shield. SKIN: No special skin protection is usually necessary. Avoid
prolonged or frequently repeated skin contact with this material. Wearing protective clothing can minimize skin
contact. Wash thoroughly with soap and water after handling.
RESPIRATORY: Handling of this product is not likely to present an airborne exposure concern during normal
handling. In the event of an accidental discharge of the material during manufacture or handling which produces a
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heavy mist, workers should put on respiratory protection equipment. Consult respirator manufacturer to determine
appropriate type of equipment. Observe respirator use limitations specified by NIOSH MSHA or the manufacturer.
For application of product in accordance with label instructions, no special respiratory protection is required.
ENGINEERING CONTROLS: No special ventilation is usually necessary. However, if operating conditions create
high airborned concentrations of this material, special ventilation may be needed.
Section IX - Special Precautions
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HANDLING AND STORAGE: GENERAL PROCEDURES: Keep pesticide in original container. Store in a secure,
preferably locked, storage area. Protect container from freezing. STORAGE TEMPERATURE: Do not store below
32 degrees Fahrenheit.
Section X - Regulatory Information
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SARA TITLE III HAZARD CATEGORY:
IMMEDIATE: Yes FIRE: No DELAYED: No REACTIVE: No
SUDDEN RELEASE OF PRESSURE: No
SUBSTANCES REGULATED UNDER SARA, TITLE III, SECT. 313: None
NOTICE: This information is believed to be accurate and reliable. However, no guarantee expressed or implied is
made with respect to the information contained herein.
KEEP OUT OF REACH OF CHILDREN
ABBREVIATION KEY
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N/A: NOT AVAILABLE OR APPLICABLE N/E: NOT ESTABLISHED
TLV: THRESHOLD LIMIT VALUE TWA: TIME WEIGHTED AVG./8 HOUR WORKDAY
STEL: SHORT TERM EXPOSURE LIMIT D.O.T.: DEPARTMENT OF TRANSPORTATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith.
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