NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 03556 FINAL 19/08/02 Page 1
MAVRIK庐 FLO
PRODUCT IDENTIFICATION
: 3082 D.G. Class ...... : 9
UN Number ..............................
: 2X Sub. Risk........... : marine pollutant
Hazchem ..................................
rd
Toxic Substances Schedule ... : 3 schedule, standard poison (tau-fluvalinate)
: III IMDG.................. : page 150
Pack. Grp ..................................
NFPA ....... : (Health) - (Flammability) - (Reactivity)
2 - 0 - 1
Use
A synthetic pyrethroid insecticide for the control of insect pests in fruit, vegetable, arable and
crops.
Ingredients CAS No Proportion % w/v
Tau-fluvalinate 102851-06-9 24
Ethylene glycol 107-21-1 9.3
Other ingredients determined not to be hazardous - To volume
Physical Description/Properties
: white-yellowish, milky liquid, characteristic odour
Appearance..................
: Not determined
Boiling Range..............
Melting Range ............. : Not applicable
: Miscible
Solubility in Water.......
Vapour Pressure ......... : 17.5 mmHg
: Not determined
Vapour Density............
Volatile Component .... : Not determined
: 1.07 鈥? 1.11g/mL @ 20掳C
Specific Gravity...........
: >100掳 (cc)
C
Flash Point...................
Flammability Limits .... : Non flammable, (combustible)
: Not explosive
Explosive Limits..........
Autoignition Temp ...... : Not determined
Form ............................. : Liquid, suspension concentrate
pH ................................. : 3 鈥? 7 (1% soluzione)
Continued on next page 鈥︹??.
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 03556 FINAL 19/08/02 Page 2
MAVRIK庐 FLO
HEALTH HAZARD INFORMATION
Acute Effects
Eye
Slightly irritating.
Skin
Slightly irritating.
Inhaled
No data available.
Swallowed
No data available.
Other Health Effects
None known.
Chronic Effects
Tau-fluvalinate technical has been tested on laboratory animals and in test-tube systems. No
evidence of mutagenic, teratogenic or reproductive effects were observed.
First Aid
Eye
Flush eyes with plenty of water for 15 minutes holding eyelids open if necessary. Seek medical
assistance.
Skin
Immediately flush body and clothes with large amounts of water. Remove contaminated
clothing and footwear. Wash affected areas with soap and water. If a large area is affected
seek medical assistance.
Inhaled
Remove patient to fresh air. Lay down and keep warm and rested. If breathing is shallow or
has stopped ensure airway is clear and apply resuscitation. Seek medical assistance
immediately.
Swallowed
Never give anything by mouth to an unconscious person. If swallowed do NOT induce vomiting.
For advice, contact the National Poisons Centre (0800 764 766). Seek medical assistance
immediately.
Other First Aid
None known.
Advice to Doctor
No specific antidote is available. Treat symptomatically.
Toxicity Data
Acute oral LD50(rat) >2000mg/kg
Acute dermal LD50(rat) >2000mg/kg
Acute inhalation LC50(rat, 4h) >5.5mg/L/4hr (technical tau-fluvalinate)
Eye irritant (rabbit) Non irritant
Skin irritant (rabbit) Non irritant
Skin sensitisation (rat) Non-sensitising (technical tau-fluvalinate)
Continued on next page 鈥? 鈥? .
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 03556 FINAL 19/08/02 Page 3
MAVRIK庐 FLO
PRECAUTIONS FOR USE
Exposure Standards
No exposure standards have been established for this product.
3
WES TWA for ethylene glycol = ceiling 50ppm (127mg/m )
Engineering Controls
For preparation and application of the spray mixture natural ventilation is adequate.
Facilities storing or utilising this material should be equipped with an eyewash facility and safety
shower.
Personal Protection
Avoid all personal contact.
Wear cotton overalls, nitrile rubber gloves, hat, boots, safety goggles, half mask respirator with
organic vapour cartridge + dust/mist pre-filter.
Do not enter treated areas without protective clothing until the spray has dried.
Wash protective clothing before storage or reuse.
Wash thoroughly after handling and before eating, drinking or smoking.
Flammability
Non flammable, non combustible.
Environment
Tau-fluvalinate technical is extremely toxic to fish and other aquatic organisms and may cause
long-term adverse effects in the aquatic environment.
LC50(96h), bluegill sunfish = 0.006mg/L
LC50(96h), rainbow trout = 0.003mg/L
EC50(72h), algae = >100mg/L
LC50(48h), daphnia = 0.011mg/L
Tau-fluvalinate technical is of low toxicity to birds
LD50, bobwhite quail = >2510mg/kg
Tau-fluvalinate technical is of low toxicity to bees.
Do not discharge into drain or the environment.
Continued on next page 鈥? 鈥? .
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 03556 FINAL 19/08/02 Page 4
MAVRIK庐 FLO
SAFE HANDLING INFORMATION
Storage and Transport
ROAD TRANSPORT: Environmentally hazardous substance, liquid, N.O.S. (tau-fluvalinate
24%)
UN#3082 Hazchem 2X
Class 9 Packaging group III
SEA TRANSPORT: Environmentally hazardous substance, liquid, N.O.S. (tau-fluvalinate
24%)
UN#3082 IMDG code page 150
Class 9 Packaging group III
STORAGE: Store in original container in a cool, dry, ventilated place away from direct heat or
direct sunlight. Store away from insecticides, foodstuffs, children and animals. Keep container
sealed when not in use.
Note: when stored in high temperatures for prolonged periods very hazardous gases may be
produced in the product container. Inhalation of these vapours is extremely dangerous.
Packaging and Labelling
1L HDPE jerrycan
POISON 鈥? keep out of reach of children
Marine pollutant
Spills and Disposal
Spills: Wear protective clothing. Clear area of unprotected personnel.
Contain spill and absorb with sand, soil or absorbent granules. Do not allow
product or washings to enter the waterways or sewer. If spill does enter
waterways contact the local authority. Collect in an appropriate sealable
container for disposal in an approved landfill.
Product To avoid disposal all attempts should be made to utilise the product completely
Disposal: in accordance with it鈥檚 registered use. Dilute unusable product according to the
label and pour onto fallow land. Prevent the product from entering natural water
sources.
Container Triple rinse container and add residue to spray tank while it is filling. Burn
Disposal: empty container if wind direction permits, otherwise crush and bury in landfill.
Reactivity Data
Stable under normal conditions.
Avoid extreme heat above 40掳C, strong acids and bases.
Thermal decomposition products may produce toxic and/or irritating gas.
When product is stored in high heat for prolonged periods, very low levels of hydrogen cyanide
may be released in the head-space of the closed container.
Continued on next page 鈥? 鈥? .
NUFARM NZ
Division of Nufarm Limited
2 Sterling Ave, Manurewa, Auckland
P.O. Box 22407, Auckland 1133
Telephone 0-9-268 2920 Fax 0-9-267 8444
www.nufarm.co.nz
MATERIAL SAFETY DATA SHEET
Nufarm Number: 03556 FINAL 19/08/02 Page 5
MAVRIK庐 FLO
Fire/Explosion Hazard
Wear full protective clothing and self contained breathing apparatus.
Extinguishing media: Water spray, foam, dry chemical, carbon dioxide. DO NOT use direct
water jets.
Dike fire control water for later disposal. Prevent all discharge into the environment.
ADDITIONAL INFORMATION
Supersedes: 04/12/01
CONTACT POINTS
NORMAL HOURS: Emergency Response Co-ordinator: (649) 268 2920
24Hr Tollfree Emergency No: Phone: 0800 651 911
IN AN EMERGENCY, DIAL 111 - FIRE OR POLICE
24Hr Emergency No: National Poisons Centre Phone: 0800 764 766
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