MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 6/29/04
Product Code: 67019
CLIPPER* 25 OD HERBICIDE MSDS: 007916
NOTE TO PHYSICIAN: In cases where several ounces
1. PRODUCT AND COMPANY IDENTIFICATION:
have been ingested, consider the use of ethanol and
PRODUCT: Clipper* 25 OD Herbicide hemodialysis in the treatment. Consult standard literature for
details of treatment. If ethanol is used, a therapeutically
COMPANY IDENTIFICATION: effective blood concentration in the range of 100-150 mg/dl
Dow AgroSciences LLC may be achieved by rapid loading dose followed by a
9330 Zionsville Road continuous intravenous infusion. Consult standard literature
Indianapolis, IN 46268-1189 for details of treatment. 4-methyl pyrazole (Antizol) 庐 is an
effective blocker of alcohol dehydrogenase and should be
2. COMPOSITION/INFORMATION ON INGREDIENTS: used in the treatment of ethylene glycol, di- or triethylene
glycol, ethylene glycol butyl ether, or methanol intoxication if
Penoxsulam: CAS # 219714-96-2 2.67%
available. Fomepizole protocol (Brent, J et al. New Eng J
2-(2,2-difluoroethoxy)-
Med Feb 8, 2001 344:6, p424-9): loading dose 15 mg/kg IV,
N-(5,8-dimethoxy[1,2,4]
follow by bolus dose of 10 mg/kg every 12 hours; after 48
triazolo[1,5-c]pyrimidin-
hours, increase bolus dose to 15 mg/kg every 12 hours.
2-yl)-6-(trifluoromethyl)
Continue fomepizole until serum methanol, EG, DEG, or
benzenesulfonamide
TEG are undetectable. The signs and symptoms of
Balance, Total, Including 97.33%
poisoning include anion gap metabolic acidosis, central
Adjuvant which contains
nervous system depression, renal tubular injury, and
Methanol CAS # 000067-56-1
possible late stage cranial nerve involvement. Respiratory
3. HAZARDOUS IDENTIFICATIONS: symptoms, including pulmonary edema, may be delayed.
Persons receiving significant exposure should be observed
EMERGENCY OVERVIEW 24-48 hours for signs of respiratory distress. In severe
Yellow turbid liquid with an oily odor. May cause eye and poisoning, respiratory support with mechanical ventilation
skin irritation. Toxic to aquatic organisms and avian. and positive and expiratory pressure may be required. If
lavage is performed, suggest endotracheal and/or
EMERGENCY PHONE NUMBER: 800-992-5994
esophageal control. Danger from lung aspiration must be
weighed against toxicity when considering emptying the
4. FIRST AID:
stomach. These precautions are suggested for conditions
EYE: Flush eyes thoroughly with water for several minutes. with a high potential for exposure. If handling procedures
Remove contact lenses after initial 1-2 minutes and continue are such that there is only a low potential for exposure, less
protection may be needed. Emergency conditions may
flushing for several additional minutes. If effects occur,
require additional precautions.
consult a physician, preferably an ophthalmologist.
5. FIRE FIGHTING MEASURES:
SKIN: Immediately flush skin with water while removing
o o
contaminated clothing and shoes. Get medical attention if FLASH POINT: >212 F (>100 C)
symptoms occur. Wash clothing before reuse. Destroy
contaminated articles that can not be washed including FLAMMABLE LIMITS
leather items such as shoes. LFL: Not determined
UFL: Not determined
INGESTION: Do not induce vomiting. Do not give anything
by mouth. Seek medical attention immediately. EXTINGUISHING MEDIA: Foam, CO2, or Dry chemical
INHALATION: Move person to fresh air; if effects occur, FIRE AND EXPLOSION HAZARDS: Foam fire
consult a physician. extinguishing system is preferred because uncontrolled
water can spread possible contamination. Toxic irritating
gases may be formed under fire conditions.
*Trademark of Dow AgroSciences LLC
1
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 6/29/04
Product Code: 67019
CLIPPER* 25 OD HERBICIDE MSDS: 007916
FIRE-FIGHTING EQUIPMENT: Use positive-pressure, self- RECOMMENDATIONS FOR MANUFACTURING,
contained breathing apparatus and full protective COMMERCIAL BLENDING, AND PACKAGING
equipment. WORKERS:
6. ACCIDENTAL RELEASE MEASURES: EYE/FACE PROTECTION: Use safety glasses.
ACTION TO TAKE FOR SPILLS: Absorb small spills with a
SKIN PROTECTION: Use protective clothing chemically
non-reactive absorbent such as sand and place in a
resistant to this material. Selection of specific items such as
container suitable for disposal. Report large spills to Dow
faceshield, gloves, boots, apron, or full-body suit will depend
AgroSciences on 800-992-5994.
on operation. Safety shower should be located in immediate
work area. Remove contaminated clothing immediately,
7. HANDLING AND STORAGE:
wash skin area with soap and water, and launder clothing
PRECAUTIONS TO BE TAKEN IN HANDLING AND before reuse or dispose of properly. Items, which cannot be
STORAGE: Keep out of reach of children. Do not swallow. decontaminated, such as shoes, belts and watchbands,
Avoid contact with eyes, skin, and clothing. Avoid breathing should be removed and disposed of properly.
vapors and spray mist. Handle concentrate in ventilated
area. Wash thoroughly with soap and water after handling RESPIRATORY PROTECTION: Atmospheric levels should
and before eating, chewing gum, using tobacco, using the be maintained below the exposure guideline. When
toilet or smoking. Keep away from food, feedstuffs, and respiratory protection is required, use a NIOSH approved
water supplies. air-purifying or positive-pressure supplied-air respirator
depending on the potential airborne concentration. For
8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
emergency and other conditions where the exposure
guideline may be exceeded, use a NIOSH approved
These precautions are suggested for conditions where a
positive-pressure self-contained breathing apparatus or
potential for exposure exists. Emergency conditions may
positive-pressure airline with auxiliary self-contained air
require additional precautions.
supply.
EXPOSURE GUIDELINES:
Methanol alcohol (methanol): ACGIH TLV is 200 ppm TWA, APPLICATORS AND ALL OTHER HANDLERS: Refer to
the product label for personal protective clothing and
250 ppm STEL, Skin. OSHA PEL IS 200 ppm TWA.
equipment.
A 鈥榮kin鈥? notation following the exposure guideline refers to
the potential for dermal absorption of the material including 9. PHYSICAL AND CHEMICAL PROPERTIES:
mucous membranes and the eyes either by contact with APPEARANCE: Yellow liquid
vapors or by direct skin contact. It is intended to alert the ODOR: Oily
reader that inhalation may not be the only route of exposure DENSITY: 0.936 g/mL @20oC
and that measures to minimize dermal exposures should be SOLUBILITY IN WATER: Emulsifiable
considered.
ENGINEERING CONTROLS: Provide general and/or local
exhaust ventilation to control airborne levels below the
exposure guidelines.
*Trademark of Dow AgroSciences LLC
2
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 6/29/04
Product Code: 67019
CLIPPER* 25 OD HERBICIDE MSDS: 007916
INHALATION: Contains small amounts of methanol. In
10. STABILITY AND REACTIVITY:
confined or poorly ventilated areas, vapors of methanol may
STABILITY: (CONDITIONS TO AVOID) Stable under accumulate and pose a hazard. Inhalation of methanol may
normal storage conditions. cause effects ranging from headache, narcosis and visual
impairment to metabolic acidosis, blindness, and even
INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) death. Excessive exposure may cause irritation to upper
None known. respiratory tract (nose and throat). Effects may be delayed.
May cause abdominal discomfort or diarrhea.
HAZARDOUS DECOMPOSITION PRODUCTS: None
known. SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: For the
active ingredient, in animals, effects have been reported on
HAZARDOUS POLYMERIZATION: Not known to occur. the following organs: kidney and liver. Methanol is highly
toxic to humans and may cause central nervous system
11. TOXICOLOGICAL INFORMATION: effects, visual disturbances up to blindness, metabolic
acidosis, and degenerative damage to other organs
POTENTIAL HEALTH EFFECTS: This section includes
possible adverse effects, which could occur if this material is including liver, kidney, and heart.
not handled in the recommended manner.
CANCER INFORMATION: No relevant information found.
EYE: May cause eye irritation.
TERATOLOGY (BIRTH DEFECTS): The active ingredient
did not cause birth defects or other effects in the fetus even
SKIN: Brief contact is essentially non-irritating to the skin.
at doses which caused toxic effects in the mother. Methanol
Prolonged contact may cause skin irritation with local
has caused birth defects in mice at doses non-toxic to the
redness. Prolonged skin contact is unlikely to result in
mother as well as slight behavioral effects in offspring of
absorption of harmful amounts. Repeated skin contact may
rats.
result in absorption of harmful amounts. The dermal LD50
has not been determined. Contains small amounts of
REPRODUCTIVE EFFECTS: The active ingredient, in
methanol. Effects of methanol are the same as observed via
animal studies, did not interfere with reproduction.
oral and inhalation exposure and include central nervous
system depression, visual impairment up to blindness,
MUTAGENICITY: For the active ingredient, in-vitro and
metabolic acidosis, with effects on organ systems such as
animal genetic toxicity studies were negative.
liver, kidneys and heart, even death.
12. ECOLOGICAL INFORMATION:
INGESTION: Low toxicity if swallowed. Small amounts
swallowed incidental to normal handling operations are not ENVIRONMENTAL DATA:
likely to cause injury; however, swallowing larger amounts
may cause injury. Aspiration into the lungs may occur during MOVEMENT & PARTITIONING:
ingestion or vomiting, causing lung damage or even death Based largely or completely on information for the active
due to chemical pneumonia. Single dose oral LD50 has not ingredient:
been determined. Contains small amounts of methanol. The Bioconcentration potential is low (BCD <100 or Log Pow
lethal dose in humans for methanol is approximately 1-8 <3).
ounces (29 鈥? 237 mL). Ingestion may cause blindness. Expected to be relatively immobile in soil (Koc is
Effects may be delayed. Symptoms of excessive exposure >5000).
may be anesthetic or narcotic effects; dizziness and
drowsiness may be observed. Methanol is highly toxic to
humans and may cause central nervous system effects,
visual disturbances up to blindness, metabolic acidosis and
degenerative damage to other organs including liver, kidney
and heart.
*Trademark of Dow AgroSciences LLC
3
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 6/29/04
Product Code: 67019
CLIPPER* 25 OD HERBICIDE MSDS: 007916
DEGRADATION & PERSISTENCE: 15. REGULATORY INFORMATION:
Based largely or completely on information for the active
NOTICE: The information herein is presented in good faith
ingredient:
and believed to be accurate as of the effective date shown
Degradation is expected in the atmospheric
above. However, no warranty, express or implied, is given.
environment within minutes to hours.
Regulatory requirements are subject to change and may
differ from one location to another; it is the buyer鈥檚
ECOTOXICOLOGY: Based largely or completely on
responsibility to ensure that its activities comply with federal,
information for active ingredient:
Material is highly toxic to aquatic organisms on an acute state or provincial, and local laws. The following specific
information is made for the purpose of complying with
basis (LC50 or EC50 is between 0.1 and 1 mg/L in most
numerous federal, state or provincial, and local laws and
sensitive species).
regulations.
Material is practically non-toxic to birds on an acute
basis LD50 is >2000 mg/kg).
Material is slightly toxic to birds on a dietary basis (LC50 U.S. REGULATIONS
is between 1001 and 5000 ppm).
SARA 313 INFORMATION: This product contains the
13. DISPOSAL CONSIDERATIONS: following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and
DISPOSAL METHOD: If wastes and/or containers cannot
Reauthorization Act of 1986 and 40 CFR Part 372:
be disposed of according to the product label directions,
disposal of this material must be in accordance with your
CHEMICAL NAME CAS NUMBER CONCENTRATION
local or area regulatory authorities. This information
presented below only applies to the material as supplied.
Methanol 000067-56-1 ~1.5%
The identification based on characteristic(s) or listing may
not apply if the material has been used or otherwise
SARA HAZARD CATEGORY: This product has been
contaminated. It is the responsibility of the waste generator
reviewed according to the EPA 鈥淗azard Categories鈥?
to determine the toxicity and physical properties of the
promulgated under Section 311 and 312 of the Superfund
material generated to determine the proper waste
Amendment and Reauthorization Act of 1986 (SARA Title
identification and disposal methods in compliance with
III) and is considered, under applicable definitions, to meet
applicable regulations. If the material as supplied becomes
the following categories:
a waste, follow all applicable regional, national and local
laws and regulations.
An immediate health hazard
A delayed health hazard
14. TRANSPORT INFORMATION:
U.S. DEPARTMENT OF TRANSPORTATION TOXIC SUBSTANCES CONTROL ACT (TSCA): All
INFORMATION: ingredients are on the TSCA inventory or are not required to
be listed on the TSCA inventory.
For all package sizes shipped by land and air transportation:
This material is not regulated for transport.
For all package sizes shipped by vessel:
ENVIRONMENTALLY HAZARDOUS SUBSTANCES,
LIQUID, N.O.S./(CONTAINS PENOXSULAM/9/UN 3082/
PG III/MARINE POLLUTANT
*Trademark of Dow AgroSciences LLC
4
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 6/29/04
Product Code: 67019
CLIPPER* 25 OD HERBICIDE MSDS: 007916
STATE RIGHT-TO-KNOW: The following product
components are cited on certain state lists as mentioned.
Non-listed components may be shown in the composition
section of the MSDS.
CHEMICAL NAME CAS NUMBER LIST
Methanol 000067-56-1 NJ1 NJ2 NJ3 PA1 PA3
NJ1=New Jersey Special Health Hazard Substance (present at >
or = to 0.1%).
NJ2=New Jersey Environmental Hazardous Substance (present at
> or = to 1.0%).
NJ3=New Jersey Workplace Hazardous Substance (present at >
or = or equal to 1.0%).
PA1=Pennsylvania Hazardous Substance (present at > or = to
1.0%).
PA3=Pennsylvania Environmental Hazardous Substance (present
at > or = to 1.0%).
OSHA HAZARD COMMUNICATION STANDARD: This
product is a 鈥淗azardous chemical鈥? as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.
COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA, or
SUPERFUND): This product contains the following
substance(s) listed as "Hazardous Substances" under
CERCLA, which may require reporting of releases:
Chemical Name CAS Number RQ % in Product
Methanol 000067-56-1 5000 lbs 1.5%
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
RATINGS:
Category Rating
Health 2
Flammability 1
Reactivity 0
16. OTHER INFORMATION:
MSDS STATUS: Revised Sections: 15
Reference: DR-0386-2144
Replaces RSSDS Dated: 5/12/04
The Information Herein Is Given In Good Faith, But No
Warranty, Express or Implied, Is Made. Consult Dow
AgroSciences for Further Information.
*Trademark of Dow AgroSciences LLC
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