MSDS PAGE: CAS 7789-29-9 800-00-2 11-14-0 MSDS fluorideaction

Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

Chemical: Potassium Bifluoride NFPA: H=3 F=0 I=0 S=None
HMIS: H=3 F=0 R=0 PPE= Supplied by user;
dependent on conditions
MSDS Number: KBF-1103
Effective Date: 14 November 2003
Issued by: Solvay Chemicals, Inc. Regulatory Affairs Department
Not valid three years after effective date or after issuance of superseding MSDS, whichever is
earlier. French or Spanish translations of this MSDS may be available. Check www.solvaychemicals.us
or call Solvay Fluorides, LLC to verify the latest version or translation availability.
Material Safety Data Sheets contain country specific regulatory information. Therefore, the MSDS’s
provided are for use only by customers of Solvay Fluorides, LLC in North America. If you are located in
a country other than Canada, Mexico or the United States, please contact the Solvay Group company
in your country for MSDS information applicable to your location.

1. Company and Product Identification
1.1 Product Name: Potassium Bifluoride
Chemical Name: Potassium bifluoride
Synonyms: Potassium hydrogen fluoride
Chemical Formula: KF•HF
Molecular Weight: 78
CAS Number: 7789-29-9
EINECS Number: 232-156-2
Grade/Trade Names: None
1.2 Recommended Uses: Chemical industry; metal treatment; welding and soldering agents;
Intermediates
1.3 Supplier: Solvay Fluorides, LLC
PO BOX 27328 Houston, TX 77227-7328
3333 Richmond Ave. Houston, Texas 77098
1.4 Emergency Telephone Numbers
Emergencies (USA): 1-800-424-9300 (CHEMTREC®)
Transportation Emergencies (INTERNATIONAL/MARITIME): 1-703-527-3887 (CHEMTREC®)
Transportation Emergencies (CANADA): 1-613-996-6666 (CANUTEC)
Transportation Emergencies (MEXICO-SETIQ): 01-800-00-214-00 (MEX. REPUBLIC)
525-559-1588 (Mexico City and metro
area)

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
Page 1/11 www.solvaychemicals.us 1.800.765.8292
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

2. Composition/Information on Ingredients
INGREDIENTS FORMULA WT. PERCENT CAS #
Potassium bifluoride KF•HF 7789-29-9
Ca. 99

3. Hazards Identification
Emergency Overview:
�? Corrosive product, hazardous to human health.
�? Presents hazards from its ionizing fluorine.
�? In case of decomposition, releases hydrogen fluoride.
�? Hazardous product for the aquatic environment.
3.1 Route of Entry: Inhalation: Yes Skin: Yes Ingestion: Yes
3.2 Potential Effects of exposure:
�? Corrosive to mucous membranes, eyes, and skin.
�? Risk of cardiac and nervous disorders.
�? The seriousness of the lesion and the prognosis of intoxication depend directly on the
concentration and duration of exposure.
�? Chronic exposure to the product can cause bone fluorosis.
Inhalation:
�? Severe irritation of the nose and throat.
�? Spasmodic cough and difficulty in breathing.
�? At high concentrations, risk of chemical pneumonitis, pulmonary edema.
�? At high concentrations, risk of hypocalcemia with nervous problems (tetany) and
cardiac arrhythmia.
�? In the case of repeated or prolonged exposure: risk of sore throat, nosebleeds,
chronic bronchitis.
Eyes:
�? Severe eye irritation, watering, redness and swelling of the eyelids.
�? Burns.
�? Risk of serious or permanent eye lesions or blindness.
Skin contact:
�? Painful irritation, delayed appearance.
�? Risk of severe burns; slow healing.
�? Risk of shock.
�? If fingernails are touched, severe pain after several hours.
�? Risk of hypocalcemia depending the extent of the lesions.
Ingestion:
�? Severe irritation, burns, perforation of the gastrointestinal tract accompanied by shock.
�? Risk of throat edema and suffocation.
�? Nausea, vomiting (bloody), abdominal cramps and diarrhea (bloody).
�? Cough and difficulty breathing.
�? Risk of hypocalcemia with nervous disorders (tetany) and cardiac rhythm disorders.
�? Risk of convulsions, loss of consciousness, deep coma and cardiopulmonary arrest.
�? Risk of general symptoms having a severe prognosis.
Carcinogenicity: See section 11.3.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 2/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

4. First-Aid Measures
4.1 General Recommendations:
Inhalation:
�? Remove the subject from the contaminated area as son as possible; transport
him/her lying down, with the head higher than the body, to a quiet, uncontaminated and
well-ventilated location.
�? Administer oxygen or cardiopulmonary resuscitation if necessary.
�? Keep warm (blanket).
�? Consult a physician in all cases.
�? Take to a hospital.
Eyes:
�? Consult an ophthalmologist immediately in all cases.
�? Take to a hospital immediately.
�? Flush eyes as soon as possible with running water for 15 minutes, while keeping the
eyelids wide open.
�? Rinse the eyes with calcium gluconate (1% solution in physiological serum)
(10 ml of calcium gluconate 10% in 90 ml of physiological serum).
�? In case of difficulty opening the lids, administer an analgesic eyewash
(oxybuprocaine).
Skin:
�? Remove contaminated shoes, socks and clothing, under the shower if necessary;
wash the affected skin with running water.
�? Immediately apply calcium gluconate gel (2.5%) and massage into the affected area
using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes
after pain is relieved.
�? If fingers/fingernails are touched, even if there is no pain, dip them in a bath of 5%
calcium gluconate for 15 to 20 minutes.
�? Keep warm (blanket); provide clean clothing.
�? Consult a physician in all cases.
Ingestion:
General recommendations:
�? Consult a physician immediately in all cases.
�? Take to a hospital immediately.
If the subject is completely conscious:
�? Rinse mouth with fresh water.
�? Give a 1% aqueous calcium gluconate solution to drink.
�? Do not induce vomiting.
�? If the subject presents nervous, respiratory or cardiovascular disorders:
administer oxygen.
If the subject is unconscious:
�? NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
�? Administer classical resuscitation measures.
4.2 Medical Treatment/Notes to Physician: See section 4.1.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 3/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

5. Fire-Fighting Measures
5.1 Flash point: Not applicable.
5.2 Auto-ignition Temperature: Not applicable.
5.3 Flammability Limits: Not applicable.
5.4 Unusual Fire and Explosion Hazards: None.
5.5 Extinguishing Methods:
Common: In case of fire in close proximity, all means of extinguishing are acceptable
(subject to section below).
Inappropriate extinguishing means: No restriction.
5.6 Fire Fighting Procedures:
Specific hazards:
�? Non-combustible/non-flammable, but may produce dangerous fumes if involved in fire.
�? Formation of dangerous gas/vapors in case of decomposition (see section 10).
�? Formation of flammable gas on contact with certain metals (see section 10).
Protective measures in case of intervention:
�? Evacuate all non-essential personnel.
�? Intervention only by capable personnel who are trained and aware of the hazards of
the product.
�? In all cases wear self-contained breathing apparatus.
�? When intervention in close proximity, wear full protective acid-resistant suit.
�? Protect intervention team with water spray when approaching the fire.
�? After intervention, take a shower, remove clothing carefully, clean and check equipment.
Other precautions:
�? If safe to do so, remove the exposed containers, or cool with large quantities of water.
�? Approach from upwind.
�? Disperse gas/vapors with water spray.
�? After the fire, proceed rapidly to clean the surfaces exposed to the fumes in order to limit
the damage to the equipment.
�? As for any fire, ventilate and clean the rooms before reentry.

6. Accidental Release Measures
6.1 Precautions:
�? Follow the protective measures given in section 8.
�? Keep away materials and products which are incompatible with the product
(see section 10).
�? Avoid dispersing the dust into a cloud.
6.2 Cleanup methods:
�? Collect the product with suitable means avoiding dust formation.
�? Place everything into a closed, labeled container compatible with the product.
�? For disposal methods, refer to section 13.
�? Clean the area with large quantities of water
6.3 Precautions for protection of the environment:
�? Immediately notify the appropriate authorities in case of significant discharge.
�? Prevent discharges into the environment (sewers, rivers, soils, etc.).

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 4/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

7. Handling and Storage
7.1 Handling:
�? Use only equipment and materials which are compatible with the product.
�? Keep away from reactive products (see section 10).
�? Avoid heating the product above the decomposition temperature (see section 9).
7.2 Storage:
�? Keep in original packaging, closed.
�? Store in a ventilated, cool, dry area.
�? Keep away from heat sources.
7.3 Specific Uses: See Section 1.2.
7.4 Other precautions:
�? Avoid dust and formation of dust clouds.
�? Follow the protective measures given in section 8.
�? Warn people about the dangers of the product.
7.5 Packaging:
�? Cardboard + PE.
�? Paper + PE.

8. Exposure Controls/Personal Protection
8.1 Exposure Limit Values:
Authorized limit Values TLV® ACGIH®-USA (2002) OSHA PEL
Fluorides 2.5 mg/m3 (as F) 2.5 mg Fluoride/m3 as 8 hr TWA
ACGIH® and TLV® are registered trademarks of the American Conference of Governmental Industrial Hygienists.

8.2 Exposure Controls:
�? Maintain employee exposures to levels below the applicable exposure limits.
�? Follow the protective measures given in section 7.
8.2.1 Occupational Exposure Controls:
8.2.1.1 Ventilation:
�? Provide local ventilation suitable for the product decomposition risk (see section 10).
�? Provide local ventilation suitable for the dust risk.
8.2.1.2 Respiratory protection:
�? Self-contained breathing apparatus in medium confinement/insufficient oxygen/in
case of large uncontrolled emissions/in all circumstances when the mask and
cartridge do not give adequate protection.
�? Use only respiratory protection that conforms to international/national standards.
8.2.1.3 Hand protection: Protective gloves - chemical-resistant: PVC, neoprene, rubber.
8.2.1.4 Eye protection: Dustproof goggles obligatory.
8.2.1.5 Skin protection:
�? Impervious overalls.
�? Apron/boots of PVC, neoprene, rubber in all case of dusts.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 5/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

8.3 Other precautions:
�? Do not smoke, eat, or drink in working area.
�? Remove contaminated clothing immediately after work.
�? Provide shower and eyewash stations.
�? Consult the industrial hygienist or the safety manager for the selection of personal
protective equipment suitable for the working conditions.
8.4 Other information: Respect local, state and federal regulations for aqueous emissions
(see section 15).

9. Physical and Chemical Properties
9.1 Appearance: Crystalline, hygroscopic powder.
Color: White.
Odor: Slightly pungent.
9.2 Important Health, Safety and Environmental information:
pH: 1 - Concentration: 7.8 g/l @ 20°C (68°F).
Change of state:
Melting point: 225°C (437°F).
Boiling point: Decomposition.
Decomposition Temperature: > 400°C (> 750°F).
Flash Point: Not applicable.
Flammability: Not applicable.
Explosive Properties: No data.
Oxidizing Properties: Not applicable.
Vapor pressure: Not applicable.
Relative Density:
Specific gravity (H2O=1): 2.37.
Solubility:
Water: 390 g/l @ 20°C (68°F). Dissolution with heat release.
Fat: No data.
Partition coefficient: Not applicable.
Viscosity: No data.
Vapor Density (air=1): Not applicable.
Evaporation Rate: Not applicable.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 6/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

10. Stability and Reactivity
Stability:
10.1 Conditions to avoid:
�? Heating the product to its decomposition temperature (see section 9).
�? Moisture.
10.2 Materials and substances to avoid:
�? Strong acids.
�? Strong bases.
�? Silicate-containing materials (glass, cement, etc.).
�? Metals.
10.3 Hazardous decomposition products:
�? Hydrogen fluoride.
�? Potassium hydroxide.
�? Potassium fluoride.
10.4 Hazardous Polymerization: Will not occur.
10.5 Other information:
�? Exothermic reaction when dissolved in water.
�? Corrosive action on some metals when moisture is present.
�? In presence of humidity, contact with metals releases hydrogen.

11. Toxicological Information
11.1 Acute toxicity:
Inhalation: No data.
Oral: LD50, 160 mg/kg, rat.
Dermal: No data.
Irritation: Corrosive.
Sensitization: No data.
Comments:
�? Toxic effect linked with corrosive properties.
�? Chronic exposure may entail dental or skeletal fluorosis.
�? The carcinogenic effect found in animals is not demonstrated in humans.
�? Risk of toxic effect on reproduction.
11.2 Chronic toxicity:
�? Oral route, after prolonged exposure, rat/mouse, Target organ: skeleton / thyroid / testes
/ kidney, liver, ca. 1 mg/kg, observed effect.
�? Ambiguous mutagenic effect.
�? Ambiguous carcinogenic effect.
�? Foetotoxic and fertility effects.
11.3 Carcinogenic Designation: None.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 7/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

12. Ecological Information
12.1 Acute ecotoxicity:
�? 10 mg KF•HF/l: pH = 3.9; 100 mg KF.HF/l: pH = 2.9.
�? 10 mg HF/l: pH = 3.15; 100 mg HF/l: pH = 2.65.
�? Fish, Poecilia reticulate, LC50, 96 h, from 65-80 mg/l.
�? Algae, Scenedesmus sp., LOEC, 110 mg/l.
�? Fish, Salmo gairdneri, LC50, 96 h, 51 mg/l (fluorides).
�? Crustaceans, Daphnia magna, EC50, 48 h, 97 mg/l; Conditions: fresh water (fluorides).
�? Crustaceans, Mysidopsis bahia, EC50, 96 h, 10.5 mg/l; Conditions: salt water (fluorides).
�? Algae, Scenedesmus sp., EC50, 96 h, 43 mg/l (fluorides).
12.2 Chronic ecotoxicity:
�? Fish, Salmo gairdneri, LC50, 21 days, from 2.7-4.7 mg/l (fluorides).
�? Crustaceans, Daphnia magna, NOEC, 21 days, 3.7 mg/l (fluorides).
12.3 Mobility:
�? Air - mobility as solid aerosols.
�? Water - considerable solubility and mobility.
�? Soil / sediments - adsorption on mineral soil constituents.
Conditions: slightly acid pH (Fluorides).
12.4 Degradation
Abiotic:
�? Air - neutralization by natural alkalinity.
�? Water / soil - ionization/neutralization.
�? Water / Soil - complexation/precipitation of inorganic materials.
Degradation products: aluminum / iron / calcium / phosphate complexes
and/or precipitates as a function of pH (fluorides).
Biotic: Not applicable (inorganic compound).
12.5 Potential for bioaccumulation:
�? Bioconcentration: log Po/w - not applicable (ionizable inorganic compound).
�? Result: accumulation into vegetable leafs (fluorides).
12.6 Other adverse effects /Comments:
�? Harmful for aquatic organisms.
�? Hazard for the aquatic environment is limited due to product properties: low
chronic toxicity.
�? Product is highly dependent on environmental conditions: pH, temperature,
oxidoreductive potential, mineral and organic content of the medium.

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 8/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

13. Disposal Considerations
13.1 Waste treatment: Consult current federal, state and local regulations regarding the proper
disposal of this material.
13.2 Packaging treatment:
�? Consult current federal, state and local regulations regarding the proper disposal of
emptied containers.
�? Rinse the empty containers with alkaline water and treat the effluent in the same way
as waste.
�? Dispose of the containers by dispatching them to an approved incineration facility for
hazardous waste.
13.3 RCRA Hazardous Waste: Listed as D002 (Corrosive).

14. Transport Information
Mode DOT IMDG IATA
UN Number 1811 1811 1811
Class (Subsidiary) 8 8 8
Proper Shipping Name Potassium Bifluoride, Solid Potassium Bifluoride, Solid Potassium Bifluoride, Solid
Hazard label (Subsidiary) 8 Corrosive Corrosive
Placard [Subsidiary] Corrosive 1811
Packing Group II II II
Reportable Quantity
MFAG
Emergency Info ERG: 154 EmS: 8-06 ERG Code: 8P

15. Regulatory Information
National Regulations (US)
TSCA Inventory 8(b): Yes.
SARA Title III Sec. 302/303 Extremely Hazardous Substances (40 CFR 355): No.
SARA Title III Sec. 311/312 (40 CFR 370):
Hazard Category: Acute and chronic health hazard.
Threshold planning quantity: 10,000 lbs.
SARA Title III Sec. 313 Toxic Chemical Emissions Reporting (40 CFR 372): No.
CERCLA Hazardous Substance (40 CFR Part 302):
Listed: No.
Unlisted Substance: Yes, Reportable Quantity 100 lbs.
Characteristic: D002 (Corrosive).

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 9/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

State Component Listing:
State Comment
CA Airborne Contaminants & Emissions Inventory
CA Hazardous Substance List
CT Hazardous Materials Survey
IL Toxic Substances Disclosure to Employees Act
IN Occupational Health & Safety Standards - Air
KY Occupational Health & Safety Standards - Air
MN Hazardous Substance List
NJ Right to Know Substances List
NC Exposure limits for Air Contaminants
PA Right to Know
RI Right to Know
National Regulations (Canada)
Canadian DSL Registration: DSL.
WHMIS Classification: D2B - Toxic Material.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations, and the
MSDS contains all the information required by the Controlled Products Regulations.

Labeling according to Directive 1999/45/EC.
Category ID Phrase
Symbols T Toxic.
C Corrosive.
Phrases R 25 Toxic if swallowed.
34 Causes burns.
Phrases S 22 Do not breathe dust.
26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
37 Wear suitable gloves.
45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 10/11
Potassium Bifluoride
Potassium Bifluoride
Material Safety Data Sheet

16. Other Information
16.1 Ratings:
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION)
Health = 03 Flammability = 0 Instability = 0 Special = None
HMIS (HAZARDOUS MATERIAL INFORMATION SYSTEM)
Health = 3 Fire = 0 Reactivity = 0 PPE = Supplied by User; dependent on local conditions
16.2 Other Information:
The previous information is based upon our current knowledge and experience of our product and
is not exhaustive. It applies to the product as defined by the specifications. In case of combinations
or mixtures, one must confirm that no new hazards are likely to exist. In any case, the user is not
exempt from observing all legal, administrative and regulatory procedures relating to the product,
personal hygiene, and integrity of the work environment. (Unless noted to the contrary, the technical
information applies only to pure product).
To our actual knowledge, the information contained herein is accurate as of the date of this
document. However, neither Solvay Fluorides, LLC nor any of its affiliates makes any warranty,
express or implied, or accepts any liability in connection with this information or its use. This
information is for use by technically skilled persons at their own discretion and risk and does
not relate to the use of this product in combination with any other substance or any other
process. This is not a license under any patent or other proprietary right. The user alone must
finally determine suitability of any information or material for any contemplated use, the
manner of use and whether any patents are infringed. This information gives typical properties
only and is not to be used for specification purposes.
Trademarks and/or other Solvay Fluorides, LLC products referenced herein are either trademarks
or registered trademarks of Solvay Fluorides, LLC or its affiliates, unless otherwise indicated.
16.3 Reason for revision:
Supersedes edition: None
Purpose of revision: Original

MSDS No. KBF-1103 Revised 11-14-03
Copyright 2003, Solvay Fluorides, LLC
A subsidiary of Solvay Chemicals, Inc.
All Rights Reserved.
www.solvaychemicals.us 1.800.765.8292
Page 11/11

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