MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product name
Baytan庐 T Dry Seed Dressing
Other names Baytan T DS154
Product codes and Not available (10 kg)
pack sizes
Chemical group Triazole + benzoylurea
Recommended use Fungicide plus insecticide for agricultural use 鈥? seed treatment
Formulation Powder for dry seed treatment (DS)
Supplier Bayer CropScience Pty Ltd ABN 87 000 226 022
Address 391 - 393 Tooronga Road, East Hawthorn
Victoria 3123, Australia
Telephone (03) 9248 6888
Facsimile (03) 9248 6800
Website www.bayercropscience.com.au
Contact Development Manager (03) 9248 6888
Emergency Telephone
Number 1800 033 111 鈥? Orica SH&E Shared Services
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
NON-HAZARDOUS SUBSTANCE 鈥? NON-DANGEROUS GOOD
Harmful to aquatic organisms
Hazard classification Not Hazardous (National Occupational Health and Safety Commission - NOHSC)
Risk phrases None assigned
Safety phrases See Sections 4, 5, 6, 7, 8, 10, 12, 13
ADG classification Not a 鈥淒angerous good鈥? for transport by road or rail according to the Australian Code for
the Transport of Dangerous Goods by Road and Rail.
SUSDP classification 5 (Standard for the Uniform Scheduling of Drugs and Poisons)
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients CAS Number Concentration (g/kg)
Triadimenol [55219-65-3] 150
Triflumuron [64628-44-0] 4
Talc [14807-96-6] 511
Other ingredients, including emulsifiers, dispersing (non hazardous) 335
agents, dye and carriers
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MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
4. FIRST AID MEASURES
If poisoning occurs, immediately contact a doctor or Poisons Information Centre (telephone 13 11 26), and
follow the advice given. Show this Material Safety Data Sheet to the doctor.
Inhalation If inhaled remove to fresh air and keep at rest. Obtain medical advice.
Skin contact Carefully remove contaminated clothing. Wash affected areas with soap and water.
Seek medical aid if at all worried.
Eye contact Rinse eyes immediately with clean water for at least 15 minutes and obtain medical aid.
Ingestion Wash out mouth with water. Do NOT induce vomiting. Keep patient at rest and seek
medical advice as above.
First Aid Facilities Ensure eyewash and shower facilities are available.
Medical attention Triadimenol is a triazole compound. Symptoms of poisoning have not been recorded.
Local contamination:
In case of skin or eye contamination, treat as above under First Aid Measures.
Systemic poisoning:
There is no specific antidote. Treat symptoms. An aqueous suspension of activated
charcoal may be administered to absorb remaining toxicant.
5. FIRE FIGHTING MEASURES
Extinguishing media Water spray, foam, dry chemical, carbon dioxide, sand
Hazards from In a fire, formation of hydrogen chloride, hydrogen cyanide, hydrogen fluoride, carbon
combustion products monoxide and nitrogen oxides can be expected.
Precautions for fire Fire fighters should wear full protective gear, including self-contained breathing
fighters apparatus (AS/NZS 1715/1716). Keep unnecessary people away. If it can be done
safely, remove intact containers from the fire. Bund area with sand or earth to prevent
contamination of drains or waterways. Dispose of extinguishing agent and spillage safely
later.
Hazchem code Not applicable
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled material or contaminated surfaces. Do not smoke, eat or drink during the clean up
process. Wear personal protective clothing and equipment as detailed in Section 8 PERSONAL PROTECTION.
Keep people and animals away. Prevent spilled material from entering drains or watercourses. Avoid creation of
dust, damping down if necessary. Sweep up and collect and store in properly labelled drums for safe disposal.
Clean floor with a damp cloth and place it in the drum. Seal drums and label ready for safe disposal. Deal with all
spillages immediately. If contamination of drains, streams, watercourses etc. is unavoidable, warn the local water
authority.
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MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
7. HANDLING AND STORAGE
Handling Keep out of reach of children. Avoid contact with eyes and skin. Do not inhale dust from
product, grain or treated seed. Wash hands after use. Do not allow seed treated with
this product to contaminate seed intended for human or animal consumption. Bags
which have held treated seed are not to be used for any other purpose.
Storage Store product in the closed original container in a dry, cool, well-ventilated area out of
direct sunlight. When treated seed is stored it should be kept apart from other grain and
the bags or other containers should be clearly marked to indicate the contents have been
treated with this product.
Flammability Not flammable, but fine dust particles can form explosive mixtures with air.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure standards The NOHSC exposure standard (TWA) for talc is: 2.5 mg/m鲁
Exposure standard 鈥? Time Weighted Average (TWA) means the average airborne
concentration of a particular substance when calculated over a normal eight-hour working
day, for a five-day working week.
Biological limit values None allocated
Engineering controls Control process conditions to avoid contact. Use in a well-ventilated area only.
Personal Protective Eyes: Safety goggles if exposure is possible
Equipment Clothing: Cotton overalls buttoned to the neck and wrist and a washable hat
Gloves: Elbow-length PVC gloves
Respiratory: Wear a disposable dust mask.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue powder
Odour: Weak characteristic
pH: 7.5 to 9.0 (10% in water)
Vapour pressure: Not available
Vapour density: Not available
Boiling point: Not applicable
Freezing/melting
point: Not available
Solubility: Practically insoluble in water
Bulk density: 210 / 130 mL/100 g (loose / packed)
Flash Point: Not applicable
Flammability
(explosive) limits: Not applicable
Auto-ignition
temperature: Not available
Partition coefficient
(octanol/water): Triadimenol: Log Pow = 3.08 to 3.28 at 25掳 C
Triflumuron: Log Pow = 4.9 at 22掳 C
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MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
10. STABILITY AND REACTIVITY
Chemical stability Stable under normal conditions of use.
Conditions to avoid Excessive heat, creation of dust
Incompatible materials Oxidising agents, alkaline materials.
Hazardous In a fire, formation of hydrogen chloride, hydrogen cyanide, hydrogen fluoride, carbon
decomposition monoxide and nitrogen oxides can be expected.
products
Hazardous reactions None
11. TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
Inhalation Harmful if inhaled. May cause respiratory irritation if inhaled.
Skin contact May irritate the skin.
Eye contact May irritate the eyes.
Ingestion Harmful if swallowed.
ANIMAL TOXICITY DATA
Acute:
Oral toxicity LD50 rat: 689 mg/kg 鈥? (triadimenol)
LD50 rat: > 5000 mg/kg 鈥? (triflumuron)
Dermal toxicity LD50 rat: > 5000 mg/kg 鈥? (triadimenol)
LD50 rat: > 5000 mg/kg 鈥? (triflumuron)
Inhalation toxicity LC50 rat (4 hour): > 954 mg/L 鈥? (triadimenol)- highest attainable concentration
LC50 rat (4 hour): > 1.55 mg/L (dust) 鈥? (triflumuron)- highest attainable concentration
Skin irritation Non irritating (rabbit) 鈥? (triadimenol)
Non irritating (rabbit) 鈥? (triflumuron)
Eye irritation Non irritating (rabbit) 鈥? (triadimenol)
Non irritating (rabbit) 鈥? (triflumuron)
Sensitisation Not a skin sensitiser (guinea pig) (triadimenol)
Not a skin sensitiser (guinea pig) (triflumuron)
Chronic:
Animal studies with triadimenol showed no evidence of oncogenic effects, no evidence of carcinogenic effects
and no teratogenic potential. Triadimenol was not mutagenic.
Triflumuron had no mutagenic activity in various in vitro and in vivo tests.
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MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
12. ECOLOGICAL INFORMATION
Triadimenol is harmful to aquatic organisms. It has a low toxicity to birds, bees and earthworms.
Triflumuron is very toxic to aquatic organisms, but it is present at a low concentration in this product. Triflumuron is
toxic to bees, but used as a seed treatment according to label directions should not put hives at risk.
Baytan T Dry Seed Dressing is harmful to fish and aquatic arthropods. DO NOT feed treated seed or otherwise
expose to wildlife or domestic birds. DO NOT contaminate streams, rivers, or waterways with the chemical, used
containers, treated seed or bags which have held treated seed.
Ecotoxicity Triadimenol:
Fish toxicity: LC50 (96 h) bluegill sunfish (Lepomis macrochirus) 15 mg/L
LC50 (96 h) rainbow trout (Onchorhynchus mykiss) 21.3 mg/L
Daphnia toxicity: EC50 (48 h) water flea (Daphnia magna) 51 mg/L
Algal toxicity:
Growth rate: EC50 (72 h) green algae (Pseudokirchneriella subcapitata) 38 mg/L
Bird toxicity:
Acute oral LD50 bobwhite quail > 2000 mg/kg
Bacteria toxicity: EC50 activated sludge > 10000 mg/L
Triflumuron:
Fish toxicity: LC50 (96 h) bluegill sunfish (Lepomis macrochirus) > 20.8 碌g/L
LC50 (96 h) rainbow trout (Onchorhynchus mykiss) > 24.2 碌g/L
Daphnia toxicity: EC50 (48 h) water flea (Daphnia magna) 1.6 碌g/L
Algal toxicity:
Growth rate: IC50 (72 h) green algae (Desmodesmus subspicatus) > 0.025 mg/L
Bird toxicity:
Acute oral LD50 bobwhite quail 561 mg/kg
Bacteria toxicity: EC50 activated sludge > 10000 mg/L
Environmental fate, Triadimenol is inherently biodegradable 鈮? 70% in 28 days.
persistence and Bioconcentration factor (BCF): 21
degradability, mobility DT50 in sandy loam is 110 to 375 days; in loam 240 to 270 days.
Triflumuron degrades fairly rapidly in soil.
Triflumuron bioconcentration factor (BCF): 612
13. DISPOSAL CONSIDERATIONS
Single rinse containers before disposal. Add rinsings to disposal pit. Do not dispose of undiluted chemicals on-
site. Puncture and bury empty containers in a local authority landfill. If not available, bury containers below 500
mm in a disposal pit specifically marked and set up for this purpose clear of waterways, vegetation and roots.
Empty containers and product should not be burnt. Dispose of waste product through a reputable waste contractor.
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MATERIAL SAFETY DATA SHEET
Date of Issue: August 2, 2004
14. TRANSPORT INFORMATION
UN number Not applicable
Proper shipping Not applicable
name
Class and Subsidiary Not applicable
Risk
Packing Group Not applicable
EPG Not applicable
Hazchem code Not applicable
Marine Pollutant No (Baytan T Dry Seed Dressing contains 0.4% triflumuron. Triflumuron is classified as a
Marine Pollutant 鈥淧鈥? in Europe, but it is not on the IMDG list.)
15. REGULATORY INFORMATION
Registered according to the Agricultural and Veterinary Chemicals Act 1988
Australian Pesticides and Veterinary Medicines Authority approval number: 40405 See also Section 2.
16. OTHER INFORMATION
Trademark Baytan庐 is a Registered Trademark of Bayer.
information
Preparation Replaces August 1, 2002 MSDS.
information Reasons for revision: 16 heading format, First Aid, Exposure standard for talc, Toxicity
data, Ecological information
This MSDS summarises our best knowledge of the health and safety hazard information of the product and how to
safely handle and use the product in the workplace. Each user should read this MSDS and consider the information
in the context of how the product will be handled and used in the workplace including in conjunction with other
products.
If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user
should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our
customers and is also available on request.
END OF MSDS
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