13521-B4 ACTIVE INGREDIENT
Oxyfluorfen
2-chloro-1-(3-ethoxy-4-nitrophenoxy)-
4-(trifluoromethyl) benzene ...............................19.4%*
INERT INGREDIENTS ........................................80.6%
TOTAL 100.0%
*Equivalent to 1.6 lbs. active ingredient per gallon.
EPA Reg. No. 707-174
T/O
DIRECTIONS FOR USE
ORNAMENTAL HERBICIDE
It is a violation of Federal law to use this product in a manner inconsistent with
its labeling.
USE DIRECTIONS FOR:
Do not apply this product in a way that will contact workers or other persons,
鈥? CONIFER either directly or through drift. Only protected handlers may be in the area during
application.
For any requirements specific to your State or Tribe, consult the agency
Before using this product, read the entire Precautionary Statements, responsible for pesticide regulation.
Conditions of Sale and Warranty, Directions for Use, Use Restrictions and
Storage and Disposal Instructions. If the Conditions of Sale and Warranty are
not acceptable, return the product unopened within thirty days of purchase AGRICULTURAL USE REQUIREMENTS
to the place of purchase. Use this product only in accordance with its labeling and with the Worker
Protection Standard, 40 CFR part 170. This Standard contains
requirements for the protection of agricultural workers on farms, forests,
KEEP OUT OF REACH OF CHILDREN nurseries, and greenhouses, and handlers of agricultural pesticides. It
contains requirements for training, decontamination, notification, and
WARNING busque a alguien para que se la explique a
AVISO emergency assistance. It also contains specific instructions and
exceptions pertaining to the statements on this label about personal
Si usted no entiende la etiqueta,
protective equipment (PPE) and restricted-entry interval. The
usted en detalle. (If you do not understand the label, find someone to explain it to
requirements in this box only apply to uses of this product that are covered
you in detail.)
by the Worker Protection Standard.
STATEMENT OF PRACTICAL TREATMENT Do not enter or allow worker entry into treated areas during the restricted-
IF IN EYES: Flush eyes with a large amount of water for at least 15 minutes. entry interval (REI) of 24 hours.
Get prompt medical attention. IF ON SKIN: Wash thoroughly with plenty of soap PPE required for early entry to treated areas that is permitted under the
and water. If irritation develops, get medical attention. IF SWALLOWED: Do not Worker Protection Standard and that involves contact with anything that
induce vomiting. Dilute by giving 2 glasses of water to drink. Call a physician. Do has been treated, such as plants, soil or water, is:
not induce vomiting or give anything by mouth to an unconscious person. 鈥? Coveralls over short-sleeved shirt and short pants
IF INHALED: Move victim to fresh air. NOTE TO PHYSICIAN: Contains 鈥? Chemical-resistant gloves, such as Barrier Laminate or Viton
petroleum distillates. Aspiration hazard may contraindicate the use of gastric 鈥? Chemical-resistant footwear plus socks
lavage. 鈥? Protective eyewear
PRECAUTIONARY STATEMENTS 鈥? Chemical-resistant headgear for overhead exposure
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
WARNING
NON-AGRICULTURAL USE REQUIREMENTS
Causes substantial but temporary eye injury and skin irritation. Do not get in
The requirements in this box apply to uses of this product that are not
eyes, on skin, or on clothing. This material may be harmful if swallowed.
within the scope of the Worker Protection Standard for agricultural
PERSONAL PROTECTIVE EQUIPMENT (PPE)
pesticides (40 CFR Part 170). The WPS applies when this product is used
Some materials that are chemical-resistant to this product are listed below. If you
to produce agricultural plants on farms, forests, nurseries or greenhouses.
want more options, follow the instructions for category G on an EPA chemical
鈥? Keep unprotected persons out of treated area until sprays have dried.
resistance category selection chart.
Applicators and other handlers must wear:
鈥? Coveralls over short-sleeved shirt and short pants
鈥? Chemical-resistant gloves, such as Barrier Laminate or Viton
CONDITIONS OF SALE AND WARRANTY
鈥? Chemical-resistant footwear plus socks
Rohm and Haas warrants that the product conforms to its chemical description and
鈥? Protective eyewear
is reasonably fit for the purpose stated on the label only when used in accordance
鈥? Chemical-resistant headgear for overhead exposure
with label directions under normal conditions of use. ROHM AND HAAS MAKES NO
鈥? Chemical-resistant apron when cleaning equipment, mixing, or loading
OTHER EXPRESS OR IMPLIED WARRANTIES EITHER OF MERCHANTABILITY OR
Discard clothing and other absorbent materials that have been drenched or FITNESS FOR A PARTICULAR USE. Handling, storage and use of the product by
heavily contaminated with this product's concentrate. Do not reuse them. Follow Buyer or User are beyond the control of Rohm and Haas and Seller. Risks such as crop
manufacturer's instructions for cleaning/maintaining PPE. If no such instructions injury, ineffectiveness or other unintended consequences resulting from, but not limited
for washables, use detergent and hot water. Keep and wash PPE separately from to, weather or soil conditions, presence of other materials, disease, pests, drift to other
other laundry. crops or property or failure to follow label directions will be assumed by the Buyer or
User. IN NO CASE WILL ROHM AND HAAS OR SELLER BE HELD LIABLE FOR
When handlers use closed systems, enclosed cabs, or aircraft in a manner that
CONSEQUENTIAL, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE
meets the requirements listed in the Worker Protection Standards (WPS) for
HANDLING, STORAGE OR USE OF THIS PRODUCT.
agricultural pesticides [40 CFR 170.240(d) (4-6)], the handler PPE requirements
may be reduced or modified as specified in the WPS.
CHEMIGATION
USER SAFETY RECOMMENDATIONS Do not apply this product through any type of irrigation system.
Users should:
GENERAL USE INFORMATION
鈥? Wash hands before eating, drinking, chewing gum, using tobacco or using
Unless otherwise directed by registered supplemental labeling, follow the
the toilet.
Directions for Use in each crop group section.
鈥? Remove clothing immediately if pesticide gets inside. Then wash
thoroughly and put on clean clothing.
CULTURAL CONSIDERATIONS
In order for GOAL T/O herbicide to provide maximum preemergence activity:
ENVIRONMENTAL HAZARDS Prior to application, the bed or soil surface should be smooth and free of crop
and weed trash (decaying leaves, clippings, dead weeds, etc.). Leaves and trash
Do not apply directly to water, to areas where surface water is present or to
may be removed by blowing the area to be treated or by thoroughly mixing the
intertidal areas below the mean high water mark. Do not contaminate water by
trash into the soil through cultivation prior to herbicide application.
cleaning of equipment or disposal of equipment washwaters.
After application, at least one-quarter inch (1/4 inch) of irrigation or rainfall should
This product is highly toxic to aquatic invertebrates, aquatic plants, wildlife and
occur within 3 or 4 weeks after application. The best results from GOAL T/O
fish. Use with care when applying in areas frequented by wildlife or adjacent to
herbicide are from applications to established beds or soil surfaces that are left
any body of water or wetland area. Do not apply when weather conditions favor
undisturbed during the time period for which weed control is desired. Cultural
drift or erosion from target areas.
practices that result in redistribution or disturbance of the soil surface after
PHYSICAL OR CHEMICAL HAZARDS treatment will decrease the herbicidal effectiveness of GOAL T/O herbicide.
Combustible. Cutting water furrows or cultivations that mix untreated soil into treated areas will
also reduce the effectiveness of the treatment.
Do not use or store near heat or open flame.
1
Calandrinia caulescens
MIXING DIRECTIONS REDMAIDS
Sisymbrium irio
ROCKET, LONDON
Fill the spray tank at least one-third full of clean water. With the pump and
agitator running, add the recommended amount of herbicides to the spray tank. Spergularia rubra
SANDSPURRY, RED
The order of addition to the spray tank should be wettable powders first, Capsella bursa-pastoris
*SHEPHERDSPURSE
flowables second and liquids last. Complete filling of the spray tank with water. Sida spinosa
SIDA, PRICKLY
Polygonum pensylvanicum
SMARTWEED, PENNSYLVANIA
For all applications of GOAL T/O herbicide where postemergence weed control
is desired, add 2 to 4 pints of an 80% active nonionic surfactant cleared for Rumex acetosella
SORREL, RED (FROM SEED)
application to growing crops per each 100 gallons of spray. The addition of 4 Sonchus oleraceus
SOWTHISTLE, ANNUAL
pints of an 80% active nonionic surfactant per 100 gallons of spray is Veronica persica
SPEEDWELL, BIRDSEYE
recommended to enhance postemergence activity when hard water (greater than Euphorbia supina
**SPURGE, PROSTRATE
600 ppm) is used as the carrier. Maintain agitation until spraying is completed. Euphorbia maculata
**SPURGE, SPOTTED
Spray equipment should be calibrated carefully before each use. Spergula arvensis
SPURRY, CORN
Descurainia pinnata
TANSYMUSTARD
Dosages listed on this label are for broadcast application. For banded applica-
Cirsium vulgare
**THISTLE, BULL
tion, the amount of T/O herbicide used per acre should be reduced
according to the following formula: Salsola kali
THISTLE, RUSSIAN
Abutilon theophrasti
VELVETLEAF
Band Width (in inches) Rate per Amount Needed per Acre Panicum capillare
WITCHGRASS
X =
Oxalis stricta
**WOODSORREL, YELLOW
Row Width (in inches) Broadcast Acre for Banded Application
*Highest rate and/or multiple applications may be required for acceptable control.
CONIFER SEEDBEDS, TRANSPLANTS **Preemergence control only.
AND CONTAINER STOCK GOAL T/O herbicide is most effective when applied preemergence to annual
GENERAL INFORMATION grasses. Postemergence applications should be made to seedling grasses not
exceeding the 2-leaf stage. The addition of 0.25% (2 pints/100 gallons of spray
GOAL T/O herbicide is effective as a preemergence and/or postemergence
herbicide for the control of certain annual grassy and broadleaf weeds in conifer solution) of an 80% active nonionic surfactant, cleared for application on growing
seedbeds, transplant and container stock. The most effective postemergence crops, enhances the GOAL T/O herbicide activity on emerged weeds.
weed control is achieved when GOAL T/O herbicide is applied to seedling weeds
CONIFER SEEDBEDS
less than 4 inches in height. Preemergence control is most effective when spray
is applied to clean, weed-free soil surfaces. Treated soil surfaces should not be To assist in the establishment of conifer seedbeds, a preemergence application
disturbed as the herbicidal effectiveness of GOAL T/O herbicide may be should be made after seeding but prior to conifer emergence. Postemergence
decreased. Seedling weeds are controlled during emergence as they come in applications should not be made until a minimum of 5 weeks after emergence
contact with the soil-applied herbicide. of the conifer seedlings. Additional care should be taken if cool, cloudy weather
occurs during emergence to make certain that seedlings have hardened off prior
IMPORTANT: Some varieties or cultivars of conifers and ornamental species
to spraying.
listed may be susceptible to GOAL T/O herbicide. Care should be taken to
ensure that the particular variety to be sprayed with GOAL T/O herbicide is Conifers are tolerant to preemergence and postemergence applications of GOAL
tolerant. It is suggested that unfamiliar species be tested in limited areas prior to T/O herbicide. Applied postemergence, GOAL T/O herbicide will provide both
application for preemergence and postemergence weed control.
postemergence and residual preemergence control of many broadleaf weeds
and annual grass species.
WEEDS CONTROLLED
When GOAL T/O herbicide is applied preemergence or postemergence at CONIFER SPECIES
recommended dosages and weed stages, the following grasses and broadleaf GOAL T/O herbicide may be applied to conifer seedbeds of numerous species
weeds are controlled. including the following:
Echinochloa crus-galli
*BARNYARDGRASS Pseudotsuga menziesii
DOUGLAS FIR
Galium aparine
BEDSTRAW, CATCHWEED
FIR
Cardamine oligosperma
BITTERCRESS, LESSER
Abies fraseri
FRASER
Poa annua
*BLUEGRASS, ANNUAL
Abies grandis
GRAND
Polygonum convolvulus
BUCKWHEAT, WILD
Abies procera
NOBLE
Medicago, hipida
BURCLOVER
HEMLOCK
Mollugo verticillata
CARPETWEED
Tsuga canadensis
EASTERN HEMLOCK
Trifolium pratense
*CLOVER, RED
Trifolium repens
*CLOVER, WHITE PINE
Pinus nigra
Xanthium pensylvanicum AUSTRIAN
COCKLEBUR, COMMON
Pinus strobus
EASTERN WHITE
Digitaria sanguinalis
*CRABGRASS, LARGE
Pinus wallichiana
HIMALAYAN
Amsinckia intermedia
*FIDDLENECK, COAST
Pinus banksiana
JACK
Erodium botrys
FILAREE, BROADLEAF
Pinus taeda
LOBLOLLY
Erodium cicutarium
FILAREE, REDSTEM
Pinus contorta
LODGEPOLE
Epilobium angustifolium
FIREWEED (FROM SEED)
Pinus palustris
LONGLEAF
Descurainia sophia
FLIXWEED
Pinus radiata
MONTEREY
Setaria faberi
*FOXTAIL, GIANT
Pinus mugo
MUGHO
Eleusine indica
*GOOSEGRASS Pinus ponderosa
PONDEROSA
GROUNDCHERRY, CUTLEAF Physalis angulata Pinus sylvestris
SCOTCH
Physalis wrightii
GROUNDCHERRY, WRIGHT Pinus echinata
SHORTLEAF
Senecio vulgaris
GROUNDSEL, COMMON Pinus elliottii
SLASH
Lamium amplexicaule
HENBIT Pinus virginiana
VIRGINIA
Datura stramonium
JIMSONWEED
SPRUCE
Polygonum aviculare
KNOTWEED, PROSTRATE Picea pungens
BLUE
Polygonum persicaria
LADYSTHUMB Picea glauca conica
DWARF ALBERTA
Chenopodium album
LAMBSQUARTERS, COMMON Picea abies
NORWAY
Lactuca serriola
LETTUCE, PRICKLY Picea sitchensis
SITKA
Malva parviflora
MALLOW, LITTLE
PREEMERGENCE DOSAGE
Anthemis cotula
MAYWEED
Montia perfoliata Apply 1.25 to 5 pints (0.25 to 1.0 lb. active) of GOAL T/O herbicide per
MINERSLETTUCE
broadcast acre as a preemergence application. Where grassy weeds are
Ipomoea species
*MORNINGGLORY, IVYLEAF
present, a minimum rate of 2.5 pints (0.5 lbs. active) of GOAL T/O herbicide per
Ipomoea purpurea
MORNINGGLORY, TALL
broadcast acre is suggested. In known areas of high weed competition, 5 pints
Chorispora tenella
MUSTARD, BLUE
(1.0 lb. active) of GOAL T/O herbicide per broadcast acre are recommended.
Sisymbrium altissimum
MUSTARD, TUMBLE
Brassica kaber
MUSTARD, WILD
TIMING AND METHOD OF APPLICATION
Urtica urens
NETTLE, BURNING
Apply recommended dosage after seeding but prior to conifer emergence.
Solanum nigrum
NIGHTSHADE, BLACK
GOAL T/O herbicide should be thoroughly mixed with clean water at
Solanum sarachoides
NIGHTSHADE, HAIRY recommended concentration and applied at 20 to 40 psi in a minimum of 20
Avena fatua
OATS, WILD gallons of water per treated acre. Broadcast to beds and irrigate prior to weed
Atriplex rosea
ORACH, RED emergence with 1/2 to 3/4 inch of sprinkler irrigation.
Lepidium perfoliatum
PEPPERWEED, YELLOWFLOWER
Amaranthus blitoides
PIGWEED, PROSTRATE POSTEMERGENCE DOSAGE
Amaranthus retroflexus
PIGWEED, REDROOT Apply 1.25 to 2.5 pints (0.25 to 0.5 lbs. active) of GOAL T/O herbicide per
Anagallis arvensis broadcast acre with each postemergence application. Two or three
PIMPERNEL, SCARLET
postemergence applications may be necessary for season-long weed control.
Portulaca oleracea
PURSLANE, COMMON
2
TIMING AND METHOD OF APPLICATION See GOAL T/O herbicide label for minimum recommended rates of GOAL T/O
herbicide and see Vantage label for minimum recommended rates of Vantage.
Apply recommended dosage to seedbeds no sooner than 5 weeks after
Two or three applications may be needed for season-long control. In some
emergence of conifer seedlings. Additional care should be taken if cool, cloudy
cases, reduced grass control with Vantage may be experienced when tank mixed
weather occurs during emergence to make certain that seedlings have hardened
with GOAL T/O herbicide.
off prior to spraying. Application should be made to seedling weeds (less than 4
inches in height). GOAL T/O herbicide should be thoroughly mixed with clean
water at recommended concentration and applied as a broadcast application at TIMING
20 to 40 psi in a minimum of 20 gallons of water per treated acre. Applications should be made when weeds are actively growing but before
conifer bud break or after conifer foliage has had an opportunity to harden off.
Broadleaf weeds must be within the height limitations indicated on the GOAL
CONIFER TRANSPLANTS AND CONTAINER STOCK
T/O herbicide label.
(INCLUDES 2-0 SEEDLING AND CHRISTMAS TREE
PLANTINGS)
METHOD OF APPLICATION
Many container-grown conifers and conifer transplants are tolerant to
Fill the spray tank at least one-third full of clean water and add the recommended
preemergence and postemergence applications of GOAL T/O herbicide. Applied
amounts of GOAL T/O herbicide and Vantage while the pump and agitator are
postemergence, GOAL T/O herbicide will provide both postemergence and
running. Complete filling of the spray tank with water. Apply at 20 to 40 psi in
preemergence control of many broadleaf weeds and grasses. Postemergence
a minimum of 20 gallons of water per treated acre. Heavy rainfall immediately
applications should be applied before bud break or after foliage has had an
following application to emerged weeds may reduce effectiveness.
opportunity to harden off. Conifers may be transplanted from seedbeds and
sprayed directly providing bud break has not occurred. IMPORTANT: When tank mixing, always read all individual manufacturers'
labels. In interpreting all labels for the tank mixture, the most restrictive
The following conifer species, in addition to species listed under the CONIFER
situations must apply.
SEEDBED section, have been shown to be tolerant to GOAL T/O herbicide.
CONIFER 鈥? SPECIFIC USE RESTRICTIONS
ARBORVITAE RED CEDAR
鈥? Read and observe all label directions before using. When tank mixing, always
Thuja occidentalis Juniperus virginiana
read all individual manufacturers' labels. In interpreting all labels for the tank
Thuja orientalis
mixture, the most restrictive situations must apply.
JUNIPER WESTERN HEMLOCK
鈥? NOT FOR CONIFER RELEASE IN FOREST MANAGEMENT PROGRAMS OR FOR
Juniperus chinensis Tsuga heterophylla
FOREST REGENERATION APPLICATIONS.
Juniperus horizontalis
Juniperus procumbens YEW 鈥? Do not apply GOAL T/O herbicide in an enclosed greenhouse structure as injury
Juniperus sabina Taxus species to plant foliage may result.
Juniperus scopulorum 鈥? Do not store or transport treated container stock in an enclosed structure until
completion of 4 irrigations (minimum 21 days) as injury to non-labeled plants
DOSAGE may occur.
For preemergence or postemergence weed control apply 5 to 10 pints (1.0 to
鈥? Always apply GOAL T/O herbicide only to healthy conifer stock. Do not apply
2.0 lbs. active) of GOAL T/O herbicide per broadcast acre.
GOAL T/O herbicide to conifers that are under stress from excessive fertilizer
or soil salts, disease, nematodes, frost, drought, flooding, previously applied
TIMING AND METHOD OF APPLICATION
pesticides, soil insects, or winter injury, as severe injury may result.
For optimum weed control, preemergence applications should be made imme-
diately after transplanting seedlings or to weed-free container stock. Postemer-
GENERAL USE RESTRICTIONS
gence applications should be made to weeds less than 4 inches in height. Two
鈥? Do not contaminate irrigation water or water used for domestic purposes.
applications may be necessary, in fall-transplanted conifer fields, for season-
鈥? Do not use any plants treated with GOAL T/O herbicide for feed or forage.
long weed control. The addition of 0.25% (2 pints/100 gals. of spray solution) of
an 80% active nonionic surfactant, cleared for application to growing crops, 鈥? Do not feed or allow animals to graze on any areas treated with GOAL T/O
enhances GOAL T/O herbicide activity on emerged weeds. GOAL T/O herbicide herbicide.
must be applied only to conifer transplants prior to bud break or after foliage has
鈥? GOAL T/O herbicide should be applied only by ground application equipment
had an opportunity to harden off. Thoroughly mix with clean water at
except as specifically directed on this label or on other approved Rohm and
recommended concentration and apply at 20 to 40 psi in a minimum of 20 gallons
Haas Company Supplemental Labeling.
of water per treated acre. Spray over the top of transplants. Heavy rainfall
鈥? Do not apply when weather conditions favor drift. Avoid drift to all non-target
immediately following application to emerged weeds may reduce effectiveness.
areas. GOAL T/O herbicide is phytotoxic to plant foliage.
VANTAGE庐 HERBICIDE TANK MIX IN CONIFER 鈥? Thoroughly flush spray equipment (tank, pump, hoses and boom) with clean
water before and after each use. Residual GOAL T/O herbicide remaining in
PLANTATIONS
spray equipment may damage other crops. To assist removal of GOAL T/O
FOR USE ONLY IN THE STATES OF ALABAMA, GEORGIA, herbicide residues in spray equipment, an 80% active nonionic surfactant may
KENTUCKY, NORTH CAROLINA, SOUTH CAROLINA, be added at the rate of 1 quart per 100 gallons of water during flushing.
TENNESSEE, VIRGINIA AND WEST VIRGINIA 鈥? Use GOAL T/O herbicide only for recommended purposes and at
recommended rates.
GENERAL INFORMATION
鈥? Do not treat ditch banks or waterways with GOAL T/O herbicide.
GOAL T/O is effective as a preemergence and/or postemergence herbicide for
the control of certain annual grassy and broadleaf weeds in conifer plantations.
鈥? CHEMIGATION: Do not apply this product through any type of irrigation
The tank mix of GOAL T/O herbicide with Vantage will provide additional control
system.
of certain annual and perennial grass weeds (see Vantage label for weeds).
鈥? ROTATION CROP RESTRICTIONS
The following plants are tolerant to a tank mix of GOAL T/O herbicide plus
Vantage: Do not rotate to small-grain crops (includes barley, buckwheat, corn, proso
millet, pearl millet, oats, popcorn, rice, rye, sorghum, triticale, wheat, wild rice)
COMMON NAME SCIENTIFIC NAME within 10 months following a GOAL treatment.
Abies fraseri
FIR, FRASER Do not direct-seed any crops, other than GOAL-labeled crops, within 60 days
Tsuga canadensis
*HEMLOCK, CANADA
following a GOAL treatment.
Pinus virginiana
PINE, VIRGINIA
Pinus strobus
PINE, WHITE Do not transplant seedling crops, other than GOAL-labeled crops, within 30 days
Picea abies
SPRUCE, NORWAY following a GOAL treatment. IMPORTANT: TREATED SOIL MUST BE
THOROUGHLY INCORPORATED TO A DEPTH OF 4 INCHES AFTER HARVEST (OR
*Canada Hemlock has a prolonged period of bud break and new growth, thus,
ABANDONING) OF THE TREATED CROP BUT PRIOR TO PLANTING OF THE
directed applications are recommended during this period.
ROTATIONAL CROP. FAILURE TO ACHIEVE THIS THOROUGH AND COMPLETE
Broadleaf weeds controlled: See GOAL T/O herbicide label. INCORPORATION OR TO FOLLOW THE REQUIRED MINIMUM PLANT-BACK
Grasses controlled: See Vantage herbicide label. INTERVAL MAY RESULT IN CROP INJURY, STAND REDUCTION AND/OR VIGOR
REDUCTION OF THE PLANT-BACK CROP.
GOAL T/O herbicide and Vantage rates: A maximum of 10 pints per acre per
season of GOAL T/O herbicide may be tank mixed with Vantage. A maximum of
2.5 pints of Vantage may be tank mixed with GOAL T/O herbicide.
3
SUPPLEMENTAL LABELING INFORMATION
FOR DISTRIBUTION AND USE ONLY WITHIN CALIFORNIA
WEED CONTROL FOR NON-CROP USE IN THE STATE OF CALIFORNIA
GOAL庐 T/O HERBICIDE EPA SLN NO. CA-830065
DIRECTIONS FOR USE
It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
NOTICE: Before using this product, read the entire Precautionary Statements, Conditions of Sale and Warranty, Directions for Use, Use Precautions and Storage and Disposal
Instructions. If the Conditions of Sale and Warranty are not acceptable, return the product unopened within thirty days of purchase to the place of purchase.
GENERAL INFORMATION
GOAL T/O herbicide provides postemergence and preemergence control of many susceptible weeds on non-crop areas including fence rows, storage yards, levee banks (use
only on the side of levee away from water channels), roadsides, farmsteads and other similar non-crop locations.
This pesticide is toxic to wildlife and fish. Use with care when applying in areas frequented by wildlife or adjacent to any body of water. Refer to container label for additional
handling and use warnings.
GOAL T/O HERBICIDE USED ALONE
DOSAGE
GOAL T/O herbicide is recommended for postemergence and preemergence control of susceptible weed species. GOAL T/O herbicide is recommended for postemergence
control at 2.5 to 10 pints (0.5 to 2.0 lbs. active) per broadcast acre. The lower rate is recommended for the control of susceptible weeds in the early postemergence stage,
less than 4 inches in height. The higher rate (2.0 lbs. active) should be used for weeds less than 12 inches in height. For preemergence control of susceptible weeds, GOAL
T/O herbicide is recommended at 10 pints (2.0 lbs. active) per broadcast acre.
WEEDS CONTROLLED POSTEMERGENCE WEEDS CONTROLLED PREEMERGENCE
Cheeseweed (Malva) Malva parviflora Medicago hipida
Burclover
Amsinckia intermedia Cheeseweed (Malva) Malva parviflora
Fiddleneck, Coast
Erodium botrys Amsinckia intermedia
Filaree, Broadleaf Fiddleneck, Coast
Erodium cicutarium Erodium botrys
Filaree, Redstem Filaree, Broadleaf
Senecio vulgaris Erodium cicutarium
Groundsel, Common Filaree, Redstem
Lamium amplexicaule Senecio vulgaris
Henbit Groundsel, Common
Montia perfoliata Lamium amplexicaule
Minerslettuce Henbit
Urtica urens Polygonum aviculare
Nettle, Burning Knotweed, Prostrate
Amaranthus retroflexus Chenopodium album
Pigweed, Redroot Lambsquarters, Common
Calandrinia caulescens Lactuca serriola
Redmaids Lettuce, Prickly
Capsella bursa-pastoris Amaranthus retroflexus
Shepherdspurse Pigweed, Redroot
Sonchus oleraceus Portulaca oleracea
Sowthistle, Annual Purslane, Common
Calandrinia caulescens
Redmaids
Sisymbrium irio
Rocket, London
Capsella bursa-pastoris
Shepherdspurse
Sonchus oleraceus
Sowthistle, Annual
GOAL T/O
WEED HERBICIDE RATE WEEDS
STAGE (PER BROADCAST ACRE) CONTROLLED
Early Postemergence 2.5 pints (0.5 lbs. active) Cheeseweed (Malva); Fiddleneck, Coast;
(weeds up to 4 inches high) Henbit; Redmaids; Shepherdspurse
Postemergence 5 pints (1.0 lb. active) Cheeseweed (Malva); Fiddleneck, Coast;
(weeds up to 8 inches high) Henbit; Minerslettuce; Nettle, Burning;
Redmaids; Shepherdspurse; Sowthistle,
Annual
Late Postemergence 10 pints (2.0 lbs. active) Cheeseweed (Malva); Fiddleneck, Coast;
(weeds up to 12 inches high) Filaree, Broadleaf*; Filaree, Redstem*;
Groundsel, Common; Henbit; Minerslet-
tuce; Nettle, Burning; Pigweed, Redroot;
Redmaids; Shepherdspurse; Sowthistle,
Annual
Preemergence 10 pints (2.0 lbs. active) Burclover; Cheeseweed (Malva); Fiddle-
neck, Coast; Filaree, Broadleaf; Filaree,
Redstem; Groundsel, Common; Henbit;
Knotweed, Prostrate; Lambsquarters,
Common; Lettuce, Prickly; Pigweed,
Redroot; Purslane, Common; Redmaids;
Rocket, London; Shepherdspurse;
Sowthistle, Annual
*GOAL T/O herbicide at the 10-pint rate (2.0 lbs. active) will provide control of filaree not exceeding the 4-inch stage. Applications to filaree beyond the
4-inch stage may result in partial control.
4
METHOD OF APPLICATION
GOAL T/O herbicide should be applied in a minimum of 40 gallons of water per acre. Best preemergence results are achieved when spray is applied to a relatively weed-
free soil surface. The volume of water used should be increased as the weeds become taller and more dense. Use a low-pressure sprayer equipped with flat fan nozzles.
Spray equipment should be calibrated carefully before each use.
SPRAY VOLUME:
GALLONS OF WATER
WEED STAGE PER ACRE
Early Postemergence 40 or more
(weeds up to 4 inches high)
Postemergence 100 or more
(weeds up to 8 inches high)
Late Postemergence 100 or more
(weeds up to 12 inches high)
Preemergence 40 or more
MIXING DIRECTIONS
HAND-HELD EQUIPMENT
For control of susceptible weeds listed on this label using knapsack or hand-held sprayers.
When application will be made in limited areas, it is expected that hand-held sprayers will be used. In those situations, mix 3 tablespoons (1.5 fluid ounces) of GOAL T/O
herbicide per gallon of water and apply on a spray-to-wet basis. Spray coverage should be uniform and complete. Avoid spraying to runoff. When spraying to control weeds
on a preemergence basis, 1 gallon of spray mixture should cover 400 sq. ft. It is recommended that an 80% active nonionic surfactant be added to the spray mixture at
a rate of 1 tablespoon (0.5 fluid ounces) per 1 gallon of spray.
LOW-PRESSURE SPRAYER
Fill the spray tank at least one-third full of clean water and add the recommended amount of GOAL T/O herbicide while the pump and agitator are running. Complete filling
of the spray tank with water and then add 1 quart of an 80% active nonionic surfactant cleared for application to growing crops, per each 100 gallons of spray. Maintain
agitation until spraying is completed.
CULTURAL CONSIDERATIONS
In order to provide maximum effectiveness of preemergence activity of GOAL T/O herbicide, the soil surface should be smooth and free of weed trash (decaying leaves, dead
weeds, etc.).
For acceptable preemergence activity, at least one-quarter inch (1/4 inch) of water or rainfall is necessary within 3 to 4 weeks after application. Cultural practices that result in
redistribution or disturbance of the soil surface after treatment will decrease the herbicidal effectiveness of GOAL T/O herbicide. The best results from GOAL T/O herbicide are
from applications to soil surfaces that are left undisturbed during the time period for which weed control is desired.
For postemergence control of grass species, a tank mixture of GOAL T/O herbicide with paraquat or Roundup庐 is recommended. Preemergence control of additional weed
species can be obtained when tank mixed with simazine or Karmex庐. When tank mixing, read and observe all individual manufacturers' label directions before using. In
interpreting all labels for the tank mixture, the most restrictive situations must apply.
USE PRECAUTIONS
鈥? Follow General Use Restrictions listed on the GOAL T/O herbicide label.
鈥? Do not treat ditchbanks or waterways with GOAL T/O herbicide.
鈥? CHEMIGATION: Do not apply this product through any type of irrigation system.
All applicable directions, restrictions and precautions on the EPA-registered label are to be followed.
This labeling must be in the possession of the user at the time of application.
STORAGE AND DISPOSAL
Do not contaminate water, food or feed by storage or disposal.
STORAGE: Keep from freezing. Store above 32掳F.
PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture or rinsate is a violation of Federal Law. If these wastes cannot
be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest
EPA Regional Office for guidance.
CONTAINER DISPOSAL
Plastic Containers: Triple rinse (or equivalent). Puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by State and local authorities, by burning.
If burned, stay out of smoke.
Metal Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved
by State and local authorities.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilate area. Avoid breathing vapors. Use MSHA/NIOSH self-contained breathing apparatus or
air-line respirator for large spills in confined areas. Dike the spill with inert material (sand, earth, etc.) and transfer the liquid or solid diking material to separate containers
for recovery or disposal. Remove contaminated clothing promptly and wash exposed skin areas with soap and water. Wash clothing before reuse. Keep spill out of all sewers
and bodies of water.
GOAL is a registered trademark of Rohm and Haas Company.
Karmex is a registered trademark of E. I. duPont de Nemours & Company.
Roundup is a registered trademark of Monsanto Company.
Vantage is a registered trademark of BASF-AG Corp.
13521-B4 MADE IN U.S.A.
ROHM AND HAAS COMPANY, 100 INDEPENDENCE MALL WEST, PHILADELPHIA, PA 19106-2399 TEL.: (215) 592-3000
5
1 inch
G O A L
T/O H E R B IC ID E
D a t a b a s e a n d fo r m a t co p y r i g h t 19 9 6 by C & P P r e s s . A l l ri g h t s re s e r v e d .
15 9 6 RO H M AN D HA A S
G O A L
T/O
{ h y d r o g e n
u o r i d e L o w e r E x p l o s i v e L i m i t : 1. 0 % X y le n e
{ n it r o g e n ox i d e s U p p e r E x p l o s i v e L i m i t : 8. 1 % C y c lo h e x a n o n e
H E R B IC ID E E x t i n g u i s h i n g A g e n t s : U s e th e fo ll o w in g ex t i n g u i s h -
R E A C T I V I T Y IN F O R M A T I O N
in g m e d i a w h e n g h t i n g r e s in v o lv i n g th is m a t e r ia l :
MA N U FA C T U R E R { c a r b o n d io x id e In s t a b i l i t y : T h i s m a t e r i a l is co n s id e r e d st a b le . H o w -
{ d r y ch e m i c a l ev e r, av o id c o n t a c t w i t h ig n it i o n so u r c e s (e . g . sp a r k s ,
RO H M AN D HA A S CO M PA N Y
o p e n
a m e , h e a t e d su r f a c e s ) .
{ w a t e r sp r a y
10 0 In d e p e n d e n c e M a ll W e s t
{ p o la r so lv e n t (a lc o h o l ) fo a m H a z a r d o u s D e c o m p o s i t io n P r o d u c t s : Th e r m a l de -
P h il a d e lp h i a , PA 19 1 0 6 - 2 3 9 9
c o m p o s it io n m a y yi e l d th e fo ll o w in g :
P e r s o n a l P r o t e c t i v e E q u i p m e n t : W e a r se l f - c o n t a i n e d
EM E R G E N C Y TE L E P H O N E N U M B E R S :
br e a t h in g ap p a r a t u s (p r e s s u r e - d e m a n d M S H A / N IO S H { hy d r o g e n ch l o r i d e
H E A L T H E M E R G E N C Y : 21 5 - 5 9 2 - 3 0 0 0
ap p r o v e d o r eq u iv a l e n t ) an d fu l l pr o t e c t i v e g e a r. { hy d r o g e n
u o r i d e
S P I L L E M E R G E N C Y : 21 5 - 5 9 2 - 3 0 0 0 S p e c i a l P r o c e d u r e s : C o n t a i n ru n o . R e m a i n u p w i n d . H a z a r d o u s P o l y m e r i z a t i o n : P r o d u c t w i ll n o t un d e r g o
C H E M T R E C : 80 0 - 4 2 4 - 9 3 0 0 A v o id br e a t h i n g sm o k e . U s e w a t e r sp r a y to co o l co n - p o ly m e r i z a t io n .
ta i n e r s ex p o s e d to r e . In c o m p a t i b i l i t y : A v o id co n t a c t w it h th e fo ll o w in g :
P R O D U C T ID E N T I F I C A T I O N
{ ac id s
G O A L
T/ O H e r b i c id e S P I L L O R LE A K H A N D L IN G IN F O R M A T I O N
{ ba s e s
P r o d u c t C o d e : 62 7 5 7 P e r s o n a l P r o t e c t i o n : A p p r o p r i a t e pr o t e c t i v e eq u ip - { am i n e s
K e y : 89 3 5 4 1 - 4 m e n t m u s t be w o r n w h e n h a n d li n g a sp i ll o f th i s m a t e - { ox i d i z in g ag e n t s
M S D S D a t e : 04 / 2 2 / 9 3 ria l . S e e th e P E R S O N A L P R O T E C T I O N M E A S U R E S { ha l o g e n s
S u p e r s e d e s : 07 / 2 5 / 9 1 S e c t i o n fo r re c o m m e n d a t i o n s . If ex p o s e d to m a t e r ia l { m o l t e n su l fu r
du r in g cl e a n - u p o p e r a t i o n s , se e th e FI R S T A I D P R O -
E N V I R O N M E N T A L IM P A C T
C E D U R E S S e c t io n fo r ac t i o n s to fo l lo w . R e m o v e al l
co n t a m in a t e d clo t h in g pr o m p t l y. W a s h al l ex p o s e d E n v i r o n m e n t a l To x i c i t y
Ro h m an d H a a s
sk in ar e a s w i t h so a p an d w a t e r im m e d i a t e l y af t e r ex - B o b w h i t e qu a i l, A c u t e O r a l L D 5 0 : >21 5 0 m g / k g
Sc a le
H a z a rd Ra tin g
po s u r e . T h o r o u g h ly la u n d e r cl o t h i n g be f o r e re u s e . D o B o b w h i t e qu a i l, 8 D a y O r a l LC 5 0 : >50 0 0 m g / k g
To x ic ity 3 4=E X T R E M E n o t ta k e cl o t h i n g h o m e to be la u n d e r e d . M a l la r d du c k , 8 D a y O r a l L C 5 0 : >50 0 0 m g / k g
Fir e 2 3=H I G H P r o c e d u r e s : E li m i n a t e all ig n it io n so u r c e s . Ve n t il a t e B lu e g il l su n s h (L e p o m is m a c r o c h i r u s ) , 96 H o u r L C 5 0 :
R e a c tiv ity 0 2=M O D E R A T E
th e sp il l ar e a . A v o id b r e a t h in g va p o r. C o n t a in sp il ls 0. 2 m g / l
Sp e c ia l { 1=S L IG H T
im m e d ia t e l y w i t h in e r t m a t e r i a ls (e . g . sa n d , ea r t h ) . R a i n b o w tr o u t (S a l m o ga ir d n e r i ) , 96 H o u r LC 5 0 : 0. 4 1
0=I N S IG N IF IC A N T
Tr a n s f e r liq u i d s an d so l id d ik i n g m a t e r ia l to se p a r a t e m g /l
su i t a b le co n t a in e r s fo r re c o v e r y or dis p o s a l . S e e th e
** * C O M P O N E N T IN F O R M A T I O N C h a n n e l ca t s h (l c t a lu r u s pu n c t a t u s ) , 96 H o u r L C 5 0 :
R E G U L A T O R Y IN F O R M A T I O N S e c t i o n fo r re p o r t i n g 0. 4 m g / l
re q u ir e m e n t s . G r a s s sh r i m p , 96 H o u r LC 5 0 : 32 ug / l
A M T.
CA S RE G C A U T I O N : K e e p sp i ll s an d cle a n in g ru n o o u t of m u - E a s t e r n o y s t e r, 96 H o u r E C 5 0 : 95 u g / l
No .
NO .
n ic i p a l se w e r s an d o p e n bo d i e s o f w a t e r. F i d d l e r cr a b (U c a p u g i la t o r ) , 96 H o u r L C 5 0 : >10 0 0
N O T E : Sp il ls o n po r o u s su r f a c e s ca n co n t a m in a t e
1 O x y
u o rf e n 42 8 7 4 - 0 3 - 3 20 { 2 1 m g /l
gr o u n d w a t e r.
2 X y le n e 13 3 0 -2 0 -7 9{ 1 0 F r e s h w a t e r c la m , 96 H o u r LC 5 0 : 9. 6 m g / l
H o n e y b e e , 96 H o u r LC 5 0 : >10 0 0 0 pp m
3 Eth y lb e n z e n e 10 0 - 4 1 - 4 1{ 2
H A Z A R D IN F O R M A T I O N T h e ab o v e E n v ir o n m e n t a l To x i c it y d a t a ar e fr o m st u d -
4 C y c lo h e x a n o n e 10 8 - 9 4 - 1 19 { 2 1
H E A L T H EF F E C T S FR O M O V E R E X P O S U R E ie s co n d u c t e d o n th e te c h n i c a l m a t e r ia l , 70 { 7 5 % ac -
5 R e la te d re a c tio n pr o d u c ts No n e 49 { 5 1
tiv e in g r e d ie n t .
P r i m a r y R o u t e s o f E x p o s u r e : In h a la t i o n , D e r m a l A b -
6 S u rf a c ta n t m ix tu re U n d is c lo s e d so r p t io n , S k in C o n t a c t , E y e C o n t a c t , In g e s t io n
A C C I D E N T P R E V E N T I O N IN F O R M A T I O N
In h a l a t i o n : In h a l a t i o n o f so l v e n t va p o r o r m is t ca n
7 S o lv e n t na p th a , pe tro le u m , 64 7 4 2 -9 5 -6
ca u s e th e fo ll o w i n g : { ir r it a t i o n o f n o s e , th r o a t , an d
lig h t ar o m C O M P O N E N T E X P O S U R E IN F O R M A T I O N
lu n g s
C o m p o n e n t In f o r m a t i o n
{ he a d a c h e
E M E R G E N C Y R E S P O N S E IN F O R M A T I O N
{ na u s e a
FI R S T A I D P R O C E D U R E S { d iz z i n e s s A M T.
C A S RE G
{ d r o w s in e s s
In h a l a t i o n : M o v e su b j e c t to fr e s h air. If br e a t h i n g No .
NO .
{ lo s s o f co o r d in a t i o n
is di c u l t , gi v e o x y g e n . G iv e ar t i c ia l re s p ir a t io n if
1 O x y
u o r fe n 42 8 7 4 -0 3 - 3 20 { 2 1
{ st u p o r
br e a t h i n g ha s st o p p e d . G e t pr o m p t m e d i c a l at t e n t io n .
2 Xy le n e 13 3 0 - 2 0 - 7 9{ 1 0
{ u n c o n s c io u s n e s s
E y e C o n t a c t : IM M E D I A T E L Y
u s h ey e s w it h a la r g e
E y e C o n t a c t : D ir e c t co n t a c t w it h m a t e r ia l ca n ca u s e 3 Eth y lb e n z e n e 10 0 - 4 1 - 4 1{ 2
am o u n t o f w a t e r fo r at le a s t 15 m i n u t e s . G e t pr o m p t
th e fo l lo w i n g :
m e d i c a l at t e n t io n . 4 C y c lo h e x a n o n e 10 8 - 9 4 - 1 19 { 2 1
{ se v e r e ir r it a t i o n
** * S k i n C o n t a c t : IM M E D I A T E L Y ge t un d e r a sa f e t y 5 Re la te d re a c tio n pro d u c ts No n e 49 { 5 1
{ p o s s i b l y pe r m a n e n t in j u r y
sh o w e r. W a s h a e c t e d sk in ar e a s th o r o u g h ly w i t h
** * S k i n C o n t a c t : T h e so lv e n t ( s ) in th i s m a t e r i a l ca n
so a p an d w a t e r. R e m o v e an d w a s h co n t a m i n a t e d 6 An io n ic /n o n io n ic su rf a c ta n t U n d is c lo s e d
be ab s o r b e d th r o u g h in t a c t sk in . M a t e r i a l ca n ca u s e
cl o t h i n g th o r o u g h ly . D o n o t ta k e cl o t h i n g h o m e to m ix tu re
th e fo l lo w i n g :
be la u n d e r e d . G e t pr o m p t m e d ic a l at t e n t i o n . 7 So lv e n t na p th a , pe tro le u m , 64 7 4 2 -9 5 - 6
{ se v e r e sk i n ir r it a t i o n
** * I n g e s t i o n : If sw a l lo w e d , g iv e 2 gl a s s e s o f w a t e r lig h t aro m
P r o l o n g e d o r re p e a t e d sk i n c o n t a c t c a n ca u s e th e
to dr in k . N e v e r gi v e an y t h i n g by m o u t h to an un c o n -
fo ll o w in g :
sc io u s pe r s o n . D O N O T in d u c e vo m i t in g , pe t r o l e u m
E x p o s u r e L i m i t In f o r m a t i o n
di s t i ll a t e pr e s e n t . IM M E D I A T E L Y se e a ph y s ic ia n . { d e fa t t i n g an d d r y i n g o f th e sk in w h i c h ca n le a d to
C a r e f u l ga s t r ic la v a g e m a y b e in d i c a t e d . ir r it a t io n an d d e r m a t i t is
In g e s t i o n : M a t e r ia l is po s s ib ly ha r m fu l if sw a l lo w e d .
N o t e to P h y s i c ia n : RO H M AN D
Co m - OS H A A C G IH
E x p o s u r e to xy le n e ca n a e c t th e C N S , pu l m o n a r y , ** * D e l a y e d E e c t s : HA A S
po n e n t
ca r d io v a s c u l a r, an d ga s t r o in t e s t in a l sy s t e m s . Li v e r en - R e p e a t e d ov e r e x p o s u r e to th e ac t iv e in g r e d i e n t in th is No .
TW A ST E L TW A ST E L TLV ST E L
zy m e s , E K G , se r u m ele c t r o l y t e s , an d a ch e s t X- r a y m a t e r ia l ca n c a u s e th e fo ll o w i n g : Un its
sh o u l d be do n e in ca s e s o f m a s s iv e ex p o s u r e . { liv e r da m a g e 3
1 m g /m 0.2 1.6 No n e No n e No n e No n e
D ir e c t to x ic e e c t s fr o m cy c lo h e x a n o n e in g e s t i o n ar e P r o l o n g e d o r re p e a t e d o v e r e x p o s u r e to xy le n e ca n 2 pp m 50 75 10 0 15 0 10 0 15 0
do s e re l a t e d . C o n d it io n s to be al e r t e d to in ca s e o f ex - ca u s e th e fo ll o w in g : Sk in Sk in
{ re v e r s ib le liv e r im p a ir m e n t
ce s s iv e in g e s t i o n ar e h e p a t o m e g a l y , h e p a t ic ne c r o s is , 3 pp m 50 75 10 0 12 5 10 0 12 5
re n a l fa i lu r e , co a g u l a t io n ab n o r m a l it i e s , an d se i z u r e s . { re v e r s ib le kid n e y im p a ir m e n t 4 pp m 25 75 25 No n e 25 No n e
Sk in Sk in Sk in Sk in
L iv e r dy s f u n c t i o n is lik e l y w i t h in a sh o r t ti m e if th e p e r - P r o l o n g e d o r re p e a t e d o v e r e x p o s u r e to c y c lo h e x -
5 No n e No n e No n e No n e No n e No n e
so n is sy m p t o m a t ic (i. e . na u s e a , vo m it i n g ) . D e c o n - an o n e ca n ca u s e th e fo l lo w i n g :
6 No n e No n e No n e No n e No n e No n e
ta m in a t io n o f th e gu t is ap p r o p r ia t e af t e r sig n i c a n t { liv e r da m a g e
7 pp m 50 75 No n e No n e No n e No n e
in g e s t io n . { ki d n e y da m a g e
In ac u t e ca s e s o f na p h t h a o v e r e x p o s u r e o r in g e s t io n , P r o l o n g e d o r re p e a t e d o v e r e x p o s u r e to na p h t h a ca n
P E R S O N A L PR O T E C T IO N M E A S U R E S
pa t i e n t s sh o u ld be ev a l u a t e d fo r si g n s o f re s p i r a t o r y ca u s e th e fo ll o w in g :
di s t r e s s . { liv e r da m a g e R e s p i r a t o r y P r o t e c t i o n : A re s p i r a t o r y pr o t e c t io n pr o -
{ ki d n e y da m a g e g r a m m e e t i n g O S H A 19 1 0 . 1 3 4 an d A N S I Z 8 8 . 2 re -
FI R E FI G H T I N G IN F O R M A T I O N
q u i r e m e n t s m u s t be fo ll o w e d w h e n e v e r w o r k p l a c e
FIR E A N D EX P L O S IV E PR O P E R T IE S
U n u s u a l H a z a r d s : P e s t i c i d e pa r t ic u la t e s ca n be c o m e c o n d i t io n s w a r r a n t a re s p ir a t o r 's us e . N o n e re q u i r e d
air b o r n e . a a
F l a s h P o i n t : 40 C / 1 0 4 F S e t a
a s h C l o s e d C u p if air b o r n e co n c e n t r a t io n ar e m a i n t a i n e d be l o w th e
C o m b u s t io n g e n e r a t e s to x ic fu m e s o f th e fo l l o w in g : a a
A u t o - i g n i t i o n Te m p e r a t u r e : 42 3 C / 7 9 3 F C y c lo h e x - T W A /T L V ' s lis t e d in th e C O M P O N E N T E X P O S U R E IN -
{ h y d r o g e n ch lo r id e an o n e F O R M A T I O N S e c t io n .
C o p y r ig h t c 1 9 9 6 by C & P P r e s s 3 /9 6
G O A L
T/O H E R B IC ID E
D a t a b a s e a n d fo r m a t co p y r i g h t 19 9 6 b y C & P P r e s s . A l l ri g h t s re s e r v e d .
RO H M AN D HA A S 15 9 7
U p to 10 tim e s th e TW A / T L V : W e a r a M S H A / N IO S H A c u te D a t a : at o r ab o v e de m i n i m is co n c e n t r a t i o n s . T h e fo ll o w -
ap p r o v e d (o r eq u iv a l e n t ) ha lf - m a s k , ai r - p u r if y in g re s - O r a l L D 5 0 { ra t : >50 0 m g / k g in g lis t e d ch e m i c a ls ar e p r e s e n t : (Q u a n t it y p r e s e n t is
pi r a t o r. fo u n d els e w h e r e o n th i s M S D S . )
D e r m a l LD 5 0 { ra b b it : >50 0 0 m g / k g
U p to 10 0 0 pp m o r g a n ic va p o r : W e a r a M S H A / N IO S H { Xy l e n e (m i x e d is o m e r s ) (1 3 3 0 - 2 0 - 7 )
E y e Ir r i t a t i o n { ra b b i t : se v e r e ir r it a t io n
ap p r o v e d (o r eq u iv a l e n t ) fu l l- f a c e p i e c e , air - p u r i fy i n g { E t h y lb e n z e n e (1 0 0 - 4 1 - 4 )
S k i n Ir r i t a t i o n { ra b b i t : se v e r e ir r it a t i o n
re s p i r a t o r. To x i c it y da t a fo r a co m p o s it i o n a l ly si m il a r m a t e r i a l ar e
C E R C L A IN F O R M A T I O N (4 0 C F R 3 0 2 . 4 )
A b o v e 10 0 0 pp m o r g a n i c va p o r o r U n k n o w n : W e a r a lis t e d be lo w .
M S H A / N I O S H ap p r o v e d (o r eq u i v a l e n t ) se l f- c o n t a i n e d In h a l a t i o n LC 5 0 { ra t : >22 . 6 4 m g /l fo r 4 h r T h is m a t e r i a l ha s a co m p o n e n t o r co m p o n e n t s w it h
br e a t h i n g ap p a r a t u s in th e po s i t iv e pr e s s u r e m o d e , S u b c h r o n i c / C h r o n i c D a t a : T h e fo l lo w i n g da t a pe r - a re p o r t a b le qu a n t it y u n d e r th e C o m p r e h e n s i v e E n -
OR , ta i n s to st u d ie s co n d u c t e d w i t h th e te c h n ic a l m a t e r ia l , vi r o n m e n t a l R e s p o n s e , C o m p e n s a t io n , an d L ia b i li t y
M S H A / N I O S H ap p r o v e d (o r eq u i v a l e n t ) fu ll - f a c e p ie c e 70 { 7 5 % ac t iv e in g r e d i e n t : A c t (C E R C L A ) an d th e S u p e r fu n d A m e n d m e n t s an d
air li n e re s p ir a t o r in th e p o s it iv e pr e s s u r e m o d e w i t h L iv e r n e c r o s is w a s o b s e r v e d in m i c e at 20 pp m an d R e a u t h o r i z a t io n A c t (S A R A ) T i t le III Se c t io n 30 4 . Th e
em e r g e n c y es c a p e pr o v is io n s . ab o v e ; th e o v e r a ll N O E L w a s 2 p p m (0 . 3 m g / k g ) in c o m p o n e n t s , C A S n u m b e r s , an d re p o r t a b l e qu a n t i t ie s
A i r - p u r i fy in g re s p ir a t o r s sh o u l d be eq u i p p e d w i t h pe s - m ic e . ar e lis t e d be l o w . S p i ll s o f a co m p o n e n t in ex c e s s o f
ti c id e ca r t r i d g e (o r g a n i c va p o r ca r t r i d g e an d p e s t ic id e C a r c i n o g e n i c i t y D a t a : T h e fo l l o w in g da t a pe r t a i n s to it s re p o r t a b l e qu a n t it y m u s t b e re p o r t e d to th e N a -
pr e lt e r ) . st u d ie s co n d u c t e d w i t h th e te c h n i c a l m a t e r ia l, 70 { 7 5 % tio n a l R e s p o n s e C e n t e r (1 - 8 0 0 - 4 2 4 - 8 8 0 2 ) an d to th e
E y e P r o t e c t i o n : U s e c h e m ic a l sp l a s h go g g le s (A N S I ac t i v e in g r e d ie n t : ap p r o p r i a t e st a t e an d lo c a l em e r g e n c y re s p o n s e o r -
Z8 7 . 1 o r ap p r o v e d eq u iv a le n t ) . N o ev i d e n c e o f ca r c i n o g e n ic i t y w a s o b s e r v e d in lo n g - g a n iz a t i o n s .
H a n d P r o t e c t i o n : G l o v e pe r m e a t io n da t a do e s no t te r m st u d i e s w i t h ra t s . A sl ig h t l y h ig h e r in c id e n c e (n o t X y le n e (1 3 3 0 - 2 0 - 7 ) 10 0 0 lb s .
ex is t fo r th is m a t e r ia l . Th e fo l lo w in g gl o v e ( s ) sh o u ld st a t is t ic a l ly si g n i c a n t ) o f liv e r tu m o r s w a s se e n in m a l e C y c l o h e x a n o n e (1 0 8 - 9 4 - 1 ) 50 0 0 lb s .
be us e d fo r sp l a s h pr o t e c t io n o n ly : { N i t r i le m i c e at 20 0 pp m bu t no t at 20 o r 2 p p m , an d n o t in E t h y l b e n z e n e (1 0 0 - 4 1 - 4 ) 10 0 0 lb s .
fe m a l e m ic e at an y o f th e s e do s e s . G O A L
Te c h n ic a l
G l o v e s sh o u ld be re m o v e d an d re p l a c e d im m e d ia t e l y
R C R A IN F O R M A T I O N
if th e r e is an y in d ic a t i o n o f d e g r a d a t io n o r ch e m i c a l h a s b e e n cla s s i e d as a p o s s i b l e h u m a n ca r c in o g e n
br e a k t h r o u g h . by th e U S - E P A . W h e n a de c is i o n is m a d e to dis c a r d th is m a t e r i a l as
R i n s e an d re m o v e gl o v e s im m e d i a t e ly af t e r u s e . W a s h M u t a g e n i c i t y D a t a : Th e fo l lo w i n g da t a p e r t a i n s to su p p li e d , it is cl a s s i e d as a R C R A ha z a r d o u s w a s t e
h a n d s w i t h so a p an d w a t e r. st u d ie s co n d u c t e d w i t h th e te c h n i c a l m a t e r ia l, 70 { 7 5 % w it h th e ch a r a c t e r is t ic o f ig n i t a b il it y , ha z a r d o u s w a s t e
O t h e r P r o t e c t i o n : U s e ch e m ic a l ly re s i s t a n t ap r o n o r ac t i v e in g r e d ie n t : nu m b e r: D 0 0 1
o t h e r im p e r v io u s c lo t h in g to av o i d p r o l o n g e d o r re - A m e s m u t a g e n ic it y : P o s it i v e
C H E M IC A L C O N T R O L LA W ST A T U S
pe a t e d sk i n co n t a c t . M o u s e L y m p h o m a P o i n t M u t a t i o n : P o s it i v e
T h is pr o d u c t is su b je c t to re g u l a t io n un d e r th e U. S .
In vi t r o ra t h e p a t o c y t e U n s c h e d u l e d D N A S y n t h e s i s :
FA C I L IT Y C O N T R O L M E A S U R E S F e d e r a l In s e c t i c id e , F u n g i c i d e an d R o d e n t i c i d e A c t
N e g a tiv e
Ve n t i l a t io n : U s e ex p l o s i o n p r o o f lo c a l ex h a u s t ve n t i- (F I F R A ) an d is th e r e f o r e ex e m p t fr o m U . S . To x ic S u b -
In viv o cy t o g e n e t ic as s a y (r a t ) : N e g a t i v e
la t io n w it h a m in im u m ca p t u r e ve l o c it y o f 10 0 ft /m i n . st a n c e s C o n t r o l A c t (T S C A ) In v e n t o r y lis t i n g re q u ir e -
In vi v o c h r o m o s o m e ab e r r a t io n as s a y (m o u s e bo n e
(0 . 5 m / s e c . ) at th e po in t o f va p o r ev o lu t i o n . R e fe r to m e n ts .
m a r r o w ce l ls ): N e g a t iv e
G O A L
is a tr a d e m a r k o f R o h m an d H a a s C o m p a n y
th e cu r r e n t ed i t io n o f In d u s t r ia l Ve n t i la t i o n : A M a n u a l R e p r o d u c t i v e / Te r a t o l o g y D a t a : T h e fo ll o w in g da t a
o f R e c o m m e n d e d P r a c t i c e pu b li s h e d by th e A m e r i c a n o r o n e o f it s su b s i d ia r ie s o r a l ia t e s .
pe r t a in s to st u d ie s c o n d u c t e d w it h th e te c h n ic a l m a -
C o n f e r e n c e o f G o v e r n m e n t a l In d u s t r ia l H y g ie n is t s fo r A B B R E V IA T IO N S :
te r ia l , 70 { 7 5 % ac t i v e in g r e d i e n t :
in f o r m a t i o n o n th e d e s i g n , in s t a l la t i o n , us e , an d m a i n - A C G IH = A m e r i c a n C o n f e r e n c e o f G o v e r n m e n t a l In -
N o ev id e n c e of te r a t o g e n i c it y w a s o b s e r v e d in st u d ie s
te n a n c e o f ex h a u s t sy s t e m s . d u s t r i a l H y g ie n is t s
w i t h ra b b i t s .
G O A L
Te c h n ic a l w a s n o t te r a t o g e n i c o r em b r y o -
O t h e r P r o t e c t i v e E q u i p m e n t : F a c il it i e s st o r in g o r u t i- O S H A = O c c u p a t i o n a l S a f e t y an d H e a l t h A d m i n i s t r a -
liz in g th is m a t e r i a l sh o u l d be eq u i p p e d w i t h an ey e - tio n
fe t o t o x ic in ra t s at do s e s th a t w e r e n o t m a t e r n a ll y to x ic
w a s h fa c i li t y an d a sa f e t y sh o w e r. T L V = T h r e s h o ld L im i t Va lu e
(1 5 m g /k g ), ho w e v e r at m a t e r n a ll y to x i c do s e s (1 5 0
m g / k g ) em b r y o - f e t o t o x i c i t y an d sk e le t a l m a lf o r m a t i o n s P E L = P e r m is s ib le E x p o s u r e Li m i t
S T O R A G E A N D H A N D L I N G IN F O R M A T IO N
w e r e ev id e n t . N o e e c t s o n re p r o d u c t iv e pe r f o r m a n c e T W A = Ti m e W e i g h t e d A v e r a g e
S t o r a g e C o n d i t i o n s : Th e m in im u m re c o m m e n d e d in ra t s w a s ev i d e n t at do s e s u p to an d in c lu d i n g 40 0 S T E L = S h o r t - T e r m E x p o s u r e L im it
a a
st o r a g e te m p e r a t u r e fo r th is m a t e r ia l is 0 C / 3 2 F. pp m . B A c = B u t y l ac e t a t e
D o n o t st o r e th i s m a t e r i a l ne a r fo o d , fe e d , o r d r i n k - S e n s i t iz a t i o n D a t a : T h e fo ll o w in g da t a pe r t a i n s to ** * de n o t e s a re v i s i o n fr o m pr e v io u s M S D S in th is
in g w a t e r. S t o r e aw a y fr o m ex c e s s iv e h e a t (e . g . st u d ie s co n d u c t e d w i t h th e te c h n i c a l m a t e r ia l, 70 { 7 5 % ar e a .
st e a m p i p e s , ra d i a t o r s ), fr o m so u r c e s of ig n it i o n an d ac t i v e in g r e d ie n t : T h e in f o r m a tio n co n ta in e d he re in re la te s on ly to th e sp e c i c
fr o m re a c t iv e m a t e r i a ls . A v o id all ig n it io n so u r c e s . S e n s i t iz a t i o n { hu m a n : N o al le r g i c re s p o n s e o b - m a te ria l id e n ti e d . R o h m an d H a a s Co m p a n y be lie v e s th a t
G r o u n d al l m e t a l co n t a i n e r s du r i n g st o r a g e an d h a n - su c h in f o rm a tio n is ac c u ra te an d re lia b le as of th e da te of th is
se r v e d .
m a te ria l sa f e ty da ta sh e e t, bu t no re p re s e n ta tio n , gu a ra n te e
dl in g . D e l a y e d C o n t a c t H y p e r s e n s i t i v i t y { g u in e a pi g : N o
or w a r ra n ty, ex p re s s or im p lie d , is m a d e as to th e ac c u r a c y ,
H a n d lin g Pr o c e d u r e s : D o no t ha n d le m a te r ia l ne a r al le r g ic re s p o n s e o b s e r v e d . re lia b ility , or co m p le te n e s s of th e in fo rm a tio n . R o h m an d H a a s
fo o d , fe e d , o r d r i n k i n g w a t e r. G r o u n d al l co n t a i n e r s
C o m p a n y urg e s pe rs o n s re c e iv in g th is in f o rm a tio n to m a k e
W A S T E D IS P O S A L
w h e n tr a n s f e r r in g m a t e r ia l . T h i s m a t e r ia l is a se v e r e ir - th e ir ow n de te rm in a tio n as to th e in f o r m a tio n 's su ita b ility an d
rit a n t . Se e th e P E R S O N A L P R O T E C T I O N M E A S U R E S P r o c e d u r e : In c in e r a t e liq u id an d co n t a m in a t e d so li d s co m p le te n e s s fo r th e ir pa rtic u la r ap p lic a tio n .
S e c t i o n pr io r to h a n d l in g . in ac c o r d a n c e w it h lo c a l, st a t e , an d fe d e r a l re g u l a - 89
O t h e r : C O N T A IN E R S H A Z A R D O U S W H E N E M P T Y. ti o n s .
S in c e em p t ie d c o n t a in e r s re t a i n pr o d u c t re s id u e (v a -
po r s an d / o r li q u i d ) fo ll o w all M S D S an d la b e l w a r n in g s R E G U L A T O R Y IN F O R M A T I O N
ev e n af t e r co n t a i n e r is em p t i e d . R e s id u a l va p o r s in
W O R K P L A C E C L A S S IF IC A T IO N S
em p t y co n t a in e r s m a y ex p l o d e on ig n i t io n . D O N O T
cu t , dr il l, gr in d , o r w e ld o n o r ne a r co n t a in e r. Tr i p le T h i s pr o d u c t is co n s i d e r e d ha z a r d o u s u n d e r th e O S H A
rin s e (o r eq u i v a le n t ) an d pu n c t u r e em p t y co n t a in e r. H a z a r d C o m m u n ic a t io n S t a n d a r d (2 9 C F R 19 1 0 . 1 2 0 0 ) .
D is p o s e em p t y co n t a i n e r in a sa n it a r y la n d l l o r b y T h i s pr o d u c t is su b je c t to re g u la t io n un d e r th e C a n a -
in c i n e r a t io n as al lo w e d b y st a t e an d lo c a l au t h o r it ie s . di a n P e s t C o n t r o l P r o d u c t s A c t (P. C . P. A c t ) . Th e r e f o r e ,
A v o i d in h a l a t io n o f sm o k e if in c i n e r a t e d . th is pr o d u c t is ex c lu d e d fr o m th e su p p l ie r la b e l in g an d
m a t e r ia l sa fe t y da t a sh e e t re q u i r e m e n t s as sp e c i e d
S U P P L E M E N T A L IN F O R M A T I O N in S e c t io n 12 o f th e H a z a r d o u s P r o d u c t s A c t .
TY P I C A L P H Y S I C A L P R O P E R T IE S TR A N S P O R T A T I O N C L A S S I F I C A T I O N S
Ap p ea rance : Opaqu e U S D O T H a z a r d C la s s : N O N R E G U L A T E D
C o lo r : Da r k co lo r e d T h i s cla s s i c a t io n is u s e d w h e n sh i p p i n g in n o n - b u l k
S t a t e : L iq u id pa c k a g e s fo r do m e s t i c su r fa c e tr a n s p o r t a t io n o n l y .
E x c e p t i o n s in C F R 49 P a r t s 17 1 - 1 7 7 m a y ap p ly . C o n -
O d o r C h a r a c t e r i s t i c : A r o m a t ic o d o r
su l t C F R 49 P a r t s 17 1 - 1 7 7 to d e t e r m i n e ap p r o p r i a t e
p H : 7. 0
cl a s s i c a t i o n w h e n sh ip p in g in bu l k pa c k a g e s o r w h e n
V i s c o s it y : 0. 5 1 C P S
sh i p p i n g by air o r oc e a n .
S p e c i c G r a v i t y (W a t e r = 1) : 0. 9 9 2
Va p o r D e n s i t y (A i r = 1) : 21 . 9
EM E R G E N C Y PL A N N IN G & C O M M U N IT Y RIG H T -
a a
Va p o r P r e s s u r e : 4. 0 m m H g @ 20 C / 6 8 F
TO - K N O W (S A R A T IT L E 3 )
M e ltin g Po in t: N o D a ta
a a a a
B o i l i n g P o i n t : 13 9 {1 5 6 C / 2 8 2 {3 1 3 F S e c t i o n 3 1 1 / 3 1 2 C a t e g o r i z a t io n s (4 0 C F R 3 7 0 ) :
S o l u b i l i t y in W a t e r : D i s p e r s i b le T h i s pr o d u c t is a ha z a r d o u s ch e m ic a l u n d e r 29 C F R
19 1 0 . 1 2 0 0 , an d is ca t e g o r iz e d as an im m e d ia t e an d
P e r c e n t Vo l a t i l i t y : 45 { 8 0 %
de l a y e d h e a lt h , an d
a m m a b il it y ph y s ic a l h a z a r d .
E v a p o r a t i o n R a t e (B A c = 1) : <1
S e c t i o n 31 3 In f o r m a t i o n (4 0 C F R 37 2 ) : T h i s p r o d -
TO X I C I T Y IN F O R M A T I O N u c t co n t a in s a ch e m i c a l w h i c h is lis t e d in S e c t io n 31 3
C o p y r ig h t c 1 9 9 6 by C & P P r e s s 3 /9 6
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