PAINTABLE MIST Mold Release
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Validation Date July 20, 2004 Material Safety Data Sheet L-0125&126A
Section 1 鈥? PRODUCT AND COMPANY INFORMATION
Manufacturer IMS Company Emergency Phone 800-424-9300
10373 Stafford Road Office Phone 440-543-1615
Chagrin Falls, OH 44023-5296 Prepared by Product Safety Advisor
E-mail sales@imscompany.com Prepared/Revised July 15, 2004
Item Numbers Paintable Mist Mold Release Container Former Item Number
113658 9.25 Ounces net AER1-P112-A
113649 12 Ounces net AER1-P116-A
Product use Designed as a hand held, very portable, aerosol can spray, to achieve easier ejection of parts from any mold
type such as injection, compression, composite, etc. and any mold material such as ferrous, non-ferrous,
and composite molds.
Hazardous Material Information System
Health 1* Flammability 4 Reactivity 1 Protection X
0 Normal use Material 0 Will Not Burn 0 Stable X = Consult the
1 Slight Hazard (temporary) 1 Possible to Burn 1 Unstable if Heated MSDS and
2 Health Affected (lengthy) 2 Burns if Heated 2 Violent Ch emical Change your supervisor
3 Extreme Danger 3 Easily Burns 3 Shock and Heat Sensitive for your special
4 Severe or Fatal 4 Very Easily Burns 4 May Explode workplace need
* Chronic (Accumulates)
NOTE The HMIS may not be enough hazard information for this chemical in all workplaces. The HMIS system requires employee training about the system
and about information in this MSDS.
Section 2 鈥? INGREDIENTS INFORMATION
Chemical/Common Name CAS-Number % PEL-OSHA TLV-ACGIH
(1) (4) (1) (4)
1,1-Difluoroethane (HFC-152a) 75-37-6 50 to 60
(1) (2) (1) (2)
Dimethyl Ether 115-10-6 30 to 40
(3) (1) (1)
Aliphatic Petroleum Distillate 64742-89-8 5 to 15
(1) (1)
Copolymer Organo/EthylMethylsilioxane 68037-77-4 0.1 to 10
(1)
None Established
(2)
Other exposure limits: AIHA (American Industrial Hygiene Association) WEEL (Workplace Environmental Exposure
Limit) = 500 ppm.
(3)
This ingredient may contain trace contamination of a chemical known to the State of California to cause cancer.
(4)
Manufacturer suggested Allowable Exposure Limit (AEL) = 1000 ppm.
Section 3 鈥? HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW Product is a clear compressed gas and liquid with slight ethereal odor as dispensed from the
aerosol package.. May cause chemical and mechanical eye, skin, and respiratory tract irritation. For large spills, wear
appropriate personal protective equipment. Collect released product by adsorption. CONTENTS UNDER PRESSURE. Do not
puncture or burn container
CAUTION Slippery; can cause falls if walked on. Inhalation of mist or fumes, evolved upon heating of the release agent, most
likely to be irritating to respiratory tract. The solvents and propellant evaporate quickly leaving the release agent as a residue.
To use safely, prevent overspray and prepare to control and prevent spills.
Nose FATAL OR HARMFUL IF INHALED. CNS depression with anesthetic effects such as dizziness,
headache, confusion, in-coordination, and loss of consciousness. Higher exposures to vapors may
cause temporary alteration of the heart's electrical activity, with irregular pulse, palpitations, or
inadequate circulation; or fatality from gross overexposure.
Mouth Because of the nature of the product, ingestion is unlikely. Small amounts of the release agent by
fingers should not injure and large amounts could cause digestive discomfort.
Eyes Irritation. NOTE: Direct contact with spray can result in frostbite.
Skin Irritation, defatting, dermatitis. NOTE: Direct contact with spray can result in frostbite.
Chronic Aliphatic Petroleum Distillate may contain trace contamination of a chemical known to the State of California to
cause cancer.
ROUTE OF ENTRY Inhalation, eyes, skin.
TARGET ORGANS, MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Not fully determined, however
exposure may aggravate diseases of the central nervous system, heart rhythm or other cardiovascular diseases, or
pulmonary diseases. If a person has one or more of these problems, consult medical personnel to determine what
steps should be taken.
Section 4 鈥? FIRST AID MEASURES
**Note to Medical Personnel**
Because of increased risk of disturbances of cardiac rhythm, Catecholamine drugs such as Epinephrine should be
used only with special caution and only in situations of emergency life support.
NOTE If any irritation persists, get medical help.
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Validation Date July 20, 2004 Material Safety Data Sheet L-0125&126A
Breathing Remove to fresh air. Keep person warm and quiet. Apply artificial respiration if breathing has
stopped. If breathing is difficult, give oxygen. ** Get Medical Help at once **
Eating Not expected to be a route of entry. However, if ingested, ** Get Medical Help at once **
Aspiration into lungs can cause chemical pneumonia. ** Induce vomiting ONLY IF advised by
physician ** May act as a laxative. Small amounts should be rinsed out until taste of product is
gone.
Eye Contact Flush thoroughly with water for at least 15 minutes, consult a physician.
Skin Contact Do not apply directly to skin! If accidentally discharged onto skin, wash with soap and water.
Launder contaminated clothes before re-use.
Section 5 鈥? FIRE FIGHTING MEASURES
Flash Point (estimated) ................................C)
< 0掳 F (<-18掳 Flammable Limits................................
LEL = 1 % UEL = 18 %
Autoignition temperature ................................
ND
FLAMMABLE LIQUID AND VAPOR VAPOR MAY CAUSE FLASH FIRE
Extinguishing Media Carbon Dioxide, Foam, Dry Chemical, Water Fog. Using water to cool exposed containers may be
useful.
Special Fire Fighting Procedures Firefighters should wear self-contained breathing apparatus (SCBA) with full face piece
operated in positive pressure mode, protective clothing, and avoid skin contact, due to thermal decomposition products. Use
equipment or shielding to protect personnel against rupturing or venting containers. Cooling containers with water streams
may be helpful. See decomposition products.
At elevated temperatures (> 120掳 F/>49掳 C) aerosol containers may vent or rupture.
Unusual Fire and Explosion Hazards Static-electric sparks have been known to ignite accumulated vapors of flammable
propellant mixtures. Use caution where static-electric sparks can occur. Ensure enough ventilation to avoid vapor
accumulation, especially when spraying where there is an enclosure that would otherwise let vapors accumulate. Vapors are
heavier than air, and might collect below the spray area, or might travel long distances along the floor and become ignited
elsewhere.
Section 6 鈥? ACCIDENTAL RELEASE MEASURES
Steps to be Taken in Case Material is Released or Spilled Remove sources of ignition. Ventilate area to reduce
concentration of the components below their exposure limits. Use protective equipment consistent with the situation. Pick up
the spill on absorbent material; store in closed containers for proper disposal. Remove residue to prevent a slippery condition
developing. It is slippery on walkways; use a light solvent to clean area, to remove trace residues, but do not let contaminated
liquid get to drains, sewers, public water source, or rainfall. Do not puncture or burn containers.
Section 7 鈥? HANDLING AND STORAGE
Precautions to be Taken in Handling and Storage Store in cool, dry area out of direct sunlight. Do not puncture, burn, or
store above 120掳 F (49掳 C).
SPRAY APPLICATIONS Where exposure exceeds the TLV, use a NIOSH/MSHA approved respirator, goggles, rubber gloves,
and protective clothing.
Maintenance Precautions Do not remove or deface label.
Handling Thoroughly wash after handling, and before eating, drinking, or using tobacco products.
Other Precautions Read and follow directions and cautions on the container label, and any accompanying literature.
Overspray could make floors slippery. Use housekeeping and work rules to prevent slipping. Decomposition vapor is heavier
than air and can collect in low areas. Clean up spills promptly. Monitor floors for accumulation in overspray area; clean as
needed. The aerosol package, when tested for flame projection, had a projection less than 18 inches and no burn-back toward
the nozzle.
Section 8 鈥? EXPOSURE CONTROLS 鈥? PERSONAL PROTECTION
GENERAL Usually local exhaust is not required. General room ventilation may be adequate to maintain components below
TLV/PEL, if handled at ambient temperatures, or in covered equipment. Local exhaust ventilation or other engineering controls
may be required, if ambient temperatures are exceeded, or if used in operations without good air circulation.
Maintain enough ventilation to prevent fire/flash hazard from local accumulation of vapors, especially near sources of high heat,
electric arcs or static-electric sparks. NOTE vapors are heavier than air and could collect below the area where the product is
sprayed, or could travel long distances along floor and be ignited elsewhere.
Polymeric coated apron or other body covering is recommended where there is a possibility of regular work clothing becoming
contaminated with the product. All soiled or dirty clothing and personal protective equipment should be thoroughly cleaned
before reuse.
Respiratory Protection Generally not required if sufficient ventilation is provided. If the exposure limit of the product or any of
its components is exceeded, an approved organic vapor mask should be used (consult your safety equipment supplier). If
exposures exceed limits by less than a factor of ten, use a NIOSH approved, 陆 mask facepiece respirator for particulate
matter. If exposures exceed 10 times the recommended limits, consult a professional industrial hygienist or your respiratory
protective equipment supplier for selection of the proper equipment.
Protective Gloves Where prolonged or repeated contact with the spray mist or the deposited product is likely, use polymeric
materials, neoprene, etc. for personal protective equipment, gloves and clothing.
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Validation Date July 20, 2004 Material Safety Data Sheet L-0125&126A
Other Protective Equipment If contact with the spray is likely, eye protection is recommended. Chemical Monogoggles or
safety glasses with side shields, and a face shield will provide protection in most situations.
Other Engineering Controls To determine exposure levels, monitoring should be performed. Eye bath and safety shower
station should be available.
Work Practices Do not use in confined or closed space. Use enough ventilation to maintain the concentration of the product
and its components below their exposure limits. Avoid long-term or repeated contact. Stained clothing should be removed
and laundered before re-use. Sudden release of hot vapor or mist from process equipment operating at elevated temperature
and pressure, or sudden ingress of air into hot equipment under vacuum, may result in decomposition without obvious source
of heat. Any use of this product in elevated-temperature processes must be thoroughly evaluated to establish and maintain
safe operating conditions.
Hygienic Practices As with using any chemical product, avoid contact with skin and avoid breathing vapors, do not eat,
drink, or smoke in work area; wash hands prior to eating, drinking or using restroom after handling or using. Any chemical
product can contaminate tobacco, causing illness (from inhaling components heated in tobacco smoke or ingested from
handling tobacco and/or food products).
Section 9 鈥? PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point ............................................................
N/A Specific Gravity (Water=1) ................................
<1
Vapor Pressure at 77潞 F (25潞 C)................................
60 卤 10 Percent Volatile by Volume (%)................................
> 95
Vapor Density (Air=1) ................................>1 Evaporation Rate (ether=1) ................................
Faster
VOC................................................................
95% by weight Pour point................................................................
ND
Solubility in Water ................................ NIL pH ................................................................
ND
Melting point ............................................................
ND Odor threshold .........................................................
ND
Viscosity NA
Appearance and Odor Information Clear mist with slight ethereal odor as dispensed from the aerosol package.
CONTENTS UNDER PRESSURE. Do not puncture or burn container.
Section 10 鈥? STABILITY AND REACTIVITY
Incompatibility (reactivity, Strong oxidizers, strong caustics, reactive metals such as sodium, potassium, zinc,
materials to avoid) magnesium.
Product Chemically Stable? Yes
Conditions to keep Stability Avoid heat sufficient to burst container (see special fire-fighting procedure above) and
spraying into flame or onto red hot surfaces, which may cause decomposition and/or
ignition.
Decomposition Products Not determined; however, carbon monoxide, carbon dioxide, hydrofluoric acid, fluorine, and
carbonyl fluoride would be expected. Fluorine compounds released as decomposition
products above 554掳F (290掳C) could cause lung irritation and pulmonary edema, which
require medical treatment.
Will Hazardous Polymerization Occur? Product is stable. Hazardous polymerization will not occur.
Sensitivity to mechanical impact None
Sensitivity to static discharge (ESD) With all spray procedures, potential to being a source of ESD and being ignited from
ESD.
Section 11 鈥? TOXICOLOGICAL INFORMATION
LD50, LC50 NA
Reproductive Toxicity NA
Irritancy, sensitivity See other sections, 3 - Hazard Identification, 4 - First Aid, and 15 鈥? Regulatory Information.
Section 12 鈥? ECOLOGICAL INFORMATION
The product is not expected to present an environmental hazard. Ecological or environmental effects not known
Section 13 鈥? DISPOSAL CONSIDERATIONS
Waste Disposal Methods The dried residue, remaining material does not exhibit any characteristics of a hazardous waste.
Product may be mixed with absorbent materials to point of being a non-liquid and disposed in normal trash, unless local
regulations prohibit. Give leaking, or full, containers to a disposal service equipped to handle such residue containers.
Observe all warnings and precautions listed for the product. As prepared, product as a whole is considered hazardous.
Observe proper safety and handling. Do not allow empty containers to be used for any purpose except to store and ship
product. Recovered liquids may be re-used if compatible with user鈥檚 processes. Contaminated material may be disposed of in
a permitted waste management facility suitable for the contamination. Do not puncture or burn containers.
Reclamation/recycling is encouraged where possible. Where reclamation is not practical, this product may be incinerated
where permitted by Federal, State, County/Provincial, and Local regulations. Never dispose by means of public sewers or
drainage.
Section 14 鈥? TRANSPORT INFORMATION
Ground (US DOT).... Consumer Commodity OR Aerosols (Limited Quantity)
Class ORM-D 2.1
ERG 126 126
Air (IATA)................ Consumer commodity
Class 9 (Label Diamond required)
PAINTABLE MIST Mold Release
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Validation Date July 20, 2004 Material Safety Data Sheet L-0125&126A
UN/ID No. ID 8000
Packing 1900
Authorization Limited Quantity
Vessel .................... Aerosols (Limited Quantity)
Class 2.1
UN No 1950
EmS No. 2-13
ERG 126
Section 15 鈥? REGULATORY INFORMATION
CFC, HCFC, HFC, ODS Y
EPA - CAA, CWA Y
EU risk phrase #鈥檚 N
IDLH N
OSHA listed Y
PROP 65 listed Y
RCRA listed Y
SARA 313 list N
TSCA listed Y
USDA H-1, -2 H-2
This product has been classified in accordance with hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
Section 16 鈥? OTHER INFORMATION
CAUTION Intentional misuse of this chemical product, as with any industrial chemical in contact with the body, can
be harmful or fatal. This includes such things as deliberately breathing, placing in mouth, swallowing, placing on
skin, or any other body contact, or repeated, or continuous contact.
IMS provides this information in good faith, but makes no representation as to its comprehensiveness or its accuracy. This
document is offered as a guide to a trained person, for appropriate precautionary handling. Persons using the product and receiving
the information must exercise independent judgment in determining the appropriateness of the use and the safety information for
their particular purpose. IMS MAKES NO REPRESENTATIONS OR WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING
WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THIS INFORMATION OR TO THE PRODUCT. ACCORDINGLY, IMS WILL NOT BE RESPONSIBLE FOR
DAMAGES RESULTING FROM USE OF OR RELIANCE ON THIS INFORMATION.
ACGIH American Conference of Governmental Hygienists NA Not Applicable, Not Available
AKA Also Known As, Synonym ND Not Determined
CAS Chemical Abstract Service NIL Not measurable, significant, noticeable, or an affect
NTP National Toxicology Program
H-1, -2 USDA, plant process chemicals that do not touch food stuff OSHA Occupational Safety and Health Administration
IARC International Agency for Research of Cancer ppm parts per million
IDLH Immediately Dangerous to Life or Health, exposure rate/volume USDA U S Department of Agriculture
mg/m 3 milligrams per Cubic Meter Y Yes, Does Exists, Is Listed,
N No, None, Not listed, Not Known
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