Material Safety Data Sheet chemcan
Section I. Chemical Product and Company Identification
AGERITE庐 STALITE庐
Product Name/ Code 02605
Trade Name
Mixture
CAS#
Supplier R.T. VANDERBILT COMPANY, INC.
In case of Call (203)853-1400
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Not available.
Synonym
Mixture of alkylated diphenylamines
Chemical Name
Not available.
Chemical Family
Not applicable.
Chemical Formula
Material Uses Industrial applications: Antioxidant for elastomer.
Section II. Composition and Information on Ingredients
Name CAS # % by
Weight
benzenamine, N-phenyl-, reaction products with styrene and 68921-45-9 >98
2,4,4-trimethylpentene.
diphenylamine 122-39-4 <2
Section III. Hazards Identification
Red to brown liquid. Vapor or mist may be harmful if inhaled. May cause eye and skin irritation.
Emergency Overview
Section IV. First Aid Measures
Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Eye Contact
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated
Skin Contact
skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and
groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.
Allow the victim to rest in a well ventilated area. Seek immediate medical attention
Inhalation
Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs.
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AGERITE庐 STALITE庐 Page Number: 2
Section V. Fire and Explosion Data
Not available.
Flammability of the Product
Not available.
Auto-Ignition Temperature
OPEN CUP: 210掳C (410掳F) (Cleveland.).
Flash Points
Not available.
Flammable Limits
Oxides of carbon and nitrogen, small amounts of aromatic and aliphatic hydrocarbons.
Products of Combustion
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemicals, CO2, water spray or foam.
Fire Fighting Media
LARGE FIRE: CO2 may be ineffective on larger fires due to lack of cooling capacity which may result in
and Instructions
reignition.
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section VI. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal
Small Spill
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
Large Spill
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements. Prevent entry into sewers, basements or confined areas; dike if needed.
Section VII. Handling and Storage
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly
Storage
closed. Keep in a cool, well-ventilated place. Store above 22掳C (72掳F) to prevent crystallization.
Manipulate in a well ventilated area. Avoid breathing vapors or spray mists. Avoid contact with skin and
Handling Procedures and
eyes. After handling, always wash hands thoroughly with soap and water.
Equipment
Section VIII. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
Engineering Controls
their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Protection
Gloves.
diphenylamine
TLV/PEL
TWA: 10 (mg/m3) from ACGIH (TLV)
TWA: 10 (mg/m3) from OSHA (PEL)
TWA: 10 (mg/m3) from ACGIH
TWA: 10 (mg/m3) from RQMT
Consult local authorities for acceptable exposure limits.
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AGERITE庐 STALITE庐 Page Number: 3
Section IX. Physical and Chemical Properties
Brownish-red. Liquid.
Appearance
Not applicable.
Molecular Weight
Not applicable.
pH (1% soln/water)
Not available.
Boiling/Condensation Point
7掳C (44.6掳F)
Melting/Sublimation Point
0.995 (Water = 1)
Specific Gravity
The only known value is 1.16 g/cm3 (DIPHENYLAMINE).
Density
Not available.
Vapor Pressure
Not available.
Vapor Density
Volatility 0.25% (v/v).
Odor / Odor Threshold Amine like. (Slight.)
Evaporation rate Not available.
1,150 cSt @25掳C, 16 cSt@100掳C
Viscosity
Not available.
Water/Oil Dist. Coeff.
Solubility Insoluble in cold water. Very soluble in alcohol and toluene.
Section X. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Strong oxidizing agents such as permanganates, perchlorates and hydrogen peroxide.
Incompatibility with
Various Substances
Not available.
Corrosivity
Special Remarks on Reactivity Not available.
Section XI. Toxicological Information
Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of Entry
Acute oral toxicity (LD50): 15000 mg/kg [Rabbit]
Toxicity to Animals
Not available.
Special Remarks on
Toxicity to Animals
Acute Effects
This product may irritate eyes upon contact.
Eye contact
Prolonged or repeated contact may cause irritation.
Skin contact
No data available.
Sensitization
The product is of low acute oral toxicity.
Ingestion
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AGERITE庐 STALITE庐 Page Number: 4
Vapors generated from hot processes may be irritating.
Inhalation
Product contains diphenylamine which may contribute to irritation. Diphenylamine may be absorbed through
Remark
the skin in toxic amounts. Diphenylamine may cause methemoglobinemia and red blood cell damage.
CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
TERATOGENIC EFFECTS Not available.
:
DEVELOPMENTAL TOXICITY Not available.
:
Effects of overexposure: Diphenylamines may be irritating to mucous membranes. Heating may generate
Remarks
vapors which can irritate the eyes and respiratory passages. Dust may be irrritating to the upper respiratory
tract. Drying of skin and mucous membranes leading to irritation may be possible from prolonged or repeated
contact. Overexposure to vapors from heating the product may cause and/or skin irritation and respiratory
tract irritation with symptoms such as, but not limited to, dizziness and flu-like symptoms. Diphenylamine is
reported teratogenic in rats.
Section XII. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Not available.
Biodegradability
Not available.
Special Remarks on the
Products of Biodegradation
Section XIII. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste information
Not available.
Waste stream
Section XIV. Transport Information
Not controlled under TDG (Canada).
TDG Road/Rail
Not applicable.
Remarks
Not available.
Maritime
Transportation
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AGERITE庐 STALITE庐 Page Number: 5
Section XV. Other Regulatory Information and Pictograms
Federal & Provincial
CEPA DSL: AGERITE庐 STALITE庐
Regulations.
WHMIS Class D-2A: Material causing other toxic effects (VERY TOXIC).
WHMIS (Canada)
Remark No additional remark.
Other regulatory lists TSCA 8(b) inventory: AGERITE庐 STALITE庐
EINECS: This product is on the European Inventory of Existing Commercial Chemical
Substances.
Japan (MITI): AGERITE庐 STALITE庐
* National Fire
1
Hazardous Material Health Hazard Flammability
1
Protection Association
Information System 1
Fire Hazard
1 0
(U.S.A.)
(U.S.A.) Reactivity
Health
0
Physical Hazard
h
Personal Protection Specific hazard
WHMIS (Canada)
(Pictograms)
Protective Clothing
(Pictograms)
Section XVI. Other Information
Not available.
References
Not available.
Other Special
Considerations
Validated by Romana Uzar on 1/22/2007. Verified by Romana Uzar.
Printed 1/24/2007.
Information Contact (203) 853-1400
Corporate Risk Management Department
Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our
knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in
violation of any patent or in violation of any law or regulation. It is the user鈥檚 responsibility to determine for himself the suitability of any
material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained
in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of
any material supplied by us.
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