Material Safety Data Sheet chemec
Section 1. Chemical Product and Company Identification
DARVAN庐 L
Product Name/ Code 13782
Trade Name
Mixture
CAS#
Supplier R.T. VANDERBILT COMPANY, INC. Call (203)853-1400
In Case of
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Ammonium salts of alkyl phosphate
Synonym
Ammonium salts of alkyl phosphate
Chemical name
Chemical Family Not available.
Not applicable.
Chemical Formula
Industrial applications: Mold lubricant, antitack
Material Uses
Section 2. Composition, Information on Ingredients
EINECS # /
% by
CAS # Classification
Name
ELINCS #
Weight
Neutralized mixed alkylphosphates 80-90 270-200-2 R36-41
alcohols, C12-16 68855-56-1 2.5-10 272-490-6 Not available.
n-butanol 71-36-3 0-3 200-751-6 R10-22-37/38-41-67
For additional information regarding European classification see sections 15 & 16.
Section 3. Hazards Identification
White paste with ammonical odor. Eye, skin, and respiratory irritant.
Emergency Overview
Section 4. First Aid Measures
Check for and remove any contact lenses. Flush with plenty of water for at least 15 minutes, occasionally
Eye Contact
lifting the upper and lower eyelids. Seek medical attention if irritation persits.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash
clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention.
Inhalation
Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs.
Continued on Next Page
DARVAN庐 L Page Number: 2
Section 5. Fire and Explosion Data
Non-flammable.
Flammability of the Product
Not available.
Autoignition Temperature
OPEN CUP: 138掳C (280.4掳F).
Flash point
Not available.
Flammable Limits
carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...)
Products of Combustion
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Not available.
Special Remarks on Fire
Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Put spilled solid in a waste disposal container. Finish cleaning by spreading water on the contaminated
Small Spill
surface and dispose of according to local and state regulations.
Absorb with an inert material and put the spilled material in an appropriate waste disposal. DO NOT touch
Large Spill
spilled material. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements. Prevent water from entering drinking water supplies or streams.
Section 7. Handling and Storage
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Avoid contact with skin and eyes. Avoid breathing vapors or spray mists. Do not ingest. Freezing will affect
Handling Procedures and
physical condition, but will not damage. Thaw and mix before using. After handling, always wash hands
Equipment
thoroughly with soap and water.
Section 8. Exposure Controls, Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
Engineering Controls
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Precautions
Gloves.
ammonium hydroxide(as ammonia)
TLV/PEL
TWA: 25 (ppm) from ACGIH
TWA: 35 (ppm) from OSHA
Consult local authorities for acceptable exposure limits.
Continued on Next Page
DARVAN庐 L Page Number: 3
Section 9. Physical and Chemical Properties
White. Solid. (Solid paste.)
Appearance
Not applicable.
Molecular Weight
7 [Neutral.]
pH (1% soln/water)
Not available.
Boiling/Condensation Point
Not available.
Melting/Freezing Point
1.04 (Water = 1)
Specific Gravity
The only known value is 0.9 Mg/m鲁 (ammonium hydroxide).
Density
Not applicable.
Vapor Pressure
Not available.
Vapor Density
20% (v/v).
Volatility
Ammoniacal.
Odor
Not available.
Evaporation Rate
Not available.
Viscosity
The product is more soluble in water.
Water/Oil Dist. Coeff.
Dispersible in water.
Solubility
OPEN CUP: 138掳C (280.4掳F).
Flash Point
Section 10. Stability and Reactivity
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Not available.
Incompatibility with Various
Substances
Not available.
Corrosivity
Special Remarks on Reactivity No additional remark.
Section 11. Toxicological Information
Eye contact. Ingestion. Inhalation. Skin contact.
Routes of Entry
Acute oral toxicity (LD50): 790 mg/kg [Rat]. (1-BUTANOL)
Toxicity to Animals
Acute dermal toxicity (LD50): 4200 mg/kg [Rabbit]. (1-BUTANOL)
Acute toxicity of the vapor (LC50): 8000 ppm 4 hour(s) [Rat]. (1-BUTANOL)
Special Remarks on Toxicity to Oral ALD (rats) >11,000 mg/kg (product).
Animals
Acute Effects
Very hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness,
Eye Contact
watering, and itching. Repeated or prolonged exposure can lead to eye corrosion with corneal or conjunctival
ulceration.
Irritant to skin and mucous membranes
Skin Contact
Continued on Next Page
DARVAN庐 L Page Number: 4
The product is untested for skin sensitization, but similar compounds are known to cause defatting of skin.
Sensitization
Ingestion Product is of low acute toxicity, however ingestion may cause corrosive injury to the mouth, esophagus and
stomach leading to pain, vomiting, and circulatory collapse.
Inhalation Inhalation hazard. Ihalation of ammonia can cause upper respiratory irritation, headache, nausea and
weakness.
Remarks Not available.
CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
TERATOGENIC EFFECTS Not available.
:
DEVELOPMENTAL TOXICITY Not available.
:
Remarks
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
The product is easily biodegradable.
Biodegradability
Not available.
Special Remarks
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Not available.
Waste Stream
Section 14. Transport Information
Not controlled under ADR (Europe).
ADR Classification
PIN Not applicable.
Not available.
IMDG Classification.
Not available.
IATA Classification Not controlled under IATA.
Continued on Next Page
DARVAN庐 L Page Number: 5
Section 15. Other Regulatory Information and Pictograms
Regulatory Lists EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
No additional remark.
Remark
R38- Irritating to skin. S26- In case of contact with eyes, rinse immediately with plenty of water
EC Classification /
R41- Risk of serious and seek medical advice. S28- After contact with skin, wash immediately
Labelling
damage to eyes. with plenty of water S37/39- Wear suitable gloves and eye/face
protection.
Flammability
0
Hazardous Material *3 National Fire Protection
Health Hazard
3 0 Reactivity
Health
Information System Association (U.S.A.)
0
Fire Hazard
(U.S.A.)
0
Physical Hazard Specific hazard
E
Personal Protection
TSCA 8(b) inventory: DARVAN庐 L
Other Regulations
CEPA DSL: DARVAN庐 L
Australia (NICNAS): DARVAN庐 L
Japan (MITI): DARVAN庐 L
Korea (TCCL): Darvan庐 L
Protective Clothing
(Pictograms)
Section 16. Other Information
R38- Irritating to skin.R41- Risk of serious damage to eyes.
Relevant R phrases:
References Not available.
Other Special Not available.
Considerations
Verified by Romana Uzar.
Validated by Romana Uzar on 2/14/2007.
Printed 2/14/2007.
Information Contact (203) 853-1400
Corporate Risk Management Department
Notice to Reader
Continued on Next Page
DARVAN庐 L Page Number: 6
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user鈥檚 responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.
|