Material Safety Data Sheet chemusa
Section I. Chemical Product and Company Identification
BUTYL TUADS庐
Product Name/ 40850
Code
Trade Name
1634-02-2
CAS#
Supplier R.T. VANDERBILT COMPANY, INC.
Call: (203) 853-1400
In Case of
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Disulfide, bis(dibutylthiocarbamoyl); tetrabutylthiruam disulfide
Synonym
Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetrabutyl-
Chemical name
Not available.
Chemical Family
Chemical Formula C18H36N2S4
Industrial applications: Elastomer accelerator.
Material Uses
TSCA 8(b) inventory: BUTYL TUADS庐
TSCA Status
Section II. Composition and Information on Ingredients
Name CAS # % by Weight
tetrabutylthiuram disulfide 1634-02-2 100
Section III. Hazards Identification
Dark amber liquid. Do not ingest alcoholic beverages immediately before and after handling this material
Emergency Overview
(antabuse reaction). Product may discolor skin by reaction with iron and copper metals in the skin. No data
available on irritation.
Section IV. First Aid Measures
Check for and remove any contact lenses. Flush with running water for at least 15 minutes. Do not use an
Eye Contact
eye ointment. Seek medical attention.
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated
Skin Contact
skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and
groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.
Allow the victim to rest in a well ventilated area. Seek immediate medical attention
Inhalation
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
Ingestion
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
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BUTYL TUADS庐 Page Number: 2
Section V. Fire and Explosion Data
Not available.
Flammability of the Product
Not available.
Autoignition Temperature
OPEN CUP: 138掳C (280.4掳F) (Cleveland.).
Flash Point
Not available.
Flammable Limits
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...).
Products of Combustion
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Not available.
Special Remarks on Fire
Hazards
Special Remarks on Explosion Not available.
Hazards
Section VI. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal
Small Spill
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
Large Spill
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Section VII. Handling and Storage
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly
Storage
closed. Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme
heat and away from strong oxidizing agents.
Avoid contact with eyes Avoid contact with skin and clothing. Wash thoroughly after handling
Handling Procedures and
Equipment
Section VIII. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
Engineering Controls
their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Protection
Gloves.
Not available.
TLV / PEL
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BUTYL TUADS庐 Page Number: 3
Section IX. Physical and Chemical Properties
Amber. (Dark.) Liquid.
Appearance
408.76
Molecular Weight
Not applicable.
pH (1% soln/water)
Not available.
Boiling/Condensation Point
Not available.
Melting Point
1.06 (Water = 1)
Specific Gravity
1.06 mg/m3 at 25掳C (77掳F)
Density
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Volatility
Not available.
Odor
Not available.
Evaporation Rate
Not available.
Viscosity
Not available.
Water/Oil Dist. Coeff.
Insoluble in cold water. Slightly soluble in methanol. Very soluble in toluene.
Solubility
Section X. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Reactive with oxidizing agents.
Incompatibility with Various
Substances
Not available.
Corrosivity
Special Remarks on Reactivity Not available.
Section XI. Toxicological Information
Eye contact. Inhalation. Ingestion.
Routes of Entry
Acute oral toxicity (LD50): 2350 mg/kg [Rat]. (tetrabutylthiuram disulfide)
Toxicity to Animals
Special Remarks on Toxicity to Not available.
Animals
Acute Effects
No data available.
Eye Contact
No data available on skin irritation. Product can cause skin discoloration upon repeated or prolonged contact.
Skin Contact
No data available.
Sensitization
No data available.
Ingestion
No data available.
Inhalation
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BUTYL TUADS庐 Page Number: 4
Ingestion/inhalation of this product may cause unpleasant symptoms if alcohol is consumed whithin hours of
Remarks
exposure (antabuse effect).
CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
DEVELOPMENTAL TOXICITY Not available.
:
REPRODUCTIVE TOXICITY Not available.
:
Repeated or prolonged exposure is not known to aggravate medical condition.
Not available.
Remarks
Section XII. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Not available.
Biodegradability
Not available.
Special Remarks on the
Products of Biodegradation
Section XIII. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Not available.
Waste Stream
Section XIV. Transport Information
Not a DOT controlled material (United States).
DOT
Not applicable.
Not applicable.
Remarks
Not available.
Maritime transportation
Section XV. Other Regulatory Information and Pictograms
Not controlled under the HCS (United States).
Classification HCS (USA)
TSCA 8(b) inventory: BUTYL TUADS庐
Federal and State
Regulations
Not applicable.
Remarks
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BUTYL TUADS庐 Page Number: 5
National Fire Protection
Hazardous Material Flammability
1
2
Health Hazard
Association (U.S.A.)
Information System
1 2 0
Fire Hazard
(U.S.A.) Reactivity
Health
0
Reactivity
Specific hazard
h
Personal Protection
Other regulatory EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
specifications
CEPA DSL: BUTYL TUADS庐
Australia: BUTYL TUADS庐
Japan (MITI): BUTYL TUADS庐
Korea: BUTYL TUADS庐
Philippines: BUTYL TUADS庐
China: BUTYL TUADS庐
Protective Clothing
(Pictograms)
Section XVI. Other Information
Not available.
References
Not available.
Other Special
Considerations
Validated by Erin A. Bendig on 8/8/2003. Verified by Erin A. Bendig.
Previous Validation Date: 8/8/2003. Printed 8/8/2003.
Information Contact David Bower, Ph.D. (203) 853-1400 ext. 233
Corporate Risk Management
Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user鈥檚 responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.
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