Part Number(s):
MATERIAL SAFETY DATA SHEET 17-111-11
Form WI04-11A Rev. 1
Product Name: ELASTIBITE Release Date: March 10, 2006
1. Product and Company Identification
Trade Name & Synonyms MSDS Code Number
GAC Elastibite GAC-BITE
Chemical Name Manufacture / Distributor
Ethylene-vinyl acetate copolymer GAC International Inc.
C.A.S. Number Address
24937-78-8 355 Knickerbocker Ave.
Bohemia, NY USA 11716
Grades or Minor Variant Identities Information Telephone Number
NA 1-631-419-1700
Product Use (for Canada) Emergency Telephone Number
NA 1-631-419-1700
2. Composition of Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
Ethylene vinyl acetate copolymer NA
24937-78-8 NA
Ingredient name: Escorene Ultra LD 723
The composition of this mixture may be proprietary
information. In the event of medical emergency,
compositional information will be provided to a physician or
nurse. This product is hazardous as defined in 29 CFR
1910.1200, based on the following compositional
information.
OSHA HAZARD COMPONENT
ACGIH/TLV Vinyl acetate
Possible human carcinogen Vinyl acetate
3. Hazard Identification
Emergency Overview
NA
Routes of Signs and Symptoms Single, Repeated, or Severity (Mild, Acute and Chronic Target
Exposure Lifetime Exposure Moderate, Severe) Health Effect(s) Organ(s)
Particulates may scratch NA NA NA NA
Eye
eye surfaces/cause
mechanical irritation.
Negligible hazard at Exposure to hot NA NA NA
Skin
ambient temperatures (- material may cause
18 to 38 deg C; 0-100 deg thermal burns.
F)
Negligible hazard at NA NA NA NA
Inhalation
ambient temperature (-18
to 38 deg c; 0-100 deg F).
Vapors and/or aerosols,
which may be formed at
elevated temperatures,
may be irritating to eyes
and respiratory tract.
Minimal toxicity. NA NA NA NA
Ingestion
Chronic effects: This NA NA NA NA
Other
product contains vinyl
acetate monomer. No
carcinogen effects were
observed in long-term
drinking water studies in
rats. Drinking water
studies in rats. Long-
term inhalation of this
chemical at air conditions
of 600 PPM produces
nasal tremors in rats.
Mice exposed to the same
condition were nor
affected.
Page 1 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-111-11
Form WI04-11A Rev. 1
Product Name: ELASTIBITE Release Date: March 10, 2006
Medical Conditions Aggravated by Exposure
NA
Carcinogenicity (IARC, NTP)
The international agecy for research on cancer (IARC) evaluated vinyl acetate in 1995 and found it to be a possible human carcinogen, classification
2B. The American conference of governmental industrial hygienists (ACGIH) has evaluated vinyl acetate and found it to be a group A3, animal
carcinogen. The ACGIH also reported that available evidence suggests that the agent is not likely to cause cancer in humans at the recommended
exposure levels.
Potential Environmental Effects
NA
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
NA NA
Eye
This product is an inert solid. If in
eye, remove as one would any
foreign object.
For hot product, immediately Get prompt medical attention. NA
Skin
immerse in or flush the affected
area with large amounts of cold
water to dissipate heat. Cover with
clean cotton sheeting or gauze and
get prompt medical attention. No
attempt should be made to remove
materials from skin or to remove
contaminated clothing, as the
damaged flesh can be easily torn.
In case of adverse exposure to Call for prompt medical NA
Inhalation
vapors/ or aerosols formed at attention.
elevated temperatures,
immediately remove the affected
victim from exposure. Administer
artificial respiration if breathing is
stopped. Keep at rest.
First aid is normally not required. NA NA
Ingestion
NA NA NA
Other
Note to Physicians (Treatment, Testing, and Monitoring)
NA
5. Fire and Explosion Data
Flashpoint & Method: Flammable (Explosive) Limits in Air Autoignition Temperature Other
掳C /649 掳F Note: LEL: N/A UEL: N/A N/A
General hazard: Solid
Estimated, greater than.
material may burn at or
above flashpoint, and
Properties Contributing to Flammability Classification
Flame Propagation or Burning
airborne dust may explode if
Fire Intensity Health- , Flammability- , Reactivity-NA
NA ignited. Toxic gases will
NA
form upon combustion.
Static discharge, material
can accumulate static
charges, which can cause in
incendiary electrical
discharge.
Extinguishing Media Extinguishing Media to Avoid
NA NA
Protection and Procedures for Firefighters
Use water spray to cool fire-exposed surfaces, protect personnel, and extinguish the fire. Respiratory and eye protection required for fire fighting
personnel.
Unusual Fire and Explosion Hazards
Decomposition products under fire conditions: Oxygen-lean conditions may produce carbon monoxide and irritating smoke, acetic acid.
Page 2 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-111-11
Form WI04-11A Rev. 1
Product Name: ELASTIBITE Release Date: March 10, 2006
6. Accidental Release Measures
Containment Techniques
Land spill: Recover spilled material and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and
ensure conformity to local disposal regulations.
Spill/Leak Clean-Up Procedures and Equipment
Water spill: Plastic pellets are defined by the USA EPA under the clean water act (40 CFR 122.26) as a 鈥? significant material鈥? which requires any
industrial plant that may expose pellets to storm water to secure a storm water permit. Violations of the rule carry the same penalties as other clean
water act violations. Pellets found in storm water runoff are subject to EPA regulations with the potential for substantial fines and penalties. Skim
from surface. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Recover the spilled material
and place in suitable containers for recycle or disposal.
Evacuation Procedures
NA
Special Instructions
NA
Reporting Requirements
NA
7. Handling and Storage
Handling Practices and Warnings
Electrostatic accumulation handling: Yes, use proper bonding and/or grounding procedure.
Storage Practices and Warnings
Storage temperature: Deg F Ambient. Loading/unloading temperature: Deg F Ambient. Storage/ Transport pressure, MMHG:Atmospheric.
Loading/unloading viscosity, CST: Solid.
Storage and Handling: Keep container closed. Handle and open containers with care. Store in a cool, well-ventilated place away from incompatible
materials. Do not handle or store near an open flame, heat or other sources of ignition. Protect material from direct sunlight. Material may
accumulate static charges, which may cause an electrical spark (ignition source). Use proper bonding and / or grounding procedures.
Shelf life: 2 years.
8. Exposure Control/Personal Protection
Ventilation Other Engineering Controls
Local exhaust ventilation of process equipment may be needed to NA
control particulate exposures to below the recommended exposure
limit.
Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies:
Eye/Face Where contact may occur with hot material, wear face shield. Where NA
contact is likely with open systems at ambient temperatures (-18 to 38
deg C, 0 鈥? 100 deg F) wear safety glasses with side shields.
Skin Where contact may occur with hot material, wear thermal resistant NA
gloves, arm protection.
Inhalation NA NA
General Hygiene Considerations and Work Practices
OSHA REGULATION 29 CF1910.1000 REQUIRES THE FOLLOWING PERMISSABLE EXPOSURE LIMITS:
5/MG/M3 ( Respirable dust ), and 15/MG/M3 ( Total dust) based on OSHA PEL for nuisance dust. A TWA of 10PPM (30 mg.m3) and a STEL of
20 PPM (60 mg/m3) for vinyl acetate. The recommended permissible exposure levels indicated above reflect the levels revised by OSHA in 1989 or
in subsequent regulatory activity. Although the 1989 levels have since been vacated by the 11th circuit court of appeals, Exxon Mobil chemical
company recommends that the lower exposure levels be observed as reasonable worker protection.
THE ACGIH RECOMMENDS THE FOLLOWING THRESHOLD LIMIT VALUES:
A TWA of 10/MG/M3 for inhalation particulate (total dust) and a TWA of 3 MG/M3 for respirable particulate (total dust) for particulates not
otherwise classified (PNOC). A TWA of 10 PPM (35 MG/M3 and a STEL of 15 PPM (53 MG/M3) for vinyl acetate, with an A3 designation.
Protective Measures During Repair and Maintenance of Contaminated Equipment
NA
Other Protective Measures and Equipment
NA
Page 3 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-111-11
Form WI04-11A Rev. 1
Product Name: ELASTIBITE Release Date: March 10, 2006
9. Physical and Chemical Characteristics
Appearance Odor
Pellets. Color: Opaque white to transparent. NA
Boiling Point 掳C / 掳F N/A
Normal Physical State:
Liquid Gas Melting Point 99-115 掳C 210-240掳F
Freezing Point 掳C / 掳F
Solid (Other)
Specific Gravity or Density (H20=1) Solubility in Water pH
.091 - .96 Insoluble NA
Vapor Pressure (mm Hg @ 20掳C) Vapor Density (AIR= 1) Evaporation Rate (Butyl Acetate = 1)
N/A NA NA
Other
Viscosity of liquid: N/A
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid)
Temperatures above 300 F (150C) with fluorine.
Hazardous Products Produced During Decomposition
Will not occur
Hazardous Polymerization? Conditions to Avoid
掳C / 掳F N/A
May Occur May Not Occur
Stability? Conditions to Avoid
掳C / 掳F N/A
Stable Unstable
11. Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic or Reproductive Effects, or Structure Activity Data
Please refer to section 3 for available information on potential health effects.
12. Ecological Information
Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements
No specific ecological data are available for this product. Please refer to section 6 for information regarding accidental releases and section 15 for
regulatory reporting information.
13. Disposal Considerations
Regulations
Please refer to sections 5, 6, and 15 for disposal and regulatory information.
Properties (Physical/Chemical) Affecting Disposal
NA
14. Transport Information
Regulated for shipping? Proper Shipping Name Packing Group
Elastibite NA
Yes No
Hazard Class Identification Number
Do changes in quantity, packaging, or shipment method change product classification?
NA NA
Yes No
Other
Not regulated under US department of transportation.
Page 4 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-111-11
Form WI04-11A Rev. 1
Product Name: ELASTIBITE Release Date: March 10, 2006
15. Regulatory Information
Federal Regulations
CERCLA: If this product is accidentally spilled, it is not subject to any special reporting under the requirements of the
comprehensive environmental response, compensation and liability act (CERCLA). We recommend you contact local
authorities to determine if there may be other local reporting requirements.
SARA TITLE III: Under the provisions of title III, sections 311/312 of the superfund amendments and reauthorization
act, this product is classified into the following hazard categories: Delayed health. This information may be subject to
the provisions of the community right to know reporting requirements (40 CFR 370) if threshold quantity criteria are
met.
This component Vinyl acetate CAS NO 108-05-4 Maximum % .2
International Regulations
NA
Other
HMIS RATINGS: Health 0 Flammability 0 Reactivity 0
NFPA 0= Minimal 1= Slight 2= Moderate 3= Serious 4= Severe
The CAS registry number for ethylene-vinyl acetate copolymer is 24937-78-8.
National Fire Protection association standards NFPA 654 and 68 indicate possible explosion hazard of dust particles.
Conform accordingly. Avoid accumulation of dust or dust clouds; Operate handling and storage systems leak free,
practice good housekeeping. Keep from sources of ignition. Do not store near heat, flame, or strong oxidants. Assure
proper electrical grounding of all handling equipment.
Product may also contain varying levels of additives, such as slip and antiblocking agents, antioxidants, stabilizers,
and corrosion inhibitors. Special precautions: Should significant vapors/fumes be generated during thermal processing
of this product, it is recommended that work stations be monitored fir the presence of thermal degradation by products,
vinyl acetate and acetic acid which may be evolve elevated temperatures. It is recommended that the current ACGIH-
TLV鈥檚 for these materials be observed.
16. Other Information
Supplier Number: 31/17 Supplier Release: October 6, 2003 Rev: 02
N/E = not established. N/D = not determined. N/A = not applicable.
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