MSDS PAGE: CAS 25213-24-5 MSDS celanese

產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004

材料安全數據�?
1. 產品與公司識別資�?

Product:Celvol?Polyvinyl alcohol
MSDS 號碼: 465
材料號碼:80465

Celanese Pte Ltd
501 Orchard Road
Wheelock Place #11-01
Singapore 238880
Tel No: (65) 67331767

運輸緊�?�情況電話號碼﹕
+ (65) 66639259 (Operations Room direct dial)
+ (65) 62656917 (Operations Room direct dial)
+ (65) 62650177(Switchboard, ask for Operations Room)

or fax request to
+(65) 62644190 (Facsimile to Operations Room)
+(65) 62664696 (Facsimile to Operations Room)

or email to
opsroom@semco.psa.com.sg

or Call CHEMTREC 703 527 3887 (USA), collect calls accepted
"+" = International Dialing Access Code

2. 成分/成分資料

成分及化學文摘服務處號碼重量% OSHA 規定�?�?:
成分及化學文摘服務處
號碼
Acetic acid ethenyl ester, polymer with 25213-24-5 92 危險
ethenol

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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
1 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004
The following specific grades of Celvol are covered by this MSDS:

Celvol 711, Polyvinyl alcohol
Celvol 804, Polyvinyl alcohol
Celvol 805, Polyvinyl alcohol
Celvol 818, Polyvinyl alcohol
Celvol 823, Polyvinyl alcohol
Celvol 830, Polyvinyl alcohol
Celvol 840, Polyvinyl alcohol
Celvol 831, Polyvinyl alcohol

Specific technical information on a Celvol grade should be obtained from the sales specification sheet
available at www.celvol.com

3. 危險識別

緊�?�情�?:
小心!
可�?�成眼睛刺激�?
該產品的塵末可形成爆炸�?�有機物塵雲�?

產品說明

外貌: White granulated powder
味道: 無味�?

潛在健康影響
暴露途徑: 皮膚、眼睛�?�吸入�?�嚥下�??

即時影響
皮膚: 基本上沒有刺�?性�??

眼睛: 可能會刺�?眼睛�? 暴露的徵�?可能包括�? 眼睛刺激或灼燒的感覺�?

吸入: 可能會引起呼吸道刺激�? 暴露的徵�?可能包括�?
流鼻水�?�嘶啞�?�咳嗽�?�胸痛和呼吸困難�?

嚥下: 根據成分基本上沒有毒性�?? 暴露的徵�?可能包括�? 口�?�喉、食管和/或胃發炎�?

生殖: 無不良生殖影響的證明�?

致癌�?: 聚乙烯醇是﹕
列為IARC�?3組無法分類其對人類的致癌性﹕

突變�?: 在大部分試管測驗中並未顯示突變可能�?��?? 在活體小核試驗中未顯示誘變能力�??

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2 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004
對特定器官的影響: 過度（長期或反復）接觸可導致�?
刺激呼吸�?
刺激消化�?
接觸處局部刺�?

大量接觸該化學品可能會對患有下列急�?�和慢�?�器官疾病的病人有不利影響：
�?般認為在暴露後會使病情惡化的呼吸�?
病況: 眼睛
消化系統

有關詳情，參�?: �?5部分 �? 滅火措施
�?4部分 �? 急救措施 �?6部分 �? 意外釋放措施
�?8部分 �? 暴露控制/個人保護
�?9部分 �? 物理與化學特�?
�?10部分 �? 穩定性與反應�?

4. 急救措施

皮膚: 立即用大量清水沖洗皮膚或眼睛至少15分鐘，並同時脫下污染的衣服和鞋子。立即尋
求治療�?�衣服應洗乾淨後才能再穿。污染的鞋子應毀滅�??

眼睛: 立即用大量清水沖洗眼睛至�?15分鐘。如果有戴隱形眼鏡並可以輕易取下時，應將�?
取下。立即尋求治療�??

吸入: 移往空氣清新處�?�如果停止呼吸，應施人工呼吸。如果呼吸困難，應給氧氣，並尋求
治療�?

嚥下: 如果嚥下大量本物質，立即聯絡醫生。除非經醫療人員的指示，否則切勿引起嘔吐�?
切勿餵昏迷的人任何東西�?�尋求治療�??

5. 滅火措施

NFPA: Health: 1 Flammability: 1 Reactivity: 0

易燃特�??

閃點（測試方法）�? None

易燃限度，在空氣，容�?%
上限: Not Applicable
下限: Not Applicable

自動點燃溫度: Not Applicable

燃燒產品�? �?氧化碳�??

滅火媒介: 大火使用酒精類的水溶成膜泡沫�? 小火使用二氧化碳或乾化學品�??
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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
3 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004

消防說明將人員撤離火源至迎風地點。如果有可能暴露在蒸氣下或有可燃燒的產品存在，應�?
全套消防裝備和NIOSH核准的獨立呼吸裝備�?�氧化化學品在著火的情況下可能會加�?�燃
燒的速度�?

消防環保問題再用儲藏庫設備和其它滅火設備前應完全清除污染�?

6. 意外釋放措施

溢出或洩漏說�? 參見�?8部分有關適當的人員保護設備�?�用土堤或非易燃的吸收劑隔離溢出物，使污�?
保持在最小的範圍內�??
應避免流入下水道及�?�往水道的溝渠�?�若州及地方有規定，應�?�知地方當局。將洩漏
的容器置於�?�風良好處�?? 掃除溢出物�??

Keep unnecessary people away; isolate hazard area and deny entry.

7. 處理與儲�?

處理: 在�?�風足夠的環境下使用。不使用時應將容器關緊�?�避免吸入塵埃�?�避免產生過多塵
埃�?�避免與眼睛、皮膚或衣服接觸。處理後應用肥皂和水徹底洗乾淨�?�沾污的衣服�?
徹底清除污染後才再使用�??

The powder can explode if mixed in air and ignited in a confined space. If
unconfined, ignition will give rise to a Class A fire. Care should be
taken to prevent the accumulation of polyvinyl alcohol dust. PVOH dust is
an explosion hazard. However, the explosive hazard is highly dependent on
particle size; the finer the particles, the higher the explosion strength.

Emptying of bags of powder directly into vessels where flammable vapors
exist should be strictly prohibited because static discharges can be
generated of sufficient strength to produce an explosion.

儲藏: 請勿與不兼容的材料儲存�?�參見�?�第10部分，穩定�?�與反應性�?��??
不使用時，將�?有容器關緊�?�儲存在沒有陽光照射和不可滲透的地板上�??

8. 暴露控制/個人保護

工程控制 �?般或�?釋�?�風作為雇員暴露的唯�?控制方法通常是不足夠的�?��?�常優先選擇的是�?
部�?�風�?

應隨時準備好安全淋浴和洗眼設備�??
個人保護設備
皮膚保護: 穿�?�不過的衣服和手套以便預防接觸�?�建議使用氯丁橡膠�?�視情況，如果有足夠的降
解和滲�?�資料，可使用其它保護材料�?�如果在使用本化學品的同時使用其它化學品�?
選擇的材料應能保護所有使用的化學品�??
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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
4 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004

眼睛/臉部保護: 如有可能接觸眼睛時應戴化學護目鏡�?

呼吸道保�?: 根據工作場所的污染程度及防毒面罩的工作限度，使用經�?�全國職業安全與保健學會
�?(NIOSH)
核准使用的防毒面罩�?�以下是建議職業暴露水平至少應有的裝備�?�參見第3�?8�?11�?
分以便估計職業暴露水平�??
濃度高於職業暴露水平1倍，但低�?10倍﹕使用罩蓋整�?�臉的空氣淨化防毒面罩及有機
蒸氣筒或濾毒罐的HEPA子粒過濾器或裝上有機蒸氣筒HEPA子粒過濾器�?�罩蓋整個臉�?
電動空氣淨化防毒面罩。空氣淨化部件必須有結束服務壽命的顯示器，或必須有一�?
更換時間表的文件。否則使用輸送的空氣�?
濃度高於職業暴露水平10倍，但低於職業暴露水平的100倍或IDLH﹕使用C型罩蓋整�?
臉�?�在壓力要求或不斷輸送空氣的防毒面罩�?
濃度高於職業暴露水平100倍或高於IDLH水平或濃度不�?(例如在緊急情況下)﹕使用罩
蓋整個臉、在正壓�?態下運作的獨立呼吸裝置�?�含輔助正壓獨立呼吸裝置逃生系統的C
型正壓罩蓋整個臉、輸送空氣的防毒面罩�?
逃生﹕使用罩蓋整個臉的獨立呼吸裝置或任何特別准許供�?�生用的防毒面罩�?

暴露指南
重量% ACGIH ACGIH ACGIH OSHA OSHA OSHA Celanese Mexico Mexico Mexico
成分及化學文摘服�? 成分及化 TWA STEL CEILING TWA STEL CEILING WEL TWA STEL CEILING
處號�? 學文摘服 (工作場所
務處號碼接觸限度)
Acetic acid ethenyl 25213-24- 92 - - - - - - - - - -
ester, polymer with 5
ethenol

成分及化學文摘服務處號碼重量% 1990 NIOSH IDLH 1994 NIOSH IDLH
成分及化學文摘服務處 (Recognized by OSHA)
號碼
Acetic acid ethenyl ester, polymer 25213-24-5 92 - -
with ethenol

Comments: ACGIH �? OSHA均未設定暴露準則�?
NIOSH未建立IDLH 水平�?

OSHA Particulate limits: 15 mg/m3 Total Dust; 5 mg/m3 Respirable Fraction.

9. 物理和化學特�?

外貌: White granulated powder

味道: 無味�?

Physical State:: 固體
pH: 4.0 - 7.5 (4% solution)

Vapor Pressure: Not Applicable

Vapor Density (Air=1 @ 20 C): Not Applicable

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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
5 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004
Boiling Point (760 mmHgA): Not Applicable

Melting Point:: 230C - 240C (446F - 464F)

Solubility: Soluble in hot water

Bulk Density:: 0.61 - 0.67 gms/cm^3

Molecular Weight:: Mixture

10. 穩定性與反應�?

穩定�?: 穩定�?

應避免的情況: 避免產生灰塵�?

應避免的材料: Keep away from oxygen, peroxides, perchlorates, nitrates and other
oxidizers. Keep away from reactive metals (sodium, zinc, copper, calcium,
etc.).

危險易燃或分解產�?: 熱分解產品可能含有碳的氧化物�?

危險聚合作用: 不會產生危險的聚合作用�??

11. 毒�?�資�?

Product Toxicological
Information:
Information on this specific product is not available. Information
representative of the major component, polyvinyl alcohol homopolymer (CAS#
25213-24-5), is listed next. Information on other, minor components is
available on request.

Component Toxicological Information

成分及化學文摘服務處號碼 Acetic acid ethenyl ester, polymer with ethenol

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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
6 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004
Acute Exposure:

Oral LD50:>5000 mg/kg (rats); practically nontoxic to animals by
ingestion.

Inhalation LC50:>20.0 mg/l (rats; dust with 3-5 micron particle size; 1
hr. exposure). NOTE: This study is of limited quality since the
concentration reported was nominal (i.e., not measured analytically):
practically nontoxic to animals by acute inhalation exposure.

Skin:In powder form, Polyvinyl Alcohol was nonirritating to rabbit skin.
In aqueous solution, slight irritation to rabbit skin was noted. Not a
skin sensitizer in guinea pigs when dosed as a 10% aqueous solution.
Practically nontoxic to animals (LD50, rabbits: >1,000 mg/kg).

Eye: The powder and aqueous solutions are slightly irritating to rabbit
eyes; irritation subsided by 48 hrs after exposure.

Mutagenicity: Not mutagenic in vitro (Ames Test; Cytogenetic (Chromosomal
Aberration) Assay in Chinese Hamster V-79 Cells)). Not mutagenic in vivo
(mouse micronucleus assay).

Carcinogenicity: The National Toxicology Program (NTP) conducted a two-
year carcinogenicity study of intravaginally administered Polyvinyl
Alcohol (PVOH) in mice. Three groups of 100 female B6C3F1 mice were used:
an untreated control group, a vehicle control group receiving 0.02 ml
deionized water vehicle only and a PVOH group receiving 0.02 ml of 25%
PVOH in deionized water. There were no tumors or non-neoplastic lesions
considered related to treatment with Polyvinyl Alcohol. Other studies
were not designed/conducted according to established scientific
principles. IARC categorized Polyvinyl Alcohol in Group 3, "not
classifiable as to (its) carcinogenicity in humans".

Reproductive/Developmental Effects: No information available.

Repeated Exposure:Female rats dosed dermally at 1000 mg/kg with undiluted
PVOH once daily, 5days/week for 5 weeks showed no adverse effects. Male
rats treated similarly exhibited lower hematocrit and red blood cell
values than controls, but no effects were observed on gross pathological
examination at the end of the study. Other studies were not
designed/conducted according to established scientific principles (e.g.,
no controls) and/or were conducted via routes of exposure not relevant to
the workplace (e.g., injection; implantation). A review of Polyvinyl
Alcohol studies by the Cosmetic Ingredient Review Expert Panel is
available in the published literature (Int. J. Toxicology, 17(Suppl. 5):
67-92 (1998)). The Panel concluded that Polyvinyl Alcohol is safe as used
in cosmetic formulations.

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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
7 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004

12. 生態資料

Product Ecological Information:

Information on this specific product is not available. Information
representative of the major component, polyvinyl alcohol homopolymer (CAS#
25213-24-5), is listed next. Information on other, minor components is
available on request.

Component Ecological Information

成分及化學文摘服務處號碼 Acetic acid ethenyl ester, polymer with ethenol
Ecotoxicity:
Polyvinyl alcohol exhibits low acute toxicity to aquatic species.
Fish (Pimephales promelas) 96-hr. LC50: > 40,000 ppm.
Fish (Lepomis macrochirus) 96-hr. LC50: >10,000 ppm.
Crustacean (Ceriodaphnia dubia) 48-hr. LC50 = 7,850 ppm.
Crustacean (Daphnia magna) 48-hr. LC50 = 8,300 ppm.
Bacteria (Photobacterium phosphoreum), Microtox Method, EC50: >50,000 ppm.

Environmental Fate:

Biodegradation:
Polyvinyl alcohol (PVOH) has been reported to be substantially biodegraded
in several test systems after a lag time for microbial acclimation. For
example, the 5-day and 28-day BODs with unacclimated cultures indicated
essentially no degradation, but the 30-day BOD with a PVOH-acclimated
culture indicated 100% degradation. In another study using a laboratory
complete mixing activated sludge (CMAS) system, >90% of the PVOH present
in the influent could be continuously removed by acclimated organisms.
PVOH was totally degraded in mixed culture activated sludges as determined
by both synthetic and actual domestic wastewater studies in which PVOH was
added to the influent to a small scale multi-stage OASES correlation unit.
Biodegradation was greater than 90% in the Zahn Wellens Test (OECD 302B).

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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
8 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004
13. 丟棄時的注意事項

根據州和當地規定以聯邦非危險定義處理溢出物�?�請注意，此資料僅應用在�?製�?�的材料；加工�?�使用或污染可能
會使本資料不適當、不正確或不完整�?

請注意﹕這一處理與丟棄資料也可能適用於空容器、墊和殘渣�?�州或當地規定或限制非常複雜，�?�且可能異於聯邦
規定。本資料的目的是協助適當的處理與丟棄；處理與丟棄的最後責任由廢料的擁有人負責。參見�?�第9部分，物�?
與化學特性�?��??

14. 運輸資料

US Department of Transportation:
Shipping name: CELVOL POLYVINYL ALCOHOL
Hazard class: Not regulated

ICAO/IATA:
Proper Shipping Name: CELVOL POLYVINYL ALCOHOL
Hazard Classification: Not Regulated.

IMDG:
Proper Shipping Name: CELVOL POLYVINYL ALCOHOL
Hazard Class: Not Regulated.
閃點（測試方法）�? None

Transport Canada

Trade Information
Schedule B Code (export): 3905.30.0000

15. 法規資料
S phrases
S 22 請勿吸入塵埃�?
S 26 若接觸眼睛，應立即使用大量清水沖洗，並尋求治療�??
S 51 只能在�?�風的地�?使用�?

INTERNATIONAL REGULATIONS
化學詳細目錄
列於下列國家的化學詳細目錄的項目符合豁免資格:
AUSTRALIA,.CANADA,EUROPE,KOREA,., JAPAN
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運輸緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
9 of 10
產品名稱: Celvol�?, Polyvinyl alcohol
MSDS 號碼: 465
材料號碼: 80465
公佈日期�? 11/01/2004

16. 其它資料

提供單位: 產品指導�?
Celanese 公司

危險等級本資料僅供經NFPA �?/�? HMIS 系統訓練的人員使用�??

NFPA: Health: 1 Flammability: 1 Reactivity: 0

HMIS: Health: 1 Flammability: 1 Reactivity: 0

下列資料是最新版本MSDS出版後的 The following sections have been revised since the last issue of this
修正: MSDS.

1. 產品與公司識別資�?

此處含有資訊之精確程度為我�?�最大限度之�?知�?�我們並不表示或保證此處�?列之任何危險為僅有之危險。就你所購得之材料之�?
全使用（或與其它物質�?併使用），Celanese
公司不提供任何明確或暗示之保用�?�其它材料可加重本材料的危險性，本材料亦可加重或增加其它材料的危險�?��?�本材料可從直接
或間接由其製成的氣體、液體或固體材料中釋出�?�使用�?�對確定本材料是否適於任何使用及�?計劃的使用方式負完全責任。使用�??
必須符合�?有有關安全及健康標準。材料安全資訊單由Celanese公司在網際網絡上提供，作爲對客戶的一項服務�??
擁有網際網絡的材料安全資訊單並不表示該材料安全資訊單持有人即為有關產品的購買人或用戶�?

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celanese_com---307-70135498.asp	64-19-7
celanese_com---314-08758544.asp	2517-43-3
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celanese_com---351-90435791.asp	N/A
celanese_com---355-51208496.asp	64-19-7
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