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MSDS Material Safety Data Sheet
CAS

61-82-5

File Name: agrippina_bcs_deakin_edu_au---3-amino-124-triazole.asp
                              SIGMA-ALDRICH

Material Safety Data Sheet

Date Printed: 16/JUN/2005
Date Updated: 27/APR/2005
Version 2.1
According to 91/155/EEC

Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.

1 - Product and Company Information

Product Name 3-AMINO-1,2,4-TRIAZOLE
Product Number A8056

Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)

2 - Composition/Information on Ingredients

Product Name CAS # EC no Annex I
Index Number
3-AMINO-1,2,4-TRIAZOLE 61-82-5 200-521-5 613-011-00-6

Formula C2H4N4
Molecular Weight 84.08 AMU
Synonyms Aminotriazole (plant regulator) *
3-Aminotriazole * 3-Amino-s-triazole *
3-Amino-1,2,4-triazole *
3-Amino-1H-1,2,4-triazole *
3-Amino-1,2,4-triazole (ACGIH) * Amino triazole
weedkiller 90 * Aminotriazol-spritzpulver *
Amitol * Amitrol * Amitrol 90 * Amitrole (ACGIH)
* Amitrol-T * Amizol * AT * ATA * 3,A-T *
Campaprim A 1544 * Cytrol * Cytrole * Diurol *
Diurol 5030 * Elmasil * Emisol * Emisol 50 *
Emisol F * ENT 25445 * Herbidal total *
Herbizole * Kleer-lot * Orga-414 * Radoxone TL *
Ramizol * RCRA waste number U011 * Simazol *
Solution concentree T271 * Triazolamine *
1H-1,2,4-Triazol-3-amine * USAF XR-22 * Vorox *
Vorox AA * Vorox AS * Weedar ADS * Weedar AT *
Weedazin * Weedazin arginit * Weedazol * Weedex
granulat * X-All liquid

3 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful: danger of serious damage to health by prolonged exposure
if swallowed. Possible risk of harm to the unborn child. Toxic to
aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Repr. Cat.3
4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.

AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.

AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.

AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.

SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves. Wear disposable coveralls and discard them after
use.

METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.

STORAGE
Conditions of Storage: Keep tightly closed.
Store at -20掳C

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.


SIGMA - A8056 www.sigma-aldrich.com Page 2
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.

EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 0.2 mg/m3
Remarks: K

EXPOSURE LIMITS - GERMANY
Source Type Value
TRGS 900 OEL 0.2 mg/m3, E

EXPOSURE LIMITS - SWITZERLAND
Source Type Value
OEL OEL 0.2 mg/m3
Remarks: E

PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

Appearance Physical State: Solid

Property Value At Temperature or Pressure

pH N/A
BP/BP Range N/A
MP/MP Range 150 - 153 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents, Strong acids, Copper
Iron and iron salts.



SIGMA - A8056 www.sigma-aldrich.com Page 3
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides.

HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

RTECS NUMBER: XZ3850000

ACUTE TOXICITY
LD50
Oral
Rat
25,000 mg/kg
LD50
Oral
Rat
> 2,000 mg/kg
LD50
Oral
Mouse
> 5,000 mg/kg
LC50
Inhalation
Rat
> 400 mg/m3
4H

LD50
Oral
Rat
1100 mg/kg

LD50
Skin
Rat
> 10000 mg/kg

LD50
Oral
Mouse
14700 mg/kg

LD50
Intraperitoneal
Mouse
200 MG/KG

LD50
Intravenous
Mouse
>5 GM/KG

LD50
Oral
Quail
> 316 mg/kg

IRRITATION DATA
Eyes


SIGMA - A8056 www.sigma-aldrich.com Page 4
Rabbit
Remarks: Mild irritation effect
Skin
Rabbit
Remarks: Mild irritation effect

ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.

TARGET ORGAN INFORMATION
Thyroid. Liver. Kidneys.

CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that has been
reported to be possibly carcinogenic based on its IARC, ACGIH,
NTP, or EPA classification.

Rat
Route of Application: Oral
Exposure Time: 2.5Y
Result: Tumorigenic:Carcinogenic by RTECS criteria.
Endocrine:Tumors. Endocrine:Thyroid tumors.

Mouse
Route of Application: Oral
Exposure Time: 3W
Result: Tumorigenic:Carcinogenic by RTECS criteria. Liver:Tumors.

Rat
Route of Application: Oral
Exposure Time: 2Y
Result: Tumorigenic:Neoplastic by RTECS criteria.
Endocrine:Thyroid tumors.

Rat
Route of Application: Oral
Exposure Time: 70W
Result: Tumorigenic:Carcinogenic by RTECS criteria.
Endocrine:Thyroid tumors.

Rat
Route of Application: Oral
Exposure Time: 60W
Result: Tumorigenic:Carcinogenic by RTECS criteria.
Endocrine:Thyroid tumors.

Mouse
Route of Application: Oral
Exposure Time: 26W
Result: Tumorigenic:Equivocal tumorigenic agent by RTECS
criteria. Liver:Tumors.

IARC CARCINOGEN LIST

Rating: Group 2B

CHRONIC EXPOSURE - MUTAGEN


SIGMA - A8056 www.sigma-aldrich.com Page 5
Result: Laboratory experiments have shown mutagenic effects.

Human
100 MMOL/L
Cell Type: fibroblast
DNA inhibition

Rat
80 MG/L
Cell Type: Embryo
Morphological transformation.

Mouse
125 MG/L
Cell Type: Embryo
Morphological transformation.

Mouse
12 MG/KG
Cell Type: S. typhimurium
Host-mediated assay

Hamster
10 MG/L
Cell Type: Embryo
Morphological transformation.

Hamster
250 MG/L
Cell Type: kidney
Morphological transformation.

Hamster
1 MG/L
Cell Type: Embryo
Mutation in mammalian somatic cells.

CHRONIC EXPOSURE - TERATOGEN
Result: Laboratory experiments have shown teratogenic effects.

Species: Rat
Dose: 700 UG/KG
Route of Application: Oral
Exposure Time: (22D PREG)
Result: Specific Developmental Abnormalities: Endocrine system.

Species: Mouse
Dose: 2600 MG/KG
Route of Application: Oral
Exposure Time: (6-18D PREG)
Result: Effects on Embryo or Fetus: Fetotoxicity (except death,
e.g., stunted fetus).

Species: Mouse
Dose: 1935 MG/KG
Route of Application: Oral
Exposure Time: (6-14D PREG)
Result: Effects on Embryo or Fetus: Fetotoxicity (except death,
e.g., stunted fetus). Effects on Embryo or Fetus: Fetal death.

CHRONIC EXPOSURE - REPRODUCTIVE HAZARD



SIGMA - A8056 www.sigma-aldrich.com Page 6
Species: Mouse
Dose: 4176 MG/KG
Route of Application: Subcutaneous
Exposure Time: (6-14D PREG)
Result: Effects on Fertility: Litter size (e.g.; # fetuses per
litter; measured before birth). Effects on Embryo or Fetus:
Fetotoxicity (except death, e.g., stunted fetus). Effects on
Embryo or Fetus: Fetal death.
CMR CAT.: Carc. Cat.3

12 - Ecological Information

N/A

ECOTOXICOLOGICAL EFFECTS
Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 48 h
Value: 30 mg/l

Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 16 - 21 h

Test Type: EC50 Algae
Species: Scenedesmus subspicatus
Time: 96 h
Value: 11.4 mg/l

Test Type: LC50 Fish
Species: Onchorhynchus mykiss (Rainbow trout)
Time: 48 h
Value: 325 mg/l

Test Type: LC50 Fish
Species: Pimephales promelas (Fathead minnow)
Time: 96 h
Value: > 100 mg/l

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous
substance, solid, n.o.s

IMDG
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous


SIGMA - A8056 www.sigma-aldrich.com Page 7
substance, solid, n.o.s
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required

IATA
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous
substance, solid, n.o.s
Inhalation Packing Group I: No
Technical Name: Required

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 613-011-00-6
INDICATION OF DANGER: Xn N
Harmful. Dangerous for the environment.
R-PHRASES: 48/22 63 51/53
Harmful: danger of serious damage to health by prolonged
exposure if swallowed. Possible risk of harm to the unborn
child. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
S-PHRASES: 13 36/37 61
Keep away from food, drink, and animal feedingstuffs. Wear
suitable protective clothing and gloves. Avoid release to the
environment. Refer to special instructions/safety data sheets.

COUNTRY SPECIFIC INFORMATION

Germany
WGK: 2

SWITZERLAND
SWISS POISON CLASS: 1

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

DISCLAIMER
For R&D use only. Not for drug, household or other uses.




SIGMA - A8056 www.sigma-aldrich.com Page 8

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