MATERIAL SAFETY DATA SHEET
PRODUCT NAME: TINOFIX ECO
MSDS CODE : C0923660D9
VERSION : 3
UPDATED : December 2001
Not classified as hazardous according to criteria of NOHSC Australia
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn:
CHEMICAL SAFETY OFFICER
or
EMERGENCY RESPONSE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: TINOFIX ECO
Other name(s)..: AQUEOUS SOLUTION BASED ON POLYETHYLENE POLYAMINE
Correct Shipping name: ENVIRONMENTALLY HAZARDOUS LIQUID, N.O.S
UN Number . . . . . : 3082
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (IATA ONLY) group . . : III
HAZCHEM Code . . . . : CONTAIN SPILL
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE CHEMICAL
which are processed below 200 deg. C.
Refer to Technical Data Sheet.
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Appearance. . . . . . : YELLOW LIQUID WITH A CHARACTERISTIC ODOUR.
Boiling/Melting point : ca. 100 (deg.C)
Vapour pressure . . . : NOT AVAILABLE
Density . . . . . . . : NOT AVAILABLE
Flash Point . . . . . : NOT AVAILABLE
Flammability Limits . : not applicable
Solubility in water . : MISCIBLE (g/L @ 20 deg.C)
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Chemical Entity CAS No. Proportion
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral,Rat LD50) > 2000 mg/kg
Eye . . . : NON-IRRITANT, OECD 405 RABBIT - SEE "HEALTH
EFFECTS - CHRONIC" BELOW.
Skin . . : NON-IRRITANT, OECD 404 RABBIT - SEE "HEALTH
EFFECTS - CHRONIC" BELOW.
Inhaled . : NOT YET AVAILABLE - SEE "HEALTH EFFECTS - CHRONIC"
BELOW.
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THIS PRODUCT CONTAINS ACETIC ACID, WHICH IS A SKIN AND EYE IRRITANT,
AND CAN CAUSE BURNS IN CONCENTRATED FORM, GASTRO-INTESTINAL IRRITATION
AND MODERATE HEALTH EFFECTS BY INHALATION OF VAPOURS AND INGESTION.
AVOID INHALATION OF VAPOURS AND DIRECT CONTACT.
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Swallowed : WASH OUT MOUTH WITH WATER, DRINK PLENTY OF WATER.
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES. SEEK MEDICAL ADVICE.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING. SEEK
MEDICAL ADVICE.
Inhaled . : REMOVE PATIENT TO FRESH AIR, REST. SEEK MEDICAL
ATTENTION IF YOU FEEL UNWELL OR IF EXPOSURE
PROLONGED.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE EXPOSURE LIMITS ARE MET. STATE REGULATIONS ON SPEED
AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND GOGGLES ARE RECOMMENDED
TO BE WORN WITH THIS PRODUCT.
WHERE SUFFICIENT VENTILATION IS NOT AVAILABLE, AVOID BREATHING
AEROSOLS OR VAPOURS BY WEARING THE FOLLOWING AS1716 APPROVED
RESPIRATORY PROTECTION: HALF FACE RESPIRATOR WITH CLASS A2 ORGANIC
VAPOUR CARTRIDGE.
Where sufficient ventilation is not available, avoid breathing dust by
wearing the following AS 1716 approved respiratory protection:
Half facepiece particulate filter respirator - Class P2 or P3. When
positive local ventilation is in operation, a particulate filter Class
P1 (Dust Mask) is required.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION. KEEP CONTAINERS CLOSED.
UN Number . . . . . : 3082
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (IATA ONLY) group . . : III
HAZCHEM Code . . . . : CONTAIN SPILL
IATA Class . . . . . : 9 11C
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: CONTAIN SPILL
STACK CAREFULLY. USE FRACTURE-PROOF CONTAINER LABELLED ACCORDING TO
THE REGULATIONS OR TAKE THE ORIGINAL PACKAGING.
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE -
CONTAIN FIRST, SOAK UP ALL RESIDUES IN INERT ABSORBANCE MATERIAL (i.e.
VERMICULITE, SAND).PLACE INTO MARKED CONTAINERS FOR DISPOSAL AS
CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH
TEMPERATURE INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY
CONTAINERS MUST BE DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT,
CONTACT CIBA SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
THERMAL DECOMPOSITION OR BURNING MAY RELEASE OXIDES OF CARBON AND
NITROGEN. IN CASE OF FIRE, SELF-CONTAINED BREATHING APPARATUS MUST BE
WORN.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 10 mg02/g
COD . . . . . . . . . . . . : 255 mg02/g
TOC . . . . . . . . . . . . : 14.7 %
Fish toxicity . . . . . . . : SPECIES : ZEBRA FISH
LC50 : 2 mg/l, 96 hrs
DAPHNIA TOXICITY:
LC50 : 4 mg/l, 48 hrs (OECD 202)
Toxicity to Bacteria . . . : IC50 : > 100 mg/l, 3hrs
OECD Biological degredation : > 70 %, OECD 303B/ISO 9888/EEC 88/302C
Heavy-metal content . . . . : 1.5 % ZINC
BIOELIMINATION SUMMARY: ELIMINATED BY ADSORPTION ON EFFLUENT TREATMENT
SLUDGE. NITROGEN CONTENT: ca. 10 %.
TESTED MATERIAL: STANDISED PRODUCT.
TOXIC TO AQUATIC LIFE, PREVENT DISCHARGE TO NATURAL WATERWAYS AND
SEWER. CONTAIN ANY RESIDUES AND DISPOSE AS SHOWN ABOVE. DO NOT RELEASE
CHEMICALLY CONTAINATED WATER INTO DRAINS OR SOIL. SUFFICIENT MEASURES
MUST BE TAKEN TO RETAIN THE WATER FOR EXTINGUISHING. DISPOSE OF
CONTAMINATED WATER AND SOIL ACCORDING TO LOCAL REGULATIONS.
"THE CLASS 9 CLASSIFICATION OF THIS PRODUCT APPLIES IN THE EC AND
REFERENCE SHOULD BE MADE TO THE LATEST ISSUE OF THE 'ARTDG' (OR
RELEVANT DG CODE) FOR LOCAL CLASSIFICATION FOR ROAD, RAIL, AND SEA
TRANSPORT. IF IN DOUBT, CONTACT CIBA SPECIALTY CHEMICALS".
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EEC classification/labelling: ** NOT CLASSIFIED AS HAZARDOUS **
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: DEANGGU1 Date: 14 December 01
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