SIGMA-ALDRICH



                         Material Safety Data Sheet



                                                 Date Printed: 02/JUN/2005

                                                 Date Updated: 12/MAR/2004

                                                               Version 1.1

                                                   According to 91/155/EEC



Classified as Hazardous according to the criteria of EU Annex 1 and

NOHSC.



1 - Product and Company Information



Product Name                     TITANIUM(III) FLUORIDE

Product Number                   399817



Company                          Sigma-Aldrich Pty, Ltd

                                 Unit 2, 14 Anella Avenue

                                 Castle Hill NSW 1765

                                 Australia

Technical Phone #                +61 2 9841 0555

Fax                              +61 2 9841 0500

Emergency Phone #                +61 2 9841 0566



2 - Composition/Information on Ingredients



Product Name                           CAS #        EC no       Annex I

                                                                Index Number

TITANIUM TRIFLUORIDE                   13470-08-1   236-732-4   None



Formula             TiF3

Molecular Weight    104.9 AMU



3 - Hazards Identification



SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT

   Reacts violently with water. Contact with acids liberates very

   toxic gas. Causes burns.





4 - First Aid Measures



AFTER INHALATION

   If inhaled, remove to fresh air. If not breathing give

   artificial respiration. If breathing is difficult, give oxygen.



AFTER SKIN CONTACT

   In case of contact, immediately wash skin with soap and copious

   amounts of water.



AFTER EYE CONTACT

   In case of contact, immediately flush eyes with copious amounts

   of water for at least 15 minutes.



AFTER INGESTION

   If swallowed, wash out mouth with water provided person is

   conscious. Call a physician.



5 - Fire Fighting Measures



EXTINGUISHING MEDIA

   Suitable: Use approved class D extinguishers or smother with dry

   sand, dry ground limestone, or dry clay.

   Unsuitable: Do not use water.



SPECIAL RISKS

   Specific Hazard(s): Emits toxic fumes under fire conditions.



SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS

   Wear self-contained breathing apparatus and protective clothing

   to prevent contact with skin and eyes.



6 - Accidental Release Measures



PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL

   Evacuate area.



PROCEDURE(S) OF PERSONAL PRECAUTION(S)

   Wear self-contained breathing apparatus, rubber boots, and heavy

   rubber gloves.



METHODS FOR CLEANING UP

   Cover with dry-lime, sand, or soda ash. Place in covered

   containers using non-sparking tools and transport outdoors.

   Ventilate area and wash spill site after material pickup is

   complete.



7 - Handling and Storage



HANDLING

   Directions for Safe Handling: Avoid inhalation. Do not get in

   eyes, on skin, on clothing. Avoid prolonged or repeated exposure.



STORAGE

   Conditions of Storage: Keep tightly closed. Store in a cool dry

   place. Handle and store under nitrogen.

   Incompatible Materials: Do not allow contact with water Avoid

   contact with acid.



8 - Exposure Controls / Personal Protection



ENGINEERING CONTROLS

   Use only in a chemical fume hood. Safety shower and eye bath.



GENERAL HYGIENE MEASURES

   Wash thoroughly after handling. Wash contaminated clothing before

   reuse.



PERSONAL PROTECTIVE EQUIPMENT

   Special Protective Measures: Wear appropriate government approved

   respirator, chemical-resistant gloves, safety goggles, other

   protective clothing. Faceshield (8-inch minimum).



9 - Physical and Chemical Properties



Appearance              Color: Light brown

                        Form: Powder



Property                Value                 At Temperature or Pressure



pH                      N/A

BP/BP Range             N/A

MP/MP Range             N/A





ALDRICH - 399817                www.sigma-aldrich.com          Page    2

Flash Point             N/A

Flammability            N/A

Autoignition Temp       N/A

Oxidizing Properties    N/A

Explosive Properties    N/A

Explosion Limits        N/A

Vapor Pressure          N/A

SG/Density              3.4 g/cm3

Partition Coefficient   N/A

Viscosity               N/A

Vapor Density           N/A

Saturated Vapor Conc.   N/A

Evaporation Rate        N/A

Bulk Density            N/A

Decomposition Temp.     N/A

Solvent Content         N/A

Water Content           N/A

Surface Tension         N/A

Conductivity            N/A

Miscellaneous Data      N/A

Solubility              N/A



10 - Stability and Reactivity



STABILITY

   Reactions to Avoid: Reacts violently with:

   Conditions to Avoid: Heat.

   Materials to Avoid: Water, Strong oxidizing agents, Acids.



HAZARDOUS DECOMPOSITION PRODUCTS

   Hazardous Decomposition Products: Hydrogen fluoride,

   Titanium/titanium oxides.



11 - Toxicological Information



SIGNS AND SYMPTOMS OF EXPOSURE

   Material is extremely destructive to tissue of the mucous

   membranes and upper respiratory tract, eyes, and skin.

   Inhalation may result in spasm, inflammation and edema of the

   larynxand bronchi, chemical pneumonitis, and pulmonary edema.

   Symptoms of exposure may include burning sensation, coughing,

   wheezing, laryngitis, shortness of breath, headache, nausea, and

   vomiting. Symptoms of fluoride overexposure may include

   salivation, nausea, vomiting, abdominal pain, fever, and labored

   breathing. Fluoride ion can reduce serum calcium levels possibly

   causing fatal hypocalcemia. Prolonged exposure to fluoride

   dusts, vapors, or mists results in perforation of the nasal

   septum. Chronic effects include excessive calcification of the

   bones, ligaments, and tendons. To the best of our knowledge, the

   chemical, physical, and toxicological properties have not been

   thoroughly investigated.



ROUTE OF EXPOSURE

   Multiple Routes: Harmful if swallowed, inhaled, or absorbed

   through skin.



TARGET ORGAN INFORMATION

   Kidneys. Liver. Lungs. Bones.



12 - Ecological Information



No data available.





ALDRICH - 399817                 www.sigma-aldrich.com          Page   3

13 - Disposal Considerations



SUBSTANCE DISPOSAL

   Contact a licensed professional waste disposal service to dispose

   of this material. Observe all federal, state, and local

   environmental regulations.



14 - Transport Information



RID/ADR

   UN#: 3260

   Class: 8

   PG: II

   Proper Shipping Name: Corrosive solid, acidic,

   inorganic, n.o.s.



IMDG

   UN#: 3260

   Class: 8

   PG: II

   Proper Shipping Name: CORROSIVE SOLID, ACIDIC,

   INORGANIC, N.O.S.

   Marine Pollutant: No

   Severe Marine Pollutant: No

   Technical Name: Required



IATA

   UN#: 3260

   Class: 8

   PG: II

   Proper Shipping Name: Corrosive solid, acidic,

   inorganic, n.o.s.

   Inhalation Packing Group I: No

   Technical Name: Required



15 - Regulatory Information



CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES

   INDICATION OF DANGER: C

     Corrosive.

   R-PHRASES: 14 32 34

     Reacts violently with water. Contact with acids liberates very

     toxic gas. Causes burns.

   S-PHRASES: 26 36/37/39 45

     In case of contact with eyes, rinse immediately with plenty of

     water and seek medical advice. Wear suitable protective

     clothing, gloves, and eye/face protection. In case of accident

     or if you feel unwell, seek medical advice immediately (show

     the label where possible).



16 - Other Information



WARRANTY

   The above information is believed to be correct but does not

   purport to be all inclusive and shall be used only as a guide. The

   information in this document is based on the present state of our

   knowledge and is applicable to the product with regard to

   appropriate safety precautions. It does not represent any

   guarantee of the properties of the product. Sigma-Aldrich Inc.,

   shall not be held liable for any damage resulting from handling or

   from contact with the above product. See reverse side of invoice





ALDRICH - 399817               www.sigma-aldrich.com         Page      4

   or packing slip for additional terms and conditions of sale.

   Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited

   paper copies for internal use only.



DISCLAIMER

   For R&D use only. Not for drug, household or other uses.









ALDRICH - 399817               www.sigma-aldrich.com          Page   5